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RESEARCH PAPER · Inorganic Chemistry · 2018

Intriguing Structural Transition Inducing Variable Birefringences in ABa2MS4Cl (A = Rb, Cs; M = Ge, Sn)

Yu Chu, Kui Wu, Xin Su, Jian Wei Han, Zhihua Yang, Shilie Pan

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Intriguing Structural Transition Inducing Variable Birefringences in ABa2MS4Cl (A = Rb, Cs; M = Ge, Sn)OriginalABaSbQ 3 (A = Li, Na; Q = S, Se): diverse arrangement modes of isolated SbQ 3 ligands regulating the magnitudes of birefringences50Combined experimental and theoretical investigations of Ba 3 GaS 4 I: interesting structural transformation originated from halogen substitution16Structural modulation induced by M IIIA metals in Ba 3 MQ 4 X (M = Al, Ga, In; Q = S, Se; X = Cl, Br): an experimental and computational analysis7Balanced Second-Order Nonlinear Optical Properties of Adducts CHI3·(S8)3 and AsI3·(S8)3: A Systematic Survey48From BiF 3 to BiF 3 ·H 2 O: diverse Bi( iii ) coordination for structural transformation and birefringence regulation14LiBa4Ga5Q12 (Q = S, Se): Noncentrosymmetric Metal Chalcogenides with a Cesium Chloride Topological Structure Displaying a Remarkable Laser Damage Threshold32Functional Chalcogenide Na2HgSn2Se6 and K2MnGe2Se6 Exhibiting Flexible Chain Structure and Intriguing Birefringence Tunability16Chalcophosphates: A Treasure House of Infrared Nonlinear Optical Materials75Intriguing Dimensional Transition Inducing Variable Birefringence in K2Na2Sn3S8 and Rb3NaSn3Se828Synthesis, characterization and theoretical investigation of a new chalcohalide, Ba 4 GaS 4 F 311Cs2ZnSn3S8: A Sulfide Compound Realizes a Large Birefringence by Modulating the Dimensional Structure25Synthesis and Characterizations of Two Tellurides β-BaGa2Te4 and Ba5Ga2Ge3Te12 with Flexible Chain Structure16CsCu 3 SbS 4 : rational design of a two-dimensional layered material with giant birefringence derived from Cu 3 SbS 442AIn 4 S 6 Cl (A = Rb and Cs) and Pb 5 Sn 3 Q 10 Cl 2 (Q = S and Se): quaternary chalcohalides with mixed anionic coordination exhibit photocurrent responses11Ba 6 In 2 Ge 2 Te 15 : a THz birefringent material with an intriguing quasi-[Te 5 ] 4− chain possessing large optical anisotropy and an ultrawide transmission range7KAg3Ga8S14: An Mid- and Far-infrared Nonlinear Optical Material Exhibiting High Laser-induced Damage Threshold※3Na 4 Ga 8 S 14 : a Ga-enriched wide band gap ternary alkali-metal sulfide with unique [Ga 12 S 42 ] 12-membered rings2Pb 3 SBrI 3 : the first Pb-based chalcohalide with multiple halogens features a unique two-dimensional structure composed of diverse Pb-centered polyhedra12The synthesis and structure–property relation analysis of metal chalcohalide crystals Cs 2 InPS 4 X 2 (X = Cl, Br) with mixed anions6Ba6(CuxZy)Sn4S16 (Z = Mg, Mn, Zn, Cd, In, Bi, Sn): High Chemical Flexibility Resulting in Good Nonlinear-Optical Properties12NaBaBS3: A Promising Infrared Functional Material with Large Birefringence Induced by π-Conjugated [BS3] Units32Ag4SnGe2S7: A Noncentrosymmetric Chalcogenide in I4–II–IV2–VI7 System with Non-Diamond-Like Structure Featuring 1D ∞[SnGe2S8]6– Infinite Chain2[Ba 4 X][In 19 S 32 ] (X = Cl, Br): two quaternary metal chalcohalides exhibiting remarkable photocurrent responses1Stereochemically active lone-pair-driven giant enhancement of birefringence from three-dimensional CsZn 4 Ga 5 Se 12 to two-dimensional CsZnAsSe 319K2CdGe3S8: A New Infrared Nonlinear Optical Sulfide6AGe2O4Q (A = Ba, Sr; Q = S, Se): A series of heteroanionic oxychalcogenides with large birefringence9From [Ba3S][GeS4] to [Ba3CO3][MS4] (M = Ge, Sn): Enhancing optical anisotropy in IR birefringent crystals via functional group implantation11A wide band gap selenohalide Cs 9 Si 8 Se 20 Cl with unprecedented [CsSe 7 Cl] mixed anionic units2Mixed-anion chalcogenide-halide semiconductors A 2 BaTaS 4 Cl (A = K, Rb, Cs) and K 2 BaNbS 4 Cl1CaYIIIS 4 (III = Ga, In): Two Olivine-Type Compounds Exhibiting Exceptional Birefringence Properties1Ba 4 CdGa 2 S 6 F 4 : A Chalcohalide Birefringent Crystal with Large Band Gap Designed by the Cation and Anion Cosubstitution Strategy2[La3Br][GeS4]2: Cationic-Moiety-Guided Strategy Enables Record Birefringence and Broad Optical Window0

