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RESEARCH PAPER · ACS Omega · 2018

[(( R )-C8H12N)4][Bi2Br10] and [(( S )-C8H12N)4][Bi2Br10]: Chiral Hybrid Bismuth Bromides Templated by Chiral Organic Cations

Tae Hwan Moon, Seung‐Jin Oh, Kang Min Ok

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[(( R )-C8H12N)4][Bi2Br10] and [(( S )-C8H12N)4][Bi2Br10]: Chiral Hybrid Bismuth Bromides Templated by Chiral Organic CationsOriginalBroad-Band Emission in a Zero-Dimensional Hybrid Organic [PbBr6] Trimer with Intrinsic Vacancies114Exploration of Chiral Organic–Inorganic Hybrid Semiconducting Lead Halides47Ferroelectricity in Ethylammonium Bismuth-Based Organic–Inorganic Hybrid: (C2H5NH3)2[BiBr5]57Correlation between crystal structures and polar (ferroelectric) properties of hybrids of haloantimonates( iii ) and halobismuthates( iii )62Chiral-perovskite optoelectronics909Broad-band emission in metal halide perovskites: Mechanism, materials, and applications288Band Gap-Tunable, Chiral Hybrid Metal Halides Displaying Second-Harmonic Generation110Highly Distorted Chiral Two-Dimensional Tin Iodide Perovskites for Spin Polarized Charge Transport422The crystal structures of α-Rb7Sb3Br16, α- and β-Tl7Bi3Br16 and their relationship to close packings of spheres3Chiral Template‐Driven Macroscopic Chirality Control: Structure‐Second‐Harmonic Generation Properties Relationship24(C 2 H 5 NH 3 ) 3 [InBr 6 ]: an indium( iii ) organic–inorganic hybrid phase transition compound exhibiting a switchable dielectric response9Recent Progress on Two-Dimensional Materials472Spin selectivity in chiral metal–halide semiconductors40Chiral halide perovskite crystals for optoelectronic applications238Chiral Perovskites for Next‐Generation Photonics: From Chirality Transfer to Chiroptical Activity263Circularly polarized luminescence of agglomerate emitters174Recent Progress of Chiral Perovskites: Materials, Synthesis, and Properties314Strong Second- and Third-Harmonic Generation in 1D Chiral Hybrid Bismuth Halides159Hybrid Metal‐Halide Infrared Nonlinear Optical Crystals of (TMEDA)MI5 (M = Sb, Bi) with High Stability36Crystal structure and semiconductor properties of copper(II) complex incorporating chiral (R)-(+)-α-Ethylbenzylammonium cations:[(R)-C9H14N]3[CuBr4].Br.18A zero-dimensional lead-free bismuth-based metal halide: [C 6 H 5 (CH 2 ) 2 CH(NH 3 )CH 3 ] 2 BiCl 51Advances in single crystals and thin films of chiral hybrid metal halides38Chiral Ligand‐Driven Systematic Synthesis of Coordination Polymers with Non‐centrosymmetric Structures12Rationalizing the design and implementation of chiral hybrid perovskites129Chiral Methylbenzylammonium Bismuth Iodide with Zero-Dimensional Perovskite Derivative Structure37Structural Asymmetry and Chiroptical Activity of Chiral Antimony‐Halide Hybrids23Control of light, spin and charge with chiral metal halide semiconductors203Optically Induced Long-Lived Chirality Memory in the Color-Tunable Chiral Lead-Free Semiconductor (R)/(S)-CHEA4Bi2BrxI10–x (x = 0–10)53Dimensional Control of Chiral Antimony Halide Compounds for Enhanced Circular Dichroism12Chiral 2D Cu(I) Halide Frameworks53Spin‐Selective Charge Transport in Lead‐Free Chiral Perovskites: The Key towards High‐Anisotropy in Circularly‐Polarized Light Detection63Spin‐Selective Charge Transport in Lead‐Free Chiral Perovskites: The Key towards High‐Anisotropy in Circularly‐Polarized Light Detection16Multilayered Alternating‐Cations‐Intercalation Chiral Hybrid Perovskites with High Circular Polarization Sensitivity28Origin of high piezoelectricity of a bismuth-based organic–inorganic hybrid crystal14A photoluminescent chiral lead-free hybrid ferroelastic semiconductor with switchable second-harmonic generation23Influence of crystal structure and composition on optical and electronic properties of pyridinium-based bismuth iodide complexes12Strong anisotropic second-order nonlinear optical responses in 0D lead-free chiral perovskite single-crystalline microwire arrays21Centimeter‐Sized Piezoelectric Single Crystal of Chiral Bismuth‐Based Hybrid Halide with Superior Electrostrictive Coefficient26Highly Anisotropic Second-Order Nonlinear Optical Effects in the Chiral Lead-Free Perovskite Spiral Microplates93Ligand Chemistry of Inorganic Lead Halide Perovskite Nanocrystals388Magnetic Fano resonance enhanced second-harmonic generation in chiral hybrid bismuth halides8Optical properties of two-dimensional perovskites9Progressive Structural Complexity in Ferroelectric 1,2,4-Triazolium Hexabromoantimonate(III): Interplay of “Order–Disorder” and “Displacive” Contributions to the Structural Phase Transitions5Unprecedented Chiral Three‐dimensional Hybrid Organic‐Inorganic Perovskitoids36Unprecedented Chiral Three‐dimensional Hybrid Organic‐Inorganic Perovskitoids0Green and Red Photoluminescent Manganese Bromides with Aminomethylpyridine Isomers6Enhanced Circular Dichroism and Polarized Emission in an Achiral, Low Band Gap Bismuth Iodide Perovskite Derivative14A review of the relationship between the structure and nonlinear optical properties of organic-inorganic hybrid materials150Impact of Chiral Symmetry Breaking on Spin-Texture and Lone Pair Expression in Chiral Crystals of Hybrid Antimony and Bismuth Halides31A new zero-dimensional (0D) hybrid bismuth (III) halide: Synthesis, crystal structure, thermal analysis, photophysical properties and DFT calculations12Synthesis and Optical Properties of One Year Air-Stable Chiral Sb(III) Halide Semiconductors16Chiral amino acid-templated tin fluorides tailoring nonlinear optical properties, birefringence, and photoluminescence17(C 2 H 5 NH 3 ) 2 BiCl 5− x Br x perovskites containing 1D chains: effect of Br substitution on their structural and optical properties6Synthesis, optical, electronic and magnetic studies of air-stable chiral Cu( ii ) chlorides3Twisted oxide membranes: A perspective38From C4H7N2Ge0.4Sn0.6Br3 to C6H11N2Ge0.4Sn0.6Br3: Effective Modulation of the Second Harmonic Generation Effect and Optical Band Gap by Planar π-Conjugated Organic Cation Size11Manipulating Chiroptical Activities in 0D Chiral Hybrid Manganese Bromides by Solvent Molecular Engineering26Narrow-Bandgap Tellurium-Based Chiral Hybrid Perovskite Single Crystals with Rashba–Dresselhaus Effect and Piezoelectricity3A New centrosymmetric supramolecular Hybrid Antimony (III)-based material :X-ray characterization, vibrational studies, theoretical (DFT and TD-DFT) studies, thermal behavior, opto-electric properties and atomic Hirshfeld surface analysis.3Chiral Templating in a Hybrid Chromium Chloride Hydrate2New lead-freeIodoantimonatehalide semiconductor: Synthesis, Structural characterization, DFT calculations, Hirshfeld surface, Thermal behavior, vibrational and optical properties4Unveiling Chirality Transfer between Chiral Centers and Metal Halides in Chiral Organic–Inorganic Hybrid Metal Halides25Structural asymmetry, physicochemical characterization and optical properties of a new luminescent zero dimensional organic-inorganic hybrid compound4Chiral optical properties of metasurfaces comprised of chiral media: effects of geometric and material chirality2Chiral-driven formation of hybrid cyanurates with large birefringence2Chiral organic hybrids for nonlinear optical applications and solvent-induced reversible red–yellow color change2Probing the significance of phenylethyl ammonium doping in Cs 3 Bi 2 Br 9 halide perovskite nanosheets: a structural and optical perspective3Chiral light–matter interactions in solution-processable semiconductors60Decoding Chirality Transfer Strengths and Structure–Property Relationships in Bismuth-Containing Chiral Hybrid Organic–Inorganic Semiconductors10Crystal structure and optical properties of a new 0D organic-inorganic compound, (3-picolylammonium)2[Bi2Cl10]·2H2O: Experimental and theoretical insights4Chiral Metal Halides toward Circularly Polarized Photodetectors13Chiral perovskites: From chirality mechanisms to photovoltaics2Chiral-induced spin selectivity in two-dimensional chiral materials: Mechanisms, chirality transfer, and spintronic applications1Zero-Dimensional Bismuth Halide Thin Films with High Orientation and Broadband Emission0

