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RESEARCH PAPER · Chinese Journal of Structural Chemistry · 2023

Accurate design and synthesis of nonlinear optical crystals employing KBe2BO3F2 as structural template

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Accurate design and synthesis of nonlinear optical crystals employing KBe2BO3F2 as structural templateOriginalGa(IO 3 ) 3 : a mid-IR nonlinear optical iodate with balanced performance between band gap and second harmonic generation response4Cs 2 Mg(H 2 C 3 N 3 S 3 ) 4 ·8H 2 O: An Excellent Birefringent Material with Giant Optical Anisotropy in π-Conjugated Trithiocyanurate19Recent Progress in Crystalline Borates with Edge-Sharing BO4 Tetrahedra21Na1.5Cs0.5[Al{BO3}{B9O15(OH)3}1/3]: An Acentric Layered Aluminoborate with Nonlinear-Optical Properties9A Non‐π‐Conjugated Molecular Crystal with Balanced Second‐Harmonic Generation, Bandgap, and Birefringence10Sr(NH2SO3)(NO3)·H2O: An Ultraviolet Nonlinear Optical Material Exhibiting Strong Second-Harmonic Generation Response and Sufficient Birefringence10Tailored Synthesis of Two Metal Borates KSrM3B2O9 (M = Al and Ga) Exhibiting Wide Ultraviolet Transparency4Synthesis, crystal structure, and spectroscopic characterization of aminoguanidinium thiosulfate, (CN4H7)2S2O35Two van der Waals Layered Antimony(III) Phosphites as UV Optical Materials11Enhancing nonlinear optical responses via Methoxy Positional Isomerism in Chalcone-Based Materials15Deep‐Ultraviolet Transparent Mixed Metal Sulfamates with Enhanced Nonlinear Optical Properties and Birefringence11Deep‐Ultraviolet Transparent Mixed Metal Sulfamates with Enhanced Nonlinear Optical Properties and Birefringence75Angular non-critical phase-matching second harmonic generation with the Ba3(ZnB5O10)PO4 crystal5Na 2 CeF 6 : A Highly Laser Damage‐Tolerant Double Perovskite Type Ce(IV) Fluoride Exhibiting Strong Second‐Harmonic Generation Effect30A Ferroelectric Nonlinear Optical Crystal for Deep‐UV Quasi‐Phase‐Matching51CsSn2(HPO3)2I: The first inorganic metal phosphite iodide as a promising birefringent material exhibits a large birefringence with ideally layered framework24A nonlinear optical crystal with deep-ultraviolet transparency and appropriate birefringence achieved using π-conjugated confined [B 3 O 3 F 4 (OH)] 2−14Galloborates as ultraviolet nonlinear optical crystals: advances and perspectives8Rare-earth oxychalcogenide Eu 2 ZnGe 2 OS 6 : a phase-matching infrared nonlinear optical material with [GeOS 3 ] units7Designing Optical Anisotropy: Silver-Aminoalkylpyridine Nitrate Complexes with Tunable Structures3Li13YGe4O16: A Mid-infrared Rare-Earth Germanate Nonlinear Optical Crystal Featuring a Broad Transmission Range and an Enlarged Band Gap10The local state of hydrogen atoms and proton transfer in the crystal structure of natural berborite, Be2(BO3)(OH)‧H2O: Low-temperature single crystal X-ray analysis, IR and 1H NMR spectroscopy, and crystal chemistry and structural complexity of beryllium borates8Crystal Growth, Optical, Thermal, DFT and Z‐Scan Studies of Imidazolium Hydrogen Fumarate Crystal for Nonlinear Optical Applications3Pb3[O10Pb20](SiO4)4X10 (X = Cl, Br): The First Pb-Containing Halogen Silicates with Mirror-Symmetric Pseudo-Aurivillius Bilayers3Sr2[B5O8(OH)]2 ⋅ [B(OH)3] ⋅ H2O: A Strontium Borate That Shows Deep‐Ultraviolet‐Transparent Nonlinear Optical