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RESEARCH PAPER · Dalton Transactions · 2019

Flux crystal growth: a versatile technique to reveal the crystal chemistry of complex uranium oxides

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Flux crystal growth: a versatile technique to reveal the crystal chemistry of complex uranium oxidesOriginalSoluble human leukocyte antigen-G (SHLA-G) in Tunisian kidney transplantation.2Flux crystal growth of uranium( v ) containing oxyfluoride perovskites13Discovery of Cs2(UO2)Al2O5 by Molten Flux Methods: A Uranium Aluminate Containing Solely Aluminate Tetrahedra as the Secondary Building Unit11Size-Driven Stability of Lanthanide Thiophosphates Grown from an Iodide Flux30Molten Alkali Halide Flux Growth of an Extensive Family of Noncentrosymmetric Rare Earth Sulfides: Structure and Magnetic and Optical (SHG) Properties47Framework Polymorphism and Modular Crystal Structures of Uranyl Vanadates of Divalent Cations: Synthesis and Characterization of M(UO2)(V2O7) (M = Ca, Sr) and Sr3(UO2)(V2O7)215Observation of the Same New Sheet Topology in Both the Layered Uranyl Oxide-Phosphate Cs11[(UO2)12(PO4)3O13] and the Layered Uranyl Oxyfluoride-Phosphate Rb11[(UO2)12(PO4)3O12F2] Prepared by Flux Crystal Growth13Flux Crystal Growth of Lanthanide Tungsten Oxychlorides, La8.64W6O30.45Cl, Ce8.64W5.74O30Cl, and Ln8.33W6O30Cl (Ln = Pr, Nd): Structural Stability in the Presence of Extreme Cation and Anion Disorder5Crystal growth of novel 3D skeleton uranyl germanium complexes: influence of synthetic conditions on crystal structures10Cu I Cu II and Ag I p -isocyanobenzoates as novel 1D semiconducting coordination oligomers4Targeted crystal growth of uranium gallophosphates via the systematic exploration of the UF 4 –GaPO 4 –ACl (A = Cs, Rb) phase space7Nearly Identical but Not Isotypic: Influence of Lanthanide Contraction on Cs2NaLn(PS4)2 (Ln = La–Nd, Sm, and Gd–Ho)23New Rubidium-Containing Mixed-Metal Titanium Hollandites8Flux Growth of Phosphide and Arsenide Crystals40Crystal Growth of Alkali Uranyl Borates from Molten Salt Fluxes: Characterization and Ion Exchange Behavior of A2(UO2)B2O5 (A = Cs, Rb, K)13“Soft” Alkali Bromide and Iodide Fluxes for Crystal Growth36Magnetic anisotropy and anomalous Hall effect in monoclinic single crystal Cr5Te828Flux crystal growth of a new BaTa2O6 polymorph, and of the novel tantalum oxyfluoride salt inclusion phase [Ba3F]Ta4O12F: Flux dependent phase formation5Flux Growth of Uranyl Titanates: Rare Examples of TiO4 Tetrahedra and TiO5 Square Bipyramids10Dimensional reduction upon calcium incorporation in Cs 0.3 (Ca 0.3 Ln 0.7 )PS 4 and Cs 0.5 (Ca 0.5 Ln 0.5 )PS 45Beyond structural motifs: the frontier of actinide-containing metal–organic frameworks65Trends in rare earth thiophosphate syntheses: Rb 3 Ln(PS 4 ) 2 (Ln = La, Ce, Pr), Rb 3−x Na x Ln(PS 4 ) 2 (Ln = Ce, Pr; x = 0.50, 0.55), and RbEuPS 4 obtained by molten flux crystal growth5Flux crystal growth of cesium bismuth silicates Cs3BiSi8O19 and Cs4Bi2Si8O21: Structure modification via Eu doping to yield Cs4Bi1.72Eu0.28Si8O21 and alkali metal ion exchange to yield Cs0.79K2.21BiSi8O190A Density-Functional Theory Structural Database for Discovery of Novel Actinide Waste Forms7Lanthanide thioborates, an emerging class of nonlinear optical materials, efficiently synthesized using the boron–chalcogen mixture method23Uranyl Titanate Silicates: Syntheses, Structures, and Family Relations5Structures and Magnetic Properties of K2Pd4U6S17, K2Pt4U6S17, Rb2Pt4U6S17, and Cs2Pt4U6S17 Synthesized Using the Boron–Chalcogen Mixture Method10Transuranium Sulfide via the Boron Chalcogen Mixture Method and Reversible Water Uptake in the NaCuTS3 Family21Single-Crystal Nickel-Based Cathodes: Fundamentals and Recent Advances97U(VI) Coordination Modes in Complex Uranium Silicates: Cs[(UO6)2(UO2)9(Si2O7)F] and Rb2[(PtO4)(UO2)5(Si2O7)]6Advances in Chalcogenide Crystal Growth: Flux and Solution Syntheses, and Approaches for Postsynthetic Modifications13Comparative Study on Crystal Structures and Synthetic Techniques of Ternary Hafnium/Zirconium Fluorides7Utilizing Ionic Liquids as Bifunctional Reagents for the Ionothermal Synthesis of Uranyl Compounds13Crystal structure and magnetism of actinide oxides: a review22Bulk Crystal Growth and Single-Crystal-to-Single-Crystal Phase Transitions in the Averievite CsClCu5V2O105Three uranyl silicate framework structures, Cs1.8K0.2[(UO2)(Si2O6)], K4Sr[(UO2)(Si4O12)], and [Cs2KF][(UO2)(Si4O10)], and theoretical calculation of density functional theory for salt-inclusion material2Ionothermal Synthesis of Am 4 B 22 O 42 Cl 12 : A Chiral Cubic Americium Borate Cluster2A low-temperature, one-step synthesis for monazite can transform monazite into a readily usable advanced nuclear waste form17A novel microporous uranyl silicate prepared by high temperature flux technique0Investigation of Americium-Containing Phosphates, Silicates, Borates, Molybdates, and Fluorides Synthesized via High-Temperature Flux Crystal Growth6Chemical Facets of Superconductivity in UTe24Co-generation of NaREE(MoO4)2 and REEPO4 in multiple habits by solid-flux crystal growth3PROCESSING OF URANIUM-SILICIDE SPENT NUCLEAR FUEL IN MOLYBDENUM MELTS0Li 6 Lu(BO 3 ) 3 : A Rare-Earth Borate Crystal Exhibiting Large Birefringence and Broad UV Transparency1Rich Chemical Behavior and Topological Variation in Uranium Phosphates via Flux Growth under an Inert Atmosphere0Synthesis and Characterization of Layered Actinide (U, Np, Pu) Oxide and Hydroxide Phases0Low‐Temperature Hydrothermal Synthesis of PbUO 40Synthesis and Characterization of RE 3 LiSiSe 7 (RE = La–Nd, Sm, Gd, and Tb) Exhibiting Enhanced Nonlinear Optical (NLO) Properties0Synthesis‐Driven Structure–Property Correlations in Metal Oxytellurides for Emerging Device Applications0

