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RESEARCH PAPER · Inorganic Chemistry · 2018

Synthesis and Characterization of MgCr2S4 Thiospinel as a Potential Magnesium Cathode

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Synthesis and Characterization of MgCr2S4 Thiospinel as a Potential Magnesium CathodeOriginalMgSc2Se4—A Magnesium Solid Ionic Conductor for All‐Solid‐State Mg Batteries?74Direct observation of MgO formation at cathode electrolyte interface of a spinel MgCo2O4 cathode upon electrochemical Mg removal and insertion12Synthesis and Characterization of Ba2Ag2Se2(Se2)24Chemical Flexibility of Mg in Pnictide Materials: Structure and Properties Diversity27Predicting the Structure Stability of Layered Heteroanionic Materials Exhibiting Anion Order16Recent Progress on Layered Cathode Materials for Nonaqueous Rechargeable Magnesium Batteries82Yttrium Manganese Oxide Phase Stability and Selectivity Using Lithium Carbonate Assisted Metathesis Reactions17Atomic-scale observation of phase transition of MgMn2O4 cubic spinel upon the charging in Mg-ion battery36Exploits, advances and challenges benefiting beyond Li-ion battery technologies238Probing Electrochemical Mg-Ion Activity in MgCr 2– x V x O 4 Spinel Oxides37Selective metathesis synthesis of MgCr 2 S 4 by control of thermodynamic driving forces43Structural Peculiarities and Thermoelectric Study of Iron Indium Thiospinel13First-principle investigation of ferromagnetism and thermoelectric characteristics of MgCr2X4 (X = S, Se) spinels48Recent Advances in Rechargeable Magnesium‐Based Batteries for High‐Efficiency Energy Storage243Solvent-Free Mechanochemical Approach towards Thiospinel MgCr2S4 as a Potential Electrode for Post-Lithium Ion Batteries4Ab-initio computations of CaV2S4 and CaMn2S4 spinels for spintronics and energy storage system applications24Spin-dependent rare-earth-based MgPr2X4 (X = S, Se) spinels investigations for spintronic and sustainable energy systems applications46Promises and Challenges of Next-Generation “Beyond Li-ion” Batteries for Electric Vehicles and Grid Decarbonization1625Lithium Thiostannate Spinels: Air-Stable Cubic Semiconductors15Toward the Development of a High-Voltage Mg Cathode Using a Chromium Sulfide Host19A general review on the thiospinels and their energy applications31First principle study of half metallic ferromagnetism and transport properties of spinel’s ZnFe 2 (S/Se) 4 for spintronic21Selectivity in Yttrium Manganese Oxide Synthesis via Local Chemical Potentials in Hyperdimensional Phase Space45Structural, opto-electronic, and transport properties of HgSc 2 S 4 and HgSc 2 Se 4 spinel compounds based on density functional theory6Layered Transition Metal Oxides as Ca Intercalation Cathodes: A Systematic First‐Principles Evaluation24Exchange mechanism, ferromagnetic and transport characteristics of Mg-based spinel chalcogenides for spintronic applications14A new non-stoichiometric quaternary sulfide Ba3.14(4)Sn0.61(1)Bi2.39(1)S8: Synthesis, crystal structure, physical properties, and electronic structure8Metathesis routes to materials6Review of computational approaches to predict the thermodynamic stability of inorganic solids197Low Thermal Conductivity in Heteroanionic Materials with Layers of Homoleptic Polyhedra42Study of half metallic ferromagnetism and thermoelectric properties of spinel chalcogenides BaCr2X4 (X = S, Se, Te) for spintronic and energy harvesting54Room temperature ferromagnetism and thermoelectric behavior of calcium based spinel chalcogenides CaZ2S4 (Z = Ti, V, Cr, Fe) for spintronic applications49Reaction Selectivity in Cometathesis: Yttrium Manganese Oxides7Physical characteristics of ferromagnetic Cr-based LiCr2X4 (X = S, Se) spinels for spintronic and solar energy devices applications7Synthesis, characterization, and electronic structure of SrBi2S43Systemically study of optoelectronic and transport properties of chalcopyrite HgAl2X4 (X= S, Se) compounds for solar cell device applications9Analysis of Mg-based spinels MgGd2X4 (X = S, Se) for spintronic and thermoelectric device applications: Ab-initio calculations27Computational