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RESEARCH PAPER · Crystal Growth & Design · 2017

A New KBBF-Family Nonlinear Optical Material with Strong Interlayer Bonding

Yaoguo Shen, Sangen Zhao, Yi Jin Yang, Liling Cao, Zujian Wang, Bingqing Zhao, Zhihua Sun, Zheshuai Lin, Junhua Luo

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A New KBBF-Family Nonlinear Optical Material with Strong Interlayer BondingOriginalThe Next‐Generation of Nonlinear Optical Materials: Rb3Ba3Li2Al4B6O20F—Synthesis, Characterization, and Crystal Growth87Flux Exploration, Growth, and Optical Spectroscopic Properties of Large Size LaBSiO5 and Eu3+-Substituted LaBSiO5 Crystals16K2[B3O3(OH)5]: A new deep-UV nonlinear optical crystal with isolated [B3O3(OH)5]2- anionic groups31BaLiZn 3 (BO 3 ) 3 : a new member of the KBe 2 BO 3 F 2 family possessing dense BO 3 triangles and the smallest interlayer distance16Na 3 Ca 4 (TeO 3 )(PO 4 ) 3 : a new noncentrosymmetric tellurite phosphate with fascinating multimember-ring architectures and intriguing nonlinear optical performance30Deep-ultraviolet nonlinear optical materials: Development trend and innovative exploration16The role of cations in second-order nonlinear optical materials based on π-conjugated [BO 3 ] 3− groups195Deep‐Ultraviolet Nonlinear Optical Crystal Cs2Al2(B3O6)2O: A Benign Member of the Sr2Be2(BO3)2O Family with [Al2(B3O6)2O]2− Double Layers70Beryllium-Free Nonlinear-Optical Crystals A 3 Ba 3 Li 2 Ga 4 B 6 O 20 F (A = K and Rb): Members of the Sr 2 Be 2 (BO 3 ) 2 O Family with a Strong Covalent Connection between the ∞ 2 [Li 2 Ga 4 B 6 O 20 F] 9– Double Layers27Li2BaSc(BO3)2F and LiBa2Pb(BO3)2F with Layered Structures featuring Special Li−O/F Configurations11The linear and nonlinear optical response of CsGeX3 (X=Cl, Br, and I): The finite field and first-principles investigation26Ba 3 Ca 4 (BO 3 ) 3 (SiO 4 )Cl: a new non-centrosymmetric complex alkaline-earth metal borosilicate chloride with a deep-ultraviolet cut-off edge19Exploration of the deep-ultraviolet nonlinear optical materials in the derivatives of KBe2BO3F27Sn 2 B 7 O 12 F with a 2∞[B 14 O 24 ] 6− layer constructed from the unprecedented [B 7 O 16 ] 11− fundamental building block18Rational Design via Synergistic Combination Leads to an Outstanding Deep-Ultraviolet Birefringent Li2Na2B2O5 Material with an Unvalued B2O5 Functional Gene284Research and Development of Zincoborates: Crystal Growth, Structural Chemistry and Physicochemical Properties20[NH4]12[(MoO2)2O(HPO4)2]4[PO4]Cl·0.5H2O: A mixed phosphomolybdate with nonlinear optical properties4Structural Origin of Thermally Induced Second Harmonic Generation Enhancement in RbNaMgP2O721Electrochemiluminescence immunoassay for the N-terminal pro-B-type natriuretic peptide based on resonance energy transfer between a self-enhanced luminophore composed of silver nanocubes on gold nanoparticles and a metal-organic framework of type MIL-12527Syntheses, characterization, and theoretical calculation of Rb2Mg3(P2O7)2 polymorphs with deep-ultraviolet cutoff edges18Syntheses, characterization and calculations of LimAnM6O15 (A=Rb, Cs; M=Si, Ge; m+n=6)18Borates: A Rich Source for Optical Materials1089BaZn 3 (BO 3 ) 2 F 2 : a new beryllium-free zincoborate with a KBBF-type structure11Ultraviolet nonlinear optical crystals A 3 SrBi(P 2 O 7 ) 2 (A = K, Rb) with large second harmonic generation responses15Borosilicate Crystal LaBSiO5: A New Promising Ultraviolet Quasiphase Matching Material31Vibrational and optical studies of a nonlinear optical crystal, Cs2Bi2O(Ge2O7)3Third‐Order Nonlinear Optical Response‐Driven Upconversion Phosphors8Exploring Deep-UV Nonlinear Optical Materials with Enhanced Second Harmonic Generation Response and Birefringence in Fluoroaluminoborate Crystals69Modified KBBF-like Material for Energy Storage Applications: ZnNiBO3(OH) with Enhanced Cycle Life23Inorganic nonlinear optical materials7[C(NH2)3]2Zn(CO3)2: A Guanidinium-Templated Ultraviolet Nonlinear Optical Material20Li0.5Na0.5AlB2O4F2: Fluoroaluminoborate with Aligned 1∞[BO2] Chain Induced by Unprecedented [AlO3F3]6− Species Features Enhanced Birefringence30Aluminoborates as Nonlinear Optical Materials79Aluminoborates as Nonlinear Optical Materials14A promising ultraviolet nonlinear optical crystal: Rb 3 Ba 3 Li 2 Al 4 B 6 O 20 F—crystal growth, physical properties, and 266 nm laser generation17Accurate design and synthesis of nonlinear optical crystals employing KBe2BO3F2 as structural template55Fluorooxoborates: A precious treasure of deep-ultraviolet nonlinear optical materials24A Rare‐Earth Selenite with Unexpectedly Well‐Balanced Ultraviolet Nonlinear Optical Functionality, Sc(HSeO 3 ) 331Recent progress in ultraviolet and deep-ultraviolet nonlinear optical aluminoborates17Rb 3 MgB 5 O 10 and LiBaAl(BO 3 ) 2 : covalent tetrahedra MO 4 -containing borates with deep-ultraviolet cutoff edges91D Cu( i )-based chiral organic–inorganic hybrid material with second harmonic generation and circular polarized luminescence10LiASi2O5 (A = K, Rb): Effects of cations on crystal structure and optical properties1Toward the ultraviolet (UV) or deep-UV nonlinear optical crystals: The combination of π-conjugated planar [XY3] and tetrahedral [XY4]80Review on birefringence in borates based on birefringence-active functional groups and arrangements57Synthesis and large crystal growth of a family of mixed-anionic methanesulfonate salts by anionic site-substitution: Na 5 (SO 3 CH 3 ) 4 (X) (X = BF 4 − , ClO 4 − , PF 6 − , I − )9层状结构深紫外非线性光学晶体研究进展（特邀）2A Promising Short-Wave UV NLO Crystal with an Optimized KBBF-like Structure and Well-Balanced Properties Achieved via a Chemical Substitution Strategy6MOF-derived hollow (single-double-, triple-, and quadruple-shell) nanostructure for energy conversion and storage applications: A review21Cation‐Dominated Second‐Order Nonlinear Optical Response Enabled by π‐Conjugated Guanidinium Derivatives5Cation‐Dominated Second‐Order Nonlinear Optical Response Enabled by π‐Conjugated Guanidinium Derivatives0K3Sr3Li2Ga4B6O20F: A Sr2Be2B2O7-Type Ultraviolet Nonlinear Optical Crystal0

