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RESEARCH PAPER · Inorganic Chemistry Frontiers · 2017

Solvent-controlled syntheses of mixed-alkali-metal borates exhibiting UV nonlinear optical properties

Chao Wu, Longhua Li, Jun‐Ling Song, Gang Yang, Mark Graeme Humphrey, Chi Zhang

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Solvent-controlled syntheses of mixed-alkali-metal borates exhibiting UV nonlinear optical propertiesOriginalLow-temperature-flux syntheses of ultraviolet-transparent borophosphates Na 4 MB 2 P 3 O 13 (M = Rb, Cs) exhibiting a second-harmonic generation response23Ba 2 ZnSc(BO 3 ) 3 and Ba 4 Zn 5 Sc 2 (BO 3 ) 8 : first examples of borates in the Zn–Sc–B–O system featuring special structure configurations15BaLiZn 3 (BO 3 ) 3 : a new member of the KBe 2 BO 3 F 2 family possessing dense BO 3 triangles and the smallest interlayer distance16Flexible coordination of Pb atoms and variable zinc–borate frameworks to construct three Pb 5 Zn 4 B 6 O 18 polymorphs8Ion-induced structural and optical performance evolution in LBO-like crystals: experimental and theoretical investigation13Recent advances in ultraviolet and deep-ultraviolet second-order nonlinear optical crystals257From LiB3O5 to NaRbB6O9F2: Fluorine‐Directed Evolution of Structural Chemistry33The First Examples of Lithium‐Containing Mixed‐Alkali Strontium Borates with Different Dimensional Anionic Architectures and Short Cutoff Edges16From centrosymmetric to noncentrosymmetric: cation-directed structural evolution in X 3 ZnB 5 O 10 (X = Na, K, Rb) and Cs 12 Zn 4 (B 5 O 10 ) 4 crystals26Sn 2 B 7 O 12 F with a 2∞[B 14 O 24 ] 6− layer constructed from the unprecedented [B 7 O 16 ] 11− fundamental building block18Three new phosphates, Cs8Pb4(P2O7)4, CsLi7(P2O7)2 and LiCa(PO3)3: structural comparison, characterization and theoretical calculation23Transformation of the B–O Units from Corner-Sharing to Edge-Sharing Linkages in BaMBO4 (M = Ga, Al)33β‐CsB9O14: A Triple‐Layered Borate with Edge‐Sharing BO4 Tetrahedra Exhibiting a Short Cutoff Edge and a Large Birefringence30Pb 3 Ba 3 Zn 6 (BO 3 ) 8 and α-BaZn 2 (BO 3 ) 2 : new members of the zincoborates containing two different dimensional Zn–O units8Rb 3 BaTeB 7 O 15 : a novel [B 7 O 16 ] fundamental building block in a new telluroborate with [TeO 3 ] polyhedra11Three non-centrosymmetric bismuth phosphates, Li 2 ABi(PO 4 ) 2 (A = K, Rb, and Cs): effects of cations on the crystal structure and SHG response23The first rare-earth lead phosphates Pb3AP3O12 (A=Sc, Gd) with remarkable SHG enhancement8Sn3B8O15: A Ternary Tin(II) Borate with Flexible [B8O18]12– Fundamental Building Block Formed by [B7O16]11– and [BO3]3– Groups10In situ hydrothermal synthesis of polar second-order nonlinear optical selenate Na 5 (SeO 4 )(HSeO 4 ) 3 (H 2 O) 219Ba 10 LuB 18 O 32 F 13 : the first example of borate in the Lu–B–O–F system with the unprecedented FBB [B 9 O 22 ]12Cs2B4O5(OH)4: A new hydrated borate with a short UV cutoff edge2Research on Nonlinear Optical Materials Based on BO 3 and BO 4 Hydroxy Tetraborates4

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  1. Low-temperature-flux syntheses of ultraviolet-transparent borophosphates Na 4 MB 2 P 3 O 13 (M = Rb, Cs) exhibiting a second-harmonic generation response

    Dalton Transactions · 2017-01-01

    Chao Wu, Longhua Li, Gang Yang, Jun‐Ling Song, Bing Yan, Mark Graeme Humphrey, Long Zhang, Jianda Shao, Chi Zhang

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  2. Ba 2 ZnSc(BO 3 ) 3 and Ba 4 Zn 5 Sc 2 (BO 3 ) 8 : first examples of borates in the Zn–Sc–B–O system featuring special structure configurations

    Inorganic Chemistry Frontiers · 2018-01-01

    Yanna Chen, Min Zhang, Cong Hu, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  3. BaLiZn 3 (BO 3 ) 3 : a new member of the KBe 2 BO 3 F 2 family possessing dense BO 3 triangles and the smallest interlayer distance

    New Journal of Chemistry · 2018-01-01

    Yanna Chen, Min Zhang, Shilie Pan

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  4. Flexible coordination of Pb atoms and variable zinc–borate frameworks to construct three Pb 5 Zn 4 B 6 O 18 polymorphs

    Inorganic Chemistry Frontiers · 2018-01-01

    Xiaobo Pan, Hongping Wu, Ming Wen, Bingbing Zhang, Zhihua Yang, Shilie Pan

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  5. Ion-induced structural and optical performance evolution in LBO-like crystals: experimental and theoretical investigation