modelling on the stability of solid electrolytes in magnesium-ion batteries0Study of ferromagnetism and thermoelectric behaviour of thiospinels MgFe 2 (S/Se) 4 for spintronics and energy harvesting5Recent progress on cathode materials for rechargeable magnesium batteries83First Principles Investigation of Electronic, Optical, and Magnetic Properties of MgYb2X4 (X = S, Se, Te)5Computational studies on magnesium spinel’s [MgY2S4 and MgY2Se4]4Tunable magnetic interactions in mono-transition metal spinels MgCr2X4 (X=O,S,Se) and ACr2S4 (A=Ca,Sr,Ba)2Study of role of spin in ferromagnetism and thermoelectric characteristics of spinel chalcognides MgEr2(S/Se)4 for spintronic and clean energy12Half-metallic ferromagnetism and thermoelectric effect in spinel chalcogenides SrX2S4 (X = Mn, Fe, Co) for spintronics and energy harvesting25Na4–xSn2–xSbxGe5O16, an Air-Stable Solid-State Na-Ion Conductor3Mechanical, Magnetic, and Optical Characteristics of Tm‐Based Chalcogenides for Energy‐Harvesting Applications0Electronic, magnetic and transport properties of anti-ferromagnetic semiconductor BaGd2X4(X S, Se)36First-principle study of Mg-based rare earth spinels MgSm2Y4 (Y S, Se) for spintronic and thermoelectric devices10Computational study of Cd-based chalcogenide spinels CdSm2(S/Se)4 for spintronic applications11Rare earth based Mg- chalcogenides MgDy2(S/Se)4 as an emerging aspirant for spintronic and thermoelectric applications25Accessing Mg‐Ion Storage in V2PS10 via Combined Cationic‐Anionic Redox with Selective Bond Cleavage5Accessing Mg‐Ion Storage in V2PS10 via Combined Cationic‐Anionic Redox with Selective Bond Cleavage2Cu2Mg5Sn5Se16 – the first selenospinel of the A2B5C5X16 type1Control of spin on ferromagnetism and thermoelectric properties of Sr(V/Cr)2S4; emergent spintronic aspirant16Mechanical, magnetic, and electronic characteristics of Sm-based chalcogenides for spintronics and device applications6DFT study of rare-earth ferromagnetic spinels HgNd2Z4 (Z = S, Se) for spintronics applications10Computationally Guided Synthesis of Battery Materials11Half metallic ferromagnetic and transport behavior of rare earth based CdGd2(S/Se)4 spinels8Study of the Physical Properties of the New Spinel Oxide NaMgMn₂O₄ Material1Understanding the Formation of Colloidal Ferrimagnetic CuCr 2 Se 4 Nanocrystals with Strong Room-Temperature Magnetic Circular Dichroism7Establishing baselines for generative discovery of inorganic crystals10Syntheses and Characterization of Ba16Si8Te44+δ and Ba6Si4Te6(Te3)3 Structures with Complex Te–Te Interactions3Spin-polarized analysis of ferromagnetism, optoelectronic and transport characteristics of HgGd2(S/Se)4 spinels: DFT-calculations4Advancements in cathode materials for high-performance rechargeable magnesium-ion batteries20Electronic, magnetic, thermoelectric and optoelectronic properties of CaPr2(S/Se)4 for spintronic and energy applications2Recent advancements in high-performance and durable electrodes materials for magnesium-ion batteries28DFT Calculations of Structural, Opto-Electronic, and Transport Properties of HgLu2(S/Se)4 Spinel Compounds1Simultaneous Enhancement of Interface Stability and Ionic Transport by Li+ and BH4– in Magnesium-Based Energy Storage6Investigating sulfur precursor effects on wet-chemically synthesized Cu Co bimetallic sulfides for supercapacitor applications via electrochemical measurement and thermodynamic and DFT calculations11Investigation of Curie temperature, magnetic, and transport aspects of CaEr2(S/Se)4 chalcogenides for spintronic applications2Anharmonic effects on the dynamical stability of Ce–Co–Cu intermetallic ternary compounds0Crystal growth of metal tellurides from a boron–tellurium mixture: MTr 2 Te 4 (M = Sr, Eu; Tr = In, Ga)1First-principles investigation of half-metallic, optical and thermoelectric properties in CaX₂Se₄ (X = Mn, V) spinels1Synthesis and Properties of Bulk Mg 3 WN 4 in a Wurtzite-Derived Structure0First-principles study of ferromagnetism and thermoelectric aspects of Sr(Pr/Nd)2S4 spinel chalcogenides as promising aspirants for spintronic and energy applications0

