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RESEARCH PAPER · Advanced Optical Materials · 2021

Hybrid Metal‐Halide Infrared Nonlinear Optical Crystals of (TMEDA)MI5 (M = Sb, Bi) with High Stability

Kunjie Liu, Chenkai Deng, Chunxiao Li, Xusheng Zhang, Jindong Cao, Jiyong Yao, Jing Wei Zhao, Xingxing Jiang, Zheshuai Lin, Quanlin Liu

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Hybrid Metal‐Halide Infrared Nonlinear Optical Crystals of (TMEDA)MI5 (M = Sb, Bi) with High StabilityOriginalAntimony-doped enhanced photoluminescence quantum yield in zero-dimensional lead-free metal halide Rb 2 CsBiCl 6 crystals20Nearly one-fold enhancement in photoluminescence quantum yield for isostructural zero-dimensional hybrid antimony( iii ) bromides by supramolecular interaction adjustments30Symmetry breaking of A 3 M 2 X 9 -type perovskite derivatives induced by polar quaternary ammonium cations: achieving efficient nonlinear optical properties28Thermal stable zinc-based hybrid halides with high external quantum efficiency as temperature detectors29Chiral Hybrid Copper(I) Halides for High Efficiency Second Harmonic Generation with a Broadband Transparency Window112Chiral Hybrid Copper(I) Halides for High Efficiency Second Harmonic Generation with a Broadband Transparency Window13One-Center and Two-Center Self-Trapped Excitons in Zero-Dimensional Hybrid Copper Halides: Tricolor Luminescence with High Quantum Yields34Nonlinear Optical Benzoindolium-Based Single Crystals: H-Contacts Induced Noncentrosymmetric Alignment Approaching Efficient Terahertz-Wave Generation17Zero-Dimensional Molecular Ferroelectrics with Significant Nonlinear Effect and Giant Entropy33Two-Dimensional Hybrid Perovskitoid Micro/nanosheets: Colorful Ultralong Phosphorescence, Delayed Fluorescence, and Anisotropic Optical Waveguide20From H 12 C 4 N 2 CdI 4 to H 11 C 4 N 2 CdI 3 : a highly polarizable CdNI 3 tetrahedron induced a sharp enhancement of second harmonic generation response and birefringence50(C 5 N 2 H 14 )GeBr 4 : A 2D Organic Germanium Bromide Perovskite with Strong Orange Photoluminescence Properties21Efficient Solar Spectrum‐Like White‐Light Emission in Zinc‐Based Zero‐Dimensional Hybrid Metal Halides37Designing a Dimension Reduced Hybrid Perovskite with Robust Large Birefringence by Expanding Cationic π‐Delocation40Second-Harmonic Generation in Homochiral Antimony Halides Directed by l -Histidine24A review of the relationship between the structure and nonlinear optical properties of organic-inorganic hybrid materials149Advancing nonlinear optics: discovery and characterization of new non-centrosymmetric phenazine-based halides6Long-Persistent High-Temperature Phosphorescence of Zero-Dimensional Metal Halide Hybrid for Temperature-Sensitive Anticounterfeiting12Polymorphism and Red Photoluminescence Emission from 5s2 Electron Pairs of Sb(III) in a New One-Dimensional Organic–Inorganic Hybrid Based on Methylhydrazine: MHy2SbI581D Tin(II)‐Based Chiral Hybrid Perovskite Single Crystals with Extremely Distorted Inorganic Chains for Second Harmonic Generation38Near‐Infrared Light Emitting Metal Halides: Materials, Mechanisms, and Applications168Synthesis, Structure, and Optical Properties of a 0D Hybrid Organic–Inorganic Metal Halide (C 5 N 2 H 14 Cl)GeCl 317Chiral Organic Cations and Distorted Inorganic Polyhedra Composing Metal Halide Nonlinear Optical Materials22Polar Thiazole Derivative-Induced Second Harmonic Response in Hybrid Bismuth Chlorate with Reversible Photochromism9Ferroelectric, Switchable Dielectric and Nonlinear Optical Properties in Inorganic–Organic Lead-Free 1D Hybrids Based on Bi(III) and Azetidine: (C3NH8)2[BiCl5], (C3NH8)2[BiBr5]9Chiral Bimetallic Cuprous-Lead Hybrid Iodide Single Crystals toward Occurrence of Second Harmonic Generation3(C 14 H 14 N 2 )MCl 4 (M = Zn, Cd): two hybrid metal halides exhibiting strong second harmonic generation responses, large birefringence, and broadband photoluminescence12Chiral organic hybrids for nonlinear optical applications and solvent-induced reversible red–yellow color change2Facile preparation and crystallographic characterization of a new zero-dimensional antimony (III)-based organic-inorganic material with white light emission properties6Pb:Sn Ratio-Driven Polytypism and Band Modulation in Photoresponsive Hexagonal Perovskitoids10Hybrid Bismuth Halide with Rich Polymorphism and Second Harmonic Generation Response8The 1D Hybrid Material Allylimidazolium Iodoantimonate: A Combined Experimental and Theoretical Study2Internally and externally induced chiral hybrid metal halide materials for advanced chiroptoelectronic applications23Single Crystal Growth and Characterization of Semi-Organic L-Phenylalanine Barium Chloride via Slow Evaporation Method0Radiation stability and microhardness enhancement in AgCl0.25Br0.75 – TlI scintillation materials0Covalent Linkage Engineering of a Bismuth Iodide Framework for Near‐Infrared‐Driven CO 2 ‐to‐C 2 Photoreduction in Aqueous Solution0

