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RESEARCH PAPER · Journal of The Electrochemical Society · 2017

The Electrochemical Properties of Sr(Ti,Fe)O3-δfor Anodes in Solid Oxide Fuel Cells

Andreas Nenning, Lukas Volgger, Elizabeth C. Miller, Liliana Mogni, Scott Alexander Barnett, Jürgen Fleig

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The Electrochemical Properties of Sr(Ti,Fe)O3-δfor Anodes in Solid Oxide Fuel CellsOriginalCobalt-substituted SrTi 0.3 Fe 0.7 O 3−δ : a stable high-performance oxygen electrode material for intermediate-temperature solid oxide electrochemical cells134The enhanced electrochemical response of Sr(Ti 0.3 Fe 0.7 Ru 0.07 )O 3−δ anodes due to exsolved Ru–Fe nanoparticles59Oxygen surface exchange kinetics measurement by simultaneous optical transmission relaxation and impedance spectroscopy: Sr(Ti,Fe)O3-x thin film case study26Ni-Substituted Sr(Ti,Fe)O3 SOFC Anodes: Achieving High Performance via Metal Alloy Nanoparticle Exsolution320Electrochemical XPS investigation of metal exsolution on SOFC electrodes: Controlling the electrode oxygen partial pressure in ultra-high-vacuum43Electrochemical properties of porous Sr0.86Ti0.65Fe0.35O3 oxygen electrodes in solid oxide cells: Impedance study of symmetrical electrodes31Template-free mesoporous La0.3Sr0.7Ti1-xFexO3±δ for CH4 and CO oxidation catalysis72In Situ Method Correlating Raman Vibrational Characteristics to Chemical Expansion via Oxygen Nonstoichiometry of Perovskite Thin Films64Low oxygen partial pressure increases grain boundary ion conductivity in Gd-doped ceria thin films21Exsolution and electrochemistry in perovskite solid oxide fuel cell anodes: Role of stoichiometry in Sr(Ti,Fe,Ni)O383Solid oxide fuel and electrolysis cells20Advanced oxygen-electrode-supported solid oxide electrochemical cells with Sr(Ti,Fe)O 3−δ -based fuel electrodes for electricity generation and hydrogen production43Outstanding Oxygen Reduction Kinetics of La0.6Sr0.4FeO3−δ Surfaces Decorated with Platinum Nanoparticles23The Relation of Microstructure, Materials Properties and Impedance of SOFC Electrodes: A Case Study of Ni/GDC Anodes75Effect of sintering temperature on electrochemical performance of porous SrTi1-xFexO3-δ (x = 0.35, 0.5, 0.7) oxygen electrodes for solid oxide cells10Sr(Ti,Fe)O 3− δ Based Intermediate Temperature Solid Oxide Fuel Cell Anode with Self-precipitated (Ni,Fe) and Gd 0.1 Ce 0.9 O 2− δ Nano Particles2Excellent kinetics of single-phase Gd-doped ceria fuel electrodes in solid oxide cells60Iron-based electrode materials for solid oxide fuel cells and electrolysers129Performance Benchmark of Planar Solid Oxide Cells Based on Material Development and Designs60Quantitative analysis of the platinum surface decoration on lanthanum strontium iron oxide thin films via online-LASIL-ICP-MS7Understanding Oxygen Release from Nanoporous Perovskite Oxides and Its Effect on the Catalytic Oxidation of CH 4 and CO36Simulation of the Electrochemical Impedance in a Three-Dimensional, Complex Microstructure of Solid Oxide Fuel Cell Cathode and Its Application in the Microstructure Characterization12Effect of Phase Ratio on Hydrogen Separation of Dual‐phase Membrane Reactors6A Review of Electrochemical Cells with Geometrically Well-defined Interfaces for Solid Oxide Fuel Cell Anodes0Catalytic and Electrocatalytic Performance of Sr(Ti0.3fe0.7ru0.07)O3-Δ for Applications in Solid Oxide Fuel Cells Supplied with Ethanol Steam Reforming Mixtures18In situ techniques reveal the true capabilities of SOFC cathode materials and their sudden degradation due to omnipresent sulfur trace impurities41Tracking the nanoparticle exsolution/reoxidation processes of Ni-doped SrTi 0.3 Fe 0.7 O 3− δ electrodes for intermediate temperature symmetric solid oxide fuel cells47Electrochemical Performance Investigation of Sr(Ti 1−x Fe x )O 3− δ Fuel Electrodes with Different Fe Contents for Solid Oxide Electrochemical Cells3Exsolution-Driven Surface Transformation in the Host Oxide51Operational Aspects of a Perovskite Chromite-Based Fuel Electrode in Solid Oxide Electrolysis Cells (SOEC)22Simulation of dynamic response of mixed-potential hydrogen sensors4Surface and Defect Chemistry of Porous La0.6Sr0.4FeO3−δ Electrodes on Polarized Three-Electrode Cells9Comparative study on the electrochemical performance of Sr(Ti0.3Fe0.7)O3-δ fuel electrode in different fuel gases for solid oxide electrochemical cells11Mass and Charge Transport in Li1−δCoO2 Thin Films─A Complete Set of Properties and Its Defect Chemical Interpretation12Ion irradiation to control size, composition and dispersion of metal nanoparticle exsolution25Raman spectra and defect chemical characteristics of Sr(Ti,Fe)O 3− y solid solution of bulk pellets vs. thin films25Preparation of SOFC Anodes at Lower Temperature with Boosted Electrochemical Performance11Roadmap on exsolution for energy applications71A kinetic study of La0.75Sr0.25Cr0.5Mn0.5O3-δ nano-structured electrodes for intermediate temperature symmetric solid oxide fuel cells14Phase stability, redox-behavior and carbon-tolerance of Sr 1− x (Ti 0.3 Fe 0.7− y Ni y )O 3− δ with exsolved nanoparticles10Transmission line revisited – the impedance of mixed ionic and electronic conductors56Reversal of chronic surface degradation of Sr(Ti,Fe)O3 perovskite-based fuel cell cathodes by surface acid/base engineering30A-site alkali metal-doped SrTi0.3Fe0.7O3-δ: A highly stable symmetrical electrode material for solid oxide electrochemical cells5Highly efficient perovskite-based fuel electrodes for solid oxide electrochemical cells via in-situ nanoparticle exsolution and electron conduction enhancement19Study of La0.1Sr0.9TiO3 electrochemical response as anode for SOFC and its relation with microstructure6A comprehensive study of phase evolution and electrochemical performance of the Sr0.98Ti0.5Fe0.5O3-δ perovskite as fuel electrode for steam electrolysis4Mapping phase instability to electrochemical degradation in SrTi 1− x Fe x O 3− δ under solid oxide cell fuel-electrode conditions4The dark side of metal exsolution: a combined in situ surface spectroscopic and electrochemical study on perovskite-type cathodes for high-temperature CO 2 electrolysis13UHV-based analytics with electrochemical oxygen activity control3Characterization and testing of strontium titanium ferrite-based solid oxide cells for reversible and co-electrolysis operation6When ions are in charge: Generalized ionic impedance spectroscopy for characterizing energy materials and devices2Return of the solid-state coulometric titration: A new hope to expand the p(O2) range1Quantification and deconvolution of gas diffusion and conversion losses in solid oxide single-cell testing0

