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RESEARCH PAPER · Chemistry - An Asian Journal · 2021

The Rise of Infrared Nonlinear Optical Pnictides: Advances and Outlooks

He‐Di Yang, Mao‐Yin Ran, Wenbo Wei, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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The Rise of Infrared Nonlinear Optical Pnictides: Advances and OutlooksOriginalAliovalent-cation-substitution-induced structure transformation: a new path toward high-performance IR nonlinear optical materials47Ba 2 Ge 2 Te 5 : a ternary NLO-active telluride with unusual one-dimensional helical chains and giant second harmonic-generation tensors31Add a Pinch of Tetrel: The Transformation of a Centrosymmetric Metal into a Nonsymmorphic and Chiral Semiconductor8Quaternary Noncentrosymmetric Rare-Earth Sulfides Ba4RE2Cd3S10 (RE = Sm, Gd, or Tb): A Joint Experimental and Theoretical Investigation17From Cc to P 6 3 mc : Structural Variation in La 3 S 2 Cl 2 [SbS 3 ] and La 3 OSCl 2 [SbS 3 ] Induced by the Isovalent Anion Substitution22A comprehensive review on metal chalcogenides with three-dimensional frameworks for infrared nonlinear optical applications114Ag4SnGe2S7: A Noncentrosymmetric Chalcogenide in I4–II–IV2–VI7 System with Non-Diamond-Like Structure Featuring 1D ∞[SnGe2S8]6– Infinite Chain2Predicting Diamond-like Nitrides as Infrared Nonlinear Optical Materials with High Thermal Conductivity20An overview of Mg-based IR nonlinear optical materials22IrSi 3 As 3 : a first transition metal arsenide non-linear optical material10Nitrides: a promising class of nonlinear optical material candidates9Machine Learning Regression Model for Predicting the Formation Energy of Nonlinear Optical Crystals5Recent progress in the design of IR nonlinear optical materials by partial chemical substitution: Structural evolution and performance optimization133Shooting mid-infrared nonlinear optical materials with targeted balance performances in ternary d0-transition metal oxides through first-principles13The induced polarization enhanced birefringence in AlPS4 family: A first-principles investigation6Recent advances in IR nonlinear optical chalcogenides with well-balanced comprehensive performance56Advances in Solid-State Nonlinear Optical Materials: From Fundamentals to Applications61Ga-based IR nonlinear optical materials: Synthesis, structures, and properties65Nonlinear Optical Phosphide CuInSi2P4: The Inaugural Member of Diamond-Like Family I–III–IV2–V4 Inspired by ZnGeP216Rare-earth-based chalcogenides and their derivatives: an encouraging IR nonlinear optical material candidate70Structural strategy for advancing nonlinear optical effects in 1D-[MX 2 ] ∞ chains: internal distortion and atomic types2EuSi7P10: An Inorganic Supramolecular Nonlinear Optical Crystal Exhibiting Strong Second-Harmonic Generation Response4Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units66FeSi4P4 and CoSi3P3: Hidden Gems of Ternary Tetrel Pnictides with Outstanding Nonlinear Optical Properties11Structural, electronic and conductive properties of single wall MgGeN2 nanotube: A first principles investigation3Emergent Mid‐Infrared Nonlinear Optical Candidates With Targeted Balance Performances17BaAs 2 : an arsenide with giant second harmonic generation enabled by interesting As–As bonds1Assembly between diverse polycations and diamond-like anionic frameworks in salt-inclusion phosphides enables excellent nonlinear optical properties4Cd5As2Br4: A Ternary Arsenide with Nonlinear Optical Property3Pnictides: An Overview of Crystal Structures, Properties and Applications5Structure-property relationships in IR nonlinear optical chalcogenides with stereochemically active lone pairs29A high-performance IR nonlinear optical material Sr 3 MnGe 2 S 8 achieved via partial cation substitution-induced structural transformation2ABCQ4型硫属化物红外非线性光学材料的构效关系（特邀）0Cs X Si 15 P 21 ( X = Sn or Pb): Polar Noncentrosymmetric Si–P Frameworks Stabilized by Covalent X –P Bonding3From AgGaSe2 to MIIGa2Se4 (MII = Zn, Cd): Heterovalent Substitution Creates Ordered Vacancies for Balanced IR-NLO Performance0Beyond the bandgap bottleneck: structure–property design principles for infrared nonlinear optical phosphides0

