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RESEARCH PAPER · Chemical Communications · 2021

Ba 2 BS 3 Cl and Ba 5 B 2 S 8 Cl 2 : first alkaline-earth metal thioborate halides with [BS 3 ] units

Jiazheng Zhou, Yu Chu, Junjie Li, Shilie Pan

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Ba 2 BS 3 Cl and Ba 5 B 2 S 8 Cl 2 : first alkaline-earth metal thioborate halides with [BS 3 ] unitsOriginalRbPb 8 O 4 Cl 9 : the first alkali metal lead oxyhalide with distorted [PbO 3 Cl 3 ] and [PbOCl 5 ] mixed-anion groups6Lanthanide thioborates, an emerging class of nonlinear optical materials, efficiently synthesized using the boron–chalcogen mixture method23Na 4 Ga 8 S 14 : a Ga-enriched wide band gap ternary alkali-metal sulfide with unique [Ga 12 S 42 ] 12-membered rings2Second-Harmonic Generation-Positive Na 2 Ga 2 SiS 6 with a Broad Band Gap and a High Laser Damage Threshold14NaBaBS3: A Promising Infrared Functional Material with Large Birefringence Induced by π-Conjugated [BS3] Units32Ag4SnGe2S7: A Noncentrosymmetric Chalcogenide in I4–II–IV2–VI7 System with Non-Diamond-Like Structure Featuring 1D ∞[SnGe2S8]6– Infinite Chain2Ba 3 (BS 3 )(PS 4 ): the first alkaline-earth metal thioborate–thiophosphate with strong optical anisotropy originating from planar [BS 3 ] units8Discovery of SrZn 2 B 6 O 12 with an unprecedented quadruple-layered configuration0From BPS 4 to AB 3 P 2 S 10 (A = Na, K): cations inducing dimension reduction and bandgap enlargement7LiCs 3 AlB 7 O 14 : achieving enhanced optical anisotropy via [AlO 4 ] tetrahedron introduction to rearrange the anionic framework5MB 3 P 2 S 10 (M = Rb, Cs): two new alkali metal thioboratephosphates with [B 6 P 4 S 20 ] T3-supertetrahedra2K2CdGe3S8: A New Infrared Nonlinear Optical Sulfide6Na3SiS3F: A Wide Bandgap Fluorothiosilicate with Unique [SiS3F] Unit and High Laser‐Induced Damage Threshold39HgB2S4: A d10 Metal Thioborate with Giant Birefringence and Wide Band Gap31Improved Birefringence Activated by Tetrahedra Decorated with a Single Linear Unit38Improved Birefringence Activated by Tetrahedra Decorated with a Single Linear Unit1Na 10 Zn(NO 3 ) 4 (SO 3 S) 4 : a nonlinear optical crystal combining inorganic π-conjugated and non-π-conjugated heteroanion groups8A I B 3 II C 2 III Q 6 VI X VII : A Thioborate Halide Family for Developing Wide Bandgap Infrared Nonlinear Materials by Coupling Planar [BS 3 ] and Polycations25Selenoborates: a latent structure resource for infrared functional crystal materials1Stereochemically active lone pair-induced large optical anisotropy in a novel infrared birefringent crystal Ba 2 La 2 Sb 4 S 10 (S 2 )5BaLa4(SiS4)2(BS3)2: Structurally Ordered Thioborate-Thiosilicate Obtained by Adjusting the Cationic Size2

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  1. RbPb 8 O 4 Cl 9 : the first alkali metal lead oxyhalide with distorted [PbO 3 Cl 3 ] and [PbOCl 5 ] mixed-anion groups

    Dalton Transactions · 2021-01-01

    Zhongxu Fan, Chen Bai, Hongsheng Shi, Min Zhang, Bei Zhang, Jun Zhang, Junjie Li

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  2. Lanthanide thioborates, an emerging class of nonlinear optical materials, efficiently synthesized using the boron–chalcogen mixture method

    Chemical Communications · 2022-01-01

    Logan S. Breton, Gregory W. Morrison, Matthew R. Lacroix, P. Shiv Halasyamani, Hans‐Conrad zur Loye

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  3. Na 4 Ga 8 S 14 : a Ga-enriched wide band gap ternary alkali-metal sulfide with unique [Ga 12 S 42 ] 12-membered rings

    Dalton Transactions · 2022-01-01

    Ling Luo, Linan Wang, Chen Bai, Jiazheng Zhou, Lai Wei, Xin Su

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  4. Second-Harmonic Generation-Positive Na 2 Ga 2 SiS 6 with a Broad Band Gap and a High Laser Damage Threshold

    Inorganic Chemistry · 2022-05-05

    Wenlong Xie, Yihan Yun, Lihan Deng, Guangmao Li, Shilie Pan

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  5. NaBaBS3: A Promising Infrared Functional Material with Large Birefringence Induced by π-Conjugated [BS3] Units

    Chemistry of Materials · 2022-05-25

    Yihan Yun, Wenlong Xie, Yi Huang, Zhihua Yang, Kui Wu, Guangmao Li, Shilie Pan

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  6. Ag4SnGe2S7: A Noncentrosymmetric Chalcogenide in I4–II–IV2–VI7 System with Non-Diamond-Like Structure Featuring 1D ∞[SnGe2S8]6– Infinite Chain