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  1. Cobalt-substituted SrTi 0.3 Fe 0.7 O 3−δ : a stable high-performance oxygen electrode material for intermediate-temperature solid oxide electrochemical cells

    Energy & Environmental Science · 2018-01-01

    Shan-Lin Zhang, Hongqiang Wang, Matthew Y. Lu, Ai-Ping Zhang, Liliana Mogni, Qinyuan Liu, Chang‐Jiu Li, Chang‐Jiu Li, Chang-Jiu Li, Chang-Jiu Li, Scott Alexander Barnett

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  2. The enhanced electrochemical response of Sr(Ti 0.3 Fe 0.7 Ru 0.07 )O 3−δ anodes due to exsolved Ru–Fe nanoparticles

    Journal of Materials Chemistry A · 2018-01-01

    Rebecca Glaser, Tenglong Zhu, Horacio Esteban Troiani, A. Caneiro, Liliana Mogni, Scott Alexander Barnett

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  3. Oxygen surface exchange kinetics measurement by simultaneous optical transmission relaxation and impedance spectroscopy: Sr(Ti,Fe)O3-x thin film case study

    Science and Technology of Advanced Materials · 2018-02-20

    Nicola H. Perry, Jae Jin Kim, Harry Louis Tuller

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  4. Ni-Substituted Sr(Ti,Fe)O3 SOFC Anodes: Achieving High Performance via Metal Alloy Nanoparticle Exsolution

    Joule · 2018-02-28

    Tenglong Zhu, Horacio Esteban Troiani, Liliana Mogni, Minfang Han, Scott Alexander Barnett

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  5. Electrochemical XPS investigation of metal exsolution on SOFC electrodes: Controlling the electrode oxygen partial pressure in ultra-high-vacuum

