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RESEARCH PAPER · Inorganic Chemistry · 2023

Mixed Alkali Metal and Alkaline Earth Metal Scandium Borate Birefringence Material with Layered Structure and Short Ultraviolet Cutoff Edge

Wenhao Liu, Pifu Gong, Weiqi Huang, Mengran Sun, Sangen Zhao, Zheshuai Lin, Jiyong Yao

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Mixed Alkali Metal and Alkaline Earth Metal Scandium Borate Birefringence Material with Layered Structure and Short Ultraviolet Cutoff EdgeOriginalBa4Cd2Ge2Te9: A promising infrared functional crystal with large birefringent and photoluminescence properties2From BaAlBO 3 F 2 to BaAlB 3 O 6 F 2 and BaAl 2 (B 3 O 6 ) 2 F 2 : the enhancement of birefringence and band gap by extending the π-conjugated system combined with [Al–O/F] functional groups13Ba5Gd3(BO3)6F: A new alkaline earth-rare earth fluoroborate with magnetocaloric effect3NaRbB10O14(OH)4 and Na3CsB10O16(OH)2: Two Cases of Hydroxyborates with [B5Om(OH)n] Units and Deep Ultraviolet Cutoff Edges6Assembly of π‐Conjugated [B 3 O 6 ] Units by Mer‐Isomer [YO 3 F 3 ] Octahedra to Design a UV Nonlinear Optical Material, Cs 2 YB 3 O 6 F 211Assembly of π‐Conjugated [B3O6] Units by Mer‐Isomer [YO3F3] Octahedra to Design a UV Nonlinear Optical Material, Cs2YB3O6F297Old tree blossoms anew: Research progress on the structures and optical properties of ultraviolet selenites56A Rare-Earth-Based Borate Optical Crystal with Enlarged Dihedral Angles of Distinct [BO3] Groups Exhibiting a Wide UV Transparent Range8(C3N2H5)B3O3F2(OH)2: Realizing Large Birefringence via a Synergistic Effect between Anion F/OH‐Ratio Optimization and Cation Activation25(C 7 H 3 NO 4 ) 2 Sb 2 F 2 ·2H 2 O: a pyridine-based compound shows large optical anisotropy4From NaSc 3 Ga 2 Q 8 (Q = S, Se) to KGa 2 In 3 S 8 : substitution of Sc 3+ with In 3+ to achieve doubled birefringence17Sr2Zn(C3N3O3)2: An Alkaline Earth and d10 Transition Metal Based Ultraviolet Cyanurate with Large Birefringence6Recent progress in structural design strategies of high-birefringence optical crystals54Modulation of Crystal Structure and Birefringence: Cation Size Effect in Alkali Metal Fluoroaluminoborates4Charge Compensation via Heterovalent Cation Disorder for Birefringence Modulation to Design UV Nonlinear Optical Crystal0Exploring the luminescence behaviour of RE³ + (Gd, Tb, Eu) activated borate host K₅Mg₂La₃(BO₃)₆0Review on recent trends in NIR-emitting trivalent chromium (Cr 3+ ) ion-doped phosphors for applications in pc-LEDs0

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  1. Ba4Cd2Ge2Te9: A promising infrared functional crystal with large birefringent and photoluminescence properties

    Journal of Alloys and Compounds · 2023-12-29

    Mengran Sun, Haojian Su, Wenhao Liu, Jiyong Yao

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  2. From BaAlBO 3 F 2 to BaAlB 3 O 6 F 2 and BaAl 2 (B 3 O 6 ) 2 F 2 : the enhancement of birefringence and band gap by extending the π-conjugated system combined with [Al–O/F] functional groups

    Inorganic Chemistry Frontiers · 2024-01-01

    Cheng Chen, Danyang Dou, Yunjie Bai, Bingbing Zhang, Ying Wang

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  3. Ba5Gd3(BO3)6F: A new alkaline earth-rare earth fluoroborate with magnetocaloric effect

    Journal of Solid State Chemistry · 2024-04-19

    Yuwei Chen, Pifu Gong, Zuhua Chen, Juhe Liu, Ruixin Guo, Jun Shen, Heng Tu, Guochun Zhang

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  4. NaRbB10O14(OH)4 and Na3CsB10O16(OH)2: Two Cases of Hydroxyborates with [B5Om(OH)n] Units and Deep Ultraviolet Cutoff Edges