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  1. The Next‐Generation of Nonlinear Optical Materials: Rb3Ba3Li2Al4B6O20F—Synthesis, Characterization, and Crystal Growth

    Advanced Optical Materials · 2017-10-10

    Hongwei Yu, Joshua Young, Hongping Wu, Weiguo Zhang, James M. Rondinelli, P. Shiv Halasyamani

    Read original paper ↗ ·

  2. Flux Exploration, Growth, and Optical Spectroscopic Properties of Large Size LaBSiO5 and Eu3+-Substituted LaBSiO5 Crystals

    Crystal Growth & Design · 2017-10-11

    Lingyun Li, Yanping Lin, Lizhen Zhang, Qiuchan Cai, Yan Yu

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  3. K2[B3O3(OH)5]: A new deep-UV nonlinear optical crystal with isolated [B3O3(OH)5]2- anionic groups

    Journal of Alloys and Compounds · 2017-11-16

    Qian Wang, Chensheng Lin, Guohong Zou, Mengjiao Liu, Daojiang Gao, Jian Bi, Ling Huang

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  4. BaLiZn 3 (BO 3 ) 3 : a new member of the KBe 2 BO 3 F 2 family possessing dense BO 3 triangles and the smallest interlayer distance

    New Journal of Chemistry · 2018-01-01

    Yanna Chen, Min Zhang, Shilie Pan

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  5. Na 3 Ca 4 (TeO 3 )(PO 4 ) 3 : a new noncentrosymmetric tellurite phosphate with fascinating multimember-ring architectures and intriguing nonlinear optical performance

    Dalton Transactions · 2018-01-01

    Zhuang Li, Shengzi Zhang, Wenlong Yin, Zheshuai Lin, Jiyong Yao, Yicheng Wu

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  6. Deep-ultraviolet nonlinear optical materials: Development trend and innovative exploration