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  1. Soluble human leukocyte antigen-G (SHLA-G) in Tunisian kidney transplantation.

    PubMed · 2011-01-01

    R. Bardi, Imen Sfar, Hajer Aounallah Skhiri, C Kallala, E. Abderrahim, Taieb Ben Abdallah, Yosr Gorgi

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  2. Flux crystal growth of uranium( v ) containing oxyfluoride perovskites

    Inorganic Chemistry Frontiers · 2019-01-01

    Christian A. Juillerat, Vancho Kocevski, Gregory W. Morrison, S. Karakalos, Deepak Patil, Scott T. Misture, Theodore M. Besmann, Hans‐Conrad zur Loye

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  3. Discovery of Cs2(UO2)Al2O5 by Molten Flux Methods: A Uranium Aluminate Containing Solely Aluminate Tetrahedra as the Secondary Building Unit

    Inorganic Chemistry · 2019-03-12

    Christian A. Juillerat, Vancho Kocevski, Theodore M. Besmann, Hans‐Conrad zur Loye

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  4. Size-Driven Stability of Lanthanide Thiophosphates Grown from an Iodide Flux

    Inorganic Chemistry · 2019-04-23

    Vladislav V. Klepov, Logan S. Breton, Kristen A. Pace, Vancho Kocevski, Theodore M. Besmann, Hans‐Conrad zur Loye

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  5. Molten Alkali Halide Flux Growth of an Extensive Family of Noncentrosymmetric Rare Earth Sulfides: Structure and Magnetic and Optical (SHG) Properties

