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RESEARCH PAPER · Journal of the American Chemical Society · 2017

Observation of Intense X-ray Scintillation in a Family of Mixed Anion Silicates, Cs3RESi4O10F2 (RE = Y, Eu–Lu), Obtained via an Enhanced Flux Crystal Growth Technique

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Observation of Intense X-ray Scintillation in a Family of Mixed Anion Silicates, Cs3RESi4O10F2 (RE = Y, Eu–Lu), Obtained via an Enhanced Flux Crystal Growth TechniqueOriginalA Fluorooxosilicophosphate with an Unprecedented SiO2F4 Species56A Fluorooxosilicophosphate with an Unprecedented SiO2F4 Species5A stoichiometric terbium-europium dyad molecular thermometer: energy transfer properties149NaCa5BO3(SiO4)2 with Interesting Isolated [BO3] and [SiO4] Units in Alkali- and Alkaline-Earth-Metal Borosilicates14Cs3REIIIGe3O9 (RE = Pr, Nd, and Sm–Yb) and Cs8TbIII2TbIVGe9O27: A Rare Example of a Mixed-Valent Tb(III)/Tb(IV) Oxide20Molten Alkali Halide Flux Growth of an Extensive Family of Noncentrosymmetric Rare Earth Sulfides: Structure and Magnetic and Optical (SHG) Properties47A new barium-containing alkali metal silicate fluoride NaBa3Si2O7F with deep-UV optical property12One-Dimensional Quaternary and Penternary Alkali Rare Earth Thiophosphates Obtained via Alkali Halide Flux Crystal Growth12Superwadeites: Elucidation of a Structural Family Related to the Wadeite Structure and Prediction of Cs2Ge5O116Color-tunable X-ray scintillation based on a series of isotypic lanthanide–organic frameworks99Oxyfluoride Pb2Ti4O9F2 as a Stable Anode Material for Photoelectrochemical Water Oxidation20BaWO 2 F 4 : a mixed anion X-ray scintillator with excellent photoluminescence quantum efficiency18Crystal growth of novel 3D skeleton uranyl germanium complexes: influence of synthetic conditions on crystal structures10New germanate and mixed cobalt germanate salt inclusion materials: [(Rb 6 F)(Rb 4 F)][Ge 14 O 32 ] and [(Rb 6 F)(Rb 3.1 Co 0.9 F 0.96 )][Co 3.8 Ge 10.2 O 30 F 2 ]10New Rubidium-Containing Mixed-Metal Titanium Hollandites8Dual-Mode Light-Emitting Lanthanide Metal–Organic Frameworks with High Water and Thermal Stability and Their Application in White LEDs104Silicate-germanate K2Y[(Si3Ge)O10(OH)] with unusual complex corrugated layer and its correlation to ring silicate gerenite and chain silicate chkalovite0Synthesis and Crystal Structure of a 6H Hexagonal Fluoro-Perovskite: RbMgF39Hydrothermal synthesis and properties of MMF5(H2O)7 (M = Co2+ and Ni2+, M = Mn3+, Ga3+, and In3+)8Expanding the Chemistry of Salt-Inclusion Materials: Utilizing the Titanyl Ion as a Structure Directing Agent for the Targeted Synthesis of Salt-Inclusion Titanium Silicates14Crystal structure of K3EuSi2O71Solution-processed lead-free bulk 0D Cs3Cu2I5 single crystal for indirect gamma-ray spectroscopy application41Rb1.66Cs1.34Tb[Si5.43Ge0.57O15]·H2O, a New Member of the OD-Family of Natural and Synthetic Layered Silicates: Topology-Symmetry Analysis and Structure Prediction6Flux crystal growth of cesium bismuth silicates Cs3BiSi8O19 and Cs4Bi2Si8O21: Structure modification via Eu doping to yield Cs4Bi1.72Eu0.28Si8O21 and alkali metal ion exchange to yield Cs0.79K2.21BiSi8O190Pentanary cesium titanyl/titanate silicate oxyfluorides: Syntheses and structures2Low-temperature phase transition and magnetic properties of K3YbSi2O73Electrochemical Crystal Growth of Titanium Oxyfluorides—A Strategy for Development of Electron-Doped Materials2Synthesis of Hydrated Ternary Lanthanide-Containing Chlorides Exhibiting X-ray Scintillation and Luminescence7A two-dimensional perovskite oxyfluoride Pb 3 Fe 2 O 5 F 2 as a catalyst for electrochemical oxidation of water to oxygen9Quantum dot decorated polyaniline plastic as a multifunctional nanocomposite: experimental and theoretical approach22Luminescence and Scintillation of [Nb2O2F9]3–-Dimer-Containing Oxide–Fluorides: Cs10(Nb2O2F9)3F, Cs9.4K0.6(Nb2O2F9)3F, and Cs10(Nb2O2F9)3Cl5Synthesis, structure, and scintillation of Rb4Ta2Si8O2310Luminescence