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RESEARCH PAPER · Solid State Ionics · 2019

Atomic-scale observation of phase transition of MgMn2O4 cubic spinel upon the charging in Mg-ion battery

Quang Duc Truong, Hiroaki Kobayashi, Keiichiro Nayuki, Yoshikazu Sasaki, Itaru Honma

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Atomic-scale observation of phase transition of MgMn2O4 cubic spinel upon the charging in Mg-ion batteryOriginalReductive solvothermal synthesis of MgMn2O4 spinel nanoparticles for Mg-ion battery cathodes42Effective 3D open-channel nanostructures of a MgMn 2 O 4 positive electrode for rechargeable Mg batteries operated at room temperature32Effect of Al substitution on structure and cathode performance of MgMn2O4 spinel for magnesium rechargeable battery46The Quest for Functional Oxide Cathodes for Magnesium Batteries: A Critical Perspective77Lowering Ternary Oxide Synthesis Temperatures by Solid-State Cometathesis Reactions20Magnesium Deintercalation From the Spinel‐Type MgMn2‐yFeyO4 (0.4≤y≤2.0) by Acid‐Treatment and Electrochemistry11Progress in high-voltage MgMn2O4 oxyspinel cathode materials for Mg batteries41Magnesium Insertion and Related Structural Changes in Spinel-Type Manganese Oxides4Enabling Anionic Redox Stability of P2‐Na 5/6 Li 1/4 Mn 3/4 O 2 by Mg Substitution109One-Pot Solvothermal Synthesis of Spinel MgFe2O4 Nanoparticles as a Promising Cathode Material for Rechargeable Mg-ion Battery3One-Pot Super Critical Fluid Synthesis of Spinel MnFe2O4 Nanoparticles and its Application as Anode Material for Mg-ion Battery1Mg2+ ion-powered hybrid supercapacitor with β-MnO2 as a cathode and α-Fe2O3 as an anode22Reaction Selectivity in Cometathesis: Yttrium Manganese Oxides7Suppressing Electrolyte Decomposition at Cathode/Electrolyte Interface by Mg-Fe Binary Oxide Coating towards Room-Temperature Magnesium Rechargeable Battery Operation10Preparation of conductive Cu1.5Mn1.5O4 and Mn3O4 spinel mixture powders as positive active materials in rechargeable Mg batteries operative at room temperature2Unconventional Charge Transport in MgCr2O4 and Implications for Battery Intercalation Hosts26Self-activation effect in bimetallic MgMn2O4 and boosting its electrochemical performance using metal-organic framework template for magnesium-ion battery cathodes13Recent progress on cathode materials for rechargeable magnesium batteries82Facile one step self-template synthesis of NixMgMn2O4 (X= 0.12 to 0.50) alloys as a promising cathode for magnesium ion battery16WITHDRAWN: Twofold ion effect to develop PANI@MgCoO2 nanocomposites for magnesium batteries0Studies on role of support metal in glycerol conversion to glycerol carbonate through Mg/MnO2 and Mg/CuO heterogeneous catalyst12Unraveling the Phase Transition Behavior of MgMn2O4 Electrodes for Their Use in Rechargeable Magnesium Batteries18Elucidating Structural Transition Dynamics in the Magnesium Cathode MgCr2O47WITHDRAWN: Twofold ion effect to develop PANI@MgCoO2 nanocomposites for magnesium batteries0A Study on Surface Modification Characteristics and Charge–Discharge Mechanism of Natural Serpentinite Ore Secondary Battery2Ex-situ synthesis, comprehensive characterization, and comprehensive properties of PVA film composites coated Spinel MgMn1.8Co0.2O4 nanoparticle10Development of Oxide-Type Cathode Materials towards Room-Temperature Magnesium Rechargeable Batteries3Effects on the structure and electrochemical reactivity of surface modified magnesium cobalt oxide0SILAR synthesized α-Fe2O3 thin film anode for the development of all binder-free, high-performing Mg-ion asymmetric supercapacitors13SILAR synthesis of binder-free, nanosheets-like manganese phosphate electrodes for Mg-ion supercapacitors5Stable polyaniline-based cathode material enabled by MgMn2O4 for aqueous magnesium-ion batteries: Experimental and DFT study6High voltage cathode materials for rechargeable magnesium batteries: Structural aspects and electrochemical perspectives13Engineered MgMn2O4/rGO heterostructures as dual-functional catalysts for environmental remediation and sustainable hydrogen production0Oxide‐Type Positive Electrode Design Toward High‐Energy Rechargeable Magnesium Batteries1Study of structural and optical properties of Ni-doped MgMn₂O₄ spinel nanoparticles synthesized by a self-templating method0Unveiling Mg storage performances and phase transition behaviors of O-functionalized MXene cathodes for Mg-ion batteries by first-principles calculations0