    Inorganic Chemistry · 2019-06-19

    Mohammad Usman, Mark D. Smith, Gregory W. Morrison, Vladislav V. Klepov, Weiguo Zhang, P. Shiv Halasyamani, Hans‐Conrad zur Loye

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  6. Framework Polymorphism and Modular Crystal Structures of Uranyl Vanadates of Divalent Cations: Synthesis and Characterization of M(UO2)(V2O7) (M = Ca, Sr) and Sr3(UO2)(V2O7)2

    Zeitschrift für anorganische und allgemeine Chemie · 2019-07-18

    Saehwa Chong, Sergey M. Aksenov, Fabrice Dal Bo, Samuel N. Perry, Foteini Dimakopoulou, Peter Carman Burns

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  7. Observation of the Same New Sheet Topology in Both the Layered Uranyl Oxide-Phosphate Cs11[(UO2)12(PO4)3O13] and the Layered Uranyl Oxyfluoride-Phosphate Rb11[(UO2)12(PO4)3O12F2] Prepared by Flux Crystal Growth

    Frontiers in Chemistry · 2019-08-21

    Christian A. Juillerat, Vancho Kocevski, Theodore M. Besmann, Hans‐Conrad zur Loye

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  8. Flux Crystal Growth of Lanthanide Tungsten Oxychlorides, La8.64W6O30.45Cl, Ce8.64W5.74O30Cl, and Ln8.33W6O30Cl (Ln = Pr, Nd): Structural Stability in the Presence of Extreme Cation and Anion Disorder

    Inorganic Chemistry · 2019-12-02

    Darren Carone, Vladislav V. Klepov, Mark D. Smith, Hans‐Conrad zur Loye

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  9. Crystal growth of novel 3D skeleton uranyl germanium complexes: influence of synthetic conditions on crystal structures

    Dalton Transactions · 2020-01-01

    Haijian Li, Philip Kegler, Evgeny V. Alekseev

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  10. Cu I Cu II and Ag I p -isocyanobenzoates as novel 1D semiconducting coordination oligomers

    Dalton Transactions · 2020-01-01

    Leslie Reguera, Arely Cano, Joelis Rodríguez-Hernández, Daniel G. Rivera, Erik V. Van der Eycken, Daniel Ramírez‐Rosales, E. Reguera

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  11. Targeted crystal growth of uranium gallophosphates via the systematic exploration of the UF 4 –GaPO 4 –ACl (A = Cs, Rb) phase space

    CrystEngComm · 2020-01-01

    Christian A. Juillerat, Vladislav V. Klepov, Mark D. Smith, Hans‐Conrad zur Loye

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  12. Nearly Identical but Not Isotypic: Influence of Lanthanide Contraction on Cs2NaLn(PS4)2 (Ln = La–Nd, Sm, and Gd–Ho)

    Inorganic Chemistry · 2020-01-22

    Vladislav V. Klepov, Kristen A. Pace, Logan S. Breton, Vancho Kocevski, Theodore M. Besmann, Hans‐Conrad zur Loye

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  13. New Rubidium-Containing Mixed-Metal Titanium Hollandites

    Crystal Growth & Design · 2020-03-03

    Mohammad Usman, Vancho Kocevski, Mark D. Smith, Gregory W. Morrison, Theodore M. Besmann, Hans‐Conrad zur Loye

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  14. Flux Growth of Phosphide and Arsenide Crystals

    Frontiers in Chemistry · 2020-04-02

    Jian Wang, Philip Yox, Kirill A. Kovnir

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  15. Crystal Growth of Alkali Uranyl Borates from Molten Salt Fluxes: Characterization and Ion Exchange Behavior of A2(UO2)B2O5 (A = Cs, Rb, K)

    Inorganic Chemistry · 2020-04-10

    Kristen A. Pace, Robert J. Koch, Mark D. Smith, Gregory W. Morrison, Vladislav V. Klepov, Theodore M. Besmann, Scott T. Misture, Hans‐Conrad zur Loye

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  16. “Soft” Alkali Bromide and Iodide Fluxes for Crystal Growth

    Frontiers in Chemistry · 2020-06-26

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  17. Magnetic anisotropy and anomalous Hall effect in monoclinic single crystal Cr5Te8

    Physical review. B./Physical review. B · 2020-10-22

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  18. Flux crystal growth of a new BaTa2O6 polymorph, and of the novel tantalum oxyfluoride salt inclusion phase [Ba3F]Ta4O12F: Flux dependent phase formation

