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RESEARCH PAPER · Angewandte Chemie · 2020

A2SnS5: A Structural Incommensurate Modulation Exhibiting Strong Second‐Harmonic Generation and a High Laser‐Induced Damage Threshold (A=Ba, Sr)

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A2SnS5: A Structural Incommensurate Modulation Exhibiting Strong Second‐Harmonic Generation and a High Laser‐Induced Damage Threshold (A=Ba, Sr)OriginalPb 18 O 8 Cl 15 I 5 : A Polar Lead Mixed Oxyhalide with Unprecedented Architecture and Excellent Infrared Nonlinear Optical Properties165Pb18O8Cl15I5: A Polar Lead Mixed Oxyhalide with Unprecedented Architecture and Excellent Infrared Nonlinear Optical Properties29A novel promising infrared nonlinear optical selenide KAg 3 Ga 8 Se 14 designed from benchmark AgGaQ 2 (Q = S, Se)55Investigation of the second-order nonlinear optical property of Sr6Sb6S173Breaking through the “3.0 eV wall” of energy band gap in mid-infrared nonlinear optical rare earth chalcogenides by charge-transfer engineering144Cu 4 MnGe 2 S 7 and Cu 2 MnGeS 4 : two polar thiogermanates exhibiting second harmonic generation in the infrared and structures derived from hexagonal diamond22Homochiral three-dimensional noncentrosymmetric lanthanide coordination polymers directed by chiral linkers: syntheses, crystal structures, and optical properties8Ternary rare-earth sulfides RE3GaS6 (RE = Ho, Er): Crystal chemistry, second-order nonlinear optical properties and theoretical investigation18A Deep‐UV Nonlinear Optical Borosulfate with Incommensurate Modulations71A Deep‐UV Nonlinear Optical Borosulfate with Incommensurate Modulations13BaYOBO3: A deep-ultraviolet rare-earth oxy-borate with a large second harmonic generation response45Li 4 MgGe 2 S 7 : The First Alkali and Alkaline‐Earth Diamond‐Like Infrared Nonlinear Optical Material with Exceptional Large Band Gap213Li4MgGe2S7: The First Alkali and Alkaline‐Earth Diamond‐Like Infrared Nonlinear Optical Material with Exceptional Large Band Gap15A Lead Mixed Halide with Three Different Coordinated Anions and Strong Second‐Harmonic Generation Response10Structural Chemistry and Excellent Nonlinear Optical Properties of a Series of Ternary Selenides GaxIn2–xSe322Sn7Br10S2: The First Ternary Halogen‐Rich Chalcohalide Exhibiting a Chiral Structure and Pronounced Nonlinear Optical Properties24Sn7Br10S2: The First Ternary Halogen‐Rich Chalcohalide Exhibiting a Chiral Structure and Pronounced Nonlinear Optical Properties145Unprecedented mid-infrared nonlinear optical materials achieved by crystal structure engineering, a case study of (KX)P 2 S 6 (X = Sb, Bi, Ba)59Chiral Ligand‐Driven Systematic Synthesis of Coordination Polymers with Non‐centrosymmetric Structures12Material research from the viewpoint of functional motifs103Sr3[SnOSe3][CO3]: A Heteroanionic Nonlinear Optical Material Containing Planar π‐conjugated [CO3] and Heteroleptic [SnOSe3] Anionic Groups78Sr3[SnOSe3][CO3]: A Heteroanionic Nonlinear Optical Material Containing Planar π‐conjugated [CO3] and Heteroleptic [SnOSe3] Anionic Groups7Na 2 Ba[Na 2 Sn 2 S 7 ]: Structural Tolerance Factor‐Guided NLO Performance Improvement50Na2Ba[Na2Sn2S7]: Structural Tolerance Factor‐Guided NLO Performance Improvement0A Rare Earth Chalcogenide Nonlinear Optical Crystal KLaGeS4: Achieving Good Balance among Band Gap, Second Harmonic Generation Effect, and Birefringence12La3Ga5HfO14: Rare-Earth Polyhedron Coupled with Structural Protected Octahedron for Designing Nonlinear Optical Material with Wide Bandgap and Well-Balanced Properties5The Influence of Different Group Distortions on the Structure–Property Relationship of Alkali Metal Thiophosphate0Disruption of chain structures leads to ultralow lattice thermal conductivity of A 2 SnS 5 (A = Sr, Ba)0Realizing Phase‐Matching of Nonlinear Optical [ABa 3 Br 2 ][Ga 5 Se 10 ] (A = Cs, Rb, K, Na) Through Large Anisotropic Lattice Distortion6Hierarchical Ordering Decouples the SHG–Birefringence–LIDT Trade‐Off in a Single‐Phase Mid‐Infrared Nonlinear Optical Crystal0