    Surface Science · 2018-10-11

    Andreas Nenning, Jürgen Fleig

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  6. Electrochemical properties of porous Sr0.86Ti0.65Fe0.35O3 oxygen electrodes in solid oxide cells: Impedance study of symmetrical electrodes

    International Journal of Hydrogen Energy · 2018-12-17

    Aleksander Mroziński, Sebastian Molin, Jakub Lech Karczewski, Tadeusz Miruszewski, Piotr Jasiński

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  7. Template-free mesoporous La0.3Sr0.7Ti1-xFexO3±δ for CH4 and CO oxidation catalysis

    Applied Catalysis B: Environmental · 2019-01-02

    Buğra Kayaalp, Siwon Lee, Kurt Klauke, Jongsu Seo, Luca Nodari, Andreas Kornowski, WooChul Jung, Simone Mascotto

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  8. In Situ Method Correlating Raman Vibrational Characteristics to Chemical Expansion via Oxygen Nonstoichiometry of Perovskite Thin Films

    Advanced Materials · 2019-06-25

    Eva Sediva, Thomas Defferriere, Nicola H. Perry, Harry Louis Tuller, Jennifer L. M. Rupp

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  9. Low oxygen partial pressure increases grain boundary ion conductivity in Gd-doped ceria thin films

    Journal of Physics Energy · 2019-08-30

    Andreas Nenning, Alexander Karl Opitz

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  10. Exsolution and electrochemistry in perovskite solid oxide fuel cell anodes: Role of stoichiometry in Sr(Ti,Fe,Ni)O3

    Journal of Power Sources · 2019-09-05

    Tenglong Zhu, Horacio Esteban Troiani, Liliana Mogni, Mariano Santaya, Minfang Han, Scott Alexander Barnett

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  11. Solid oxide fuel and electrolysis cells

    Elsevier eBooks · 2019-11-22

    Christian Lenser, David Udomsilp, Norbert Heribert Menzler, Peter Holtappels, Takaya Fujisaki, Leonard Kwati, Hiroshige Matsumoto, Antonio Gianfranco Sabato, Federico Smeacetto, Andreas Chrysanthou, Sebastian Molin

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  12. Advanced oxygen-electrode-supported solid oxide electrochemical cells with Sr(Ti,Fe)O 3−δ -based fuel electrodes for electricity generation and hydrogen production

    Journal of Materials Chemistry A · 2020-01-01

    Shan-Lin Zhang, Hongqiang Wang, Tianrang Yang, Matthew Y. Lu, Chang‐Jiu Li, Chang‐Jiu Li, Scott Alexander Barnett

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  13. Outstanding Oxygen Reduction Kinetics of La0.6Sr0.4FeO3−δ Surfaces Decorated with Platinum Nanoparticles

    Journal of The Electrochemical Society · 2020-01-06

    Christoph Riedl, Alexander Schmid, Andreas Nenning, Harald Summerer, Stefan Smetaczek, Sabine Schwarz, Johannes Bernardi, Alexander Karl Opitz, Andreas Limbeck, Jürgen Fleig

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  14. The Relation of Microstructure, Materials Properties and Impedance of SOFC Electrodes: A Case Study of Ni/GDC Anodes

    Energies · 2020-02-22

    Andreas Nenning, Cornelia Bischof, Jürgen Fleig, Martin Bram, Alexander Karl Opitz

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  15. Effect of sintering temperature on electrochemical performance of porous SrTi1-xFexO3-δ (x = 0.35, 0.5, 0.7) oxygen electrodes for solid oxide cells

    Journal of Solid State Electrochemistry · 2020-03-06

    Aleksander Mroziński, Sebastian Molin, Piotr Jasiński

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  16. Sr(Ti,Fe)O 3− δ Based Intermediate Temperature Solid Oxide Fuel Cell Anode with Self-precipitated (Ni,Fe) and Gd 0.1 Ce 0.9 O 2− δ Nano Particles

    Journal of The Electrochemical Society · 2020-11-20

    Hualin Chen, Tenglong Zhu, Xiaoyang Chen, Yunfei Bu, Qin Zhong

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  17. Excellent kinetics of single-phase Gd-doped ceria fuel electrodes in solid oxide cells

    Materials Advances · 2021-01-01

    Andreas Nenning, Manuel Holzmann, Jürgen Fleig, Alexander Karl Opitz

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  18. Iron-based electrode materials for solid oxide fuel cells and electrolysers

    Energy & Environmental Science · 2021-01-01

    Chengsheng Ni, Jun Hong Zhou, Ziye Zhang, Shuangbin Li, Jiupai Ni, Kai Wu, John T. S. Irvine

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  19. Performance Benchmark of Planar Solid Oxide Cells Based on Material Development and Designs

