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RESEARCH PAPER · Angewandte Chemie International Edition · 2019

Hybrid Metal Halides with Multiple Photoluminescence Centers

Mingze Li, Jun Zhou, Guojun Zhou, Мaxim S. Моlokeev, Jing Wei Zhao, Viktoriia Morad, Maksym V. Kovalenko, Zhiguo Xia

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Hybrid Metal Halides with Multiple Photoluminescence CentersOriginalNew strategy of designing a novel yellow-emitting phosphor Na4Hf2Si3O12:Eu2+ for multifunctional applications21Breaking Forbidden Transitions for Emission of Self-Trapped Excitons in Two Dimensional (F2CHCH2NH3)2CdBr4 Perovskite through Pb Alloying66Smart and efficient opto-electronic dual response material based on two-dimensional perovskite crystal/thin film22A moisture-stable organosulfonate-based metal–organic framework with intrinsic self-trapped white-light emission14A three-dimensional cuprous lead bromide framework with highly efficient and stable thermochromic luminescence properties27Broadband yellow light emitting performance based on zero-dimensional hybrid lead bromide trimers3Crystallization of Ionically Bonded Organic Metal Halide Hybrids4Efficient, broadband self-trapped white-light emission from haloplumbate-based metal–organic frameworks14New lead bromide chiral perovskites with ultra-broadband white-light emission68Optically pumped white light-emitting diodes based on metal halide perovskites and perovskite-related materials46Tetrameric cluster assembled one-dimensional hybrid lead halides with broadband light emission3Tunable photoluminescence in Sb 3+ -doped zero-dimensional hybrid metal halides with intrinsic and extrinsic self-trapped excitons67Synthesis, Structure, and Characterization of Variable Chains in a Series of Transition Metal Coordination Compounds6Lead-Free Tin(IV)-Based Organic–Inorganic Metal Halide Hybrids with Excellent Stability and Blue-Broadband Emission137Optical Functional Units in Zero‐Dimensional Metal Halides as a Paradigm of Tunable Photoluminescence and Multicomponent Chromophores64Bulk Assembly of Multicomponent Zero-Dimensional Metal Halides with Dual Emission94Stable Yellow Light-Emitting Devices Based on Ternary Copper Halides with Broadband Emissive Self-Trapped Excitons318Broad-band emission in metal halide perovskites: Mechanism, materials, and applications288Molecular Intercalation and Electronic Two Dimensionality in Layered Hybrid Perovskites84Molecular Intercalation and Electronic Two Dimensionality in Layered Hybrid Perovskites12Incorporating Rare‐Earth Terbium(III) Ions into Cs2AgInCl6:Bi Nanocrystals toward Tunable Photoluminescence335Incorporating Rare‐Earth Terbium(III) Ions into Cs2AgInCl6:Bi Nanocrystals toward Tunable Photoluminescence14Targeted Synthesis of Trimeric Organic–Bromoplumbate Hybrids That Display Intrinsic, Highly Stokes-Shifted, Broadband Emission29Multicomponent Organic Metal Halide Hybrid with White Emissions140Multicomponent Organic Metal Halide Hybrid with White Emissions12Halogen Substitution in Zero‐Dimensional Mixed Metal Halides toward Photoluminescence Modulation and Enhanced Quantum Yield50The Rb7Bi3−3xSb3xCl16 Family: A Fully Inorganic Solid Solution with Room‐Temperature Luminescent Members87The Rb7Bi3−3xSb3xCl16 Family: A Fully Inorganic Solid Solution with Room‐Temperature Luminescent Members18All-Inorganic Lead-Free Heterometallic Cs4MnBi2Cl12 Perovskite Single Crystal with Highly Efficient Orange Emission210Enhancing Photoluminescence Quantum Yield in 0D Metal Halides by Introducing Water Molecules159Synthesis, Crystal Structure and Green Luminescence in Zero-Dimensional Tin Halide (C8H14N2)2SnBr6110Organic solvent-free lyophilization assisted recrystallization synthesis of high-purity green emissive Cs3MnX5 (X = I, Br)36Narrow-band emitters in LED backlights for liquid-crystal displays217Design Principles for Enhancing Photoluminescence Quantum Yield in Hybrid Manganese Bromides419Lead-free violet-emitting K2CuCl3 single crystal with high photoluminescence quantum yield41High Photoluminescence Quantum Yield (>95%) of MAPbBr3 Nanocrystals via Reprecipitation from Methylamine-MAPbBr3 Liquid41Phosphorescent Manganese(II) Complexes and Their Emerging Applications155Metal