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  1. Antimony-doped enhanced photoluminescence quantum yield in zero-dimensional lead-free metal halide Rb 2 CsBiCl 6 crystals

    Inorganic Chemistry Frontiers · 2022-01-01

    Zhen Jia, Pifu Gong, Jing Wei Zhao, Mingxing Chen, Yonggang Wang, Zhigang Wang, Dong Yan, Mingjun Xia

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  2. Nearly one-fold enhancement in photoluminescence quantum yield for isostructural zero-dimensional hybrid antimony( iii ) bromides by supramolecular interaction adjustments

    Dalton Transactions · 2022-01-01

    Ying-Chen Peng, Shenghua Zhou, Jiance Jin, Qi Gu, Ting-Hui Zhuang, Liao‐Kuo Gong, Zeping Wang, Ke‐Zhao Du, Xiao‐Ying Huang

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  3. Symmetry breaking of A 3 M 2 X 9 -type perovskite derivatives induced by polar quaternary ammonium cations: achieving efficient nonlinear optical properties

    Dalton Transactions · 2022-01-01

    Jiajing Wu, Yue Guo, Wen‐Dong Yao, Wenlong Liu, Sheng‐Ping Guo

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  4. Thermal stable zinc-based hybrid halides with high external quantum efficiency as temperature detectors

    Journal of Materials Chemistry C · 2022-01-01

    Xusheng Zhang, Yan Xiong, Kunjie Liu, Na Wang, Liubing Fan, Weiwei Li, Xiaobin Zhao, Jing Wei Zhao, Quanlin Liu

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  5. Chiral Hybrid Copper(I) Halides for High Efficiency Second Harmonic Generation with a Broadband Transparency Window

    Angewandte Chemie International Edition · 2022-01-10

    Fei Ge, Bohan Li, Puxin Cheng, Geng Li, Zefeng Ren, Jialiang Xu, Xian‐He Bu

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  6. Chiral Hybrid Copper(I) Halides for High Efficiency Second Harmonic Generation with a Broadband Transparency Window

    Angewandte Chemie · 2022-01-10

    Fei Ge, Bohan Li, Puxin Cheng, Geng Li, Zefeng Ren, Jialiang Xu, Xian‐He Bu

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  7. One-Center and Two-Center Self-Trapped Excitons in Zero-Dimensional Hybrid Copper Halides: Tricolor Luminescence with High Quantum Yields

    The Journal of Physical Chemistry Letters · 2022-02-03

    Xiaoyu Liu, Yuanyuan Li, Tianyuan Liang, Wenjie Liu, Jiyang Fan

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  8. Nonlinear Optical Benzoindolium-Based Single Crystals: H-Contacts Induced Noncentrosymmetric Alignment Approaching Efficient Terahertz-Wave Generation

    Crystal Growth & Design · 2022-04-08

    Weifeng Zhang, Zelong Wang, Xinyuan Zhang, Yuye Wang, Degang Xu, Zhanggui Hu, Jianquan Yao, Yicheng Wu

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  9. Zero-Dimensional Molecular Ferroelectrics with Significant Nonlinear Effect and Giant Entropy

