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RESEARCH PAPER · Angewandte Chemie · 2019

LiMII(IO3)3 (MII=Zn and Cd): Two Promising Nonlinear Optical Crystals Derived from a Tunable Structure Model of α‐LiIO3

Ying‐Jie Jia, Yi-Gang Chen, Yao Guo, Xiao‐Fang Guan, Chengbo Li, Bingxuan Li, Min‐Min Liu, Xian‐Ming Zhang

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LiMII(IO3)3 (MII=Zn and Cd): Two Promising Nonlinear Optical Crystals Derived from a Tunable Structure Model of α‐LiIO3OriginalEmergent Deep‐Ultraviolet Nonlinear Optical Candidates324Neue Kandidaten für die nichtlineare Optik im Tief‐UV‐Bereich43From centrosymmetric to noncentrosymmetric: intriguing structure evolution in d 10 -transition metal iodate fluorides36Large nonlinear optical effect in tungsten bronze structures via Li/Na cross-substitutions4M 4 LiBe 4 P 7 O 24 and M 4 Li(Li 3 P)P 7 O 24 (M = Cs, Rb): deep-ultraviolet nonlinear-optical phosphates with a tetrahedra-substituted paracelsian-like framework9Rational Design of the Nonlinear Optical Response in a Tin Iodate Fluoride Sn(IO3)2F290K2Na(IO3)2(I3O8) with Strong Second Harmonic Generation Response Activated by Two Types of Isolated Iodate Anions46High Coordinate Metal Iodate Chlorides with Diverse Structural Motifs and Tunable Birefringence10Ba2[MoO3(OH)(IO3)2]IO3: A Promising SHG Material Featuring a Λ-Shaped Functional Motif Achieved by Universal Mono-Site Substitution50Fluorine Substitution in Ethylamine Triggers Second Harmonic Generation in Noncentrosymmetric Crystalline [NH3CH2CH2F]3BiCl632Enhanced Proton Conductivity by Aliovalent Substitution of Cadmium for Indium in Dimethylaminium-Templated Metal Anilicates29Recent Advances in Oxide‐based Nonlinear Optical Materials with Wide Infrared Transparency Beyond 6 μm38From Ag2Zr(IO3)6 to LaZr(IO3)5F2: A Case of Constructing Wide‐band‐gap Birefringent Materials through Chemical Cosubstitution11An inherently kidney-targeting near-infrared fluorophore based probe for early detection of acute kidney injury59Methylation Design Strategy to Trigger a Dual Dielectric Switch and Improve the Phase Transition Temperature13Bi 32 Cd 3 P 10 O 76 : a new congruently melting nonlinear optical crystal with a large SHG response and a wide transparent region24Simple New Method for the Preparation of La(IO3)3 Nanoparticles6A new nonlinear optical sulfate of layered structure: Cs2Zn2(SO4)319Chiral Template‐Driven Macroscopic Chirality Control: Structure‐Second‐Harmonic Generation Properties Relationship24High-Pressure Spectroscopy Study of Zn(IO3)2 Using Far-Infrared Synchrotron Radiation12[GaF(H 2 O)][IO 3 F]: a promising NLO material obtained by anisotropic polycation substitution42Pressure-dependent modifications in the optical and electronic properties of Fe(IO 3 ) 3 : the role of Fe 3d and I 5p lone–pair electrons15SrTi(IO 3 ) 6 ·2H 2 O and SrSn(IO 3 ) 6 : distinct arrangements of lone pair electrons leading to large birefringences11Na3Bi(IO3)6: An Alkali-Metal Bismuth Iodate with Intriguing One-Dimensional [BiI6O18] Chains and Pressure-Induced Structural Transition11Cd3(IO3)(IO4)F2·0.1CdO: A Nonlinear-Optical Crystal with the Introduction of Fluoride into Iodate Containing Both [IO3]− and [IO4]3– Groups18CsZrF4(IO3): The First Polar Zirconium Iodate with cis-[ZrO2F6] Polyhedra Inducing Optimized Balance of Large Band Gap and Second Harmonic Generation47Tin Chloride Sulfates A3Sn2(SO4)3–xCl1+2x (A = K, Rb, Cs; x = 0, 1) as Multifunctional Optical Materials33Sr2Pb(BeB5O10)(BO3): An Excellent Ultraviolet Nonlinear-Optical Beryllium Borate by the Pb-Modified Construction of a Conjugated System and Lone-Pair Effect14Synthesis, Structure, Characterization, and Calculation of a Noncentrosymmetric Fluorine-Containing Indium Iodate, Ba[InF3(IO3)2]10Fe–Co based synergistic catalytic graphitization of biomass: Influence of the catalyst type and the pyrolytic temperature117Ca-cluster-constructed deep-ultraviolet nonlinear-optical crystal Na2Ca17Al2(PO4)14 with strong NLO response11Synthesis and Characterization of Novel Nanoparticles of Lithium Aluminum Iodate LiAl(IO3)4, and DFT Calculations of the Crystal Structure and Physical Properties6Explorations of New SHG Materials in Mercury Iodate Sulfate System**9Novel experimental methodology and optical analysis of (Ni, Co, Fe, and Cr) iodate nanocrystals3Diversity of [M(IO3)6] Building Blocks in Iodate Families and the New Trigonal Polymorph of Cs2HIn(IO3)64Diversity of fundamental building blocks [M(IO3)6] in iodate families and new trigonal polymorph of Cs2HIn(IO3)60The Multi‐Scale Paradigm: An Integrated Design Logic for Nonlinear Optical Crystals0

