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RESEARCH PAPER · Joule · 2018

Ni-Substituted Sr(Ti,Fe)O3 SOFC Anodes: Achieving High Performance via Metal Alloy Nanoparticle Exsolution

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Ni-Substituted Sr(Ti,Fe)O3 SOFC Anodes: Achieving High Performance via Metal Alloy Nanoparticle ExsolutionOriginalSelf-assembled alloy nanoparticles in a layered double perovskite as a fuel oxidation catalyst for solid oxide fuel cells104The enhanced electrochemical response of Sr(Ti 0.3 Fe 0.7 Ru 0.07 )O 3−δ anodes due to exsolved Ru–Fe nanoparticles59Thermally driven in situ exsolution of Ni nanoparticles from (Ni, Gd)CeO 2 for high-performance solid oxide fuel cells50Exploration of Co-Fe alloy precipitation and electrochemical behavior hysteresis using Lanthanum and Cobalt co-substituted SrFeO3-δ SOFC anode67Electrochemical performance and stability of La0·5Sr0·5Fe0·9Nb0·1O3- δ symmetric electrode for solid oxide fuel cells101In-situ growth of metallic nanoparticles on perovskite parent as a hydrogen electrode for solid oxide cells57Electrochemical property of multi-layer anode supported solid oxide fuel cell fabricated through sequential tape-casting and co-firing50In situ exsolved FeNi 3 nanoparticles on nickel doped Sr 2 Fe 1.5 Mo 0.5 O 6−δ perovskite for efficient electrochemical CO 2 reduction reaction273Microstructure evolution and kinetics of B-site nanoparticle exsolution from an A-site-deficient perovskite surface: a phase-field modeling and simulation study17Novel carbon and sulfur-tolerant anode material FeNi 3 @PrBa(Fe,Ni) 1.9 Mo 0.1 O 5+δ for intermediate temperature solid oxide fuel cells51A Highly Active and Redox-Stable SrGdNi 0.2 Mn 0.8 O 4±δ Anode with in Situ Exsolution of Nanocatalysts92A-Site Ordered Double Perovskite with in Situ Exsolved Core–Shell Nanoparticles as Anode for Solid Oxide Fuel Cells97Cation-swapped homogeneous nanoparticles in perovskite oxides for high power density178A-site deficient La0.4Sr0.4TiO3-Ce0.9Gd0.1O1.95 composites as efficient and redox stable anodes for solid oxide fuel cells17Enhanced activity and stability of Sr2FeMo0.65Ni0.35O6-δ anode for solid oxide fuel cells with Na doping23Nickel enriched Ruddlesden-Popper type lanthanum strontium manganite as electrode for symmetrical solid oxide fuel cell54Facet-Dependent in Situ Growth of Nanoparticles in Epitaxial Thin Films: The Role of Interfacial Energy135Oxygen Deficient LaMn0.75Co0.25O3−δ Nanofibers as an Efficient Electrocatalyst for Oxygen Evolution Reaction and Zinc–Air Batteries114Enhanced overall water electrolysis on a bifunctional perovskite oxide through interfacial engineering56La 3+-substituted Sr2Fe1.5Ni0.1Mo0.4O6-δ as Anodes for Solid Oxide Fuel Cells4In situ exsolution of PdO nanoparticles from non-stoichiometric LaFePd0.05O3+δ electrode for impedancemetric NO2 sensor33Self-Assembled Triple-Conducting Nanocomposite as a Superior Protonic Ceramic Fuel Cell Cathode562Co-substituted Sr2Fe1.5Mo0.5O6-δ as anode materials for solid oxide fuel cells: Achieving high performance via nanoparticle exsolution68Exsolution and electrochemistry in perovskite solid oxide fuel cell anodes: Role of stoichiometry in Sr(Ti,Fe,Ni)O383Study of phase stability of SrTi0.3Fe0.7O3−δ perovskite in reducing atmosphere: Effect of microstructure22Thermal Stability of an in Situ Exsolved Metallic Nanoparticle Structured Perovskite Type Hydrogen Electrode for Solid Oxide Cells70Robust redox-reversible perovskite type steam electrolyser electrode decorated with in situ exsolved metallic nanoparticles67In Situ Observation of Nanoparticle Exsolution from Perovskite Oxides: From Atomic Scale Mechanistic Insight to Nanostructure Tailoring276Structural and electrochemical property evolutions of perovskite SOFC anodes: Role of fuel atmosphere in (La0.4Sr0.6)1-Co0.2Fe0.7Nb0.1O3-δ24Highly Efficient B-Site Exsolution Assisted by Co Doping in Lanthanum Ferrite toward High-Performance Electrocatalysts for Oxygen Evolution and Oxygen Reduction66In Situ Exsolved Ni-Decorated Ba(Ce0.9Y0.1)0.8Ni0.2O3−δ Perovskite as Carbon-Resistant Composite Anode for Hydrocarbon-Fueled Solid Oxide Fuel Cells15“Revitalizing” degraded solid oxide fuel cells in sour fuels for bifunctional oxygen catalysis in zinc–air batteries11Advanced oxygen-electrode-supported solid oxide electrochemical cells with Sr(Ti,Fe)O 3−δ -based fuel electrodes for electricity generation and hydrogen production43Fabrication and Characterization of Anode-supported Solid Oxide Fuel Cell Based on Proton Conductor Electrolyte4In Situ Investigation of Reversible Exsolution/Dissolution of CoFe Alloy Nanoparticles in a Co‐Doped Sr 2 Fe 1.5 Mo 0.5 O 6− δ Cathode for CO 2 Electrolysis340Investigation of Rh–titanate (ATiO 3 ) interactions on high-surface-area perovskite thin films prepared by atomic layer deposition18Progress in perovskite anodes for intermediate-temperature solid oxide fuel cells1Stable, efficient and cost-competitive Ni-substituted Sr(Ti,Fe)O3 cathode for solid oxide fuel cell: Effect of A-site deficiency52Materials and nano-structural processes for use in solid oxide fuel cells: a review46Advances in Porous Perovskites: Synthesis and Electrocatalytic Performance in Fuel Cells and Metal–Air Batteries181Doped (Nd,Ba)FeO3 oxides as potential electrodes for symmetrically designed protonic ceramic electrochemical cells49Cobalt and Titanium substituted SrFeO3 based perovskite as efficient symmetrical electrode for solid oxide fuel cell34Metal oxide nanocomposites as anode and cathode for low temperature solid oxide fuel cell41Redox-Reversible Electrode Material for Direct Hydrocarbon Solid Oxide Fuel Cells85Progress and Opportunities for Exsolution in Electrochemistry26Solid oxide fuel cells fueled by simulated biogas: Comparison of anode modification by infiltration and reforming catalytic layer55Electrochemical performance and anode reaction process for Ca doped Sr2Fe1·5Mo0·5O6-δ as electrodes for symmetrical solid oxide fuel cells71Metal Nanoparticle Exsolution on a Perovskite Stannate Support with High Electrical Conductivity57La0.6Sr0.4Cr0.8Co0.2O3Perovskite Decorated with Exsolved Co Nanoparticles for Stable CO2Splitting and Syngas Production64Co-generation of electricity and olefin via proton conducting fuel cells using (Pr0.3Sr0.7)0.9Ni0.1Ti0.9O3 catalyst layers66Review on exsolution and its driving forces in perovskites138In-situ exsolution of nanoparticles from Ni substituted Sr2Fe1.5Mo0.5O6 perovskite oxides with different Ni doping contents111A high-performance intermediate-to-low temperature protonic ceramic fuel cell with in-situ exsolved nickel nanoparticles in the anode56Ex‐Solved Ag Nanocatalysts on a Sr‐Free Parent Scaffold Authorize a Highly Efficient Route of Oxygen Reduction87Atomic‐Scale Insight into Exsolution of CoFe Alloy Nanoparticles in La 0.4 Sr 0.6 Co 0.2 Fe 0.7 Mo 0.1 O 3− δ with Efficient CO 2 Electrolysis185Atomic‐Scale Insight into Exsolution of CoFe Alloy Nanoparticles in La0.4Sr0.6Co0.2Fe0.7Mo0.1O3−δ with Efficient CO2 Electrolysis6Highly stable La0.5Sr0.5Fe0.9Mo0.1O3-δ electrode for reversible symmetric solid oxide cells60In Situ Exsolved Metal Nanoparticles: A