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  1. Aliovalent-cation-substitution-induced structure transformation: a new path toward high-performance IR nonlinear optical materials

    Journal of Materials Chemistry C · 2021-01-01

    Chang Liu, Shenghua Zhou, Yu Xiao, Chao Zhang, Hua Lin, Yi Liu

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  2. Ba 2 Ge 2 Te 5 : a ternary NLO-active telluride with unusual one-dimensional helical chains and giant second harmonic-generation tensors

    Inorganic Chemistry Frontiers · 2021-01-01

    Mao‐Yin Ran, Zuju Ma, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  3. Add a Pinch of Tetrel: The Transformation of a Centrosymmetric Metal into a Nonsymmorphic and Chiral Semiconductor

    Chemistry - A European Journal · 2021-12-09

    Shannon Lee, Gayatri Viswanathan, Scott L. Carnahan, Colin P. Harmer, Georgiy Akopov, Aaron J. Rossini, Gordon J. Miller, Kirill A. Kovnir

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  4. Quaternary Noncentrosymmetric Rare-Earth Sulfides Ba4RE2Cd3S10 (RE = Sm, Gd, or Tb): A Joint Experimental and Theoretical Investigation

    Inorganic Chemistry · 2022-01-11

    Qing-Gang Yue, Shenghua Zhou, Bingxuan Li, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  5. From Cc to P 6 3 mc : Structural Variation in La 3 S 2 Cl 2 [SbS 3 ] and La 3 OSCl 2 [SbS 3 ] Induced by the Isovalent Anion Substitution

    Crystal Growth & Design · 2022-01-17

    Hua‐Jun Zhao, Hedi Yang, Pengfei Liu, Hua Lin

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  6. A comprehensive review on metal chalcogenides with three-dimensional frameworks for infrared nonlinear optical applications

    Coordination Chemistry Reviews · 2022-07-19

    Hong Chen, Mao‐Yin Ran, Wenbo Wei, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  7. Ag4SnGe2S7: A Noncentrosymmetric Chalcogenide in I4–II–IV2–VI7 System with Non-Diamond-Like Structure Featuring 1D ∞[SnGe2S8]6– Infinite Chain

    Inorganic Chemistry · 2022-09-20

    Peng Wang, Maierhaba Abudoureheman, Kewang Zhang, Juanjuan Zheng, Zhaohui Chen, Qi Wu

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  8. Predicting Diamond-like Nitrides as Infrared Nonlinear Optical Materials with High Thermal Conductivity

    Chemistry of Materials · 2022-11-02

    Junben Huang, Congwei Xie, Lei Wei, Qiang Bian, Zhihua Yang, Shilie Pan

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  9. An overview of Mg-based IR nonlinear optical materials

    Inorganic Chemistry Frontiers · 2023-01-01

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  10. IrSi 3 As 3 : a first transition metal arsenide non-linear optical material

    Journal of Materials Chemistry A · 2023-01-01

    Shannon Lee, Georgiy Akopov, Adedoyin N. Adeyemi, Ernesto Soto, Kui Wu, Kirill A. Kovnir

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  11. Nitrides: a promising class of nonlinear optical material candidates

    Materials Chemistry Frontiers · 2023-01-01

    Xin Lei Zhao, Chensheng Lin, Haotian Tian, Chao Wang, Ning Ye, Min Luo

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  12. Machine Learning Regression Model for Predicting the Formation Energy of Nonlinear Optical Crystals

    Advanced Theory and Simulations · 2023-01-29

    Zhen Hong Fan, Zhixin Sun, Ai Wang, Yaohui Yin, Hui Li, Guangyong Jin, Chao Xin

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  13. Recent progress in the design of IR nonlinear optical materials by partial chemical substitution: Structural evolution and performance optimization