and Scintillation in the Niobium Doped Oxyfluoride Rb4Ge5O9F6:Nb8Polyaniline Plastic Nanocomposite as Multi‐Functional Nanomaterial16[Cs6Cl][Ga5GeQ12] (Q = S, Se): two novel porous layered chalcohalides exhibiting two-band emission and ion exchange properties6Ln2(SeO3)2(SO4)(H2O)2 (Ln=Sm, Dy, Yb): A Mixed‐Ligand Pathway to New Lanthanide(III) Multifunctional Materials Featuring Nonlinear Optical and Magnetic Anisotropy Properties36Ln2(SeO3)2(SO4)(H2O)2 (Ln=Sm, Dy, Yb): A Mixed‐Ligand Pathway to New Lanthanide(III) Multifunctional Materials Featuring Nonlinear Optical and Magnetic Anisotropy Properties2Ring Silicates Cs4Tm2[Si4O12](OH)2 and Cs4(Tm,Tb)2[Si4O12](OH)2 As Merohedral Twins0Ring Silicates Cs4Tm2[Si4O12](OH)2 and Cs4(Tm,Tb)2[Si4O12](OH)2 As Merohedral Twins2Synthesis of uranium mixed anion compounds synthesized using the Boron-Chalcogen Mixture method: Ba6Co6U0·91S13·5O0.5 and Ba5·47K0·53Zn6US13·5O0.55Metal oxide decorated polyaniline based multifunctional nanocomposites: An experimental and theoretical approach21Europium-bearing organic framework with excellent X-ray scintillating luminescence39Rb2Ln[Si2O6]F (Ln = Y, Eu–Lu): Flux Synthesis, Structure Determination, and DFT-Calculated Formation Enthalpies of a Series of Mixed-Anion Rare Earth Cyclosilicates2Striking Change in Radiative Lifetime and Asymmetry Ratio with Temperature for the Double Perovskite Cs2NaEuCl69Alkali Rare Earth Double Phosphates: Promising New High Temperature Scintillators9Ba 5 Y 12 Zn[O(SiO 4 )] 8 : a novel non-centrosymmetric silicate with a short ultraviolet cut-off edge featuring [ZnSi 4 O 16 ] and [SiO 4 ] units3Exploring the Valence Diversity of Uranium by Flux Growth of Uranium Silicate under Inert Atmosphere6Sulfate-functionalized ternary metal oxide/Polypyrrole nanocomposites: Synergistic enhancement in Photocatalytic, Corrosion inhibition, Magnetic, and Electrical properties14Amplified Circularly Polarized and X-ray-Excited Luminescence of Easily Separated Chiral Donor–Acceptor Binaphthalene Imides through a Conformation Locking Strategy7Crystal Growth of Quaternary AkRE 2 Si 2 S 8 (Ak = Ca and Sr; RE = La–Tb) Thiosilicates Using Flux-Assisted Boron Chalcogen Mixture Method: Exploring X-ray Scintillation, Luminescence, and Magnetic Properties11Iron-Based Layered Perovskite Oxyfluoride Electrocatalyst for Oxygen Evolution: Insights from Crystal Facets with Heteroanionic Coordination15Molten salt flux synthesis of two new alkali rare earth silicate fluorides: Rb3Sc2[Si4O12]F and Rb2Sm[Si4O10]F1Wide-ranging predictions of new stable compounds powered by recommendation engines12Synthesis of Mixed Anion Rare Earth Sulfate Fluorides LnSO4F·H2O (Ln = Nd, Tb, Dy, and Ho) and LnSO4F (Ln = Tb, Dy, and Ho)5Oxyfluorides for electrochemical and photoelectrochemical water oxidation: a review and basic tutorial0A Mixed-Anion Design Approach for High-Efficiency X-ray Scintillators: A Study of KLn(SO4)F2 (Ln = Eu, Gd, Tb, Dy, Ho, and Tm)3BaScSi2O6F: A barium-containing rare-earth metal silicate fluoride with a short cutoff edge0Tetrametallic Terbium/Europium Fluorenylphosphonate With Excellent X‐Ray Scintillating and Photo‐Induced Luminescence0Recent Advances in Thermally Activated Delayed Fluorescence Scintillators for X‐Ray Imaging2

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  16. Dual-Mode Light-Emitting Lanthanide Metal–Organic Frameworks with High Water and Thermal Stability and Their Application in White LEDs

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  17. Silicate-germanate K2Y[(Si3Ge)O10(OH)] with unusual complex corrugated layer and its correlation to ring silicate gerenite and chain silicate chkalovite

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  18. Synthesis and Crystal Structure of a 6H Hexagonal Fluoro-Perovskite: RbMgF3

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  19. Hydrothermal synthesis and properties of MMF5(H2O)7 (M = Co2+ and Ni2+, M = Mn3+, Ga3+, and In3+)

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