Halide Regulated Photophysical Tuning of Zero‐Dimensional Organic Metal Halide Hybrids: From Efficient Phosphorescence to Ultralong Afterglow206Metal Halide Regulated Photophysical Tuning of Zero‐Dimensional Organic Metal Halide Hybrids: From Efficient Phosphorescence to Ultralong Afterglow39Wide range zero-thermal-quenching ultralong phosphorescence from zero-dimensional metal halide hybrids289Pressure‐Engineered Photoluminescence Tuning in Zero‐Dimensional Lead Bromide Trimer Clusters104Pressure‐Engineered Photoluminescence Tuning in Zero‐Dimensional Lead Bromide Trimer Clusters21Lead chlorine cluster assembled one-dimensional halide with highly efficient broadband white-light emission27Recent Advances in Luminescent Zero‐Dimensional Organic Metal Halide Hybrids241A Guanidinium-Based Mn4+-Doped Red-Emitting Hybrid Phosphor with High Stability35Manipulation of Cl/Br transmutation in zero-dimensional Mn 2+ -based metal halides toward tunable photoluminescence and thermal quenching behaviors87Co-luminescence in a zero-dimensional organic–inorganic hybrid antimony halide with multiple coordination units67Enhancement of the photoluminescence efficiency of hybrid manganese halides through rational structural design94Recent advances in persistent luminescence based on molecular hybrid materials564Recent progress of zero-dimensional luminescent metal halides873Room-temperature synthesis of blue-emissive zero-dimensional cesium indium halide quantum dots for temperature-stable down-conversion white light-emitting diodes with a half-lifetime of 186 h45Combining Dual-Light Emissions to Achieve Efficient Broadband Yellowish-Green Luminescence in One-Dimensional Hybrid Lead Halides29Hybrid 0D Antimony Halides as Air‐Stable Luminophores for High‐Spatial‐Resolution Remote Thermography150Learning from Mineral Structures toward New Luminescence Materials for Light-Emitting Diode Applications146Photoluminescence of Singlet/Triplet Self‐Trapped Excitons in Sb3+‐Based Metal Halides293Regulation of structures and optical properties inlow-dimensional metal halides: Chemical synthesisand physical high-pressure0Tunable White Light Emission in a Zero‐Dimensional Organic–Inorganic Metal Halide Hybrid with Ultra‐High Color Rendering Index61Light‐Emitting Metal–Organic Halide 1D and 2D Structures: Near‐Unity Quantum Efficiency, Low‐Loss Optical Waveguide and Highly Polarized Emission74Light‐Emitting Metal–Organic Halide 1D and 2D Structures: Near‐Unity Quantum Efficiency, Low‐Loss Optical Waveguide and Highly Polarized Emission14Luminescence Change from Orange to Blue for Zero‐Dimensional Cs2InCl5(H2O) Metal Halides in Water and a New Post‐doping Method24An Overview for Zero‐Dimensional Broadband Emissive Metal‐Halide Single Crystals269Ultra-Broad-Band-Excitable Cu(I)-Based Organometallic Halide with Near-Unity Emission for Light-Emitting Diode Applications168Introducing Intermolecular Cation‐π Interactions for Water‐Stable Low Dimensional Hybrid Lead Halide Perovskites136Introducing Intermolecular Cation‐π Interactions for Water‐Stable Low Dimensional Hybrid Lead Halide Perovskites7Indium-antimony-halide single crystals for high-efficiency white-light emission and anti-counterfeiting252Metal Halide Scaffolded Assemblies of Organic Molecules with Enhanced Emission and Room Temperature Phosphorescence42Bulk Assembly of Zero-Dimensional Organic Copper Bromide Hybrid with Bright Self-Trapped Exciton Emission and High Antiwater Stability66Low Dimensional, Broadband, Luminescent Organic‐Inorganic Hybrid Materials for Lighting Applications57Photoluminescent ionic metal halides based on s2 typed ions and aprotic ionic liquid cations87White up-conversion luminescence properties in Yb3+/Ho3+/Tm3+ tri-doped LiGaW2O8 phosphors9Enhanced Photoluminescence of All-Inorganic Manganese Halide Perovskite-Analogue Nanocrystals by Lead Ion Incorporation27Multiexcitonic Emission in Zero-Dimensional Cs2ZrCl6:Sb3+ Perovskite Crystals275Te4+-doped Cs2InCl5·H2O single crystals for remote optical thermometry88Connecting morphology and photoluminescence emissions in β-Ag2MoO4 microcrystals20Recent Advances in All‐Inorganic Zero‐Dimensional Metal Halides28Synergistic electronic coupling/cross-talk between the isolated