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  2. Pb18O8Cl15I5: A Polar Lead Mixed Oxyhalide with Unprecedented Architecture and Excellent Infrared Nonlinear Optical Properties

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  3. A novel promising infrared nonlinear optical selenide KAg 3 Ga 8 Se 14 designed from benchmark AgGaQ 2 (Q = S, Se)

    Chemical Communications · 2020-12-17

    Jia-Nuo Li, Wen‐Dong Yao, Xiaohui Li, Wenlong Liu, Huaiguo Xue, Sheng‐Ping Guo

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  4. Investigation of the second-order nonlinear optical property of Sr6Sb6S17

    Journal of Solid State Chemistry · 2020-12-19

    Qian-Ting Xu, Wen‐Dong Yao, Xiaohui Li, Sheng‐Ping Guo

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  5. Breaking through the “3.0 eV wall” of energy band gap in mid-infrared nonlinear optical rare earth chalcogenides by charge-transfer engineering

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    Dajiang Mei, Wangzhu Cao, Naizheng Wang, Xingxing Jiang, Jun Zhao, Weikang Wang, Junhui Dang, Shiyan Zhang, Yuandong Wu, Pinhua Rao, Zheshuai Lin

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  6. Cu 4 MnGe 2 S 7 and Cu 2 MnGeS 4 : two polar thiogermanates exhibiting second harmonic generation in the infrared and structures derived from hexagonal diamond

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    Jennifer R. Glenn, Jeong Bin Cho, Yiqun Wang, Andrew J. Craig, Jian‐Han Zhang, Marvene Cribbs, Stanislav S. Stoyko, Kate E. Rosello, Christopher Barton, Allyson Bonnoni, P. Grima, Joseph H. MacNeil, James M. Rondinelli, Joon Ik Jang, Jennifer A. Aitken

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  7. Homochiral three-dimensional noncentrosymmetric lanthanide coordination polymers directed by chiral linkers: syntheses, crystal structures, and optical properties

    CrystEngComm · 2021-01-01

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  8. Ternary rare-earth sulfides RE3GaS6 (RE = Ho, Er): Crystal chemistry, second-order nonlinear optical properties and theoretical investigation

    Journal of Alloys and Compounds · 2021-02-15

    Haoyu Chen, Yingying Zhang, Yifan Yang, Sheng‐Ping Guo

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  9. A Deep‐UV Nonlinear Optical Borosulfate with Incommensurate Modulations

    Angewandte Chemie International Edition · 2021-03-09

    Yanqiang Li, Zhengyang Zhou, Sangen Zhao, Fei Liang, Qingran Ding, Junliang Sun, Zheshuai Lin, Maochun Hong, Junhua Luo

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  10. A Deep‐UV Nonlinear Optical Borosulfate with Incommensurate Modulations

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  11. BaYOBO3: A deep-ultraviolet rare-earth oxy-borate with a large second harmonic generation response

    Science China Chemistry · 2021-06-18

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  12. Li 4 MgGe 2 S 7 : The First Alkali and Alkaline‐Earth Diamond‐Like Infrared Nonlinear Optical Material with Exceptional Large Band Gap

    Angewandte Chemie International Edition · 2021-07-24

    Ailijiang Abudurusuli, Junben Huang, Peng Wang, Zhihua Yang, Shilie Pan, Junjie Li