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  1. Reductive solvothermal synthesis of MgMn2O4 spinel nanoparticles for Mg-ion battery cathodes

    Ceramics International · 2020-11-01

    Rika Yokozaki, Hiroaki Kobayashi, Itaru Honma

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  2. Effective 3D open-channel nanostructures of a MgMn 2 O 4 positive electrode for rechargeable Mg batteries operated at room temperature

    Journal of Materials Chemistry A · 2021-01-01

    Kazuki Sone, Yoshihiro Hayashi, Toshihiko Mandai, Shunsuke Yagi, Yuya Oaki, Hiroaki Imai

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  3. Effect of Al substitution on structure and cathode performance of MgMn2O4 spinel for magnesium rechargeable battery

    Journal of Alloys and Compounds · 2021-03-31

    Rika Yokozaki, Hiroaki Kobayashi, Toshihiko Mandai, Itaru Honma

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  4. The Quest for Functional Oxide Cathodes for Magnesium Batteries: A Critical Perspective

    ACS Energy Letters · 2021-04-26

    Ian D. Johnson, Brian J. Ingram, Jordi Cabana

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  5. Lowering Ternary Oxide Synthesis Temperatures by Solid-State Cometathesis Reactions

    Chemistry of Materials · 2021-05-08

    Allison Wustrow, Guanglong Huang, Matthew J. McDermott, Daniel O’Nolan, Chia-Hao Liu, Gia Thinh Tran, Brennan C. McBride, Shyam Dwaraknath, Karena W. Chapman, Simon J. L. Billinge, Kristin Aslaug Persson, Katsuyo S. Thornton, James Richmond Neilson

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  6. Magnesium Deintercalation From the Spinel‐Type MgMn2‐yFeyO4 (0.4≤y≤2.0) by Acid‐Treatment and Electrochemistry

    Chemistry - A European Journal · 2021-06-24

    Alejandro Medina, Ana I. Rodríguez, Carlos Pérez-Vicente, Ricardo Alcántara

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  7. Progress in high-voltage MgMn2O4 oxyspinel cathode materials for Mg batteries

    Current Opinion in Electrochemistry · 2021-07-29

    Alexandra Michail, Begoña Silván, Nuria Tapia‐Ruiz

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  8. Magnesium Insertion and Related Structural Changes in Spinel-Type Manganese Oxides

    Crystals · 2021-08-19

    Ana Robba, Elena Tchernychova, Jan Bitenc, Anna Randon‐Vitanova, Robert Dominko

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  9. Enabling Anionic Redox Stability of P2‐Na 5/6 Li 1/4 Mn 3/4 O 2 by Mg Substitution

    Advanced Materials · 2021-12-28

    Yangyang Huang, Yangyang Huang, Yongcheng Zhu, Anmin Nie, Haoyu Fu, Zhiwei Hu, Xueping Sun, Shu‐Chih Haw, Jin‐Ming Chen, Ting‐Shan Chan, Sijie Yu, Guang Hao Sun, Gang Jiang, Jiantao Han, Wei Hua Luo, Yunhui Huang, Yunhui Huang

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  10. One-Pot Solvothermal Synthesis of Spinel MgFe2O4 Nanoparticles as a Promising Cathode Material for Rechargeable Mg-ion Battery

    Springer Proceedings in Materials · 2022-01-01

    Vinay Gangaraju, Kunal Roy, Mahesh Shastri, Navya Rani Marilingaiah, Manjunath Shetty, Hiroaki Kobayashi, Takaaki Tomai, Prasanna Doddakunche Shivaramu, Dinesh Rangappa

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  11. One-Pot Super Critical Fluid Synthesis of Spinel MnFe2O4 Nanoparticles and its Application as Anode Material for Mg-ion Battery