Smart Approach for Optimization of Catalysts163Development and application of ex-solution nanocatalyst0Construction of Multifunctional Nanoarchitectures in One Step on a Composite Fuel Catalyst through In Situ Exsolution of La0.5Sr0.5Fe0.8Ni0.1Nb0.1O3−δ41Pr and Mo Co‐Doped SrFeO 3– δ as an Efficient Cathode for Pure CO 2 Reduction Reaction in a Solid Oxide Electrolysis Cell15Toward Reducing the Operation Temperature of Solid Oxide Fuel Cells: Our Past 15 Years of Efforts in Cathode Development298Advances in Ceramic Thin Films Fabricated by Pulsed Laser Deposition for Intermediate-Temperature Solid Oxide Fuel Cells70Exsolved Alloy Nanoparticles Decorated Ruddlesden–Popper Perovskite as Sulfur-Tolerant Anodes for Solid Oxide Fuel Cells55In-situ exsolved NiFe alloy nanoparticles on Pr0.8Sr1.2(NiFe)O4-δ for direct hydrocarbon fuel solid oxide fuel cells35A highly active and carbon-tolerant anode decorated with in situ grown cobalt nano-catalyst for intermediate-temperature solid oxide fuel cells88An all-oxide electrolysis cells for syngas production with tunable H2/CO yield via co-electrolysis of H2O and CO262Understanding electrochemical switchability of perovskite-type exsolution catalysts89Ternary Ni–Co–Fe Exsolved Nanoparticles/Perovskite System for Energy Applications: Nanostructure Characterization and Electrochemical Activity23Efficient bifunctional electrocatalysts for solid oxide cells based on the structural evolution of perovskites with abundant defects and exsolved CoFe nanoparticles72In situ and operando characterisation techniques for solid oxide electrochemical cells: recent advances30Understanding the A-site non-stoichiometry in perovskites: promotion of exsolution of metallic nanoparticles and the hydrogen oxidation reaction in solid oxide fuel cells33Organic Photochemistry-Assisted Nanoparticle Segregation on Perovskites14Modeling Exsolution of Pt from ATiO3 Perovskites (A = Ca/Sr/Ba) Using First-Principles Methods21Sr(Ti,Fe)O 3− δ Based Intermediate Temperature Solid Oxide Fuel Cell Anode with Self-precipitated (Ni,Fe) and Gd 0.1 Ce 0.9 O 2− δ Nano Particles2A Ce/Ru Codoped SrFeO 3−δ Perovskite for a Coke-Resistant Anode of a Symmetrical Solid Oxide Fuel Cell117Metal Exsolution to Enhance the Catalytic Activity of Electrodes in Solid Oxide Fuel Cells55A Thermodynamic Investigation of Ni on Thin-Film Titanates (ATiO3)10Stability and activity controls of Cu nanoparticles for high-performance solid oxide fuel cells66Nanoparticle Ex-solution for Supported Catalysts: Materials Design, Mechanism and Future Perspectives181A highly active perovskite anode with an in situ exsolved nanoalloy catalyst for direct carbon solid oxide fuel cells12A novel Ba 0.95 La 0.05 Fe 0.9 Nb 0.1 O 3− δ ceramic electrode for symmetrical solid oxide fuel cells28Defect engineering of oxide perovskites for catalysis and energy storage: synthesis of chemistry and materials science335Excellent kinetics of single-phase Gd-doped ceria fuel electrodes in solid oxide cells60Iron-based electrode materials for solid oxide fuel cells and electrolysers129Unveiling the Interface Structure of the Exsolved Co–Fe Alloy Nanoparticles from Double Perovskite and Its Application in Solid Oxide Fuel Cells18Trends and Prospects of Bimetallic Exsolution67Coupling decreased polarization resistance Sr0.95Ti0.3Fe0.6Ni0.1O3-δ cathode with efficient metal supported Solid Oxide Fuel Cell31Investigation of hetero-phases grown via in-situ exsolution on a Ni-doped (La,Sr)FeO3 cathode and the resultant activity enhancement in CO2 reduction83Engineering and optimization of electrode/electrolyte