metal halide units of zero dimensional heterometallic (Sb, Mn) halide hybrid with enhanced emission18Unveiling White Light Emission of a One-Dimensional Cu(I)-Based Organometallic Halide toward Single-Phase Light-Emitting Diode Applications39Highly emissive zero-dimensional antimony halide for anti-counterfeiting and confidential information encryption-decryption164Magnetic polaronic and bipolaronic excitons in Mn(II) doped (TDMP)PbBr4 and their high emission55Lead-free broadband orange-emitting zero-dimensional Sb3+-doped indium-based organic–inorganic metal halides16Lowering the dimensionality of cationic lead bromide units in robust coordination polymers for enhanced self-trapped broadband emission12Triplet–triplet energy transfer from Bi 3+ to Sb 3+ in zero-dimensional indium hybrids via a B-site co-doping strategy toward white-light emission34Mesoporous Trap of Molecular Sieves via Water-Selective Capture for Stable Perovskite Quantum Dots14Ternary zero-dimensional hybrid metal halides with dual emission10Thermoinduced structural-transformation and luminescent conversion in hybrid manganese halides9Emission‐Color‐Tunable Pb−Sn Alloyed Single Crystals with High Luminescent Efficiency and Stability27Crystal rigidifying strategy toward hybrid cadmium halide to achieve highly efficient and narrowband blue light emission18Excitation‐Dependent Emission in All‐Inorganic Lead‐Free Cs2ScCl5·H2O Perovskite Crystals50Shining Mn 4+ in 0D Organometallic Fluoride Hosts towards Highly Efficient Photoluminescence45Methanol-induced luminescence vapochromism based on a Sb3+-doped organic indium halide hybrid55Structural Evolution and Photoluminescence Properties of Two‐dimensional Lead Halide Perovskites4Integrated Afterglow and Self‐Trapped Exciton Emissions in Hybrid Metal Halides for Anti‐Counterfeiting Applications201Zero‐Dimensional Luminescent Metal Halide Hybrids Enabling Bulk Transparent Medium as Large‐Area X‐Ray Scintillators201Tailoring Photophysical Dynamics in a Hybrid Gallium–Bismuth Heterometallic Halide by Transferring from an Indirect to a Direct Band Structure12Controlled Modulation of the Structure and Luminescence Properties of Zero-Dimensional Manganese Halide Hybrids through Structure-Directing Metal-Ion (Cd 2+ and Zn 2+ ) Centers29Self‐Trapped Exciton Emission with High Thermal Stability in Antimony‐Doped Hybrid Manganese Chloride84Zero‐Dimensional Organic Copper(I) Iodide Hybrid with High Anti‐Water Stability for Blue‐Light‐Excitable Solid‐State Lighting114High-efficient yellow-green emission in (TDMP)MnBr4 single crystal with modulation of spin-phonon-charge interactions53Enantiomorphic Single Crystals of Linear Lead(II) Bromide Perovskitoids with White Circularly Polarized Emission64Enantiomorphic Single Crystals of Linear Lead(II) Bromide Perovskitoids with White Circularly Polarized Emission9Opportunities and challenges of low-dimensional hybrid metal halides in white light-emitting diodes25Lanthanide-doped Mn2+-based perovskite-like single crystals: Switching on highly thermal-stable near-infrared emission and LED device61Organo-Metal Halide Scintillator with Weak Thermal Quenching Up to 200 °C46Highly Distorted Antimony(III) Chloride [Sb 2 Cl 8 ] 2− Dimers for Near‐Infrared Luminescence up to 1070 nm160Highly Distorted Antimony(III) Chloride [Sb2Cl8]2− Dimers for Near‐Infrared Luminescence up to 1070 nm25Tunable Luminescence of Sb3+ Doped 0D Cs4PbCl6 Nanocrystals from Three Distinct Emission Centers46Zero-Dimensional (Piperidinium)2MnBr4: Ring Puckering-Induced Isostructural Transition and Strong Electron–Phonon Coupling-Mediated Self-Trapped Exciton Emission24New Lead-free Organic–Inorganic Hybrid Semiconductor Single Crystals for a UV–Vis–NIR Broadband Photodetector17Tunable emission color of [(2-mb)tpp]2Cd1-xMnxCl4 (x = 0–1) solid solutions synthesized via mechanochemical method for anti-counterfeit luminescent paper and WLEDs29Excitation-Dependent Luminescence of 0D ((CH3)4N)2ZrCl6 across the Full Visible Region30Molecular dimensionality and photoluminescence of hybrid metal halides92Glass-compatible and self-powered temperature alarm system by temperature-responsive organic manganese halides via backward energy transfer process16Ultrasensitive Optical