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RESEARCH PAPER · Angewandte Chemie · 2019

A Niobium Oxyiodate Sulfate with a Strong Second‐Harmonic‐Generation Response Built by Rational Multi‐Component Design

Hong‐Xin Tang, Yu‐Xiao Zhang, Chao Zhuo, Ruibiao Fu, Hua Lin, Zuju Ma, Xin‐Tao Wu

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A Niobium Oxyiodate Sulfate with a Strong Second‐Harmonic‐Generation Response Built by Rational Multi‐Component DesignOriginal(H 3 O)HCs 2 Nb(IO 3 ) 9 and SrNbO(IO 3 ) 5 : a facile synthetic method using hydrofluoric acid as a solubilizer19Cs 2 CdV 2 O 6 Cl 2 and Cs 3 CdV 4 O 12 Br: two new non-centrosymmetric oxyhalides containing d 0 and d 10 cations and exhibiting second harmonic generation activity19REI5O14 (RE=Y and Gd): Promising SHG Materials Featuring the Semicircle‐Shaped I5O143− Polyiodate Anion125REI5O14 (RE=Y and Gd): Promising SHG Materials Featuring the Semicircle‐Shaped I5O143− Polyiodate Anion62LiMII(IO3)3 (MII=Zn and Cd): Two Promising Nonlinear Optical Crystals Derived from a Tunable Structure Model of α‐LiIO398LiMII(IO3)3 (MII=Zn and Cd): Two Promising Nonlinear Optical Crystals Derived from a Tunable Structure Model of α‐LiIO337Cs 3 Pb 2 (CH 3 COO) 2 X 5 (X=I, Br): Halides with Strong Second‐Harmonic Generation Response Induced by Acetate Groups75Cs3Pb2(CH3COO)2X5 (X=I, Br): Halides with Strong Second‐Harmonic Generation Response Induced by Acetate Groups22Sb6O7(SO4)2: A Promising Ultraviolet Nonlinear Optical Material with an Enhanced Second‐Harmonic‐Generation Response Activated by SbIII Lone‐Pair Stereoactivity62Zn(NH 3 )CO 3 : a “three-in-one” UV nonlinear optical crystal built by a polar molecule bonding strategy18Be2(BO3)(IO3): The First Anion‐mixed Van der Waals Member in the KBe2BO3F2 Family with a Very Strong Second Harmonic Generation Response130Be2(BO3)(IO3): The First Anion‐mixed Van der Waals Member in the KBe2BO3F2 Family with a Very Strong Second Harmonic Generation Response8[ o ‐C 5 H 4 NHOH] 2 [I 7 O 18 (OH)]⋅3 H 2 O: An Organic–Inorganic Hybrid SHG Material Featuring an [I 7 O 18 (OH)] Branched Polyiodate Chain86[o‐C5H4NHOH]2[I7O18(OH)]⋅3 H2O: An Organic–Inorganic Hybrid SHG Material Featuring an [I7O18(OH)] Branched Polyiodate Chain21KCs2[Pb2Br5(HCOO)2]: A Polar 3D Lead‐Bromide Framework Exhibiting Strong Second‐Harmonic Generation Response10High‐Performance Sulfate Optical Materials Exhibiting Giant Second Harmonic Generation and Large Birefringence21High‐Performance Sulfate Optical Materials Exhibiting Giant Second Harmonic Generation and Large Birefringence199Explorations of New SHG Materials in Mercury Iodate Sulfate System**9A strategy to design nonlinear optical materials: Self‐assembling by π ‐ π stacking2Nonlinear optical inorganic sulfates: The improvement of the phase matching ability driven by the structural modulation41Design, Synthesis, Crystal Structure, and Thermal Studies of Ni0.779SbF3(SO4): A New Electrode Material for Electrochemical Supercapacitors8Lanthanide Contraction Eliminates Disorder while Holding Robust Second Harmonic Generation in a Series of Polyiodates13The design of a non-centrosymmetric structure in sulfates by cation-induced symmetry breaking4Cation‐Dominated Second‐Order Nonlinear Optical Response Enabled by π‐Conjugated Guanidinium Derivatives0β‐Hexasubstituted Porphyrins: Synthesis, Photophysical, Electrochemical, DFT Analysis, and Femtosecond Third‐Order Nonlinear Optical Properties0

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  1. (H 3 O)HCs 2 Nb(IO 3 ) 9 and SrNbO(IO 3 ) 5 : a facile synthetic method using hydrofluoric acid as a solubilizer