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  1. ABaSbQ 3 (A = Li, Na; Q = S, Se): diverse arrangement modes of isolated SbQ 3 ligands regulating the magnitudes of birefringences

    Chemical Communications · 2019-01-01

    Ailijiang Abudurusuli, Kui Wu, Abudukadi Tudi, Zhihua Yang, Shilie Pan

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  2. Combined experimental and theoretical investigations of Ba 3 GaS 4 I: interesting structural transformation originated from halogen substitution

    Dalton Transactions · 2019-01-01

    Mengyue Li, Yu‐Xiao Zhang, Hua Lin, Zuju Ma, Xin‐Tao Wu, Qi‐Long Zhu

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  3. Structural modulation induced by M IIIA metals in Ba 3 MQ 4 X (M = Al, Ga, In; Q = S, Se; X = Cl, Br): an experimental and computational analysis

    Dalton Transactions · 2019-01-01

    Abudukadi Tudi, Shujuan Han, Ailijiang Abudurusuli, Haohai Yu, Zhihua Yang, Shilie Pan

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  4. Balanced Second-Order Nonlinear Optical Properties of Adducts CHI3·(S8)3 and AsI3·(S8)3: A Systematic Survey

    Inorganic Chemistry · 2019-03-15

    Zhen‐Tao Lu, Zongdong Sun, Yang Chi, Huaiguo Xue, Sheng‐Ping Guo

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  5. From BiF 3 to BiF 3 ·H 2 O: diverse Bi( iii ) coordination for structural transformation and birefringence regulation

    CrystEngComm · 2020-01-01

    Xian Liu, Can Yang, Qi Wu, Juan Sun, Fei Liang

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  6. LiBa4Ga5Q12 (Q = S, Se): Noncentrosymmetric Metal Chalcogenides with a Cesium Chloride Topological Structure Displaying a Remarkable Laser Damage Threshold

    Inorganic Chemistry · 2020-04-04

    Ailijiang Abudurusuli, Junjie Li, Tinghao Tong, Zhihua Yang, Shilie Pan

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  7. Functional Chalcogenide Na2HgSn2Se6 and K2MnGe2Se6 Exhibiting Flexible Chain Structure and Intriguing Birefringence Tunability

    Inorganic Chemistry · 2020-05-15

    Zhuang Li, Youquan Liu, Shengzi Zhang, Wenhao Xing, Wenlong Yin, Zheshuai Lin, Jiyong Yao, Yicheng Wu

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  8. Chalcophosphates: A Treasure House of Infrared Nonlinear Optical Materials

    Crystal Growth & Design · 2020-10-23

    Zhuang Li, Jiyong Yao, Yicheng Wu

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  9. Intriguing Dimensional Transition Inducing Variable Birefringence in K2Na2Sn3S8 and Rb3NaSn3Se8

    Inorganic Chemistry · 2020-12-23

    Xiao Ji, Hongping Wu, Bingbing Zhang, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  10. Synthesis, characterization and theoretical investigation of a new chalcohalide, Ba 4 GaS 4 F 3