    Chinese Science Bulletin (Chinese Version) · 2018-03-22

    Minqiang Gai, Ying Wang, Shilie Pan

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  7. The role of cations in second-order nonlinear optical materials based on π-conjugated [BO 3 ] 3− groups

    Coordination Chemistry Reviews · 2018-04-06

    Yaoguo Shen, Sangen Zhao, Junhua Luo

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  8. Deep‐Ultraviolet Nonlinear Optical Crystal Cs2Al2(B3O6)2O: A Benign Member of the Sr2Be2(BO3)2O Family with [Al2(B3O6)2O]2− Double Layers

    Chemistry - A European Journal · 2018-04-15

    Zhi Gang Fang, Xingxing Jiang, Meihong Duan, Zhanyu Hou, Changcheng Tang, Mingjun Xia, Lijuan Liu, Zheshuai Lin, Feidi Fan, Lei Bai, Chuangtian Chen

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  9. Beryllium-Free Nonlinear-Optical Crystals A 3 Ba 3 Li 2 Ga 4 B 6 O 20 F (A = K and Rb): Members of the Sr 2 Be 2 (BO 3 ) 2 O Family with a Strong Covalent Connection between the ∞ 2 [Li 2 Ga 4 B 6 O 20 F] 9– Double Layers

    Inorganic Chemistry · 2018-04-20

    Xianghe Meng, Fei Liang, Mingjun Xia, Zheshuai Lin

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  10. Li2BaSc(BO3)2F and LiBa2Pb(BO3)2F with Layered Structures featuring Special Li−O/F Configurations

    Chemistry - A European Journal · 2018-09-19

    Yanna Chen, Min Zhang, Cong Hu, Hongping Wu, Zhihua Yang, Shilie Pan

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  11. The linear and nonlinear optical response of CsGeX3 (X=Cl, Br, and I): The finite field and first-principles investigation

    Optik · 2018-10-25

    Qiaoqiao Zhang, Hahaer Mushahali, Haiming Duan, Ming‐Hsien Lee, Qun Jing

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  12. Ba 3 Ca 4 (BO 3 ) 3 (SiO 4 )Cl: a new non-centrosymmetric complex alkaline-earth metal borosilicate chloride with a deep-ultraviolet cut-off edge

    Inorganic Chemistry Frontiers · 2019-01-01

    Zixiu Lu, Fangfang Zhang, Abudukadi Tudi, Sujuan Yu, Zhihua Yang, Shilie Pan

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  13. Exploration of the deep-ultraviolet nonlinear optical materials in the derivatives of KBe2BO3F2

    Acta Physica Sinica · 2019-01-01

    Minqiang Gai, Ying Wang, Shilie Pan

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  14. Sn 2 B 7 O 12 F with a 2∞[B 14 O 24 ] 6− layer constructed from the unprecedented [B 7 O 16 ] 11− fundamental building block

    Inorganic Chemistry Frontiers · 2019-01-01

    Zixiu Lu, Fangfang Zhang, Abudukadi Tudi, Zhizhong Zhang, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  15. Rational Design via Synergistic Combination Leads to an Outstanding Deep-Ultraviolet Birefringent Li2Na2B2O5 Material with an Unvalued B2O5 Functional Gene

    Journal of the American Chemical Society · 2019-01-18

    Min Zhang, Donghai An, Cong Hu, Xinglong Chen, Zhihua Yang, Shilie Pan

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  16. Research and Development of Zincoborates: Crystal Growth, Structural Chemistry and Physicochemical Properties

    Molecules · 2019-07-30

    Yanna Chen, Min Zhang, Miriding Mutailipu, Kenneth Reinhard Poeppelmeier, Shilie Pan

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  17. [NH4]12[(MoO2)2O(HPO4)2]4[PO4]Cl·0.5H2O: A mixed phosphomolybdate with nonlinear optical properties

    Inorganica Chimica Acta · 2019-10-08

    Zhongqi Jiang, Wenqiang Chen, Qun Jing, Ming‐Hsien Lee, Zhaohui Chen

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  18. Structural Origin of Thermally Induced Second Harmonic Generation Enhancement in RbNaMgP2O7

    Chemistry of Materials · 2019-11-07

    Xiaoyan Yang, Sangen Zhao, Shipeng Geng, Li Yang, Qingzhen Huang, Xiaojun Kuang, Junhua Luo, Xianran Xing

