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RESEARCH PAPER · Inorganic Chemistry · 2003

Salt-Inclusion Synthesis of Ba2MnSi2O7Cl. A Fresnoite-Type Polar Framework Containing the Acentric [Si2O7]6- Polyanion in the Anti-ReO3 Type [(Ba2Mn)Cl]6+ Cage

Xunhua Mo, Shiou‐Jyh Hwu

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Salt-Inclusion Synthesis of Ba2MnSi2O7Cl. A Fresnoite-Type Polar Framework Containing the Acentric [Si2O7]6- Polyanion in the Anti-ReO3 Type [(Ba2Mn)Cl]6+ CageOriginalSalt‐Inclusion Synthesis of Ba2MnSi2O7Cl. A Fresnoite‐Type Polar Framework Containing the Acentric [Si2O7]6‐ Polyanion in the anti‐ReO3 Type [(Ba2Mn)Cl]6+ Cage.022 New compounds and structures in the solid state220 New compounds and structures in the solid state5Synthesis, Crystal Structure, and Solid-State NMR Spectroscopy of a Salt-Inclusion Stannosilicate: [Na3F][SnSi3O9]31Destruction of Noncentrosymmetry through Chalcogenide Salt Inclusion24Report from the third workshop on future directions of solid-state chemistry: The status of solid-state chemistry and its impact in the physical sciences75Synthesis, Crystal and Band Structures, and Properties of a New Mixed Three-Dimensional Framework Metal Pnictidehalide Semiconductor, (Hg6Sb4)(CdI6)19A New Series of Chalcohalide Semiconductors with Composite CdBr2/Sb2Se3 Lattices: Synthesis and Characterization of CdSb2Se3Br2 and Indium Derivatives InSb2S4X (X = Cl and Br) and InM2Se4Br (M = Sb and Bi)37The Versatile Chemistry and Noncentrosymmetric Crystal Structures of Salt‐Inclusion Vanadate Hybrids52The Versatile Chemistry and Noncentrosymmetric Crystal Structures of Salt‐Inclusion Vanadate Hybrids1Flux Synthesis, Crystal Structures, and Luminescence Properties of Salt-Inclusion Lanthanide Silicates: [K9F2][Ln3Si12O32] (Ln = Sm, Eu, Gd)49Synthesis and Characterization of Open-Framework Niobium Silicates: Rb2(Nb2O4)(Si2O6)·H2O and the Dehydrated Phase Rb2(Nb2O4)(Si2O6)12A Series of New Infrared NLO Semiconductors, ZnY6Si2S14, AlxDy3(SiyAl1−y)S7, and Al0.33Sm3SiS7134Flux Synthesis of Salt-Inclusion Uranyl Silicates: [K3Cs4F][(UO2)3(Si2O7)2] and [NaRb6F][(UO2)3(Si2O7)2]47Synthesis, Structure, and Magnetic Properties of Na3LnMn3O3(AsO4)3(Ln = La, Sm, and Gd): A New 3d-4f Series Exhibiting One-Dimensional Manganese(III) Oxide Chains Connected via LnO9Units16Salt-Templated Mesoporous Solids Comprised of Interlinked Polyoxovanadate Clusters27Noncentrosymmetric Inorganic Oxide Materials: Synthetic Strategies and Characterisation Techniques8A3V5O14 (A = K+, Rb+, or Tl+), New Polar Oxides with a Tetragonal Tungsten Bronze Related Structural Topology: Synthesis, Structure, and Functional Properties76Hydrothermal synthesis of compounds in the fresnoite mineral family (Ba2TiSi2O8)13Extended Utility of Molten-Salt Chemistry: Unprecedented Synthesis of a Water-Soluble Salt-Inclusion Solid Comprised of High-Nuclearity Vanadium Oxide Clusters20Symmetry preservation in a new noncentrosymmetric lattice comprised of acentric POM clusters residing in bowls of Cs + -based half SOD β-cage9New Vanadium Selenites: Centrosymmetric Ca2(VO2)2(SeO3)3(H2O)2, Sr2(VO2)2(SeO3)3, and Ba(V2O5)(SeO3), and Noncentrosymmetric and Polar A4(VO2)2(SeO3)4(Se2O5) (A = Sr2+ or Pb2+)50Noncentrosymmetric salt inclusion oxides: Role of salt lattices and counter ions in bulk polarity52Synthesis and Structure of Bismuth(III)-Containing Noncentrosymmetric Phosphates, Cs3KBi2M4(PO4)6Cl (M = Mn, Fe). Monoclinic (Cc) and Tetragonal (P43) Polymorphs Templated by Chlorine-Centered Cl(Bi2Cs) Acentric Units5Chemistry of Polar Transition-Metal Oxides1Cs 7 Nd 11 (SeO 3 ) 12 Cl 16 : First Noncentrosymmetric Structure among Alkaline-Metal Lanthanide Selenite Halides22Sr3B6O11F2: a promising polar fluoroborate with short UV absorption edge and moderate second harmonic generation response30Ba4(BO3)3(SiO4)·Ba3X (X = Cl, Br): new salt-inclusion borosilicate halides as potential deep UV nonlinear optical materials58Rare‐Earth Cadmium Tellurite Chlorides with a Structural Type Exhibiting [Ln12(TeO3)12] Slabs Alternating with CdCl6 Octahedral Layers11M3(P2O7)22–-Type Open Frameworks Featuring [M2O8] and [M3O12] Multinuclear Transition-Metal Oxide Units. Serendipitous Synthesis of Six Polymorphic Salt-Inclusion Magnetic Solids: Na2M3(P2O7)2·ACl (M = Mn, Fe; A = Rb, Cs) and K2M3(P2O7)2·CsCl (M = Fe, Mn)15Borate Fluoride and Fluoroborate in Alkali-Metal Borate Prepared by an Open High-Temperature Solution Method50Na 3 B 4 O 7 X (X = Cl, Br): two new borate halides with a 1D Na-X (X = Cl, Br) chain formed by the face-sharing XNa 6 octahedra13Cs7Sm11[TeO3]12Cl16 and Rb7Nd11[TeO3]12Br16, the new tellurite halides of the tetragonal Rb6LiNd11[SeO3]12Cl16 structure type11Synthesis, crystal structures, magnetic properties, and lattice dynamics of Ba2XCu(OH)[V2O7] with X=Cl, Br8Three Unique Barium Manganese Vanadates from High-Temperature Hydrothermal Brines11Synthesis, Structures, and Luminescent Properties of Sodium Rare‐Earth Metal(III) Chloride Oxotellurates(IV), Na2Ln3Cl3[TeO3]4 (Ln = Sm, Eu, Gd, Tb, Dy, and Ho)10Synthesis and structural variety of first Mn and Bi selenites and selenite chlorides7Synthesis, Structure Determination, and Characterizations of a Polar Salt-Inclusion Scandium Germanate, Rb10Li3Sc4Ge12O36F7Negative Second Harmonic Response of Sn4+in the Fresnoite Oxysulfide Ba2SnSSi2O720