    Dalton Transactions · 2021-01-01

    Hongbo Gao, Ruijiao Chen, Kewang Zhang, Ailijiang Abudurusuli, Kangrong Lai, Junjie Li

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  11. Cs2ZnSn3S8: A Sulfide Compound Realizes a Large Birefringence by Modulating the Dimensional Structure

    Inorganic Chemistry · 2021-06-16

    Tian Tian, Zefen Li, Naizheng Wang, Sangen Zhao, Jiayue Xu, Zheshuai Lin, Dajiang Mei

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  12. Synthesis and Characterizations of Two Tellurides β-BaGa2Te4 and Ba5Ga2Ge3Te12 with Flexible Chain Structure

    Inorganic Chemistry · 2021-09-16

    Mengran Sun, Xingyu Zhang, Wenhao Xing, Zhuang Li, Wenhao Liu, Zheshuai Lin, Wenlong Yin, Jiyong Yao

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  13. CsCu 3 SbS 4 : rational design of a two-dimensional layered material with giant birefringence derived from Cu 3 SbS 4

    Inorganic Chemistry Frontiers · 2021-12-01

    Chang Liu, Shenghua Zhou, Chao Zhang, Yaying Shen, Xiaoyan Liu, Hua Lin, Yi Liu

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  14. AIn 4 S 6 Cl (A = Rb and Cs) and Pb 5 Sn 3 Q 10 Cl 2 (Q = S and Se): quaternary chalcohalides with mixed anionic coordination exhibit photocurrent responses

    Dalton Transactions · 2022-01-01

    Lin‐Tao Jiang, Mingze Li, Xiao‐Ming Jiang, Bin‐Wen Liu, Guo‐Cong Guo

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  15. Ba 6 In 2 Ge 2 Te 15 : a THz birefringent material with an intriguing quasi-[Te 5 ] 4− chain possessing large optical anisotropy and an ultrawide transmission range

    Inorganic Chemistry Frontiers · 2022-01-01

    Mengran Sun, Xingyu Zhang, Wenhao Xing, Ece Uykur, Wenlong Yin, Zheshuai Lin, Jiyong Yao

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  16. KAg3Ga8S14: An Mid- and Far-infrared Nonlinear Optical Material Exhibiting High Laser-induced Damage Threshold※

    化学学报 · 2022-01-01

    Jin-Xu Zhao, Mingshu Zhang, Wen‐Fa Chen, Xiao‐Ming Jiang, Binwen Liu, Guo‐Cong Guo

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  17. Na 4 Ga 8 S 14 : a Ga-enriched wide band gap ternary alkali-metal sulfide with unique [Ga 12 S 42 ] 12-membered rings

    Dalton Transactions · 2022-01-01

    Ling Luo, Linan Wang, Chen Bai, Jiazheng Zhou, Lai Wei, Xin Su

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  18. Pb 3 SBrI 3 : the first Pb-based chalcohalide with multiple halogens features a unique two-dimensional structure composed of diverse Pb-centered polyhedra

    Dalton Transactions · 2022-01-01

    Mei Yan, Ru‐Ling Tang, Wenfeng Zhou, Wenlong Liu, Sheng‐Ping Guo

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  19. The synthesis and structure–property relation analysis of metal chalcohalide crystals Cs 2 InPS 4 X 2 (X = Cl, Br) with mixed anions

    Dalton Transactions · 2022-01-01

    Chunlan Tang, Wenhao Xing, Naizheng Wang, Jian Tang, Zheshuai Lin, Jieyun Wu, Wenlong Yin, Bin Kang

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  20. Ba6(CuxZy)Sn4S16 (Z = Mg, Mn, Zn, Cd, In, Bi, Sn): High Chemical Flexibility Resulting in Good Nonlinear-Optical Properties

    Inorganic Chemistry · 2022-01-26

    Bingheng Ji, Kui Wu, Yunhua Chen, Fei Wang, Aaron J. Rossini, Bingbing Zhang, Jian Wang

