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RESEARCH PAPER · Dalton Transactions · 2017

Two deep-ultraviolet nonlinear optical alkaline-earth metal borates based on different types of oxoboron clusters

Qi Wei, Li Quan Sun, Jie Zhang, Guo‐Yu Yang

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Two deep-ultraviolet nonlinear optical alkaline-earth metal borates based on different types of oxoboron clustersOriginalA new mixed alkali metal borate: LiCs[B5O8(OH)]·H2O11K2[B3O3(OH)5]: A new deep-UV nonlinear optical crystal with isolated [B3O3(OH)5]2- anionic groups31MBaYB 6 O 12 (M = Rb, Cs): two new rare-earth borates with large birefringence and short ultraviolet cutoff edges42Li 2 Gd 4 (MoO 4 ) 7 crystal preparation and spectral properties applied to 2.0 μm lasers27Synthesis, structure characterization, photoluminescence properties and TD–DFT calculations for two new borates3Recent advances in ultraviolet and deep-ultraviolet second-order nonlinear optical crystals257Two New Tetra-Zr(IV)-Substituted Sandwich-Type Polyoxometalates Functionalized by Different Organic Amine Ligands8Why Some Noncentrosymmetric Borates Do Not Make Good Nonlinear Optical Materials: A Case Study with K3B5O8(OH)222Synthesis, Structure, and Properties of the Non-Centrosymmeteric Compound LiNaRbB5O8(OH)23Three Alumino/Galloborate Frameworks Templated by Organic Amines: Syntheses, Structures, and Nonlinear Optical Properties23The structure and classification of complex borates43Zr 4 -Substituted polyoxometalate dimers decorated by d -tartaric acid/glycolic acid: syntheses, structures and optical/electrochemical properties17Sn 2 B 7 O 12 F with a 2∞[B 14 O 24 ] 6− layer constructed from the unprecedented [B 7 O 16 ] 11− fundamental building block18Two novel 3D borates: porous-layer and layer-pillar frameworks19Syntheses and structures of a new 2D layered borate and a novel 3D porous-layered aluminoborate17Gd(NO 3 )(Se 2 O 5 )·3H 2 O: a nitrate–selenite nonlinear optical material with a short ultraviolet cutoff edge28K 4 (PO 2 F 2 ) 2 (S 2 O 7 ): first fluorooxophosphorsulfate with mixed-anion [S 2 O 7 ] 2− and [PO 2 F 2 ] − groups14RbB 3 O 4 F 2 : a rubidium fluorooxoborate with an unprecedented [B 3 O 5 F 2 ] 3− functionalized unit and a large birefringence37Two New Alkaline Metal Borates with Supramolecular Framework Constructed from 1D {B5}/{B6} Helical Chains5The first rare-earth lead phosphates Pb3AP3O12 (A=Sc, Gd) with remarkable SHG enhancement8A Way for Derived Carbon Materials by Thermal Etching Hybrid Borate for Electrochemical CO2 Reduction15A new acentric borate of Ba2[B5O8(OH)]2[B(OH)3]·H2O: Synthesis, structure and nonlinear optical property4Cs3B3O3F6 with a Deep-Ultraviolet Cutoff Edge and a Suitable Birefringence as the Potential Zero-Order Waveplate Material31Sn3B8O15: A Ternary Tin(II) Borate with Flexible [B8O18]12– Fundamental Building Block Formed by [B7O16]11– and [BO3]3– Groups10Five new rubidium borates with 0D clusters, 1D chains, 2D layers and 3D frameworks15Polar polymorphism: β-Ca2[B5O8(OH)]2[B(OH)3]·H2O—synthesis, structure and nonlinear optical property11Structural Chemistry of Metal‐Oxo Clusters1Structural Chemistry of Metal‐Oxo Clusters1Two deep-ultraviolet nonlinear optical barium borates framework: Alkali metal enhances the second-harmonic generation response13K2Na3[{B6O10(OH)}{B3O4(OH)3}] ⋅ H2O: A Layered Borate Built by Mixed Oxoboron Clusters with Nonlinear‐Optical Property20LiB9O15·H2dap·H2O: A Cotemplated Acentric Layer-Pillared Borate Built by Mixed Oxoboron Clusters12Ba2B13O19(OH)5·5H2O: A promising nonlinear optical material with a unique 2[B13O19(OH)5]∞ two-dimensional layer9Anisotropic thermal expansion and electronic transitions in the Co 3 BO 5 ludwigite18Li 7 SrScB 12 O 24 and Li 7 Ba 0.6 Ca 0.4 ScB 12 O 24 : two new quaternary rare-earth borates with short UV cutoff edges4Syntheses, structures and optical properties of two B 3 O 7 cluster-based borates9Ba2B10O16(OH)2·(H3BO3)(H2O): A Possible Deep-Ultraviolet Nonlinear-Optical Barium Borate36Two New Borates Built by Different Types of {B9} Cluster Units14FILLING OF CHANNELS OF THE ZEOLITE FRAMEWORK IN TRIGONAL POLAR NONABORATE Ва3Na0.9(OH)1.9[B9O16][B(OH)3]0Filling of Channels of the Zeolite Framework in Trigonal Polar Nonaborate Ва3Na0.9(OH)1.9[B9O16][B(OH)3]0Synthesis, structure, and characteristics of a hexa-Ti-oxo-cluster-added Keggin-type polyoxometalate12Preparation of novel silver borates by soft hydrothermal synthesis in sealed tubes: New representatives of larderellite and veatchite families17NaB(OH) 3 CH 3 : a deep-ultraviolet optical crystal with unprecedented methyl-modified [B(OH) 3 CH 3 ] units6NaRbB10O14(OH)4 and Na3CsB10O16(OH)2: Two Cases of Hydroxyborates with [B5Om(OH)n] Units and Deep Ultraviolet Cutoff Edges6Synthesis, structure and characterizations of the first alkali-metal/alkaline-earth-metal oxalatophosphate Na4Mg3(HPO4)4(C2O4)·2H2O3Two Alkaline Metal Borates: from Layer to Layer-Pillared Framework8Pb 2 B 10 O 16 (OH) 2 ·B(OH) 3 ·H 2 O: significantly enhanced second harmonic generation via substituting metal cations in isostructural compounds with Pb 2+2Two alkali metal borates built by {Li@B 14 } and {B 15 } cluster units1Inorganic Borate Functionalized {Ni6SiW9} Polyoxometalates: From Cluster to Cage Cluster4Tuning structure and magnetic order through Cr substitution in Co3O2BO3 Ludwigite2Li6[{BO3}{B15O21(OH)6}]: An Acentric Layered Borate Constructed from Unprecedented Oxoboron Cluster Building Units6A multi-scale birefringence modulation strategy in DUV/UV crystals induced by organic cations1CsB(OH) 4 (H 2 O) 2 and Na(NH 4 ) 2 B 10 O 16 OH(H 2 O): a hydroxylation modification strategy regulates the borate structures and optical properties0孤对电子效应羟基硼酸盐非线性光学研究进展（特邀）0Ba 5 Zn 4 (B 3 O 6 ) 2 (B 12 O 24 ): A Borate with Edge-Sharing [BO 4 ] Tetrahedral Connection by Introducing Zn into β-BaB 2 O 42Two {B 6 }-Based Borates: From 1D Chain to 3D Framework1Two Acentric Borates with 2-/3-D Frameworks: Syntheses, Structures, and Nonlinear Optical Properties0