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  3. Ferroelectricity in Ethylammonium Bismuth-Based Organic–Inorganic Hybrid: (C2H5NH3)2[BiBr5]

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  4. Correlation between crystal structures and polar (ferroelectric) properties of hybrids of haloantimonates( iii ) and halobismuthates( iii )

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  7. Band Gap-Tunable, Chiral Hybrid Metal Halides Displaying Second-Harmonic Generation

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  8. Highly Distorted Chiral Two-Dimensional Tin Iodide Perovskites for Spin Polarized Charge Transport

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  9. The crystal structures of α-Rb7Sb3Br16, α- and β-Tl7Bi3Br16 and their relationship to close packings of spheres

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  10. Chiral Template‐Driven Macroscopic Chirality Control: Structure‐Second‐Harmonic Generation Properties Relationship

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  11. (C 2 H 5 NH 3 ) 3 [InBr 6 ]: an indium( iii ) organic–inorganic hybrid phase transition compound exhibiting a switchable dielectric response

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  16. Circularly polarized luminescence of agglomerate emitters

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  17. Recent Progress of Chiral Perovskites: Materials, Synthesis, and Properties

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  18. Strong Second- and Third-Harmonic Generation in 1D Chiral Hybrid Bismuth Halides

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  19. Hybrid Metal‐Halide Infrared Nonlinear Optical Crystals of (TMEDA)MI5 (M = Sb, Bi) with High Stability

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  20. Crystal structure and semiconductor properties of copper(II) complex incorporating chiral (R)-(+)-α-Ethylbenzylammonium cations:[(R)-C9H14N]3[CuBr4].Br.

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