    Energy Technology · 2021-01-27

    David Udomsilp, Christian Lenser, Olivier Guillon, Norbert Heribert Menzler

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  20. Quantitative analysis of the platinum surface decoration on lanthanum strontium iron oxide thin films via online-LASIL-ICP-MS

    Microchemical Journal · 2021-04-05

    Maximilian Weiß, Christoph Riedl, Johannes Frank, Jürgen Fleig, Andreas Limbeck

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  21. Understanding Oxygen Release from Nanoporous Perovskite Oxides and Its Effect on the Catalytic Oxidation of CH 4 and CO

    ACS Applied Materials & Interfaces · 2021-05-19

    Elisa Poffe, Helena Kaper, Benedikt Ehrhardt, Lara Gigli, Daniel Aubert, Luca Nodari, Silvia Gross, Simone Mascotto

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  22. Simulation of the Electrochemical Impedance in a Three-Dimensional, Complex Microstructure of Solid Oxide Fuel Cell Cathode and Its Application in the Microstructure Characterization

    Frontiers in Chemistry · 2021-05-27

    Vishwas Goel, Dalton Cox, Scott Alexander Barnett, Katsuyo S. Thornton

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  23. Effect of Phase Ratio on Hydrogen Separation of Dual‐phase Membrane Reactors

    Chemie Ingenieur Technik · 2021-12-08

    Jingyi Wang, Lili Cai, Zhengqi Liang, Yue Zhu, Zhongwei Cao, Wenping Li, Xuefeng Zhu, Weishen Yang

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  24. A Review of Electrochemical Cells with Geometrically Well-defined Interfaces for Solid Oxide Fuel Cell Anodes

    Ceramist · 2021-12-31

    Yoonseok Choi

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  25. Catalytic and Electrocatalytic Performance of Sr(Ti0.3fe0.7ru0.07)O3-Δ for Applications in Solid Oxide Fuel Cells Supplied with Ethanol Steam Reforming Mixtures

    SSRN Electronic Journal · 2022-01-01

    Alessandro Donazzi, Travis Anthony Schmauss, Scott Alexander Barnett

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  26. In situ techniques reveal the true capabilities of SOFC cathode materials and their sudden degradation due to omnipresent sulfur trace impurities

    Journal of Materials Chemistry A · 2022-01-01

    Christoph Riedl, Matthäus Siebenhofer, Andreas Nenning, Alexander Schmid, Maximilian Weiß, Christoph Rameshan, Andreas Limbeck, Markus Kubicek, Alexander Karl Opitz, Jürgen Fleig

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  27. Tracking the nanoparticle exsolution/reoxidation processes of Ni-doped SrTi 0.3 Fe 0.7 O 3− δ electrodes for intermediate temperature symmetric solid oxide fuel cells

    Journal of Materials Chemistry A · 2022-01-01

    Mariano Santaya, Catalina Elena Jimenez, Horacio Esteban Troiani, Emilia Andrea Carbonio, Mauricio D. Arce, Lucía María Toscani, Raul Garcia‐Diez, Regan George Wilks, Axel Knop‐Gericke, Marcus Bär, Liliana Mogni

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  28. Electrochemical Performance Investigation of Sr(Ti 1−x Fe x )O 3− δ Fuel Electrodes with Different Fe Contents for Solid Oxide Electrochemical Cells

    Journal of The Electrochemical Society · 2022-04-01

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  29. Exsolution-Driven Surface Transformation in the Host Oxide

    Nano Letters · 2022-06-30

    Jiayue Wang, Abinash Kumar, Jenna L. Wardini, Zhan Zhang, Hua Zhou, Ethan J. Crumlin, Jerzy T. Sadowski, Kevin Benjamin Woller, William J. Bowman, James M. LeBeau, Bilge Yildiz

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  30. Operational Aspects of a Perovskite Chromite-Based Fuel Electrode in Solid Oxide Electrolysis Cells (SOEC)

    ACS Applied Energy Materials · 2022-07-08

    Diana María Amaya Dueñas, Matthias Riegraf, Andreas Nenning, Alexander Karl Opitz, Rémi Costa, K. Andreas Friedrich

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  31. Simulation of dynamic response of mixed-potential hydrogen sensors

    International Journal of Hydrogen Energy · 2022-08-26

    Jiansheng Zhang, He Zhang, Yue Teng, Jianxin Yi

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  32. Surface and Defect Chemistry of Porous La0.6Sr0.4FeO3−δ Electrodes on Polarized Three-Electrode Cells