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  1. A new mixed alkali metal borate: LiCs[B5O8(OH)]·H2O

    Inorganic Chemistry Communications · 2017-09-14

    Chong‐An Chen, Qi Wei, Guo‐Yu Yang

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  2. K2[B3O3(OH)5]: A new deep-UV nonlinear optical crystal with isolated [B3O3(OH)5]2- anionic groups

    Journal of Alloys and Compounds · 2017-11-16

    Qian Wang, Chensheng Lin, Guohong Zou, Mengjiao Liu, Daojiang Gao, Jian Bi, Ling Huang

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  3. MBaYB 6 O 12 (M = Rb, Cs): two new rare-earth borates with large birefringence and short ultraviolet cutoff edges

    Dalton Transactions · 2017-11-30

    Xinglong Chen, Fangfang Zhang, Yunjing Shi, Yanzhou Sun, Zhihua Yang, Shilie Pan

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  4. Li 2 Gd 4 (MoO 4 ) 7 crystal preparation and spectral properties applied to 2.0 μm lasers

    CrystEngComm · 2018-01-01

    Shijia Sun, Qi Wei, Weidong Chen, Fei Lou, Degao Zhong, Chen Hu, Lizhen Zhang, Zhoubin Lin, Bing Teng

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  5. Synthesis, structure characterization, photoluminescence properties and TD–DFT calculations for two new borates