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  13. Li4MgGe2S7: The First Alkali and Alkaline‐Earth Diamond‐Like Infrared Nonlinear Optical Material with Exceptional Large Band Gap

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    Ailijiang Abudurusuli, Junben Huang, Peng Wang, Zhihua Yang, Shilie Pan, Junjie Li

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  14. A Lead Mixed Halide with Three Different Coordinated Anions and Strong Second‐Harmonic Generation Response

    Chemistry - A European Journal · 2021-10-15

    Qirui Shui, Ruibiao Fu, Ziqi Zhou, Zuju Ma, Hong‐Xin Tang, Xin‐Tao Wu

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  15. Structural Chemistry and Excellent Nonlinear Optical Properties of a Series of Ternary Selenides GaxIn2–xSe3

    Inorganic Chemistry · 2021-12-10

    Qian-Ting Xu, Yang Chi, Xiaohui Li, Wenlong Liu, Sheng‐Ping Guo

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  16. Sn7Br10S2: The First Ternary Halogen‐Rich Chalcohalide Exhibiting a Chiral Structure and Pronounced Nonlinear Optical Properties

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    Xiaohui Li, Zhi‐Hui Shi, Mei Yang, Wenlong Liu, Sheng‐Ping Guo

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  17. Sn7Br10S2: The First Ternary Halogen‐Rich Chalcohalide Exhibiting a Chiral Structure and Pronounced Nonlinear Optical Properties

    Angewandte Chemie International Edition · 2021-12-24

    Xiaohui Li, Zhi‐Hui Shi, Mei Yang, Wenlong Liu, Sheng‐Ping Guo

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  18. Unprecedented mid-infrared nonlinear optical materials achieved by crystal structure engineering, a case study of (KX)P 2 S 6 (X = Sb, Bi, Ba)

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    Vivian Nguyen, Bingheng Ji, Kui Wu, Bingbing Zhang, Jian Wang

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  19. Chiral Ligand‐Driven Systematic Synthesis of Coordination Polymers with Non‐centrosymmetric Structures

    Chemistry - A European Journal · 2022-01-27

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  20. Material research from the viewpoint of functional motifs

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    Xiao‐Ming Jiang, Shuiquan Deng, Myung‐Hwan Whangbo, Guo‐Cong Guo

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  21. Sr3[SnOSe3][CO3]: A Heteroanionic Nonlinear Optical Material Containing Planar π‐conjugated [CO3] and Heteroleptic [SnOSe3] Anionic Groups

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  22. Sr3[SnOSe3][CO3]: A Heteroanionic Nonlinear Optical Material Containing Planar π‐conjugated [CO3] and Heteroleptic [SnOSe3] Anionic Groups

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  23. Na 2 Ba[Na 2 Sn 2 S 7 ]: Structural Tolerance Factor‐Guided NLO Performance Improvement

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  24. Na2Ba[Na2Sn2S7]: Structural Tolerance Factor‐Guided NLO Performance Improvement

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  25. A Rare Earth Chalcogenide Nonlinear Optical Crystal KLaGeS4: Achieving Good Balance among Band Gap, Second Harmonic Generation Effect, and Birefringence

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  26. La3Ga5HfO14: Rare-Earth Polyhedron Coupled with Structural Protected Octahedron for Designing Nonlinear Optical Material with Wide Bandgap and Well-Balanced Properties

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  27. The Influence of Different Group Distortions on the Structure–Property Relationship of Alkali Metal Thiophosphate

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  28. Disruption of chain structures leads to ultralow lattice thermal conductivity of A 2 SnS 5 (A = Sr, Ba)

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  29. Realizing Phase‐Matching of Nonlinear Optical [ABa 3 Br 2 ][Ga 5 Se 10 ] (A = Cs, Rb, K, Na) Through Large Anisotropic Lattice Distortion

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  30. Hierarchical Ordering Decouples the SHG–Birefringence–LIDT Trade‐Off in a Single‐Phase Mid‐Infrared Nonlinear Optical Crystal

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