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  1. Emergent Deep‐Ultraviolet Nonlinear Optical Candidates

    Angewandte Chemie International Edition · 2019-12-10

    Miriding Mutailipu, Shilie Pan

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  2. Neue Kandidaten für die nichtlineare Optik im Tief‐UV‐Bereich

    Angewandte Chemie · 2019-12-10

    Miriding Mutailipu, Shilie Pan

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  3. From centrosymmetric to noncentrosymmetric: intriguing structure evolution in d 10 -transition metal iodate fluorides

    Chemical Communications · 2020-01-01

    Liling Cao, Min Luo, Chensheng Lin, Yuqiao Zhou, Dan Zhao, Tao Yan, Ning Ye

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  4. Large nonlinear optical effect in tungsten bronze structures via Li/Na cross-substitutions

    Chemical Communications · 2020-01-01

    Shihang Chu, Kun Lin, Tao Yang, Chengyi Yu, Yili Cao, Yujuan Zhang, Yujiao Sun, Zerui Li, Xingxing Jiang, Zheshuai Lin, Qiang Li, Jun Chen, Kenichi Kato, Hui Wu, Qingzhen Huang, Xianran Xing

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  5. M 4 LiBe 4 P 7 O 24 and M 4 Li(Li 3 P)P 7 O 24 (M = Cs, Rb): deep-ultraviolet nonlinear-optical phosphates with a tetrahedra-substituted paracelsian-like framework

    Chemical Communications · 2020-01-01

    Yi-Gang Chen, Chunyu Yang, Fang Wang, Yao Guo, Xingxing Jiang, Xian‐Ming Zhang

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  6. Rational Design of the Nonlinear Optical Response in a Tin Iodate Fluoride Sn(IO3)2F2

    Chemistry of Materials · 2020-03-03

    Min Luo, Fei Liang, Xia Hao, Donghong Lin, Bingxuan Li, Zheshuai Lin, Ning Ye

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  7. K2Na(IO3)2(I3O8) with Strong Second Harmonic Generation Response Activated by Two Types of Isolated Iodate Anions

    Chemistry of Materials · 2020-04-02

    Tushagu Abudouwufu, Min Zhang, Shichao Cheng, Hao Zeng, Zhihua Yang, Shilie Pan

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  8. High Coordinate Metal Iodate Chlorides with Diverse Structural Motifs and Tunable Birefringence

    Crystal Growth & Design · 2020-07-07

    Ying‐Jie Jia, Yi-Gang Chen, Ting Wang, Yao Guo, Xiao‐Fang Guan, Xian‐Ming Zhang

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  9. Ba2[MoO3(OH)(IO3)2]IO3: A Promising SHG Material Featuring a Λ-Shaped Functional Motif Achieved by Universal Mono-Site Substitution