    Acta Crystallographica Section C Structural Chemistry · 2018-03-07

    Nasreddine Hadjadj, Mohamed Abdesselem Dems, Hocine Mérazig, Lamia Bendjeddou

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  6. Recent advances in ultraviolet and deep-ultraviolet second-order nonlinear optical crystals

    Coordination Chemistry Reviews · 2018-03-15

    Chao Wu, Gang Yang, Mark Graeme Humphrey, Chi Zhang

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  7. Two New Tetra-Zr(IV)-Substituted Sandwich-Type Polyoxometalates Functionalized by Different Organic Amine Ligands

    Journal of Cluster Science · 2018-08-06

    Zhi-Hui Ni, Zhong Zhang, Guo‐Yu Yang

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  8. Why Some Noncentrosymmetric Borates Do Not Make Good Nonlinear Optical Materials: A Case Study with K3B5O8(OH)2

    Inorganic Chemistry · 2018-08-31

    Fenghua Ding, Matthew Lander Nisbet, Weiguo Zhang, P. Shiv Halasyamani, Liyuan Chai, Kenneth Reinhard Poeppelmeier

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  9. Synthesis, Structure, and Properties of the Non-Centrosymmeteric Compound LiNaRbB5O8(OH)2

    Crystal Growth & Design · 2018-09-21

    Yi Jin Yang, Yi Qiu, Pifu Gong, Qian Huang, Sangen Zhao, Siyang Luo, Junliang Sun, Zheshuai Lin

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  10. Three Alumino/Galloborate Frameworks Templated by Organic Amines: Syntheses, Structures, and Nonlinear Optical Properties

    Inorganic Chemistry · 2018-10-10

    Lin Cheng, Guo‐Yu Yang

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  11. The structure and classification of complex borates

    Russian Chemical Reviews · 2018-10-25

    Anastasiya P. Topnikova, Elena L. Belokoneva

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  12. Zr 4 -Substituted polyoxometalate dimers decorated by d -tartaric acid/glycolic acid: syntheses, structures and optical/electrochemical properties

    CrystEngComm · 2018-12-12

    Zhi-Hui Ni, Hai‐Lou Li, Xuyan Li, Guo‐Yu Yang

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  13. Sn 2 B 7 O 12 F with a 2∞[B 14 O 24 ] 6− layer constructed from the unprecedented [B 7 O 16 ] 11− fundamental building block

    Inorganic Chemistry Frontiers · 2019-01-01

    Zixiu Lu, Fangfang Zhang, Abudukadi Tudi, Zhizhong Zhang, Zhihua Yang, Shilie Pan

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  14. Two novel 3D borates: porous-layer and layer-pillar frameworks

    Dalton Transactions · 2019-10-28

    Dan Qin, Tianjiao Zhang, Chengbing Ma, Guo‐Yu Yang

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  15. Syntheses and structures of a new 2D layered borate and a novel 3D porous-layered aluminoborate

    Dalton Transactions · 2019-11-07

    Chong‐An Chen, Rui Pan, Guo‐Yu Yang

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  16. Gd(NO 3 )(Se 2 O 5 )·3H 2 O: a nitrate–selenite nonlinear optical material with a short ultraviolet cutoff edge

    Dalton Transactions · 2020-01-01

    Chao Wu, Longhua Li, Lin Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  17. K 4 (PO 2 F 2 ) 2 (S 2 O 7 ): first fluorooxophosphorsulfate with mixed-anion [S 2 O 7 ] 2− and [PO 2 F 2 ] − groups

    Dalton Transactions · 2020-01-01

    Wenyao Zhang, Wenqi Jin, Zhihua Yang, Shilie Pan

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  18. RbB 3 O 4 F 2 : a rubidium fluorooxoborate with an unprecedented [B 3 O 5 F 2 ] 3− functionalized unit and a large birefringence

    Chemical Communications · 2020-01-01

    Zixiu Lu, Fangfang Zhang, Abudukadi Tudi, Zhihua Yang, Shilie Pan

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  19. Two New Alkaline Metal Borates with Supramolecular Framework Constructed from 1D {B5}/{B6} Helical Chains

    Chemical Research in Chinese Universities · 2020-01-16

    Qi–Ming Qiu, Kening Sun, Guo‐Yu Yang

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  20. The first rare-earth lead phosphates Pb3AP3O12 (A=Sc, Gd) with remarkable SHG enhancement