Thermometry via Inhibiting the Energy Transfer in Zero-Dimensional Lead-Free Metal Halide Single Crystals28Noncrystalline Hybrid Lead Halides with Liquid-Polymer Characteristics5Libra: A modular software library for quantum nonadiabatic dynamics42Factors influencing self-trapped exciton emission of low-dimensional metal halides115Multicolor light emission in manganese-based metal halide composites26Recent Advances on Mn2+‐Doping in Diverse Metal Halide Perovskites66Dynamically tunable multicolor emissions from zero-dimensional Cs 3 LnCl 6 (Ln: europium and terbium) nanocrystals with wide color gamut23Recent advances in room temperature phosphorescence materials: design strategies, internal mechanisms and intelligent optical applications39Enhancing photoluminescence of manganese chloride perovskite-analogues through phase transformations induced by Sn incorporation5Self-Trapped Excitons Mediated Energy Transfer to Sm3+ in Cs2AgIn(1–x)SmxCl6:Bi Double Perovskite Nanocrystals28A room-temperature nitrite-based hybrid bimetal molecular ferroelectric material: [( R )-3-quinuclidinol] 2 [LiCo(NO 2 ) 6 ]5Birefringence and polarized luminescence of a manganese( ii ) chloride–triphenylphosphine oxide compound: application in LEDs and photolithography13In situ recrystallization of zero-dimensional hybrid metal halide glass-ceramics toward improved scintillation performance81Regulating the coordination geometry of polyhedra in zero-dimensional metal halides for tunable emission15Zero-dimensional indium hybrids and modulated photoluminescence by Sb doping34Broadband White‐Light‐Emitting Electrochemical Cells5Green Synthesis of Ce Doped Cs3MnBr5 for Highly Stable Violet Light Emitting Diodes11Exploration of new chiral hybrid semiconducting palladium halide complexes: [(R)/(S)-2-Methylpiperazinediium]PdCl49Insight into efficient photoluminescence regulation mechanism by lattice distortion and Mn2+ doping in organic-inorganic hybrid perovskites1Probing the Electron Transfer Behavior from Excited State Organometal Lead Halide Perovskite Nanocrystals to Molybdenum Disulfide Nanoflowers6Sequential thermochromic switching in zero-dimensional Cs2ZnCl4 metal halides27Strong Dopant–Dopant Electronic Coupling in Emissive Codoped Two Dimensional Metal Halide Hybrid11Elucidating the Role of Antimony Dopant in Optical Properties of Brightly Luminescent Zero-Dimensional Organic–Inorganic Metal Halides18Mn2+‐Based Luminescent Metal Halides: Syntheses, Properties, and Applications155One-Dimensional Organic–Inorganic Lead Bromide Hybrids with Excitation-Dependent White-Light Emission Templated by Pyridinium Derivatives12Efficient White Light Emission of 0D Lead-Free Indium-Based Halide Perovskite and the Intermediate State Promotion Mechanism of the Nonadiabatic Transition to Self-Trapped Exciton via Antimony(III) Cation Doping16Synthesis and DFT calculation of germanium halide perovskites with high luminescent stability, and their applications in WLEDs and indoor photovoltaics25One-Pot Synthesis of All-Inorganic CsPbClBr2 Blue Perovskite Quantum Dots via Stoichiometric Precursor13A High-Rigidity Organic–Inorganic Metal Halide Hybrid Enabling Reversible and Enhanced Self-Trapped Exciton Emission under High Pressure33Dual Monomeric Inorganic Units Constructed Bright Emissive Zero-Dimensional Antimony Chlorides with Solvent-Induced Reversible Structural Transition27Bulk Coassembly of Zero-Dimensional Heterometallic Halide Hybrids for Broadband White Light Emission and Optical Thermometry10Manipulating Lone‐Pair‐Driven Luminescence in 0D Tin Halides by Pressure‐Tuned Stereochemical Activity from Static to Dynamic45Manipulating Lone‐Pair‐Driven Luminescence in 0D Tin Halides by Pressure‐Tuned Stereochemical Activity from Static to Dynamic6Solution-Obtained (NH4)3In0.95Sb0.05Cl6 with High External Photoluminescence Quantum Yield and Excellent Antiquenching Properties10Unveiling the Structure-Luminescence-Stability relationship in 5s2-Based Antimony halides toward High-Performance emitters26Mixed B-site driven [InBr4]− tetrahedral efficient blue emission7Luminescent Behavior of Sb3+-Activated Luminescent Metal Halide26Solid-State Synthesis and Optical Studies of Water-Stable Pb 2+ -Doped Mn 2+ Complexes8