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  19. Electrochemiluminescence immunoassay for the N-terminal pro-B-type natriuretic peptide based on resonance energy transfer between a self-enhanced luminophore composed of silver nanocubes on gold nanoparticles and a metal-organic framework of type MIL-125

    Microchimica Acta · 2019-11-19

    Dong Qian Xue, Guanhui Zhao, Xuan Li, Juncong Miao, Jinglong Fang, Qin Lei Wei, Wei Cao

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  20. Syntheses, characterization, and theoretical calculation of Rb2Mg3(P2O7)2 polymorphs with deep-ultraviolet cutoff edges

    Science China Materials · 2019-12-20

    Hongping Wu, Shiwei Liu, Shichao Cheng, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  21. Syntheses, characterization and calculations of LimAnM6O15 (A=Rb, Cs; M=Si, Ge; m+n=6)

    Science China Materials · 2020-05-15

    Jingjing Xu, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  22. Borates: A Rich Source for Optical Materials

    Chemical Reviews · 2020-12-14

    Miriding Mutailipu, Kenneth Reinhard Poeppelmeier, Shilie Pan

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  23. BaZn 3 (BO 3 ) 2 F 2 : a new beryllium-free zincoborate with a KBBF-type structure

    Dalton Transactions · 2021-01-01

    Haotian Qiu, Ming Xia, Wenbing Cai, Zhihua Yang, Yanli Liu, Miriding Mutailipu, Shilie Pan

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  24. Ultraviolet nonlinear optical crystals A 3 SrBi(P 2 O 7 ) 2 (A = K, Rb) with large second harmonic generation responses

    Inorganic Chemistry Frontiers · 2021-01-01

    Shiwei Liu, Bingbing Zhang, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  25. Borosilicate Crystal LaBSiO5: A New Promising Ultraviolet Quasiphase Matching Material

    Advanced Optical Materials · 2021-03-10

    Hongyuan Sha, Rongbing Su, Zheyao Xiong, Zujian Wang, Pai Shan, Chao He, Xiaoming Yang, Xifa Long

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  26. Vibrational and optical studies of a nonlinear optical crystal, Cs2Bi2O(Ge2O7)

    Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy · 2021-04-20

    Aneta Ciupa, Jan A. Zienkiewicz, Mariusz Stefański, Maciej Ptak, A. Majchrowski, M. Chrunik

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  27. Third‐Order Nonlinear Optical Response‐Driven Upconversion Phosphors

    Advanced Optical Materials · 2021-06-16

    Noolu Srinivasa Manikanta Viswanath, Jeong Bin Cho, Hye Ryung Byun, Joo Hyeong Han, Sanjith Unithrattil, Joon Ik Jang, Kang Min Ok, Won Bin Im

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  28. Exploring Deep-UV Nonlinear Optical Materials with Enhanced Second Harmonic Generation Response and Birefringence in Fluoroaluminoborate Crystals

    ACS Applied Materials & Interfaces · 2021-06-23

    Hongkun Liu, Bingbing Zhang, Ling Li, Ying Wang

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  29. Modified KBBF-like Material for Energy Storage Applications: ZnNiBO3(OH) with Enhanced Cycle Life

    ACS Applied Materials & Interfaces · 2022-02-01

    Iftikhar Hussain, Tanveer Hussain, Muhammad Ahmad, Xiaoxia Ma, Muhammad Sufyan Javed, Charmaine Lamiel, Yatu Chen, Rajeev Ahuja, Kaili Zhang

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  30. Inorganic nonlinear optical materials

    Elsevier eBooks · 2022-02-25

    Chunmei Huang, Fangfang Zhang, Shilie Pan

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  31. [C(NH2)3]2Zn(CO3)2: A Guanidinium-Templated Ultraviolet Nonlinear Optical Material

    Inorganic Chemistry · 2022-07-25

    Zhiyong Bai, Lehui Liu, Zhoubin Lin, Kang Min Ok

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  32. Li0.5Na0.5AlB2O4F2: Fluoroaluminoborate with Aligned 1∞[BO2] Chain Induced by Unprecedented [AlO3F3]6− Species Features Enhanced Birefringence

    Advanced Optical Materials · 2022-11-17

    Ziting Yan, Dongdong Chu, Min Zhang, Zhihua Yang, Shilie Pan

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  33. Aluminoborates as Nonlinear Optical Materials

    Angewandte Chemie International Edition · 2022-12-13

    Jiahao Jiao, Min Zhang, Shilie Pan

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  34. Aluminoborates as Nonlinear Optical Materials