    Coordination Chemistry Reviews · 2023-02-08

    Mao‐Yin Ran, A-Yang Wang, Wenbo Wei, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  14. Shooting mid-infrared nonlinear optical materials with targeted balance performances in ternary d0-transition metal oxides through first-principles

    Materials Today Physics · 2023-03-02

    Junben Huang, Gemei Cai

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  15. The induced polarization enhanced birefringence in AlPS4 family: A first-principles investigation

    Chemical Physics Letters · 2023-04-05

    Ruixin Zhang, Xiuhua Cui, Haiming Duan, Qun Jing, Zhaohui Chen, Ming‐Hsien Lee, Haibin Cao

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  16. Recent advances in IR nonlinear optical chalcogenides with well-balanced comprehensive performance

    Materials Today Physics · 2023-05-26

    Hedi Yang, Mao‐Yin Ran, Wenbo Wei, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  17. Advances in Solid-State Nonlinear Optical Materials: From Fundamentals to Applications

    ACS Applied Optical Materials · 2023-12-12

    Hafiz Zohaib Aslam, Joseph T. Doane, Michael T. Yeung, Georgiy Akopov

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  18. Ga-based IR nonlinear optical materials: Synthesis, structures, and properties

    Coordination Chemistry Reviews · 2023-12-21

    Jiaxiang Zhang, Ping Feng, Mao‐Yin Ran, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  19. Nonlinear Optical Phosphide CuInSi2P4: The Inaugural Member of Diamond-Like Family I–III–IV2–V4 Inspired by ZnGeP2

    ACS Applied Materials & Interfaces · 2023-12-27

    Ming‐Shu Zhang, Bin‐Wen Liu, Xiao‐Ming Jiang, Guo‐Cong Guo

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  20. Rare-earth-based chalcogenides and their derivatives: an encouraging IR nonlinear optical material candidate

    Chemical Science · 2024-01-01

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  21. Structural strategy for advancing nonlinear optical effects in 1D-[MX 2 ] ∞ chains: internal distortion and atomic types

    RSC Advances · 2024-01-01

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  22. EuSi7P10: An Inorganic Supramolecular Nonlinear Optical Crystal Exhibiting Strong Second-Harmonic Generation Response

    Inorganic Chemistry · 2024-05-30

    Yunxia Song, Chensheng Lin, Chao Wang, Yuqiao Zhou, Shenghao Fang, Pengxiang Dong, Bingxuan Li, Ning Ye, Xin Lei Zhao, Min Luo

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  23. Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units

    Coordination Chemistry Reviews · 2024-07-03

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  24. FeSi4P4 and CoSi3P3: Hidden Gems of Ternary Tetrel Pnictides with Outstanding Nonlinear Optical Properties

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  25. Structural, electronic and conductive properties of single wall MgGeN2 nanotube: A first principles investigation

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  26. Emergent Mid‐Infrared Nonlinear Optical Candidates With Targeted Balance Performances

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  27. BaAs 2 : an arsenide with giant second harmonic generation enabled by interesting As–As bonds

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  28. Assembly between diverse polycations and diamond-like anionic frameworks in salt-inclusion phosphides enables excellent nonlinear optical properties

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  29. Cd5As2Br4: A Ternary Arsenide with Nonlinear Optical Property

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  30. Pnictides: An Overview of Crystal Structures, Properties and Applications

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  31. Structure-property relationships in IR nonlinear optical chalcogenides with stereochemically active lone pairs

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  32. A high-performance IR nonlinear optical material Sr 3 MnGe 2 S 8 achieved via partial cation substitution-induced structural transformation

    Inorganic Chemistry Frontiers · 2025-11-14

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  33. ABCQ4型硫属化物红外非线性光学材料的构效关系（特邀）

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  34. Cs X Si 15 P 21 ( X = Sn or Pb): Polar Noncentrosymmetric Si–P Frameworks Stabilized by Covalent X –P Bonding

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  35. From AgGaSe2 to MIIGa2Se4 (MII = Zn, Cd): Heterovalent Substitution Creates Ordered Vacancies for Balanced IR-NLO Performance

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  36. Beyond the bandgap bottleneck: structure–property design principles for infrared nonlinear optical phosphides

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