    Chemistry of Materials · 2022-07-07

    Wen‐Juan Wei, Hongqiang Gao, Yang Yang, Ming Fang, Xiaodan Wang, Xi Chen, Wei-Long Qin, Gen-Qiang Chen, Ruo-Xin Li, Yun‐Zhi Tang, Yen Wei

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  10. Two-Dimensional Hybrid Perovskitoid Micro/nanosheets: Colorful Ultralong Phosphorescence, Delayed Fluorescence, and Anisotropic Optical Waveguide

    ACS Applied Materials & Interfaces · 2022-08-23

    Meiqi Dai, Bo Zhou, Xiaoyu Fang, Dongpeng Yan

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  11. From H 12 C 4 N 2 CdI 4 to H 11 C 4 N 2 CdI 3 : a highly polarizable CdNI 3 tetrahedron induced a sharp enhancement of second harmonic generation response and birefringence

    Chemical Science · 2023-01-01

    Huai‐Yu Wu, Chun‐Li Hu, Miao‐Bin Xu, Qianqian Chen, Nan Ma, Xiao‐Ying Huang, Ke‐Zhao Du, Jin Chen

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  12. (C 5 N 2 H 14 )GeBr 4 : A 2D Organic Germanium Bromide Perovskite with Strong Orange Photoluminescence Properties

    Inorganic Chemistry · 2023-01-05

    Nan He, Pifu Gong, Xingyu Zhang, Youquan Liu, Linfeng Dong, Zheshuai Lin

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  13. Efficient Solar Spectrum‐Like White‐Light Emission in Zinc‐Based Zero‐Dimensional Hybrid Metal Halides

    Advanced Optical Materials · 2023-04-27

    Shihui He, Shiqiang Hao, Liubing Fan, Kunjie Liu, Chuxin Cai, Christopher Wolverton, Jing Wei Zhao, Quanlin Liu

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  14. Designing a Dimension Reduced Hybrid Perovskite with Robust Large Birefringence by Expanding Cationic π‐Delocation

    Small · 2023-08-24

    Qian-Ting Xu, Weiqi Huang, Han Wang, Yanqiang Li, Zhou Yang, Linxi Hou, Sangen Zhao, Junhua Luo

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  15. Second-Harmonic Generation in Homochiral Antimony Halides Directed by l -Histidine

    Inorganic Chemistry · 2023-10-02

    Juan Cheng, Peiqi Qian, Meng Yang, Ling Huang, Hongmei Zeng, Guohong Zou, Zhien Lin

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  16. A review of the relationship between the structure and nonlinear optical properties of organic-inorganic hybrid materials

    Coordination Chemistry Reviews · 2023-10-06

    Yuwei Kang, Qi Wu

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  17. Advancing nonlinear optics: discovery and characterization of new non-centrosymmetric phenazine-based halides

    Dalton Transactions · 2024-01-01

    Yibo Cui, Jindong Cao, Jiawei Lin, Chunxiao Li, Jiyong Yao, Kunjie Liu, An Hou, Zhongnan Guo, Jing Wei Zhao, Quanlin Liu

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  18. Long-Persistent High-Temperature Phosphorescence of Zero-Dimensional Metal Halide Hybrid for Temperature-Sensitive Anticounterfeiting

    ACS Applied Nano Materials · 2024-01-04

    Yuerong Xie, Juntao Peng, Qianyang Qin, Binbin Luo

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  19. Polymorphism and Red Photoluminescence Emission from 5s2 Electron Pairs of Sb(III) in a New One-Dimensional Organic–Inorganic Hybrid Based on Methylhydrazine: MHy2SbI5

    Molecules · 2024-01-17

    Magdalena Rowińska, Dagmara Stefańska, Tamara J. Bednarchuk, Jan K. Zaręba, R. Jakubas, Anna Gągor

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  20. 1D Tin(II)‐Based Chiral Hybrid Perovskite Single Crystals with Extremely Distorted Inorganic Chains for Second Harmonic Generation

    Advanced Optical Materials · 2024-02-17

    Kezheng Tao, Qiang Li, Qingfeng Yan

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  21. Near‐Infrared Light Emitting Metal Halides: Materials, Mechanisms, and Applications

    Advanced Materials · 2024-02-21

    Ying Liu, Francesco Di Stasio, Chenghao Bi, Jibin Zhang, Zhiguo Xia, Zhifeng Shi, Liberato Manna

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  22. Synthesis, Structure, and Optical Properties of a 0D Hybrid Organic–Inorganic Metal Halide (C 5 N 2 H 14 Cl)GeCl 3

