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RESEARCH PAPER · Chemical Communications · 2022

Semiconducting silicon–phosphorus frameworks for caging exotic polycations

Philip Yox, Andrew P. Porter, Rick W. Dorn, Victoria Kyveryga, Aaron J. Rossini, Kirill A. Kovnir

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Semiconducting silicon–phosphorus frameworks for caging exotic polycationsOriginalMachine Learning-Guided Discovery of Ternary Compounds Containing La, P, and Group 14 Elements14BaCu T P 2 ( T = Al, Ga, In): a semiconducting black sheep in the ThCr 2 Si 2 intermetallic family7ABa6Cu31Te22 (A = K, Rb, Cs) Featuring Polyanionic Copper–Telluride Frameworks with Ultralow Thermal Conductivity3Achieving strong optical nonlinearity and wide bandgap of pnictides via ionic motif–driven directed assembly of covalent groups40Assembly between diverse polycations and diamond-like anionic frameworks in salt-inclusion phosphides enables excellent nonlinear optical properties4In and Out: Shuttling Atoms in Covalent Nanocrystals, from Synthesis in Molten Salts to Water-Splitting Electrocatalysis5Discovery and Synthesis of a Family of Boride Altermagnets8Uncovering the linear boron environment in Na 3 BP 2 through solid-state 11 B NMR spectroscopy0Cs X Si 15 P 21 ( X = Sn or Pb): Polar Noncentrosymmetric Si–P Frameworks Stabilized by Covalent X –P Bonding3Beyond the bandgap bottleneck: structure–property design principles for infrared nonlinear optical phosphides0

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10 direct citing papers saved.

  1. Machine Learning-Guided Discovery of Ternary Compounds Containing La, P, and Group 14 Elements

    Inorganic Chemistry · 2022-10-11

    Huaijun Sun, Chao Zhang, Weiyi Xia, Ling Tang, Renhai Wang, Georgiy Akopov, Nethmi W. Hewage, Kai‐Ming Ho, Kirill A. Kovnir, Cai‐Zhuang Wang

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  2. BaCu T P 2 ( T = Al, Ga, In): a semiconducting black sheep in the ThCr 2 Si 2 intermetallic family

    Journal of Materials Chemistry A · 2024-01-01

    Arka Sarkar, Andrew P. Porter, Gayatri Viswanathan, Philip Yox, Rae Ann Earnest, Jian Wang, Aaron J. Rossini, Kirill A. Kovnir

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  3. ABa6Cu31Te22 (A = K, Rb, Cs) Featuring Polyanionic Copper–Telluride Frameworks with Ultralow Thermal Conductivity

    ACS Applied Materials & Interfaces · 2024-07-16

    Arka Sarkar, Frank Cerasoli, Gayatri Viswanathan, Davide Donadio, Kirill A. Kovnir

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  4. Achieving strong optical nonlinearity and wide bandgap of pnictides via ionic motif–driven directed assembly of covalent groups

    Science Advances · 2024-11-13

    Lihua Gao, Jindong Chen, Xuemei Shi, Yan Xiao, Yinglei Han, Chensheng Lin, Huikang Jiang, Guangsai Yang, Guang Peng, Ning Ye

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  5. Assembly between diverse polycations and diamond-like anionic frameworks in salt-inclusion phosphides enables excellent nonlinear optical properties

    Science China Chemistry · 2025-02-11

    Ming‐Shu Zhang, Shao‐Min Pei, Bin‐Wen Liu, Xiao‐Ming Jiang, Guo‐Cong Guo

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  6. In and Out: Shuttling Atoms in Covalent Nanocrystals, from Synthesis in Molten Salts to Water-Splitting Electrocatalysis

    Journal of the American Chemical Society · 2025-06-04

    Yang Song, Anissa Ghoridi, Fernando Igoa, Isabel Gómez‐Recio, Daniel Janisch, Edouard de Rolland Dalon, Dominique Thiaudière, M. Luisa Ruiz‐González, José María González-Calbet, Benedikt Lassalle‐Kaiser, Andrea Zitolo, Christel Laberty‐Robert, David Portehault

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  7. Discovery and Synthesis of a Family of Boride Altermagnets

    Journal of the American Chemical Society · 2025-08-12

    Zhen Zhang, Eranga H. Gamage, Genevieve Amobi, Subhadip Pradhan, Andrey L. Kutepov, K. D. Belashchenko, Yang Sun, Kirill A. Kovnir, Vladimir Antropov

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  8. Uncovering the linear boron environment in Na 3 BP 2 through solid-state 11 B NMR spectroscopy

    Physical Chemistry Chemical Physics · 2026-01-01

    Andrew P. Porter, Rick W. Dorn, Scott L. Carnahan, Dinesh K. Amarasinghe, Kirill A. Kovnir, Aaron J. Rossini

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  9. Cs X Si 15 P 21 ( X = Sn or Pb): Polar Noncentrosymmetric Si–P Frameworks Stabilized by Covalent X –P Bonding

    Chemistry of Materials · 2026-03-31

    Philip Yox, Victoria Kyveryga, Ernesto Soto, Jessica Warner, Gayatri Viswanathan, Eranga H. Gamage, Kui Wu, Bingbing Zhang, Victor Trinquet, Geoffroy Hautier, Gian‐Marco Rignanese, Kirill A. Kovnir

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  10. Beyond the bandgap bottleneck: structure–property design principles for infrared nonlinear optical phosphides

    Coordination Chemistry Reviews · 2026-09-22

    Zichang Wang, Dajiang Mei, Ximeng Lv, Shuchang Wu, Yang Liu, Jingdong Yan, Xiangran Kong, Hongwei Leng, Zuotao Lei, Chunhui Yang

    Read original paper ↗ ·
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