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  1. Salt‐Inclusion Synthesis of Ba2MnSi2O7Cl. A Fresnoite‐Type Polar Framework Containing the Acentric [Si2O7]6‐ Polyanion in the anti‐ReO3 Type [(Ba2Mn)Cl]6+ Cage.

    ChemInform · 2003-09-15

    Xunhua Mo, Shiou‐Jyh Hwu

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  2. 22 New compounds and structures in the solid state

    Annual Reports Section A (Inorganic Chemistry) · 2004-01-01

    Gary B. Hix

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  3. 20 New compounds and structures in the solid state

    Annual Reports Section A (Inorganic Chemistry) · 2005-01-01

    Gary B. Hix

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  4. Synthesis, Crystal Structure, and Solid-State NMR Spectroscopy of a Salt-Inclusion Stannosilicate: [Na3F][SnSi3O9]

    Inorganic Chemistry · 2005-10-21

    Chen-Hui Liao, Pai-Ching Chang, Hsien‐Ming Kao, Kwang‐Hwa Lii

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  5. Destruction of Noncentrosymmetry through Chalcogenide Salt Inclusion

    Inorganic Chemistry · 2006-06-15

    Amitava Choudhury, Peter K. Dorhout

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  6. Report from the third workshop on future directions of solid-state chemistry: The status of solid-state chemistry and its impact in the physical sciences