Properties17Magneto‐chiral Nonlinear Optical Effect with Large Anisotropic Response in Two‐Dimensional Halide Perovskite52Magneto‐chiral Nonlinear Optical Effect with Large Anisotropic Response in Two‐Dimensional Halide Perovskite3Centrosymmetry-Breaking Morphotropic Phase Boundary: A Pathway to Highly Sensitive and Strong Pressure-Responsive Nonlinear Optical Switches4Coupling between cation and anion disorder in β-K 2 Ca 3 (CO 3 ) 44A Highly Optical Anisotropic Hybrid Perovskite for Efficient Manipulation of Light Polarization64M6[Cd2(CO3)2(B12O18)(OH)6] (M = K, Rb): Borate–Carbonates with Two CdCO3 Embedded in a Cyclic Oxoboron Anion10(C 8 H 7 N 2 O 2 ) 2 [Bi 2 Br 8 ]·2H 2 O and (C 8 H 7 N 2 O 2 ) 6 [Bi 2 Cl 10 ]Cl 2 ·2H 2 O: Exploring Birefringent Crystals in Hybrid Halide Systems5Zn(C6H4NO2)2·4H2O: A Solar-Blind Birefringent Crystal5Extrinsic magnetised plasma kolakoski quasicrystal3Mechanosynthesis and microstructural characterization of F− and CO32− mono- and co-substituted hydroxyapatite5Synthesis, Growth, and Luminescence Properties of Rare Earth Borates KSrY(BO3)2: Tb3+ and Tb4+6Noncentrosymmetric Crystal [C10H8NO2]2SiF6·H2O with Large Birefringence12Designing a 2D van der Waals oxide with lone-pair electrons as chemical scissor15Graph neural network guided design of novel deep-ultraviolet optical materials with high birefringence23Rational Design of Novel Polar Nonlinear Optical Materials in Alkali Metal Rare Earth Iodates5Nonlinear optical properties and structural characterization of a series of carboxyanilinium hydrogen selenite hybrids: Synthesis, first-principles calculations and correlation analysis for advanced photonic applications14From β-KB3O4F2 to α-KB3O4F2: Phase Transition-Directed Great Changes in Structure and Optical Anisotropy4The (C2N2H10)[Cu(H2O)4](TX4)2 Structural Family: When Fluoroberyllate, Sulfate, and Selenate Are Full Analogs7Ln(HCOO) 3 (Ln = Y, Gd, Ce, and La) With Triangular Configuration Exhibits Excellent UV Nonlinear Optical Performance12Polar [ NH ( CH2SO3 )2]2− Dimers Enable the First Promising Iminodimethanesulfonate with Nonlinear Optical Properties and Wide UV Transparency19Giant Birefringence Enabled by the Highly Anisotropic Linear IX 2 − (X = Cl, Br) Building Blocks6Giant Birefringence Enabled by the Highly Anisotropic Linear IX 2 − (X = Cl, Br) Building Blocks32A Promising Short-Wave UV NLO Crystal with an Optimized KBBF-like Structure and Well-Balanced Properties Achieved via a Chemical Substitution Strategy6Anion-Ordered [B3O5(OH)2] Induced by Crystal Water with Deep Ultraviolet Transparency and Large Birefringence in Boron-Rich Borophosphates4Borosilicates as deep-ultraviolet transparent nonlinear optical crystals: Structural motifs, performance limits and future directions9Five-Membered [C 5 O 5 ] 2 – Rings as Birefringence-Active Genes for Ultrabirefringent Crystals27Chiral-Unit-Driven Short-Wave Ultraviolet Nonlinear Optical Acetates with Balanced Overall Optical Properties3An Ultraviolet Transparent Nonlinear Optical Crystal Assembled from a Polarizable Tetrahedral Unit1Magnesium Methylphosphonate Ultraviolet Nonlinear Optical Crystal With Ultrawide Bandgap and Strong Second‐Harmonic Generation Response0Zn(C 2 H 4 NO 2 ) 2 (SO 2 CH 3 NH 2 ) 2 and Zn(C 2 H 4 NO 2 ) 2 [SO 2 (NH 2 ) 2 ]: Regulation of Unique ZnO(C 2 H 4 NO 2 ) 2 Units by Polar Tetrahedrons for Balanced UV Nonlinear Optical Performance0