    Chemistry of Materials · 2020-07-24

    Q. Huang, Chun‐Li Hu, Bing‐Ping Yang, Ru‐Ling Tang, Jin Chen, Zhi Gang Fang, Bingxuan Li, Jiang‐Gao Mao

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  10. Fluorine Substitution in Ethylamine Triggers Second Harmonic Generation in Noncentrosymmetric Crystalline [NH3CH2CH2F]3BiCl6

    Chemistry of Materials · 2020-07-29

    Lulu Chu, Tie Zhang, Ya-Fang Gao, Wan‐Ying Zhang, Ping‐Ping Shi, Qiong Ye, Da‐Wei Fu

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  11. Enhanced Proton Conductivity by Aliovalent Substitution of Cadmium for Indium in Dimethylaminium-Templated Metal Anilicates

    ACS Applied Materials & Interfaces · 2020-08-20

    Hui Gao, Yanbin He, Juan‐Juan Hou, Quan‐Guo Zhai, Xian‐Ming Zhang

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  12. Recent Advances in Oxide‐based Nonlinear Optical Materials with Wide Infrared Transparency Beyond 6 μm

    Chemistry - An Asian Journal · 2020-09-21

    Xinglong Chen, Kang Min Ok

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  13. From Ag2Zr(IO3)6 to LaZr(IO3)5F2: A Case of Constructing Wide‐band‐gap Birefringent Materials through Chemical Cosubstitution

    Chemistry - An Asian Journal · 2020-09-25

    Fei‐Fei Mao, Jiadi Liu, Jinyu Hu, Hua Wu

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  14. An inherently kidney-targeting near-infrared fluorophore based probe for early detection of acute kidney injury

    Biosensors and Bioelectronics · 2020-10-21

    Fangqin Wang, Xuefeng Jiang, Huaijiang Xiang, Ning Wang, Yunjing Zhang, Xi Yao, Ping Wang, Hao Pan, Li-Fang Yu, Yunfeng Cheng, Yongzhou Hu, Weiqiang Lin, Xin Li

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  15. Methylation Design Strategy to Trigger a Dual Dielectric Switch and Improve the Phase Transition Temperature

    Inorganic Chemistry · 2020-10-25

    Jia Chen Wang, Tie Zhang, Zhi‐Xu Zhang, Chang‐Yuan Su, Yi Zhang, Da‐Wei Fu

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  16. Bi 32 Cd 3 P 10 O 76 : a new congruently melting nonlinear optical crystal with a large SHG response and a wide transparent region

    Inorganic Chemistry Frontiers · 2020-10-29

    Jiankang Wang, Binkai Xiong, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  17. Simple New Method for the Preparation of La(IO3)3 Nanoparticles

    Nanomaterials · 2020-11-30

    Zoulikha Hebboul, Amira Ghozlane, Robin Turnbull, Ali Benghia, Sara Allaoui, Akun Liang, Daniel Errandonea, Amina Touhami, Abdellah Rahmani, Ibn Khaldoun Lefkaier

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  18. A new nonlinear optical sulfate of layered structure: Cs2Zn2(SO4)3

    Inorganic Chemistry Communications · 2020-12-07

    Youchao Liu, Yanqiang Li, Zhou Yang, Qingran Ding, Yangxin Chen, Sangen Zhao, Junhua Luo

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  19. Chiral Template‐Driven Macroscopic Chirality Control: Structure‐Second‐Harmonic Generation Properties Relationship

    European Journal of Inorganic Chemistry · 2020-12-22

    Hongil Jo, Xinglong Chen, Hee‐Seung Lee, Kang Min Ok

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  20. High-Pressure Spectroscopy Study of Zn(IO3)2 Using Far-Infrared Synchrotron Radiation

    Crystals · 2020-12-30

    Akun Liang, Robin Turnbull, Enrico Bandiello, Ibraheem Yousef, Cătălin Popescu, Zoulikha Hebboul, Daniel Errandonea

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  21. [GaF(H 2 O)][IO 3 F]: a promising NLO material obtained by anisotropic polycation substitution