    Progress in Solid State Chemistry · 2007-03-31

    Mercouri G. Kanatzidis, Kenneth Reinhard Poeppelmeier, Svilen Bobev, Arnold M. Guloy, Shiou Jyh Hwu, Abdessadek Lachgar, Susan E. Latturner, Raymond, E. Schaak, Dong‐Kyun Seo, Slavi Christov Sevov, Andreas Stein, B. Dąbrowski, John E. Greedan, M. Greenblatt, Clare P. Grey, Allan J. Jacobson, Douglas A. Keszler, Jing Li, Mas A. Subramanian, Younan Xia, Tahir Cagin B, Ulrich Häußermann, Timothy R. Hughbanks, S. D. Mahanti, Dane D. Morgan, Dong‐Kyun Seo, Nicola A. Spaldin, William E. Buhro, Daniel E. Giammar, Jennifer Ann Hollingsworth, David C. Johnson, Arthur J. Nozik, Xiaogang Peng, Robert L. Bedard, Nathaniel E. Brese, Guang Cao, Sandeep S. Dhingra, Cherie R. Kagan, David B. Mitzi, Margret J. Geselbracht, George C. Lisensky, Michael W. Lufaso, Paul A. Maggard, M. O’Keeffe, Angus Paul Wilkinson, Hans‐Conrad zur Loye, T. Egami, John E. Greedan, Jason P. Hodges, James D. Martin, John B. Parise, Brian H. Toby, Terrell A. Vanderah, Peter Carman Burns, Julia Y. Chan, Anne E. Meyer, Christopher B. Murray, Arthur P. Ramirez, Michael D. Ward, Lian Yu, Miguel Ángel Alario Franco, Peter D. Battle, Thomas Bein, Christopher L. Cahill, P. Shiv Halasyamani, Antoine Maignan, Ram Seshadri

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  7. Synthesis, Crystal and Band Structures, and Properties of a New Mixed Three-Dimensional Framework Metal Pnictidehalide Semiconductor, (Hg6Sb4)(CdI6)

    Inorganic Chemistry · 2007-08-01

    Jian‐Ping Zou, Yan Li, Zhangjing Zhang, Guo, Xi Liu, Ming‐Sheng Wang, Li‐Zhen Cai, Ying‐Bing Lu, Jin‐Shun Huang

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  8. A New Series of Chalcohalide Semiconductors with Composite CdBr2/Sb2Se3 Lattices: Synthesis and Characterization of CdSb2Se3Br2 and Indium Derivatives InSb2S4X (X = Cl and Br) and InM2Se4Br (M = Sb and Bi)

    Chemistry of Materials · 2007-11-13

    Lei Wang, Shiou‐Jyh Hwu

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  9. The Versatile Chemistry and Noncentrosymmetric Crystal Structures of Salt‐Inclusion Vanadate Hybrids

    Angewandte Chemie International Edition · 2008-04-09

    Wendy Lee Queen, J. Palmer West, Shiou‐Jyh Hwu, Donald G. VanDerveer, Matthew C. Zarzyczny, Ryan A. Pavlick

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  10. The Versatile Chemistry and Noncentrosymmetric Crystal Structures of Salt‐Inclusion Vanadate Hybrids

    Angewandte Chemie · 2008-04-09

    Wendy Lee Queen, J. Palmer West, Shiou‐Jyh Hwu, Donald G. VanDerveer, Matthew C. Zarzyczny, Ryan A. Pavlick

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  11. Flux Synthesis, Crystal Structures, and Luminescence Properties of Salt-Inclusion Lanthanide Silicates: [K9F2][Ln3Si12O32] (Ln = Sm, Eu, Gd)

    Inorganic Chemistry · 2008-09-03

    Ming-Feng Tang, Pei-Yun Chiang, Yu-Han Su, Yu‐Chi Jung, Guang‐Yi Hou, Bor‐Chen Chang, Kwang‐Hwa Lii

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  12. Synthesis and Characterization of Open-Framework Niobium Silicates: Rb2(Nb2O4)(Si2O6)·H2O and the Dehydrated Phase Rb2(Nb2O4)(Si2O6)

    Inorganic Chemistry · 2008-11-07

    Jhen-Ming Tasi, Po-Tao Tu, Ting‐Shan Chan, Kwang‐Hwa Lii

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  13. A Series of New Infrared NLO Semiconductors, ZnY6Si2S14, AlxDy3(SiyAl1−y)S7, and Al0.33Sm3SiS7

    Inorganic Chemistry · 2009-07-09

    Sheng‐Ping Guo, Guo‐Cong Guo, Ming‐Sheng Wang, Jian‐Ping Zou, Gang Xu, Guojian Wang, Xifa Long, Jin‐Shun Huang

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  14. Flux Synthesis of Salt-Inclusion Uranyl Silicates: [K3Cs4F][(UO2)3(Si2O7)2] and [NaRb6F][(UO2)3(Si2O7)2]

    Inorganic Chemistry · 2009-07-28

    Cheng‐Shiuan Lee, Sue‐Lein Wang, Yen-Hung Chen, Kwang‐Hwa Lii

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  15. Synthesis, Structure, and Magnetic Properties of Na3LnMn3O3(AsO4)3(Ln = La, Sm, and Gd): A New 3d-4f Series Exhibiting One-Dimensional Manganese(III) Oxide Chains Connected via LnO9Units