    Inorganic Chemistry · 2024-02-21

    Y Li, Nan He, Bohui Xu, Linfeng Dong, Xingyu Zhang, Jing J. Xu, Pifu Gong, Zheshuai Lin

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  23. Chiral Organic Cations and Distorted Inorganic Polyhedra Composing Metal Halide Nonlinear Optical Materials

    Laser & Photonics Review · 2024-06-05

    Kunjie Liu, Jing Wei Zhao, Quanlin Liu

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  24. Polar Thiazole Derivative-Induced Second Harmonic Response in Hybrid Bismuth Chlorate with Reversible Photochromism

    Inorganic Chemistry · 2024-09-23

    Ting-Jie Wang, Jin-Shuang Guo, Ning‐Ning Zhang, Yu Li, Cuncheng Li, Guang‐Ning Liu

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  25. Ferroelectric, Switchable Dielectric and Nonlinear Optical Properties in Inorganic–Organic Lead-Free 1D Hybrids Based on Bi(III) and Azetidine: (C3NH8)2[BiCl5], (C3NH8)2[BiBr5]

    The Journal of Physical Chemistry Letters · 2024-11-15

    Magdalena Rok, Bartosz Zarychta, Jan K. Zaręba, Aleksandra Krupińska, Błażej Dziuk, Piotr Durlak, Rafał Janicki, R. Jakubas, G. Bator, W. Medycki, Michaela Zamponi, Anna Piecha‐Bisiorek

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  26. Chiral Bimetallic Cuprous-Lead Hybrid Iodide Single Crystals toward Occurrence of Second Harmonic Generation

    Inorganic Chemistry · 2024-12-02

    Danping Chen, Peihan Wang, Yanqing Liu, Guokui Liu, Jing Wei, Yongshen Zheng, Yangyang Dang

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  27. (C 14 H 14 N 2 )MCl 4 (M = Zn, Cd): two hybrid metal halides exhibiting strong second harmonic generation responses, large birefringence, and broadband photoluminescence

    Inorganic Chemistry Frontiers · 2025-01-01

    Xinhui Li, Pifu Gong, Mingxing Chen, Shujuan Zhuang, Man Qi, Wenqiang Wang, Xinfang Wang, Zhen Jia, Mingjun Xia

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  28. Chiral organic hybrids for nonlinear optical applications and solvent-induced reversible red–yellow color change

    Dalton Transactions · 2025-01-01

    Hongli Yu, Ruibin Hao, Dong Lin Zhao, Lingyu Chi, Xianlong Zhao, Yibo Cui, Kunjie Liu, Jing Wei Zhao, Quanlin Liu

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  29. Facile preparation and crystallographic characterization of a new zero-dimensional antimony (III)-based organic-inorganic material with white light emission properties

    Journal of Molecular Structure · 2025-04-09

    Sahar Jarboui, Chakib Hrizi, Ali Ben Ahmed, Michael Knorr, Annika Schmidt, Carsten Strohmann, Fatma Zouari

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  30. Pb:Sn Ratio-Driven Polytypism and Band Modulation in Photoresponsive Hexagonal Perovskitoids

    Journal of the American Chemical Society · 2025-06-06

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  31. Hybrid Bismuth Halide with Rich Polymorphism and Second Harmonic Generation Response

    ACS Materials Letters · 2025-07-07

    Aleksandra D. Valueva, Sergei A. Novikov, Eric A. Gabilondo, Hunter B. Tisdale, Alevtina A. Maksimova, Mikhail Parker, Vladimir V. Reukov, Vladislav V. Klepov

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  32. The 1D Hybrid Material Allylimidazolium Iodoantimonate: A Combined Experimental and Theoretical Study

    Inorganics · 2025-07-15

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  33. Internally and externally induced chiral hybrid metal halide materials for advanced chiroptoelectronic applications

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  34. Single Crystal Growth and Characterization of Semi-Organic L-Phenylalanine Barium Chloride via Slow Evaporation Method

    Proceedings of the National Academy of Sciences India Section A Physical Sciences · 2026-06-24

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  35. Radiation stability and microhardness enhancement in AgCl0.25Br0.75 – TlI scintillation materials

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  36. Covalent Linkage Engineering of a Bismuth Iodide Framework for Near‐Infrared‐Driven CO 2 ‐to‐C 2 Photoreduction in Aqueous Solution

    Advanced Materials · 2026-09-29

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