    Journal of Solid State Chemistry · 2020-02-26

    Ming Wen, Hongping Wu, Hongwei Yu, Xiaohong Wu

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  21. A Way for Derived Carbon Materials by Thermal Etching Hybrid Borate for Electrochemical CO2 Reduction

    Inorganic Chemistry · 2020-07-16

    Ying Liu, Kang Zhou, Hongli Chen, Yun‐Nan Gong, Chun‐Yang Pan

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  22. A new acentric borate of Ba2[B5O8(OH)]2[B(OH)3]·H2O: Synthesis, structure and nonlinear optical property

    Inorganic Chemistry Communications · 2020-09-07

    Han‐Qing Wu, Yanying Li

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  23. Cs3B3O3F6 with a Deep-Ultraviolet Cutoff Edge and a Suitable Birefringence as the Potential Zero-Order Waveplate Material

    Inorganic Chemistry · 2020-09-11

    Meng Cheng, Wenqi Jin, Zhihua Yang, Shilie Pan

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  24. Sn3B8O15: A Ternary Tin(II) Borate with Flexible [B8O18]12– Fundamental Building Block Formed by [B7O16]11– and [BO3]3– Groups

    Inorganic Chemistry · 2020-12-29

    Siru Guo, Wen-Bin Zhang, Min Zhang, Zhihua Yang, Shilie Pan

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  25. Five new rubidium borates with 0D clusters, 1D chains, 2D layers and 3D frameworks

    CrystEngComm · 2021-01-01

    Qi–Ming Qiu, Kening Sun, Guo‐Yu Yang

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  26. Polar polymorphism: β-Ca2[B5O8(OH)]2[B(OH)3]·H2O—synthesis, structure and nonlinear optical property

    Journal of Solid State Chemistry · 2021-04-19

    Qi–Ming Qiu, Xuyan Li, Chong‐An Chen, Kening Sun, Guo‐Yu Yang

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  27. Structural Chemistry of Metal‐Oxo Clusters

    Unknown journal · 2021-04-19

    Xiaofeng Yi, Wei‐Hui Fang, Jinying Liu, Cheng Chen, Mingyan Wu, Lei Zhang

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  28. Structural Chemistry of Metal‐Oxo Clusters

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    Xiaofeng Yi, Wei‐Hui Fang, Jinying Liu, Cheng Chen, Mingyan Wu, Lei Zhang

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  29. Two deep-ultraviolet nonlinear optical barium borates framework: Alkali metal enhances the second-harmonic generation response

    Journal of Solid State Chemistry · 2021-06-06

    Qi–Ming Qiu, Guo‐Yu Yang

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  30. K2Na3[{B6O10(OH)}{B3O4(OH)3}] ⋅ H2O: A Layered Borate Built by Mixed Oxoboron Clusters with Nonlinear‐Optical Property

    Chemistry - An Asian Journal · 2021-08-23

    Chong‐An Chen, Qi–Ming Qiu, Guo‐Yu Yang

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  31. LiB9O15·H2dap·H2O: A Cotemplated Acentric Layer-Pillared Borate Built by Mixed Oxoboron Clusters

    Inorganic Chemistry · 2021-10-15

    Xuyan Li, Guo‐Yu Yang

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  32. Ba2B13O19(OH)5·5H2O: A promising nonlinear optical material with a unique 2[B13O19(OH)5]∞ two-dimensional layer

    Journal of Alloys and Compounds · 2021-12-09

    Kaitong Liu, Jian Wei Han, Fuming Li, Congcong Jin, Zhihua Yang, Miriding Mutailipu, Shilie Pan

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  33. Anisotropic thermal expansion and electronic transitions in the Co 3 BO 5 ludwigite

    Dalton Transactions · 2022-01-01

    Natalia V. Kazak, Ana B. Arauzo, Juan Bartolomé, Мaxim S. Моlokeev, Vyacheslav A. Dudnikov, Leonid A. Solovyov, A.A. Borus, Sergei G. Ovchinnikov

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  34. Li 7 SrScB 12 O 24 and Li 7 Ba 0.6 Ca 0.4 ScB 12 O 24 : two new quaternary rare-earth borates with short UV cutoff edges

    New Journal of Chemistry · 2022-01-01

    Jianbang Chen, Jie Zhang, Aixin Zhu, Xuchu Huang

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  35. Syntheses, structures and optical properties of two B 3 O 7 cluster-based borates