    Inorganic Chemistry · 2009-07-29

    J. Palmer West, Shiou‐Jyh Hwu, Wendy Lee Queen

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  16. Salt-Templated Mesoporous Solids Comprised of Interlinked Polyoxovanadate Clusters

    Inorganic Chemistry · 2010-01-12

    Wendy Lee Queen, Shiou‐Jyh Hwu, Shane Reighard

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  17. Noncentrosymmetric Inorganic Oxide Materials: Synthetic Strategies and Characterisation Techniques

    Unknown journal · 2010-06-11

    P. Shiv Halasyamani

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  18. A3V5O14 (A = K+, Rb+, or Tl+), New Polar Oxides with a Tetragonal Tungsten Bronze Related Structural Topology: Synthesis, Structure, and Functional Properties

    Inorganic Chemistry · 2010-07-07

    Jeongho Yeon, Sang-Hwan Kim, P. Shiv Halasyamani

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  19. Hydrothermal synthesis of compounds in the fresnoite mineral family (Ba2TiSi2O8)

    Journal of Solid State Chemistry · 2011-02-02

    Edward E. Abbott, Matthew Mann, Joseph W. Kolis

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  20. Extended Utility of Molten-Salt Chemistry: Unprecedented Synthesis of a Water-Soluble Salt-Inclusion Solid Comprised of High-Nuclearity Vanadium Oxide Clusters

    Inorganic Chemistry · 2011-09-27

    Wendy Lee Queen, J. Palmer West, JoAn S. Hudson, Shiou‐Jyh Hwu

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  21. Symmetry preservation in a new noncentrosymmetric lattice comprised of acentric POM clusters residing in bowls of Cs + -based half SOD β-cage

    Chemical Communications · 2011-11-16

    Wendy Lee Queen, J. Palmer West, Shiou‐Jyh Hwu, T. Thao Tran, P. Shiv Halasyamani, Don G. VanDerveer

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  22. New Vanadium Selenites: Centrosymmetric Ca2(VO2)2(SeO3)3(H2O)2, Sr2(VO2)2(SeO3)3, and Ba(V2O5)(SeO3), and Noncentrosymmetric and Polar A4(VO2)2(SeO3)4(Se2O5) (A = Sr2+ or Pb2+)

    Inorganic Chemistry · 2011-12-06

    Jeongho Yeon, Sang-Hwan Kim, Sau Doan Nguyen, Hana Lee, P. Shiv Halasyamani

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  23. Noncentrosymmetric salt inclusion oxides: Role of salt lattices and counter ions in bulk polarity

    Journal of Solid State Chemistry · 2012-06-20

    J. Palmer West, Shiou‐Jyh Hwu

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  24. Synthesis and Structure of Bismuth(III)-Containing Noncentrosymmetric Phosphates, Cs3KBi2M4(PO4)6Cl (M = Mn, Fe). Monoclinic (Cc) and Tetragonal (P43) Polymorphs Templated by Chlorine-Centered Cl(Bi2Cs) Acentric Units

    Inorganic Chemistry · 2012-08-27

    J. Palmer West, Dino Sulejmanovic, Shiou‐Jyh Hwu, Jian Ping He, Don G. VanDerveer, Boyd Johnson

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  25. Chemistry of Polar Transition-Metal Oxides

    Elsevier eBooks · 2013-01-01

    P. Shiv Halasyamani

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  26. Cs 7 Nd 11 (SeO 3 ) 12 Cl 16 : First Noncentrosymmetric Structure among Alkaline-Metal Lanthanide Selenite Halides

    Inorganic Chemistry · 2013-03-11

    Peter S. Berdonosov, Lev Akselrud, Yurii M. Prots', Artem M. Abakumov, Philippe Frederic Smet, Dirk Poelman, Gustaaf Van TENDELOO, В. А. Долгих

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  27. Sr3B6O11F2: a promising polar fluoroborate with short UV absorption edge and moderate second harmonic generation response

    Scripta Materialia · 2013-05-31

    Zhenjun Huang, Xin Su, Shilie Pan, Xiaoyu Dong, Shujuan Han, Hongwei Yu, Min Zhang, Yun Mo Yang, Sifang Cui, Zhihua Yang

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  28. Ba4(BO3)3(SiO4)·Ba3X (X = Cl, Br): new salt-inclusion borosilicate halides as potential deep UV nonlinear optical materials

    Journal of Materials Chemistry C · 2014-01-01

    Xiaoxia Nina Lin, Fangfang Zhang, Fangfang Zhang, Shilie Pan, Hongwei Yu, Fangyuan Zhang, Fangyuan Zhang, Xiaoyu Dong, Shujuan Han, Lingyun Dong, Chunyan Bai, Zheng Wang