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  1. Ga(IO 3 ) 3 : a mid-IR nonlinear optical iodate with balanced performance between band gap and second harmonic generation response

    Journal of Materials Chemistry C · 2023-01-01

    Dandan Wang, Xinyuan Zhang, Pifu Gong, Zheshuai Lin, Zhanggui Hu, Yicheng Wu

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  2. Cs 2 Mg(H 2 C 3 N 3 S 3 ) 4 ·8H 2 O: An Excellent Birefringent Material with Giant Optical Anisotropy in π-Conjugated Trithiocyanurate

    Inorganic Chemistry · 2023-05-11

    Xia Hao, Chensheng Lin, Min Luo, Yuqiao Zhou, Ning Ye, Enbo Shangguan

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  3. Recent Progress in Crystalline Borates with Edge-Sharing BO4 Tetrahedra

    Molecules · 2023-06-28

    Jinɡjinɡ Li, Weifeng Chen, You‐Zhao Lan, Jian‐Wen Cheng

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  4. Na1.5Cs0.5[Al{BO3}{B9O15(OH)3}1/3]: An Acentric Layered Aluminoborate with Nonlinear-Optical Properties

    Inorganic Chemistry · 2023-08-21

    Chong‐An Chen, Guo‐Yu Yang

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  5. A Non‐π‐Conjugated Molecular Crystal with Balanced Second‐Harmonic Generation, Bandgap, and Birefringence

    Small · 2023-09-08

    Zhou Yang, Nan He, Zheshuai Lin, Xiaoying Shang, Xueyuan Chen, Yanqiang Li, Weiqi Huang, Maochun Hong, Sangen Zhao, Junhua Luo

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  6. Sr(NH2SO3)(NO3)·H2O: An Ultraviolet Nonlinear Optical Material Exhibiting Strong Second-Harmonic Generation Response and Sufficient Birefringence

    Inorganic Chemistry · 2023-10-20

    Xia Hao, Chensheng Lin, Min Luo, Ning Ye

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  7. Tailored Synthesis of Two Metal Borates KSrM3B2O9 (M = Al and Ga) Exhibiting Wide Ultraviolet Transparency

    Inorganic Chemistry · 2023-10-23

    Shuaifeng Li, Jinmiao Jiao, Yuheng She, Ning Ye, Zhanggui Hu, Yicheng Wu, Conggang Li

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  8. Synthesis, crystal structure, and spectroscopic characterization of aminoguanidinium thiosulfate, (CN4H7)2S2O3

    Zeitschrift für anorganische und allgemeine Chemie · 2023-11-07

    Dmitri O. Charkin, A. M. Banaru, Semen A. Ivanov, Vadim E. Kireev, Dmitri N. Dmitriev, Sergey M. Aksenov

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  9. Two van der Waals Layered Antimony(III) Phosphites as UV Optical Materials

    Inorganic Chemistry · 2023-11-10

    Yuxi Liu, Ying Long, Wei Zeng, Yao Tian, Hongmei Zeng, Xuehua Dong, Zhien Lin, Guohong Zou

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  10. Enhancing nonlinear optical responses via Methoxy Positional Isomerism in Chalcone-Based Materials

    Materials Chemistry and Physics · 2023-11-13

    S.R. Shankara, K.M. Eshwarappa, A. Jayarama, S. S. Prabhu, R. Pinto

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  11. Deep‐Ultraviolet Transparent Mixed Metal Sulfamates with Enhanced Nonlinear Optical Properties and Birefringence

    Angewandte Chemie · 2023-11-17

    Xuefei Wang, Xudong Leng, Yunseung Kuk, Jihyun Lee, Qun Jing, Kang Min Ok

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  12. Deep‐Ultraviolet Transparent Mixed Metal Sulfamates with Enhanced Nonlinear Optical Properties and Birefringence

    Angewandte Chemie International Edition · 2023-11-17

    Xuefei Wang, Xudong Leng, Yunseung Kuk, Jihyun Lee, Qun Jing, Kang Min Ok

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  13. Angular non-critical phase-matching second harmonic generation with the Ba3(ZnB5O10)PO4 crystal

    Optical Materials · 2023-11-28

    Yun‐Ru Chen, Jialing Wu, Jiajia Wang, Shihui Ma, Hongwei Yu

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  14. Na 2 CeF 6 : A Highly Laser Damage‐Tolerant Double Perovskite Type Ce(IV) Fluoride Exhibiting Strong Second‐Harmonic Generation Effect

    Small · 2023-12-05

    Ru‐Ling Tang, Wei Xu, Xin Lian, Yue‐Qi Wei, Yi‐Lei Lv, Wenlong Liu, Sheng‐Ping Guo

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  15. A Ferroelectric Nonlinear Optical Crystal for Deep‐UV Quasi‐Phase‐Matching

    Advanced Functional Materials · 2023-12-10

    Yipeng Song, Hongwei Yu, Bingxuan Li, Xiaoqi Li, Zhou Yang, Yanqiang Li, Chao He, Ge Zhang, Junhua Luo, Sangen Zhao