interfaces to increase solid oxide fuel cell (SOFC) performances0Exsolution Catalysts—Increasing Metal Efficiency3Nanoparticle exsolution in perovskite oxide and its sustainable electrochemical energy systems43Updating the Notion that Poor Cathode Performance Typically Dominates Overall Solid Oxide Fuel Cell Response11Progress in proton‐conducting oxides as electrolytes for low‐temperature solid oxide fuel cells: From materials to devices208In situ growth of LaSr(Fe,Mo)O4 ceramic anodes with exsolved Fe–Ni nanoparticles for SOFCs: Electrochemical performance and stability in H2, CO, and syngas31Performance and Limitations of Nickel‐Doped Chromite Anodes in Electrolyte‐Supported Solid Oxide Fuel Cells16Ru exsolution in substituted La0.75Sr0.25Cr0.5Mn0.5O3-δ compound as anode material for an IT-SOFCs17Controlling exsolution with a charge-balanced doping approach24Sintering behavior and electrochemical performance of A-site deficient SrxTi0.3Fe0·7O3-δ oxygen electrodes for solid oxide electrochemical cells27A microchannel reactor-integrated ceramic fuel cell with dual-coupling effect for efficient power and syngas co-generation from methane53Tuning Point Defects by Elastic Strain Modulates Nanoparticle Exsolution on Perovskite Oxides93Exploring the Stability of Fe–Ni Alloy Nanoparticles Exsolved from Double-Layered Perovskites for Dry Reforming of Methane46Electrochemical performance and distribution of relaxation times analysis of tungsten stabilized La0·5Sr0·5Fe0·9W0·1O3-δ electrode for symmetric solid oxide fuel cells34Exsolution of Ni Nanoparticles from A-Site-Deficient Layered Double Perovskites for Dry Reforming of Methane and as an Anode Material for a Solid Oxide Fuel Cell61In-situ construction of ceria-metal/titanate heterostructure with controllable architectures for efficient fuel electrochemical conversion41Perovskite Oxides in Catalytic Combustion of Volatile Organic Compounds: Recent Advances and Future Prospects137(La,Sr)(Ti,Fe)O 3− δ perovskite with in‐situ constructed FeNi 3 nanoparticles as fuel electrode for reversible solid oxide cell17Catalyst-Exsolving Anode-Supported Low-Temperature Solid Oxide Fuel Cell0High-performance and CO2‑resistant cathode toward electrocatalytic oxygen reduction for solid oxide fuel cells: Doped ceria and SrCo0.7Nb0.1Ni0.2O3-δ composite15Examining Operando Generated Ni-Based Alloy Nanomaterials as Fuel Electrodes in Solid Oxide Cells6Unraveling the evolution of exsolved Fe–Ni alloy nanoparticles in Ni-doped La 0.3 Ca 0.7 Fe 0.7 Cr 0.3 O 3− δ and their role in enhancing CO 2 –CO electrocatalysis35Emerging anode materials architectured with NiCoFe ternary alloy nanoparticles for ethane-fueled protonic ceramic fuel cells26Plasma Driven Exsolution for Nanoscale Functionalization of Perovskite Oxides50Roadmap for Sustainable Mixed Ionic‐Electronic Conducting Membranes139Unraveling the Enhanced Kinetics of Sr2Fe1+xMo1‐xO6‐δ Electrocatalysts for High‐Performance Solid Oxide Cells98Triple-Phase Boundaries (TPBs) in Fuel Cells and Electrolyzers3Effects of mass fraction of La0.9Sr0.1Cr0.5Mn0.5O3-δ and Gd0.1Ce0.9O2-δ composite anodes for nickel free solid oxide fuel cells20Exsolution of nanoparticles on A-site-deficient lanthanum ferrite perovskites: its effect on co-electrolysis of CO 2 and H 2 O49Unveiling the key factor for the phase reconstruction and exsolved metallic particle distribution in perovskites81Layered-perovskite oxides with in situ exsolved Co–Fe alloy nanoparticles as highly efficient electrodes for high-temperature carbon dioxide electrolysis61Performance modulation through