    Journal of Solid State Chemistry · 2020-10-27

    Ceren Kütahyalı Aslani, Vladislav V. Klepov, Hans‐Conrad zur Loye

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  19. Flux Growth of Uranyl Titanates: Rare Examples of TiO4 Tetrahedra and TiO5 Square Bipyramids

    The Journal of Physical Chemistry A · 2020-11-03

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  20. Dimensional reduction upon calcium incorporation in Cs 0.3 (Ca 0.3 Ln 0.7 )PS 4 and Cs 0.5 (Ca 0.5 Ln 0.5 )PS 4

    CrystEngComm · 2020-12-09

    Vladislav V. Klepov, Vancho Kocevski, Theodore M. Besmann, Hans‐Conrad zur Loye

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  21. Beyond structural motifs: the frontier of actinide-containing metal–organic frameworks

    Chemical Science · 2021-01-01

    Corey R. Martin, Gabrielle A. Leith, Natalia B. Shustova

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  22. Trends in rare earth thiophosphate syntheses: Rb 3 Ln(PS 4 ) 2 (Ln = La, Ce, Pr), Rb 3−x Na x Ln(PS 4 ) 2 (Ln = Ce, Pr; x = 0.50, 0.55), and RbEuPS 4 obtained by molten flux crystal growth

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  23. Flux crystal growth of cesium bismuth silicates Cs3BiSi8O19 and Cs4Bi2Si8O21: Structure modification via Eu doping to yield Cs4Bi1.72Eu0.28Si8O21 and alkali metal ion exchange to yield Cs0.79K2.21BiSi8O19

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  24. A Density-Functional Theory Structural Database for Discovery of Novel Actinide Waste Forms

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  25. Lanthanide thioborates, an emerging class of nonlinear optical materials, efficiently synthesized using the boron–chalcogen mixture method

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  26. Uranyl Titanate Silicates: Syntheses, Structures, and Family Relations

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  27. Structures and Magnetic Properties of K2Pd4U6S17, K2Pt4U6S17, Rb2Pt4U6S17, and Cs2Pt4U6S17 Synthesized Using the Boron–Chalcogen Mixture Method

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    Logan S. Breton, Ryan Baumbach, Hunter B. Tisdale, Hans‐Conrad zur Loye

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  28. Transuranium Sulfide via the Boron Chalcogen Mixture Method and Reversible Water Uptake in the NaCuTS3 Family

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  29. Single-Crystal Nickel-Based Cathodes: Fundamentals and Recent Advances

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  30. U(VI) Coordination Modes in Complex Uranium Silicates: Cs[(UO6)2(UO2)9(Si2O7)F] and Rb2[(PtO4)(UO2)5(Si2O7)]

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  31. Advances in Chalcogenide Crystal Growth: Flux and Solution Syntheses, and Approaches for Postsynthetic Modifications

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  32. Comparative Study on Crystal Structures and Synthetic Techniques of Ternary Hafnium/Zirconium Fluorides

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  33. Utilizing Ionic Liquids as Bifunctional Reagents for the Ionothermal Synthesis of Uranyl Compounds

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  34. Crystal structure and magnetism of actinide oxides: a review

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  35. Bulk Crystal Growth and Single-Crystal-to-Single-Crystal Phase Transitions in the Averievite CsClCu5V2O10

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  36. Three uranyl silicate framework structures, Cs1.8K0.2[(UO2)(Si2O6)], K4Sr[(UO2)(Si4O12)], and [Cs2KF][(UO2)(Si4O10)], and theoretical calculation of density functional theory for salt-inclusion material

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  37. Ionothermal Synthesis of Am 4 B 22 O 42 Cl 12 : A Chiral Cubic Americium Borate Cluster

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  38. A low-temperature, one-step synthesis for monazite can transform monazite into a readily usable advanced nuclear waste form

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  39. A novel microporous uranyl silicate prepared by high temperature flux technique

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  40. Investigation of Americium-Containing Phosphates, Silicates, Borates, Molybdates, and Fluorides Synthesized via High-Temperature Flux Crystal Growth

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  41. Chemical Facets of Superconductivity in UTe2

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  42. Co-generation of NaREE(MoO4)2 and REEPO4 in multiple habits by solid-flux crystal growth

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  45. Rich Chemical Behavior and Topological Variation in Uranium Phosphates via Flux Growth under an Inert Atmosphere

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