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  16. CsSn2(HPO3)2I: The first inorganic metal phosphite iodide as a promising birefringent material exhibits a large birefringence with ideally layered framework

    Scripta Materialia · 2023-12-14

    Liang Ma, Wei Xu, Liyuanyue Xu, Yi‐Lei Lv, Wenlong Liu, Sheng‐Ping Guo, Ru‐Ling Tang

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  17. A nonlinear optical crystal with deep-ultraviolet transparency and appropriate birefringence achieved using π-conjugated confined [B 3 O 3 F 4 (OH)] 2−

    New Journal of Chemistry · 2024-01-01

    Tao Ouyang, Chen Xu, Shanshan Chen, Yanqiang Li, Xiaoying Shang, Zhiyong Bai, Ningtao Jiang, Zhishuo Yan, Junhua Luo, Sangen Zhao

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  18. Galloborates as ultraviolet nonlinear optical crystals: advances and perspectives

    Dalton Transactions · 2024-01-01

    Jingyi Lu, Yangfeifei Ou, Congcong Jin, Jian‐Wen Cheng

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  19. Rare-earth oxychalcogenide Eu 2 ZnGe 2 OS 6 : a phase-matching infrared nonlinear optical material with [GeOS 3 ] units

    CrystEngComm · 2024-01-01

    G F Wang, Wentian Wu, Chunxiao Li, Jiyong Yao

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  20. Designing Optical Anisotropy: Silver-Aminoalkylpyridine Nitrate Complexes with Tunable Structures

    Inorganic Chemistry · 2024-01-23

    Myung‐Ho Choi, Yang Li, Kang Min Ok

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  21. Li13YGe4O16: A Mid-infrared Rare-Earth Germanate Nonlinear Optical Crystal Featuring a Broad Transmission Range and an Enlarged Band Gap

    Inorganic Chemistry · 2024-02-15

    Jinmiao Jiao, Conggang Li, Yuheng She, Haiyan Shi, Wenhao Di, Ning Ye, Zhanggui Hu, Yicheng Wu

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  22. The local state of hydrogen atoms and proton transfer in the crystal structure of natural berborite, Be2(BO3)(OH)‧H2O: Low-temperature single crystal X-ray analysis, IR and 1H NMR spectroscopy, and crystal chemistry and structural complexity of beryllium borates

    Journal of Physics and Chemistry of Solids · 2024-02-22

    Sergey M. Aksenov, Nikita V. Chukanov, Viktor P. Tarasov, Daria A. Banaru, Stephanie A. Mackley, A. M. Banaru, Sergey V. Krivovichev, Peter Carman Burns

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  23. Crystal Growth, Optical, Thermal, DFT and Z‐Scan Studies of Imidazolium Hydrogen Fumarate Crystal for Nonlinear Optical Applications

    Crystal Research and Technology · 2024-03-04

    Elavarasi Chinnakannu, Mugundan Sankar, Senthilkumar Chandran, Keerthivasan Thamotharan, Srinivasan Manickam

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  24. Pb3[O10Pb20](SiO4)4X10 (X = Cl, Br): The First Pb-Containing Halogen Silicates with Mirror-Symmetric Pseudo-Aurivillius Bilayers

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  25. Sr2[B5O8(OH)]2 ⋅ [B(OH)3] ⋅ H2O: A Strontium Borate That Shows Deep‐Ultraviolet‐Transparent Nonlinear Optical Properties

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  26. Magneto‐chiral Nonlinear Optical Effect with Large Anisotropic Response in Two‐Dimensional Halide Perovskite

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  27. Magneto‐chiral Nonlinear Optical Effect with Large Anisotropic Response in Two‐Dimensional Halide Perovskite

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  28. Centrosymmetry-Breaking Morphotropic Phase Boundary: A Pathway to Highly Sensitive and Strong Pressure-Responsive Nonlinear Optical Switches

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  29. Coupling between cation and anion disorder in β-K 2 Ca 3 (CO 3 ) 4

    Journal of Applied Crystallography · 2024-04-12

    Sergey V. Rashchenko, Mark A. Ignatov, Anton F. Shatskiy, Anton V. Arefiev, Konstantin D. Litasov

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  30. A Highly Optical Anisotropic Hybrid Perovskite for Efficient Manipulation of Light Polarization

    Advanced Functional Materials · 2024-05-08

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  31. M6[Cd2(CO3)2(B12O18)(OH)6] (M = K, Rb): Borate–Carbonates with Two CdCO3 Embedded in a Cyclic Oxoboron Anion