    Inorganic Chemistry Frontiers · 2018-01-01

    Yun Mo Yang, Shilie Pan

    Read original paper ↗ ·

  6. Recent advances in ultraviolet and deep-ultraviolet second-order nonlinear optical crystals

    Coordination Chemistry Reviews · 2018-03-15

    Chao Wu, Gang Yang, Mark Graeme Humphrey, Chi Zhang

    Read original paper ↗ ·

  7. From LiB3O5 to NaRbB6O9F2: Fluorine‐Directed Evolution of Structural Chemistry

    Chemistry - A European Journal · 2018-06-04

    Shujuan Han, Bingbing Zhang, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  8. The First Examples of Lithium‐Containing Mixed‐Alkali Strontium Borates with Different Dimensional Anionic Architectures and Short Cutoff Edges

    Chemistry - A European Journal · 2018-08-07

    Ruru Ma, Yun Mo Yang, Cong Hu, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  9. From centrosymmetric to noncentrosymmetric: cation-directed structural evolution in X 3 ZnB 5 O 10 (X = Na, K, Rb) and Cs 12 Zn 4 (B 5 O 10 ) 4 crystals

    Inorganic Chemistry Frontiers · 2019-01-01

    Tuohetijiang Baiheti, Shujuan Han, Abudukadi Tudi, Zhihua Yang, Hualiang Yu, Shilie Pan

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  10. Sn 2 B 7 O 12 F with a 2∞[B 14 O 24 ] 6− layer constructed from the unprecedented [B 7 O 16 ] 11− fundamental building block

    Inorganic Chemistry Frontiers · 2019-01-01

    Zixiu Lu, Fangfang Zhang, Abudukadi Tudi, Zhizhong Zhang, Zhihua Yang, Shilie Pan

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  11. Three new phosphates, Cs8Pb4(P2O7)4, CsLi7(P2O7)2 and LiCa(PO3)3: structural comparison, characterization and theoretical calculation

    Dalton Transactions · 2019-01-01

    Shujuan Han, Hao Li, Zhihua Yang, Hao Yu, Shilie Pan

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  12. Transformation of the B–O Units from Corner-Sharing to Edge-Sharing Linkages in BaMBO4 (M = Ga, Al)

    Inorganic Chemistry · 2019-06-04

    Fengjiao Guo, Jian Wei Han, Shichao Cheng, Sujuan Yu, Zhihua Yang, Shilie Pan

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  13. β‐CsB9O14: A Triple‐Layered Borate with Edge‐Sharing BO4 Tetrahedra Exhibiting a Short Cutoff Edge and a Large Birefringence

    Chemistry - A European Journal · 2019-06-18

    Shujuan Han, Chunmei Huang, Abudukadi Tudi, Shuaishuai Hu, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  14. Pb 3 Ba 3 Zn 6 (BO 3 ) 8 and α-BaZn 2 (BO 3 ) 2 : new members of the zincoborates containing two different dimensional Zn–O units

    Inorganic Chemistry Frontiers · 2019-10-09

    Xiaobo Pan, Hongping Wu, Shichao Cheng, Zhengping Wang

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  15. Rb 3 BaTeB 7 O 15 : a novel [B 7 O 16 ] fundamental building block in a new telluroborate with [TeO 3 ] polyhedra

    Dalton Transactions · 2020-01-01

    Jun Sun, Miriding Mutailipu, Shichao Cheng, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  16. Three non-centrosymmetric bismuth phosphates, Li 2 ABi(PO 4 ) 2 (A = K, Rb, and Cs): effects of cations on the crystal structure and SHG response

    Inorganic Chemistry Frontiers · 2020-01-01

    Ming Wen, Cong Hu, Hongping Wu, Zhihua Yang, Hao Yu, Shilie Pan

    Read original paper ↗ ·

  17. The first rare-earth lead phosphates Pb3AP3O12 (A=Sc, Gd) with remarkable SHG enhancement

    Journal of Solid State Chemistry · 2020-02-26

    Ming Wen, Hongping Wu, Hongwei Yu, Xiaohong Wu

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  18. Sn3B8O15: A Ternary Tin(II) Borate with Flexible [B8O18]12– Fundamental Building Block Formed by [B7O16]11– and [BO3]3– Groups

    Inorganic Chemistry · 2020-12-29

    Siru Guo, Wen-Bin Zhang, Min Zhang, Zhihua Yang, Shilie Pan

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  19. In situ hydrothermal synthesis of polar second-order nonlinear optical selenate Na 5 (SeO 4 )(HSeO 4 ) 3 (H 2 O) 2

    Inorganic Chemistry Frontiers · 2021-01-01

    Chao Wu, Xingxing Jiang, Lin Lin, Tianhui Wu, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  20. Ba 10 LuB 18 O 32 F 13 : the first example of borate in the Lu–B–O–F system with the unprecedented FBB [B 9 O 22 ]

    Inorganic Chemistry Frontiers · 2022-01-01

    Jiongquan Chen, Wenqi Jin, Yanhui Zhang, Yun Mo Yang, Zhihua Yang, Shilie Pan

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  21. Cs2B4O5(OH)4: A new hydrated borate with a short UV cutoff edge

    Inorganica Chimica Acta · 2022-10-19

    Aixin Zhu, Jianbang Chen, Yanhui Zhang, Zhi Guo Su

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  22. Research on Nonlinear Optical Materials Based on BO 3 and BO 4 Hydroxy Tetraborates

    Advanced Optical Materials · 2025-09-15

    Shuai An, Bailin Chen, Fangfang Zhang, Xueling Hou, Shilie Pan

    Read original paper ↗ ·
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