    Inorganic Chemistry · 2022-09-20

    Peng Wang, Maierhaba Abudoureheman, Kewang Zhang, Juanjuan Zheng, Zhaohui Chen, Qi Wu

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  7. Ba 3 (BS 3 )(PS 4 ): the first alkaline-earth metal thioborate–thiophosphate with strong optical anisotropy originating from planar [BS 3 ] units

    Dalton Transactions · 2023-01-01

    Jiazheng Zhou, Linan Wang, Hongshan Wang, Ling Luo, Junjie Li, Feng Yu

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  8. Discovery of SrZn 2 B 6 O 12 with an unprecedented quadruple-layered configuration

    New Journal of Chemistry · 2023-01-01

    Xiangyu Long, Yan An Lv, Xueyan Wu

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  9. From BPS 4 to AB 3 P 2 S 10 (A = Na, K): cations inducing dimension reduction and bandgap enlargement

    Dalton Transactions · 2023-01-01

    Yi Huang, Dongdong Chu, Yihan Yun, Wenlong Xie, Guangmao Li, Yong an Zhang

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  10. LiCs 3 AlB 7 O 14 : achieving enhanced optical anisotropy via [AlO 4 ] tetrahedron introduction to rearrange the anionic framework

    Dalton Transactions · 2023-01-01

    Xingqi Li, Dongdong Chu, Haotian Qiu, Yabo Wu, Xueling Hou

    Read original paper ↗ ·

  11. MB 3 P 2 S 10 (M = Rb, Cs): two new alkali metal thioboratephosphates with [B 6 P 4 S 20 ] T3-supertetrahedra

    Dalton Transactions · 2023-01-01

    Jiazheng Zhou, Xin Su, Ling Luo, Junjie Li, Feng Yu

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  12. K2CdGe3S8: A New Infrared Nonlinear Optical Sulfide

    Symmetry · 2023-01-15

    Zixuan Wu, Wen‐Fa Chen, Bin‐Wen Liu, Xiao‐Ming Jiang, Guo‐Cong Guo

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  13. Na3SiS3F: A Wide Bandgap Fluorothiosilicate with Unique [SiS3F] Unit and High Laser‐Induced Damage Threshold

    Advanced Optical Materials · 2023-05-17

    Jiazheng Zhou, Linan Wang, Yu Chu, Hongshan Wang, Shilie Pan, Junjie Li

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  14. HgB2S4: A d10 Metal Thioborate with Giant Birefringence and Wide Band Gap

    Chemistry of Materials · 2023-05-24

    Yi Huang, Yong an Zhang, Dongdong Chu, Zhihua Yang, Guangmao Li, Shilie Pan

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  15. Improved Birefringence Activated by Tetrahedra Decorated with a Single Linear Unit

    Angewandte Chemie International Edition · 2023-06-29

    Wenlong Xie, Fuming Li, Jianbang Chen, Zhihuang Yang, Guangmao Li, Shilie Pan

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  16. Improved Birefringence Activated by Tetrahedra Decorated with a Single Linear Unit

    Angewandte Chemie · 2023-06-29

    Wenlong Xie, Fuming Li, Jianbang Chen, Zhihuang Yang, Guangmao Li, Shilie Pan

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  17. Na 10 Zn(NO 3 ) 4 (SO 3 S) 4 : a nonlinear optical crystal combining inorganic π-conjugated and non-π-conjugated heteroanion groups

    Inorganic Chemistry Frontiers · 2023-11-07

    Zihao Yu, Qingran Ding, Yuhang Jiang, Weiqi Huang, Changsheng Yang, Sangen Zhao, Junhua Luo

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  18. A I B 3 II C 2 III Q 6 VI X VII : A Thioborate Halide Family for Developing Wide Bandgap Infrared Nonlinear Materials by Coupling Planar [BS 3 ] and Polycations

    Small · 2023-11-27

    Jiazheng Zhou, Ketian Hou, Yu Chu, Zhihua Yang, Junjie Li, Shilie Pan

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  19. Selenoborates: a latent structure resource for infrared functional crystal materials

    Inorganic Chemistry Frontiers · 2025-01-01

    Yihan Yun, Abudukadi Tudi, Zhihua Yang, Guangmao Li, Shilie Pan

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  20. Stereochemically active lone pair-induced large optical anisotropy in a novel infrared birefringent crystal Ba 2 La 2 Sb 4 S 10 (S 2 )

    Inorganic Chemistry Frontiers · 2025-01-01

    Jingdong Yan, Xiangran Kong, Shichao Cheng, Tao Liu, Hongwei Leng, Yunfei Shang, Zuotao Lei, Chunhui Yang

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  21. BaLa4(SiS4)2(BS3)2: Structurally Ordered Thioborate-Thiosilicate Obtained by Adjusting the Cationic Size

    Inorganic Chemistry · 2025-03-19

    Ya‐Xiang Han, Mingzhi Zhang, Chun‐Li Hu, Jiang‐Gao Mao

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