    CrystEngComm · 2022-01-01

    Chong‐An Chen, Guo‐Yu Yang

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  36. Ba2B10O16(OH)2·(H3BO3)(H2O): A Possible Deep-Ultraviolet Nonlinear-Optical Barium Borate

    Inorganic Chemistry · 2022-03-01

    Wen-Zhuo Zhao, Yinan Zhang, You‐Zhao Lan, Jian‐Wen Cheng, Guo‐Yu Yang

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  37. Two New Borates Built by Different Types of {B9} Cluster Units

    Chemical Research in Chinese Universities · 2022-03-10

    Juan Chen, Jiajia Wang, Chongan Chen, Guo‐Yu Yang

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  38. FILLING OF CHANNELS OF THE ZEOLITE FRAMEWORK IN TRIGONAL POLAR NONABORATE Ва3Na0.9(OH)1.9[B9O16][B(OH)3]

    Кристаллография · 2023-03-01

    A. P. Topnikova, Elena L. Belokoneva, Olga V. Dimitrova, Anatoly S. Volkov, Leokadiya V. Zorina

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  39. Filling of Channels of the Zeolite Framework in Trigonal Polar Nonaborate Ва3Na0.9(OH)1.9[B9O16][B(OH)3]

    Crystallography Reports · 2023-04-01

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  40. Synthesis, structure, and characteristics of a hexa-Ti-oxo-cluster-added Keggin-type polyoxometalate

    Polyoxometalates · 2023-09-01

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  41. Preparation of novel silver borates by soft hydrothermal synthesis in sealed tubes: New representatives of larderellite and veatchite families

    Solid State Sciences · 2023-12-15

    Sergey N. Volkov, Sergey M. Aksenov, Dmitri O. Charkin, A. M. Banaru, Daria A. Banaru, Yulia A. Vaitieva, Maria Georgievna Krzhizhanovskaya, N. A. Yamnova, Vadim E. Kireev, Alevtina N. Gosteva, Nikita Sergeyevich Tsvetov, Yevgeny E. Savchenko, Р. С. Бубнова

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  42. NaB(OH) 3 CH 3 : a deep-ultraviolet optical crystal with unprecedented methyl-modified [B(OH) 3 CH 3 ] units

    Journal of Materials Chemistry C · 2024-01-01

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  43. NaRbB10O14(OH)4 and Na3CsB10O16(OH)2: Two Cases of Hydroxyborates with [B5Om(OH)n] Units and Deep Ultraviolet Cutoff Edges

    Inorganic Chemistry · 2024-04-24

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  44. Synthesis, structure and characterizations of the first alkali-metal/alkaline-earth-metal oxalatophosphate Na4Mg3(HPO4)4(C2O4)·2H2O

    Journal of Solid State Chemistry · 2024-11-01

    Sen Ji, Bo Xiao, Yanyang Han, Shanshan Liu, Ye Liu, Ye Liu, Xin Yang, Kai Feng

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  45. Two Alkaline Metal Borates: from Layer to Layer-Pillared Framework

    Inorganic Chemistry · 2024-12-31

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  46. Pb 2 B 10 O 16 (OH) 2 ·B(OH) 3 ·H 2 O: significantly enhanced second harmonic generation via substituting metal cations in isostructural compounds with Pb 2+

    Journal of Materials Chemistry C · 2025-01-01

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  47. Two alkali metal borates built by {Li@B 14 } and {B 15 } cluster units

    Dalton Transactions · 2025-01-01

    Mian Li, Dan Qin, Juan Chen, Qi Wei, Guo‐Yu Yang

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  48. Inorganic Borate Functionalized {Ni6SiW9} Polyoxometalates: From Cluster to Cage Cluster

    Inorganic Chemistry · 2025-03-03

    Yu Wang, Junjun Sun, Hai‐Lou Li, Juan Chen, Zhenwen Wang, Guo‐Yu Yang

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  49. Tuning structure and magnetic order through Cr substitution in Co3O2BO3 Ludwigite

    Journal of Alloys and Compounds · 2025-06-24

    Davor L. Mariano, D. R. Sánchez, D. C. Freitas, Catalina Salazar Mejía, Svetlana Sofronova, M. A. Contínentino, L. F. Cohen, L. Ghivelder

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  50. Li6[{BO3}{B15O21(OH)6}]: An Acentric Layered Borate Constructed from Unprecedented Oxoboron Cluster Building Units

    Crystal Growth & Design · 2025-08-20

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