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  1. MgSc2Se4—A Magnesium Solid Ionic Conductor for All‐Solid‐State Mg Batteries?

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  2. Direct observation of MgO formation at cathode electrolyte interface of a spinel MgCo2O4 cathode upon electrochemical Mg removal and insertion

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  3. Synthesis and Characterization of Ba2Ag2Se2(Se2)

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  4. Chemical Flexibility of Mg in Pnictide Materials: Structure and Properties Diversity

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  5. Predicting the Structure Stability of Layered Heteroanionic Materials Exhibiting Anion Order

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  6. Recent Progress on Layered Cathode Materials for Nonaqueous Rechargeable Magnesium Batteries

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  7. Yttrium Manganese Oxide Phase Stability and Selectivity Using Lithium Carbonate Assisted Metathesis Reactions

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  8. Atomic-scale observation of phase transition of MgMn2O4 cubic spinel upon the charging in Mg-ion battery

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  9. Exploits, advances and challenges benefiting beyond Li-ion battery technologies

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  10. Probing Electrochemical Mg-Ion Activity in MgCr 2– x V x O 4 Spinel Oxides

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  11. Selective metathesis synthesis of MgCr 2 S 4 by control of thermodynamic driving forces

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  12. Structural Peculiarities and Thermoelectric Study of Iron Indium Thiospinel

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  13. First-principle investigation of ferromagnetism and thermoelectric characteristics of MgCr2X4 (X = S, Se) spinels

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  14. Recent Advances in Rechargeable Magnesium‐Based Batteries for High‐Efficiency Energy Storage

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  15. Solvent-Free Mechanochemical Approach towards Thiospinel MgCr2S4 as a Potential Electrode for Post-Lithium Ion Batteries

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  16. Ab-initio computations of CaV2S4 and CaMn2S4 spinels for spintronics and energy storage system applications

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  17. Spin-dependent rare-earth-based MgPr2X4 (X = S, Se) spinels investigations for spintronic and sustainable energy systems applications

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  18. Promises and Challenges of Next-Generation “Beyond Li-ion” Batteries for Electric Vehicles and Grid Decarbonization

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  19. Lithium Thiostannate Spinels: Air-Stable Cubic Semiconductors

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  20. Toward the Development of a High-Voltage Mg Cathode Using a Chromium Sulfide Host

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  22. First principle study of half metallic ferromagnetism and transport properties of spinel’s ZnFe 2 (S/Se) 4 for spintronic

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  29. Review of computational approaches to predict the thermodynamic stability of inorganic solids

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  30. Low Thermal Conductivity in Heteroanionic Materials with Layers of Homoleptic Polyhedra

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  31. Study of half metallic ferromagnetism and thermoelectric properties of spinel chalcogenides BaCr2X4 (X = S, Se, Te) for spintronic and energy harvesting

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  33. Reaction Selectivity in Cometathesis: Yttrium Manganese Oxides

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  47. Mechanical, Magnetic, and Optical Characteristics of Tm‐Based Chalcogenides for Energy‐Harvesting Applications

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  48. Electronic, magnetic and transport properties of anti-ferromagnetic semiconductor BaGd2X4(X S, Se)

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  49. First-principle study of Mg-based rare earth spinels MgSm2Y4 (Y S, Se) for spintronic and thermoelectric devices

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  50. Computational study of Cd-based chalcogenide spinels CdSm2(S/Se)4 for spintronic applications

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