    Chemical Communications · 2019-01-01

    Fei‐Fei Mao, Chun‐Li Hu, Jin Chen, Ru‐Ling Tang, Bao-Lin Wu, Jiang‐Gao Mao

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  2. Cs 2 CdV 2 O 6 Cl 2 and Cs 3 CdV 4 O 12 Br: two new non-centrosymmetric oxyhalides containing d 0 and d 10 cations and exhibiting second harmonic generation activity

    Dalton Transactions · 2019-01-01

    Yanjun Li, Dan Zhang, Lili Liu, Weiguo Zhang, Jiang Zhang, Ye Cong, Xuanke Li, P. Shiv Halasyamani

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  3. REI5O14 (RE=Y and Gd): Promising SHG Materials Featuring the Semicircle‐Shaped I5O143− Polyiodate Anion

    Angewandte Chemie International Edition · 2019-06-18

    Jin Chen, Chun‐Li Hu, Fei‐Fei Mao, Bing‐Ping Yang, Xiao‐Han Zhang, Jiang‐Gao Mao

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  4. REI5O14 (RE=Y and Gd): Promising SHG Materials Featuring the Semicircle‐Shaped I5O143− Polyiodate Anion

    Angewandte Chemie · 2019-06-18

    Jin Chen, Chun‐Li Hu, Fei‐Fei Mao, Bing‐Ping Yang, Xiaohan Zhang, Jiang‐Gao Mao

    Read original paper ↗ ·

  5. LiMII(IO3)3 (MII=Zn and Cd): Two Promising Nonlinear Optical Crystals Derived from a Tunable Structure Model of α‐LiIO3

    Angewandte Chemie International Edition · 2019-09-20

    Ying‐Jie Jia, Yi-Gang Chen, Yao Guo, Xiao‐Fang Guan, Chengbo Li, Bingxuan Li, Minmin Liu, Xian‐Ming Zhang

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  6. LiMII(IO3)3 (MII=Zn and Cd): Two Promising Nonlinear Optical Crystals Derived from a Tunable Structure Model of α‐LiIO3

    Angewandte Chemie · 2019-09-20

    Ying‐Jie Jia, Yi-Gang Chen, Yao Guo, Xiao‐Fang Guan, Chengbo Li, Bingxuan Li, Min‐Min Liu, Xian‐Ming Zhang

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  7. Cs 3 Pb 2 (CH 3 COO) 2 X 5 (X=I, Br): Halides with Strong Second‐Harmonic Generation Response Induced by Acetate Groups

    Angewandte Chemie International Edition · 2020-10-14

    Qirui Shui, Hong‐Xin Tang, Ruibiao Fu, Yuan‐Bin Fang, Zuju Ma, Xintao Wu

    Read original paper ↗ ·

  8. Cs3Pb2(CH3COO)2X5 (X=I, Br): Halides with Strong Second‐Harmonic Generation Response Induced by Acetate Groups

    Angewandte Chemie · 2020-10-15

    Qirui Shui, Hong‐Xin Tang, Ruibiao Fu, Yuan‐Bin Fang, Zuju Ma, Xintao Wu

    Read original paper ↗ ·

  9. Sb6O7(SO4)2: A Promising Ultraviolet Nonlinear Optical Material with an Enhanced Second‐Harmonic‐Generation Response Activated by SbIII Lone‐Pair Stereoactivity

    Chemistry - A European Journal · 2020-12-23

    Qi Wei, Chao He, Kui Wang, Xiao‐Fang Duan, Xing‐Tao An, Jinhua Li, Guo‐Ming Wang

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  10. Zn(NH 3 )CO 3 : a “three-in-one” UV nonlinear optical crystal built by a polar molecule bonding strategy

    Journal of Materials Chemistry C · 2021-01-01

    Hong‐Xin Tang, Qirui Shui, Ruibiao Fu, Ziqi Zhou, Wen-Xiu Bao, Zuju Ma, Xin‐Tao Wu

    Read original paper ↗ ·

  11. Be2(BO3)(IO3): The First Anion‐mixed Van der Waals Member in the KBe2BO3F2 Family with a Very Strong Second Harmonic Generation Response

    Angewandte Chemie International Edition · 2021-05-26

    Guang Peng, Chensheng Lin, Huixin Fan, Kaichuang Chen, Bingxuan Li, Ge Zhang, Ning Ye

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  12. Be2(BO3)(IO3): The First Anion‐mixed Van der Waals Member in the KBe2BO3F2 Family with a Very Strong Second Harmonic Generation Response

    Angewandte Chemie · 2021-05-26

    Guang Peng, Chensheng Lin, Huixin Fan, Kaichuang Chen, Bingxuan Li, Ge Zhang, Ning Ye