    Inorganic Chemistry · 2024-05-09

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  32. (C 8 H 7 N 2 O 2 ) 2 [Bi 2 Br 8 ]·2H 2 O and (C 8 H 7 N 2 O 2 ) 6 [Bi 2 Cl 10 ]Cl 2 ·2H 2 O: Exploring Birefringent Crystals in Hybrid Halide Systems

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    Mingliang Ding, Qiong Sen Wu, Yaoguo Shen, Jinquan Hong, Guofa Dong, Liang Ma

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  33. Zn(C6H4NO2)2·4H2O: A Solar-Blind Birefringent Crystal

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  34. Extrinsic magnetised plasma kolakoski quasicrystal

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  35. Mechanosynthesis and microstructural characterization of F− and CO32− mono- and co-substituted hydroxyapatite

    Journal of Molecular Structure · 2024-05-30

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  36. Synthesis, Growth, and Luminescence Properties of Rare Earth Borates KSrY(BO3)2: Tb3+ and Tb4+

    Crystal Growth & Design · 2024-06-19

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  37. Noncentrosymmetric Crystal [C10H8NO2]2SiF6·H2O with Large Birefringence

    Inorganic Chemistry · 2024-07-12

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  38. Designing a 2D van der Waals oxide with lone-pair electrons as chemical scissor

    National Science Review · 2024-10-20

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  39. Graph neural network guided design of novel deep-ultraviolet optical materials with high birefringence

    Science China Materials · 2024-10-22

    Ivan A. Kruglov, Liudmila A. Bereznikova, Congwei Xie, Dongdong Chu, Ke Li, Evgenii Tikhonov, Abudukadi Tudi, Arslan Mazitov, Min Zhang, Shilie Pan, Zhihua Yang

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  40. Rational Design of Novel Polar Nonlinear Optical Materials in Alkali Metal Rare Earth Iodates

    Inorganic Chemistry · 2024-10-23

    Lijuan Liu, Haotian Tian, Mingjun Xia, Xiaoyang Wang

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  41. Nonlinear optical properties and structural characterization of a series of carboxyanilinium hydrogen selenite hybrids: Synthesis, first-principles calculations and correlation analysis for advanced photonic applications

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  42. From β-KB3O4F2 to α-KB3O4F2: Phase Transition-Directed Great Changes in Structure and Optical Anisotropy

    Inorganic Chemistry · 2024-11-06

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  43. The (C2N2H10)[Cu(H2O)4](TX4)2 Structural Family: When Fluoroberyllate, Sulfate, and Selenate Are Full Analogs

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  44. Ln(HCOO) 3 (Ln = Y, Gd, Ce, and La) With Triangular Configuration Exhibits Excellent UV Nonlinear Optical Performance

    Small · 2025-02-07

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  45. Polar [ NH ( CH2SO3 )2]2− Dimers Enable the First Promising Iminodimethanesulfonate with Nonlinear Optical Properties and Wide UV Transparency

    Chinese Journal of Chemistry · 2025-03-25

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  46. Giant Birefringence Enabled by the Highly Anisotropic Linear IX 2 − (X = Cl, Br) Building Blocks

    Angewandte Chemie · 2025-04-16

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  47. Giant Birefringence Enabled by the Highly Anisotropic Linear IX 2 − (X = Cl, Br) Building Blocks

    Angewandte Chemie International Edition · 2025-04-16

    Chong‐An Chen, Yang Li, Hongbo Huang, Congcong Jin, Bingbing Zhang, Kang Min Ok

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  48. A Promising Short-Wave UV NLO Crystal with an Optimized KBBF-like Structure and Well-Balanced Properties Achieved via a Chemical Substitution Strategy

    Inorganic Chemistry · 2025-07-02

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  49. Anion-Ordered [B3O5(OH)2] Induced by Crystal Water with Deep Ultraviolet Transparency and Large Birefringence in Boron-Rich Borophosphates

    Chemistry of Materials · 2025-08-20

    Huanhuan Zhao, Chenxu Li, Zhihua Yang, Xueling Hou, Jian Wei Han, Shilie Pan

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  50. Borosilicates as deep-ultraviolet transparent nonlinear optical crystals: Structural motifs, performance limits and future directions

    Chinese Journal of Structural Chemistry · 2025-09-01

    Yangfeifei Ou, Xiaoliang Zhou, You‐Zhao Lan, Jian‐Wen Cheng

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