    Angewandte Chemie · 2022-12-13

    Jiahao Jiao, Min Zhang, Shilie Pan

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  35. A promising ultraviolet nonlinear optical crystal: Rb 3 Ba 3 Li 2 Al 4 B 6 O 20 F—crystal growth, physical properties, and 266 nm laser generation

    Journal of Materials Chemistry C · 2022-12-15

    Jiankang Wang, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  36. Accurate design and synthesis of nonlinear optical crystals employing KBe2BO3F2 as structural template

    Chinese Journal of Structural Chemistry · 2023-01-01

    Tao Ouyang, Yaoguo Shen, Sangen Zhao

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  37. Fluorooxoborates: A precious treasure of deep-ultraviolet nonlinear optical materials

    Chinese Journal of Structural Chemistry · 2023-02-03

    Hongkang Su, Ziting Yan, Xueling Hou, Min Zhang

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  38. A Rare‐Earth Selenite with Unexpectedly Well‐Balanced Ultraviolet Nonlinear Optical Functionality, Sc(HSeO 3 ) 3

    Small · 2023-02-09

    Zhiyong Bai, Jihyun Lee, Heewon Kim, Yunseung Kuk, Myung‐Ho Choi, Chun‐Li Hu, Kang Min Ok

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  39. Recent progress in ultraviolet and deep-ultraviolet nonlinear optical aluminoborates

    Chinese Journal of Structural Chemistry · 2023-02-17

    Qingfen Li, Weifeng Chen, You‐Zhao Lan, Jian‐Wen Cheng

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  40. Rb 3 MgB 5 O 10 and LiBaAl(BO 3 ) 2 : covalent tetrahedra MO 4 -containing borates with deep-ultraviolet cutoff edges

    Dalton Transactions · 2023-12-07

    Hongkang Su, Jiahao Jiao, Shi‐Bin Wang, Donghai An, Min Zhang

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  41. 1D Cu( i )-based chiral organic–inorganic hybrid material with second harmonic generation and circular polarized luminescence

    Dalton Transactions · 2024-01-01

    Zhiyuan Wu, Muxin Yu, Ziqing Zhang, Jiaxin Jiang, Ting Liu, Feilong Jiang, Lian Chen, Maochun Hong

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  42. LiASi2O5 (A = K, Rb): Effects of cations on crystal structure and optical properties

    Optical Materials · 2024-01-08

    Jun Sun, Bo Ran, Ping Hu, Zhaofeng Wu, Ming‐Hsien Lee, Haiming Duan

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  43. Toward the ultraviolet (UV) or deep-UV nonlinear optical crystals: The combination of π-conjugated planar [XY3] and tetrahedral [XY4]

    Coordination Chemistry Reviews · 2024-02-02

    W. Zhang, Xueling Hou, Shujuan Han, Shilie Pan

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  44. Review on birefringence in borates based on birefringence-active functional groups and arrangements

    Science China Chemistry · 2024-06-14

    Qianzhen Zhang, Ran An, Zhihua Yang, Xifa Long, Shilie Pan, Yun Mo Yang

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  45. Synthesis and large crystal growth of a family of mixed-anionic methanesulfonate salts by anionic site-substitution: Na 5 (SO 3 CH 3 ) 4 (X) (X = BF 4 − , ClO 4 − , PF 6 − , I − )

    Dalton Transactions · 2025-01-01

    Eric A. Gabilondo, P. Shiv Halasyamani

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  46. 层状结构深紫外非线性光学晶体研究进展（特邀）

    Chinese Journal of Lasers · 2025-01-01

    彭广 Peng Guang, 韩言鸣 Han Yanming, 叶宁 Ye Ning

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  47. A Promising Short-Wave UV NLO Crystal with an Optimized KBBF-like Structure and Well-Balanced Properties Achieved via a Chemical Substitution Strategy

    Inorganic Chemistry · 2025-07-02

    Shuaifeng Li, Mengru Liu, Peng Zhao, Huijian Zhao, Ning Ye, Zhanggui Hu, Conggang Li

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  48. MOF-derived hollow (single-double-, triple-, and quadruple-shell) nanostructure for energy conversion and storage applications: A review

    Renewable and Sustainable Energy Reviews · 2025-08-21

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  49. Cation‐Dominated Second‐Order Nonlinear Optical Response Enabled by π‐Conjugated Guanidinium Derivatives

    Angewandte Chemie International Edition · 2026-04-09

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  50. Cation‐Dominated Second‐Order Nonlinear Optical Response Enabled by π‐Conjugated Guanidinium Derivatives

    Angewandte Chemie · 2026-04-09

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