    Chemical Science · 2021-01-01

    Q. Huang, Chun‐Li Hu, Bing‐Ping Yang, Zhi Gang Fang, Yuan Hua Lin, Jin Chen, Bingxuan Li, Jiang‐Gao Mao

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  22. Pressure-dependent modifications in the optical and electronic properties of Fe(IO 3 ) 3 : the role of Fe 3d and I 5p lone–pair electrons

    Inorganic Chemistry Frontiers · 2021-01-01

    Akun Liang, Plácida Rodríguez-Hernández, Alfonso Muñoz, Saqib Rahman, Alfredo Segura, Daniel Errandonea

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  23. SrTi(IO 3 ) 6 ·2H 2 O and SrSn(IO 3 ) 6 : distinct arrangements of lone pair electrons leading to large birefringences

    RSC Advances · 2021-01-01

    Kaitong Liu, Jian Wei Han, Junben Huang, Zhonglei Wei, Zhihua Yang, Shilie Pan

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  24. Na3Bi(IO3)6: An Alkali-Metal Bismuth Iodate with Intriguing One-Dimensional [BiI6O18] Chains and Pressure-Induced Structural Transition

    Inorganic Chemistry · 2021-02-11

    Huimin Song, Dequan Jiang, Naizheng Wang, Wenhao Xing, Ruixin Guo, Zheshuai Lin, Jiyong Yao, Yonggang Wang, Heng Tu, Guochun Zhang

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  25. Cd3(IO3)(IO4)F2·0.1CdO: A Nonlinear-Optical Crystal with the Introduction of Fluoride into Iodate Containing Both [IO3]− and [IO4]3– Groups

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  26. CsZrF4(IO3): The First Polar Zirconium Iodate with cis-[ZrO2F6] Polyhedra Inducing Optimized Balance of Large Band Gap and Second Harmonic Generation

    Chemistry of Materials · 2021-05-07

    Lin Lin, Xingxing Jiang, Chao Wu, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  27. Tin Chloride Sulfates A3Sn2(SO4)3–xCl1+2x (A = K, Rb, Cs; x = 0, 1) as Multifunctional Optical Materials

    Inorganic Chemistry · 2021-05-14

    Yuwei Ge, Qiang Wang, Fei Yang, Ling Huang, Daojiang Gao, Jian Bi, Guohong Zou

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  28. Sr2Pb(BeB5O10)(BO3): An Excellent Ultraviolet Nonlinear-Optical Beryllium Borate by the Pb-Modified Construction of a Conjugated System and Lone-Pair Effect

    Inorganic Chemistry · 2021-06-18

    Zhe Dai, Yi-Gang Chen, Yao Guo, Fang Wang, Yuanyu Yang, Xian‐Ming Zhang

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  29. Synthesis, Structure, Characterization, and Calculation of a Noncentrosymmetric Fluorine-Containing Indium Iodate, Ba[InF3(IO3)2]

    Crystal Growth & Design · 2021-06-24

    Xiaoqing Jiang, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  30. Fe–Co based synergistic catalytic graphitization of biomass: Influence of the catalyst type and the pyrolytic temperature

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  31. Ca-cluster-constructed deep-ultraviolet nonlinear-optical crystal Na2Ca17Al2(PO4)14 with strong NLO response

    Journal of Alloys and Compounds · 2021-11-30

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  32. Synthesis and Characterization of Novel Nanoparticles of Lithium Aluminum Iodate LiAl(IO3)4, and DFT Calculations of the Crystal Structure and Physical Properties

    Nanomaterials · 2021-12-03

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  33. Explorations of New SHG Materials in Mercury Iodate Sulfate System**

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  34. Novel experimental methodology and optical analysis of (Ni, Co, Fe, and Cr) iodate nanocrystals

    Inorganic Chemistry Communications · 2023-09-25

    Sara Allaoui, Zoulikha Hebboul, Souraya Goumri‐Said, Ahmed Draoui

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  35. Diversity of [M(IO3)6] Building Blocks in Iodate Families and the New Trigonal Polymorph of Cs2HIn(IO3)6

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  36. Diversity of fundamental building blocks [M(IO3)6] in iodate families and new trigonal polymorph of Cs2HIn(IO3)6

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  37. The Multi‐Scale Paradigm: An Integrated Design Logic for Nonlinear Optical Crystals

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