selective, homogenous surface doping of lanthanum strontium ferrite electrodes revealed by in situ PLD impedance measurements9Bulk and surface exsolution produces a variety of Fe-rich and Fe-depleted ellipsoidal nanostructures in La 0.6 Sr 0.4 FeO 3 thin films21Synthesis of stimuli responsive nanoparticles for electrocatalysis0Water as a hole-predatory instrument to create metal nanoparticles on triple-conducting oxides113A New Durable Surface Nanoparticles‐Modified Perovskite Cathode for Protonic Ceramic Fuel Cells from Selective Cation Exsolution under Oxidizing Atmosphere248Enhancing the Catalytic Activity and Coking Tolerance of the Perovskite Anode for Solid Oxide Fuel Cells through In Situ Exsolution of Co-Fe Nanoparticles56Development of Ni-Sr(V,Ti)O3-δ Fuel Electrodes for Solid Oxide Fuel Cells8Catalytic and Electrocatalytic Performance of Sr(Ti0.3fe0.7ru0.07)O3-Δ for Applications in Solid Oxide Fuel Cells Supplied with Ethanol Steam Reforming Mixtures18Co-improving the electrocatalytic performance and H 2 S tolerance of a Sr 2 Fe 1.5 Mo 0.5 O 6− δ based anode for solid oxide fuel cells23One-Pot Derived Thermodynamically Quasi-Stable Triple Conducting Nanocomposite as Robust Bifunctional Air Electrode for Reversible Protonic Ceramic Cells72Preparation and bifunctional properties of the A-site-deficient SrTi 0.3 Fe 0.6 Ni 0.1 O 3− δ perovskite15Tracking the nanoparticle exsolution/reoxidation processes of Ni-doped SrTi 0.3 Fe 0.7 O 3− δ electrodes for intermediate temperature symmetric solid oxide fuel cells47Water electrolysis: from textbook knowledge to the latest scientific strategies and industrial developments1980Facile Synthesis and High‐Value Utilization of Ammonia23(La0.8Sr0.2)0.98MnO3-δ-Zr0.92Y0.16O2-δ:PrOx for oxygen electrode supported solid oxide cells49A Flexible Method to Fabricate Exsolution‐Based Nanoparticle‐Decorated Materials in Seconds33An Investigation of the Electrochemical Activity of (Ba/Sr)FeO 3-y Anodes3A review on solid oxide fuel cell durability: Latest progress, mechanisms, and study tools474The metal/oxide heterointerface delivered by solid-based exsolution strategy: A review53Shape-shifting nanoparticles on a perovskite oxide for highly stable and active heterogeneous catalysis49Electrochemical Characterization of NdBa0.9Co2O5+δ SOFC Cathodes Prepared by Infiltration into Gd Doped Ceria Scaffolds4Electrochemical Performance Investigation of Sr(Ti 1−x Fe x )O 3− δ Fuel Electrodes with Different Fe Contents for Solid Oxide Electrochemical Cells3A-site deficient La 0.52 Sr 0.28 Ti 0.94 Ni 0.06 O 3 by low-pulsed electric current treatment: achieved exsolution of B-site Ni nanoparticles and significant improvement of electrocatalytic properties6Surface decorations to abrupt change performance, robustness, and stability of electrodes for solid oxide cells10Concurrent promotion of phase transition and bimetallic nanocatalyst exsolution in perovskite oxides driven by Pd doping to achieve highly active bifunctional fuel electrodes for reversible solid oxide electrochemical cells52Exsolution: A promising strategy for constructing advanced composite solids16Efficient and stable symmetrical solid oxide fuel cell via A-site non-stoichiometry17Recent Progress in the Design, Characterisation and Application of LaAlO3- and LaGaO3-Based Solid Oxide Fuel Cell Electrolytes83Bimetallic Exsolved Heterostructures of Controlled Composition with Tunable Catalytic Properties52Dynamic Surface Evolution of Metal Oxides for Autonomous Adaptation to Catalytic Reaction Environments23

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