    Asian Journal of Chemistry · 2022-01-01

    Vinay Gangaraju, Tathagata Sardar, Kunal Roy, Mahesh Shastri, Manjunath Shetty, Murthy Muniyappa, Hiroaki Kobayashi, Takaaki Tomai, Ananda Kumar C. S., Prasanna Doddakunche Shivaramu, Dinesh Rangappa

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  12. Mg2+ ion-powered hybrid supercapacitor with β-MnO2 as a cathode and α-Fe2O3 as an anode

    Journal of Energy Storage · 2022-04-13

    Navajsharif S. Shaikh, Sawanta S. Mali, Jyoti V. Patil, Ajij I. Mujawar, Jasmin Shamshoddin Shaikh, Sumayya C. Pathan, Supareak Praserthdam, Chang Kook Hong, Pongsakorn Kanjanaboos

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  13. Reaction Selectivity in Cometathesis: Yttrium Manganese Oxides

    Chemistry of Materials · 2022-05-10

    Allison Wustrow, Matthew J. McDermott, Daniel O’Nolan, Chia-Hao Liu, Gia Thinh Tran, Brennan C. McBride, Simon M. Vornholt, Chao Feng, Shyam Dwaraknath, Karena W. Chapman, Simon J. L. Billinge, Wenhao Q. Sun, Kristin Aslaug Persson, James Richmond Neilson

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  14. Suppressing Electrolyte Decomposition at Cathode/Electrolyte Interface by Mg-Fe Binary Oxide Coating towards Room-Temperature Magnesium Rechargeable Battery Operation

    Electrochemistry · 2022-05-11

    Reona Iimura, Hiroaki Kobayashi, Itaru Honma

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  15. Preparation of conductive Cu1.5Mn1.5O4 and Mn3O4 spinel mixture powders as positive active materials in rechargeable Mg batteries operative at room temperature

    Journal of Sol-Gel Science and Technology · 2022-07-14

    Hayato Takemitsu, Y. Hayashi, Hiroto Watanabe, Toshihiko Mandai, Shunsuke Yagi, Yuya Oaki, Hiroaki Imai

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  16. Unconventional Charge Transport in MgCr2O4 and Implications for Battery Intercalation Hosts

    Journal of the American Chemical Society · 2022-07-27

    Ian D. Johnson, Aashutosh N. Mistry, Liang Yin, Megan Murphy, Mark Wolfman, Timothy T. Fister, Saul H. Lapidus, Jordi Cabana, Venkat N. Srinivasan, Brian J. Ingram

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  17. Self-activation effect in bimetallic MgMn2O4 and boosting its electrochemical performance using metal-organic framework template for magnesium-ion battery cathodes

    Materials Today Energy · 2022-09-15

    Dong Cheng, Hiroaki Kobayashi, Itaru Honma

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  18. Recent progress on cathode materials for rechargeable magnesium batteries

    Energy storage materials · 2022-10-18

    Masashi Kotobuki, Binggong Yan, Li Lü

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  19. Facile one step self-template synthesis of NixMgMn2O4 (X= 0.12 to 0.50) alloys as a promising cathode for magnesium ion battery

    Materials Chemistry and Physics · 2023-01-26

    Soheila Javadian, Ali Zeinodiny, Nima Dalir, Hussein Gharibi, S.M. Javad Ghavam

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  20. WITHDRAWN: Twofold ion effect to develop PANI@MgCoO2 nanocomposites for magnesium batteries

    Research Square · 2023-03-24

    Kahla Missaoui, Karima Ferchichi, Noureddine Amdouni, Daniel Cosano, Rui Liu, Siyuan Pan, Zhanning He, Yong Yang, Gregorio F. Ortiz

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  21. Studies on role of support metal in glycerol conversion to glycerol carbonate through Mg/MnO2 and Mg/CuO heterogeneous catalyst

    Molecular Catalysis · 2023-05-27

    Siddhi Jaiswal, Sunita Maurya, Yogesh Chandra Sharma

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  22. Unraveling the Phase Transition Behavior of MgMn2O4 Electrodes for Their Use in Rechargeable Magnesium Batteries

    Materials · 2023-08-01

    Carmen Miralles, Teresa Lana‐Villarreal, Roberto Gómez

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  23. Elucidating Structural Transition Dynamics in the Magnesium Cathode MgCr2O4