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  29. Rare‐Earth Cadmium Tellurite Chlorides with a Structural Type Exhibiting [Ln12(TeO3)12] Slabs Alternating with CdCl6 Octahedral Layers

    European Journal of Inorganic Chemistry · 2014-06-03

    Ivan D. Kharitonov, Dmitri O. Charkin, Peter S. Berdonosov, Cameron Black, Lewis J. Downie, Philip Lightfoot, В. А. Долгих

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  30. M3(P2O7)22–-Type Open Frameworks Featuring [M2O8] and [M3O12] Multinuclear Transition-Metal Oxide Units. Serendipitous Synthesis of Six Polymorphic Salt-Inclusion Magnetic Solids: Na2M3(P2O7)2·ACl (M = Mn, Fe; A = Rb, Cs) and K2M3(P2O7)2·CsCl (M = Fe, Mn)

    Inorganic Chemistry · 2014-11-21

    Jianhua Gao, Jian Li, Dino Sulejmanovic, Shiou‐Jyh Hwu

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  31. Borate Fluoride and Fluoroborate in Alkali-Metal Borate Prepared by an Open High-Temperature Solution Method

    Inorganic Chemistry · 2014-12-01

    Hongping Wu, Hongwei Yu, Qiang Bian, Zhihua Yang, Shujuan Han, Shilie Pan

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  32. Na 3 B 4 O 7 X (X = Cl, Br): two new borate halides with a 1D Na-X (X = Cl, Br) chain formed by the face-sharing XNa 6 octahedra

    RSC Advances · 2015-01-01

    Chunyan Bai, Shujuan Han, Shilie Pan, Bingbing Zhang, Yun Mo Yang, Lin Li, Zhihua Yang

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  33. Cs7Sm11[TeO3]12Cl16 and Rb7Nd11[TeO3]12Br16, the new tellurite halides of the tetragonal Rb6LiNd11[SeO3]12Cl16 structure type

    Journal of Solid State Chemistry · 2015-08-30

    Dmitri O. Charkin, Cameron Black, Lewis J. Downie, Dmitry E. Sklovsky, Peter S. Berdonosov, Andrei V. Olenev, Wuzong Zhou, Philip Lightfoot, В. А. Долгих

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  34. Synthesis, crystal structures, magnetic properties, and lattice dynamics of Ba2XCu(OH)[V2O7] with X=Cl, Br

    Journal of Solid State Chemistry · 2015-09-12

    Kewen Sun, Alexander P. Litvinchuk, Joshua H. Tapp, Angela Möller

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  35. Three Unique Barium Manganese Vanadates from High-Temperature Hydrothermal Brines

    Inorganic Chemistry · 2017-03-20

    Tiffany M. Smith Pellizzeri, Colin D. McMillen, Yimei Wen, George D. Chumanov, Joseph W. Kolis

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  36. Synthesis, Structures, and Luminescent Properties of Sodium Rare‐Earth Metal(III) Chloride Oxotellurates(IV), Na2Ln3Cl3[TeO3]4 (Ln = Sm, Eu, Gd, Tb, Dy, and Ho)

    Zeitschrift für anorganische und allgemeine Chemie · 2017-10-02

    Dmitri O. Charkin, Sabine Zitzer, Stefan Greiner, Sergey Gennadievich Dorofeev, Andrei V. Olenev, Peter S. Berdonosov, Thomas Schleid, В. А. Долгих

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  37. Synthesis and structural variety of first Mn and Bi selenites and selenite chlorides

    Zeitschrift für Kristallographie - Crystalline Materials · 2018-10-16

    Vadim M. Kovrugin, Marie Colmont, Oleg I. Siidra, Dmitry O. Charkin, Almaz Aliev, Sergey V. Krivovichev, Olivier Mentré

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  38. Synthesis, Structure Determination, and Characterizations of a Polar Salt-Inclusion Scandium Germanate, Rb10Li3Sc4Ge12O36F

    Inorganic Chemistry · 2022-01-14

    Chuan Yi Tang, Mingjun Xia, Rukang K. Li

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  39. Negative Second Harmonic Response of Sn4+in the Fresnoite Oxysulfide Ba2SnSSi2O7

    Chemistry of Materials · 2022-05-05

    Batoul Almoussawi, Wen‐Dong Yao, Sheng‐Ping Guo, Myung‐Hwan Whangbo, Valérie Dupray, Simon Clevers, Shuiquan Deng, Houria Kabbour

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