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  13. [ o ‐C 5 H 4 NHOH] 2 [I 7 O 18 (OH)]⋅3 H 2 O: An Organic–Inorganic Hybrid SHG Material Featuring an [I 7 O 18 (OH)] Branched Polyiodate Chain

    Angewandte Chemie International Edition · 2021-05-31

    Qian‐Qian Chen, Chun‐Li Hu, Jin Chen, Yilin Li, Bingxuan Li, Jiang‐Gao Mao

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  14. [o‐C5H4NHOH]2[I7O18(OH)]⋅3 H2O: An Organic–Inorganic Hybrid SHG Material Featuring an [I7O18(OH)] Branched Polyiodate Chain

    Angewandte Chemie · 2021-06-01

    Qian‐Qian Chen, Chun‐Li Hu, Jin Chen, Yilin Li, Bingxuan Li, Jiang‐Gao Mao

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  15. KCs2[Pb2Br5(HCOO)2]: A Polar 3D Lead‐Bromide Framework Exhibiting Strong Second‐Harmonic Generation Response

    Chemistry - A European Journal · 2021-07-14

    Ziqi Zhou, Qirui Shui, Ruibiao Fu, Yuan‐Bin Fang, Zuju Ma, Xin‐Tao Wu

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  16. High‐Performance Sulfate Optical Materials Exhibiting Giant Second Harmonic Generation and Large Birefringence

    Angewandte Chemie · 2022-01-04

    Xuehua Dong, Ling Huang, Hongmei Zeng, Zhien Lin, Kang Min Ok, Guohong Zou

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  17. High‐Performance Sulfate Optical Materials Exhibiting Giant Second Harmonic Generation and Large Birefringence

    Angewandte Chemie International Edition · 2022-01-04

    Xuehua Dong, Ling Huang, Hongmei Zeng, Zhien Lin, Kang Min Ok, Guohong Zou

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  18. Explorations of New SHG Materials in Mercury Iodate Sulfate System**

    Chemistry - A European Journal · 2022-02-14

    Yilin Li, Mengya Ji, Chun‐Li Hu, Jin Chen, Bingxuan Li, Yuan Hua Lin, Jiang‐Gao Mao

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  19. A strategy to design nonlinear optical materials: Self‐assembling by π ‐ π stacking

    Journal of the Chinese Chemical Society · 2022-08-04

    Bo Li, Liang Peng, Chao Xu, Feng Long Gu

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  20. Nonlinear optical inorganic sulfates: The improvement of the phase matching ability driven by the structural modulation

    Coordination Chemistry Reviews · 2023-08-02

    Yanran Shang, Junxin Xu, Hongyuan Sha, Zujian Wang, Chao He, Rongbing Su, Xiaoming Yang, Xifa Long

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  21. Design, Synthesis, Crystal Structure, and Thermal Studies of Ni0.779SbF3(SO4): A New Electrode Material for Electrochemical Supercapacitors

    Crystal Growth & Design · 2023-10-18

    Sangita Das, Sayantani Paul, Bibaswan Sen, Siriyara Jagannatha Prathapa, Sk Jahir Abbas, Asoke Prasun Chattopadhyay, S. Ali

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  22. Lanthanide Contraction Eliminates Disorder while Holding Robust Second Harmonic Generation in a Series of Polyiodates

    Chemistry of Materials · 2024-10-04

    Zhenhua Li, Yi Shui, Zhengli Liang, Lehui Liu, Jiahao Wan, Xingxing Jiang, Zheshuai Lin, Hongming Liu

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  23. The design of a non-centrosymmetric structure in sulfates by cation-induced symmetry breaking

    Journal of Materials Chemistry C · 2024-11-19

    Yanran Shang, Hongyuan Sha, Dongling Yang, Zhian Li, Zujian Wang, Chao He, Rongbing Su, Bin Su, Xiaoming Yang, Xifa Long

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  24. Cation‐Dominated Second‐Order Nonlinear Optical Response Enabled by π‐Conjugated Guanidinium Derivatives

    Angewandte Chemie · 2026-04-09

    Bohui Xu, Pifu Gong, Deshuai Xiao, Xuanlin Pan, Fan Liu, Xinyuan Zhang, Z. Sheng Z. Lin

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  25. β‐Hexasubstituted Porphyrins: Synthesis, Photophysical, Electrochemical, DFT Analysis, and Femtosecond Third‐Order Nonlinear Optical Properties

    ChemistrySelect · 2026-09-01

    Waseem Arif, Supriya Pradhan, Niharika Pradhan, Amir Sohel Bulbul, Atta Ullah Kaleem, Kizafa Aftab, S. Venugopal Rao, Ravi Kumar

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