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  2. Breaking Forbidden Transitions for Emission of Self-Trapped Excitons in Two Dimensional (F2CHCH2NH3)2CdBr4 Perovskite through Pb Alloying

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  3. Smart and efficient opto-electronic dual response material based on two-dimensional perovskite crystal/thin film

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  4. A moisture-stable organosulfonate-based metal–organic framework with intrinsic self-trapped white-light emission

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  5. A three-dimensional cuprous lead bromide framework with highly efficient and stable thermochromic luminescence properties

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  6. Broadband yellow light emitting performance based on zero-dimensional hybrid lead bromide trimers

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  7. Crystallization of Ionically Bonded Organic Metal Halide Hybrids

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  8. Efficient, broadband self-trapped white-light emission from haloplumbate-based metal–organic frameworks

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  9. New lead bromide chiral perovskites with ultra-broadband white-light emission

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  10. Optically pumped white light-emitting diodes based on metal halide perovskites and perovskite-related materials

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  11. Tetrameric cluster assembled one-dimensional hybrid lead halides with broadband light emission

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  12. Tunable photoluminescence in Sb 3+ -doped zero-dimensional hybrid metal halides with intrinsic and extrinsic self-trapped excitons

    Journal of Materials Chemistry C · 2020-01-01

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  13. Synthesis, Structure, and Characterization of Variable Chains in a Series of Transition Metal Coordination Compounds

    European Journal of Inorganic Chemistry · 2020-01-02

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  14. Lead-Free Tin(IV)-Based Organic–Inorganic Metal Halide Hybrids with Excellent Stability and Blue-Broadband Emission