    Inorganic Chemistry · 2024-04-24

    Huanhuan Zhao, Die Xu, Zhaohui Chen

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  5. Assembly of π‐Conjugated [B 3 O 6 ] Units by Mer‐Isomer [YO 3 F 3 ] Octahedra to Design a UV Nonlinear Optical Material, Cs 2 YB 3 O 6 F 2

    Angewandte Chemie · 2024-05-07

    Hongping Wu, Zhijun Wei, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  6. Assembly of π‐Conjugated [B3O6] Units by Mer‐Isomer [YO3F3] Octahedra to Design a UV Nonlinear Optical Material, Cs2YB3O6F2

    Angewandte Chemie International Edition · 2024-05-08

    Hongping Wu, Zhijun Wei, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  7. Old tree blossoms anew: Research progress on the structures and optical properties of ultraviolet selenites

    Coordination Chemistry Reviews · 2024-06-15

    Pengfei Li, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

    Read original paper ↗ ·

  8. A Rare-Earth-Based Borate Optical Crystal with Enlarged Dihedral Angles of Distinct [BO3] Groups Exhibiting a Wide UV Transparent Range

    Inorganic Chemistry · 2024-07-26

    Jie Song, Xianghao Kong, Conggang Li, Jinmiao Jiao, Yuheng She, Ning Ye, Zhanggui Hu, Yicheng Wu

    Read original paper ↗ ·

  9. (C3N2H5)B3O3F2(OH)2: Realizing Large Birefringence via a Synergistic Effect between Anion F/OH‐Ratio Optimization and Cation Activation

    Small Structures · 2024-07-28

    Chenhui Hu, Chunjie Shen, Huan Zhou, Jian Wei Han, Zhihua Yang, Kenneth Reinhard Poeppelmeier, Feng Zhang, Shilie Pan

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  10. (C 7 H 3 NO 4 ) 2 Sb 2 F 2 ·2H 2 O: a pyridine-based compound shows large optical anisotropy

    Dalton Transactions · 2025-01-01

    Yaoguo Shen, Jiajia Xiong, Yiman Yang, Zhifeng Tang

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  11. From NaSc 3 Ga 2 Q 8 (Q = S, Se) to KGa 2 In 3 S 8 : substitution of Sc 3+ with In 3+ to achieve doubled birefringence

    Chemical Science · 2025-01-01

    Yun Xie, Wen‐Dong Yao, Qiu-Yang Du, Wenfeng Zhou, Nian‐Tzu Suen, Wenlong Liu, Sheng‐Ping Guo

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  12. Sr2Zn(C3N3O3)2: An Alkaline Earth and d10 Transition Metal Based Ultraviolet Cyanurate with Large Birefringence

    Inorganic Chemistry · 2025-02-03

    N.F. Wang, Xinyuan Zhang, Fei Liang, Zhanggui Hu, Yicheng Wu

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  13. Recent progress in structural design strategies of high-birefringence optical crystals

    Coordination Chemistry Reviews · 2025-05-08

    A-Lan Xu, Mao‐Yin Ran, Xintao Wu, Hua Lin, Qi‐Long Zhu

    Read original paper ↗ ·

  14. Modulation of Crystal Structure and Birefringence: Cation Size Effect in Alkali Metal Fluoroaluminoborates

    Inorganic Chemistry · 2025-08-02

    Chao Wei, Danyang Dou, Bingbing Zhang, Ying Wang

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  15. Charge Compensation via Heterovalent Cation Disorder for Birefringence Modulation to Design UV Nonlinear Optical Crystal

    Advanced Optical Materials · 2026-05-01

    Wenbin Zhang, Wenqi Jin, X. Ma, Zhihua Yang, Fangfang Zhang, Shujuan Han, Shilie Pan

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  16. Exploring the luminescence behaviour of RE³ + (Gd, Tb, Eu) activated borate host K₅Mg₂La₃(BO₃)₆

    Canadian Metallurgical Quarterly · 2026-05-15

    P.K. Tawalare, Renuka Nafdey, S. V. Moharil

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  17. Review on recent trends in NIR-emitting trivalent chromium (Cr 3+ ) ion-doped phosphors for applications in pc-LEDs

    Canadian Metallurgical Quarterly · 2026-07-03

    Shruti Prabhakar Dhale, P.K. Tawalare, Nilesh Sureshrao Ugemuge, S. V. Moharil

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