    Chemistry of Materials · 2023-10-09

    Junghwa Kim, Shashwat Anand, Colin Gilgenbach, Ian D. Johnson, Megan Murphy, Tina Chen, Matthew Moy, Aubrey N. Penn, Jordi Cabana, Gerbrand Ceder, Brian J. Ingram, James M. LeBeau

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  24. WITHDRAWN: Twofold ion effect to develop PANI@MgCoO2 nanocomposites for magnesium batteries

    Research Square · 2023-12-05

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  25. A Study on Surface Modification Characteristics and Charge–Discharge Mechanism of Natural Serpentinite Ore Secondary Battery

    Inorganics · 2023-12-27

    Jun-Ren Zhao, Kuan-Jen Chen, Fei‐Yi Hung, Yung-Yi Tsai, Po‐Ting Wu

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  26. Ex-situ synthesis, comprehensive characterization, and comprehensive properties of PVA film composites coated Spinel MgMn1.8Co0.2O4 nanoparticle

    Applied Physics A · 2024-04-17

    Mohammed O. Alziyadi, Hadeer Gamal, Asma Alkabsh, M.S. Shalaby

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  27. Development of Oxide-Type Cathode Materials towards Room-Temperature Magnesium Rechargeable Batteries

    Electrochemistry · 2024-07-17

    Hiroaki Kobayashi

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  28. Effects on the structure and electrochemical reactivity of surface modified magnesium cobalt oxide

    Journal of Electroanalytical Chemistry · 2024-08-09

    Kahla Missaoui, Karima Ferchichi, Noureddine Amdouni, Daniel Cosano, Rui Liu, Siyuan Pan, Zhanning He, Yu Su, Mingzeng Luo, Yong Yang, Gregorio F. Ortiz

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  29. SILAR synthesized α-Fe2O3 thin film anode for the development of all binder-free, high-performing Mg-ion asymmetric supercapacitors

    Journal of Energy Storage · 2024-08-24

    Tamseen M. Nejkar, Najiya R. Mulla, Umakant Mahadev Patil, Deepak Prakash Dubal, Raghunath S. Patil

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  30. SILAR synthesis of binder-free, nanosheets-like manganese phosphate electrodes for Mg-ion supercapacitors

    Solid State Communications · 2025-03-12

    Kuladip G. Belekar, Sumita Patil, Sumita Patil, Sambhaji S. Kumbhar, Shraddha Bhosale, Ganesh Jadhav, Chandrakant Dnyandev Lokhande, Umakant Mahadev Patil

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  31. Stable polyaniline-based cathode material enabled by MgMn2O4 for aqueous magnesium-ion batteries: Experimental and DFT study

    Journal of Alloys and Compounds · 2025-05-01

    Soheila Javadian, Rezvan Rostami, Esmaeil Pakizeh, Nima Dalir, Hussein Gharibi, Mokhtar Nasrollahpour, Ali Zeinodiny

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  32. High voltage cathode materials for rechargeable magnesium batteries: Structural aspects and electrochemical perspectives

    Journal of Magnesium and Alloys · 2025-08-29

    Dedy Setiawan, Jiwon Hwang, Munseok S. Chae, Seung‐Tae Hong

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  33. Engineered MgMn2O4/rGO heterostructures as dual-functional catalysts for environmental remediation and sustainable hydrogen production

    Journal of Water Process Engineering · 2026-03-04

    Janaranjani P, Shobana Priyanka D, Srinivasan Manickam

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  34. Oxide‐Type Positive Electrode Design Toward High‐Energy Rechargeable Magnesium Batteries

    Batteries & Supercaps · 2026-03-31

    T. Yabu, Reona Iimura, Masaki Matsui, Hiroaki Kobayashi

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  35. Study of structural and optical properties of Ni-doped MgMn₂O₄ spinel nanoparticles synthesized by a self-templating method

    Journal of Materials Science Materials in Electronics · 2026-04-01

    Esmaeil Pakizeh, Ali Zeinodiny, Rezvan Rostami

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  36. Unveiling Mg storage performances and phase transition behaviors of O-functionalized MXene cathodes for Mg-ion batteries by first-principles calculations

    Journal of Power Sources · 2026-07-24

    B X Li, Qianku Hu, Dandan Li, Peizhen Wu, Qinghua Wu, Aiguo Zhou

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