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  15. Optical Functional Units in Zero‐Dimensional Metal Halides as a Paradigm of Tunable Photoluminescence and Multicomponent Chromophores

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  16. Bulk Assembly of Multicomponent Zero-Dimensional Metal Halides with Dual Emission

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  17. Stable Yellow Light-Emitting Devices Based on Ternary Copper Halides with Broadband Emissive Self-Trapped Excitons

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  18. Broad-band emission in metal halide perovskites: Mechanism, materials, and applications

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  19. Molecular Intercalation and Electronic Two Dimensionality in Layered Hybrid Perovskites

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  21. Incorporating Rare‐Earth Terbium(III) Ions into Cs2AgInCl6:Bi Nanocrystals toward Tunable Photoluminescence

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  22. Incorporating Rare‐Earth Terbium(III) Ions into Cs2AgInCl6:Bi Nanocrystals toward Tunable Photoluminescence

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  23. Targeted Synthesis of Trimeric Organic–Bromoplumbate Hybrids That Display Intrinsic, Highly Stokes-Shifted, Broadband Emission

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  24. Multicomponent Organic Metal Halide Hybrid with White Emissions

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  29. All-Inorganic Lead-Free Heterometallic Cs4MnBi2Cl12 Perovskite Single Crystal with Highly Efficient Orange Emission

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  30. Enhancing Photoluminescence Quantum Yield in 0D Metal Halides by Introducing Water Molecules

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  31. Synthesis, Crystal Structure and Green Luminescence in Zero-Dimensional Tin Halide (C8H14N2)2SnBr6

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  32. Organic solvent-free lyophilization assisted recrystallization synthesis of high-purity green emissive Cs3MnX5 (X = I, Br)

    Journal of Alloys and Compounds · 2020-07-09

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  33. Narrow-band emitters in LED backlights for liquid-crystal displays

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  34. Design Principles for Enhancing Photoluminescence Quantum Yield in Hybrid Manganese Bromides

    Journal of the American Chemical Society · 2020-07-21

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  35. Lead-free violet-emitting K2CuCl3 single crystal with high photoluminescence quantum yield

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    Wanru Gao, Lixiao Yin, Jun‐Hui Yuan, Kan‐Hao Xue, Guangda Niu, Bo Yang, Qingsong Hu, Xinxing Liu, Jiang Tang

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  36. High Photoluminescence Quantum Yield (>95%) of MAPbBr3 Nanocrystals via Reprecipitation from Methylamine-MAPbBr3 Liquid

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  37. Phosphorescent Manganese(II) Complexes and Their Emerging Applications

    Advanced Optical Materials · 2020-08-16

    Peng Tao, Shujuan Liu, Wai‐Yeung Wong

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  38. Metal Halide Regulated Photophysical Tuning of Zero‐Dimensional Organic Metal Halide Hybrids: From Efficient Phosphorescence to Ultralong Afterglow

    Angewandte Chemie International Edition · 2020-09-02

    Liang‐Jin Xu, Anna Plaviak, Xinsong Lin, Michael Worku, Qingquan He, Maya Chaaban, Bumjoon J. Kim, Biwu Ma

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  39. Metal Halide Regulated Photophysical Tuning of Zero‐Dimensional Organic Metal Halide Hybrids: From Efficient Phosphorescence to Ultralong Afterglow

    Angewandte Chemie · 2020-09-02

    Liang‐Jin Xu, Anna Plaviak, Xinsong Lin, Michael Worku, Qingquan He, Maya Chaaban, Bumjoon J. Kim, Biwu Ma

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  40. Wide range zero-thermal-quenching ultralong phosphorescence from zero-dimensional metal halide hybrids

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    Shuya Liu, Xiaoyu Fang, Bo Lu, Dongpeng Yan

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  41. Pressure‐Engineered Photoluminescence Tuning in Zero‐Dimensional Lead Bromide Trimer Clusters

    Angewandte Chemie International Edition · 2020-10-22

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