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  21. NaBaBS3: A Promising Infrared Functional Material with Large Birefringence Induced by π-Conjugated [BS3] Units

    Chemistry of Materials · 2022-05-25

    Yihan Yun, Wenlong Xie, Yi Huang, Zhihua Yang, Kui Wu, Guangmao Li, Shilie Pan

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  22. Ag4SnGe2S7: A Noncentrosymmetric Chalcogenide in I4–II–IV2–VI7 System with Non-Diamond-Like Structure Featuring 1D ∞[SnGe2S8]6– Infinite Chain

    Inorganic Chemistry · 2022-09-20

    Peng Wang, Maierhaba Abudoureheman, Kewang Zhang, Juanjuan Zheng, Zhaohui Chen, Qi Wu

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  23. [Ba 4 X][In 19 S 32 ] (X = Cl, Br): two quaternary metal chalcohalides exhibiting remarkable photocurrent responses

    Dalton Transactions · 2023-01-01

    Chunlan Tang, Wenhao Xing, Fei Liang, Jian Tang, Jieyun Wu, Wenlong Yin, Bin Kang

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  24. Stereochemically active lone-pair-driven giant enhancement of birefringence from three-dimensional CsZn 4 Ga 5 Se 12 to two-dimensional CsZnAsSe 3

    Inorganic Chemistry Frontiers · 2023-01-01

    Chao Zhang, Mao‐Yin Ran, Xin Chen, Shenghua Zhou, Hua Lin, Yi Liu

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  25. K2CdGe3S8: A New Infrared Nonlinear Optical Sulfide

    Symmetry · 2023-01-15

    Zixuan Wu, Wen‐Fa Chen, Bin‐Wen Liu, Xiao‐Ming Jiang, Guo‐Cong Guo

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  26. AGe2O4Q (A = Ba, Sr; Q = S, Se): A series of heteroanionic oxychalcogenides with large birefringence

    Solid State Sciences · 2023-11-28

    Dong Gao, Fuqiang Chen, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu, P. Shiv Halasyamani

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  27. From [Ba3S][GeS4] to [Ba3CO3][MS4] (M = Ge, Sn): Enhancing optical anisotropy in IR birefringent crystals via functional group implantation

    Chinese Journal of Structural Chemistry · 2024-10-24

    Yong‐Fang Shi, Shenghua Zhou, Zuju Ma, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  28. A wide band gap selenohalide Cs 9 Si 8 Se 20 Cl with unprecedented [CsSe 7 Cl] mixed anionic units

    Dalton Transactions · 2025-01-01

    Guansong Zheng, Wang Zhao, Xiaoyu Wu, Hongshan Wang, Yi Du, Juanjuan Lu, Xiaodong Zhou, Junjie Li

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  29. Mixed-anion chalcogenide-halide semiconductors A 2 BaTaS 4 Cl (A = K, Rb, Cs) and K 2 BaNbS 4 Cl

    Dalton Transactions · 2025-01-01

    Thomas S. Ie, Siddhartha S. Nathan, James M. Rondinelli, Mercouri G. Kanatzidis

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  30. CaYIIIS 4 (III = Ga, In): Two Olivine-Type Compounds Exhibiting Exceptional Birefringence Properties

    Inorganic Chemistry · 2025-08-21

    Chengbo Li, Haipeng Zhou, Y. Q. Chen, Jinfeng Liu, Xiu Zhu, Guisheng Xu, Jiankang Wang

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  31. Ba 4 CdGa 2 S 6 F 4 : A Chalcohalide Birefringent Crystal with Large Band Gap Designed by the Cation and Anion Cosubstitution Strategy

    Inorganic Chemistry · 2026-03-02

    Jingdong Yan, Xiangran Kong, Zichang Wang, Hongwei Leng, Tao Liu, Yunfei Shang, Nikolay Yudin, Z. L. Lei, Chunhui Yang

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  32. [La3Br][GeS4]2: Cationic-Moiety-Guided Strategy Enables Record Birefringence and Broad Optical Window

    Crystal Growth & Design · 2026-10-10

    Cuier Deng, Yuhan Hu, Ruixi Wang, Jingyu Guo

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