    Journal of The Electrochemical Society · 2022-09-01

    Andreas Nenning, Stefan Reuter, Richard Schlesinger, Harald Summerer, Raffael Ramehsan, Lorenz Lindenthal, Manuel Holzmann, Tobias Martin Huber, Christoph Rameshan, Jürgen Fleig, Alexander Karl Opitz

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  33. Comparative study on the electrochemical performance of Sr(Ti0.3Fe0.7)O3-δ fuel electrode in different fuel gases for solid oxide electrochemical cells

    Ceramics International · 2022-09-21

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  34. Mass and Charge Transport in Li1−δCoO2 Thin Films─A Complete Set of Properties and Its Defect Chemical Interpretation

    Chemistry of Materials · 2022-11-21

    Andreas Ewald Bumberger, Claudia Steinbach, Joseph Ring, Jürgen Fleig

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  35. Ion irradiation to control size, composition and dispersion of metal nanoparticle exsolution

    Energy & Environmental Science · 2023-01-01

    Jiayue Wang, Kevin Benjamin Woller, Abinash Kumar, Zhan Zhang, Hua Zhou, Iradwikanari Waluyo, Adrian H. Hunt, James M. LeBeau, Bilge Yildiz

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  36. Raman spectra and defect chemical characteristics of Sr(Ti,Fe)O 3− y solid solution of bulk pellets vs. thin films

    Journal of Materials Chemistry A · 2023-01-01

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  37. Preparation of SOFC Anodes at Lower Temperature with Boosted Electrochemical Performance

    ACS Applied Energy Materials · 2023-03-07

    Zhishan Li, Meilan Peng, Xiaoxin Zhang, Lizhong Zhang, Jianhui Li, Yifei Sun

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  38. Roadmap on exsolution for energy applications

    Journal of Physics Energy · 2023-04-28

    Dragos Neagu, John T. S. Irvine, Jiayue Wang, Bilge Yildiz, Alexander Karl Opitz, Jürgen Fleig, Yuhao Wang, Jiapeng Liu, Longyun Shen, Francesco Ciucci, Brian Ashley Rosen, Yongchun Xiao, Kui Xie, Guangming Yang, Zongping Shao, Yubo Zhang, Jakob Michael Reinke, Travis Anthony Schmauss, Scott Alexander Barnett, Roelf Maring, Vasileios Kyriakou, Usman Mushtaq, Mihalis N. Tsampas, Youdong Kim, Ryan O’Hayre, Alfonso J. Carrillo, Thomas Ruh, Lorenz Lindenthal, Florian Schrenk, Christoph Rameshan, Evangelos I. Papaioannou, Kalliopi Kousi, Ian S. Metcalfe, Xiaoxiang Xu, Gang Yu Liu

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  39. A kinetic study of La0.75Sr0.25Cr0.5Mn0.5O3-δ nano-structured electrodes for intermediate temperature symmetric solid oxide fuel cells

    Ceramics International · 2023-10-24

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  40. Phase stability, redox-behavior and carbon-tolerance of Sr 1− x (Ti 0.3 Fe 0.7− y Ni y )O 3− δ with exsolved nanoparticles

    Journal of Materials Chemistry A · 2024-01-01

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  41. Transmission line revisited – the impedance of mixed ionic and electronic conductors

    Physical Chemistry Chemical Physics · 2024-01-01

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  42. Reversal of chronic surface degradation of Sr(Ti,Fe)O3 perovskite-based fuel cell cathodes by surface acid/base engineering

    Applied Catalysis B: Environmental · 2024-05-10

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  43. A-site alkali metal-doped SrTi0.3Fe0.7O3-δ: A highly stable symmetrical electrode material for solid oxide electrochemical cells

    International Journal of Hydrogen Energy · 2024-07-11

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  44. Highly efficient perovskite-based fuel electrodes for solid oxide electrochemical cells via in-situ nanoparticle exsolution and electron conduction enhancement

    Applied Catalysis B: Environmental · 2024-10-06

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  45. Study of La0.1Sr0.9TiO3 electrochemical response as anode for SOFC and its relation with microstructure

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  46. A comprehensive study of phase evolution and electrochemical performance of the Sr0.98Ti0.5Fe0.5O3-δ perovskite as fuel electrode for steam electrolysis

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  47. Mapping phase instability to electrochemical degradation in SrTi 1− x Fe x O 3− δ under solid oxide cell fuel-electrode conditions

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  48. The dark side of metal exsolution: a combined in situ surface spectroscopic and electrochemical study on perovskite-type cathodes for high-temperature CO 2 electrolysis

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  49. UHV-based analytics with electrochemical oxygen activity control

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  50. Characterization and testing of strontium titanium ferrite-based solid oxide cells for reversible and co-electrolysis operation

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