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RESEARCH PAPER · Chemistry - A European Journal · 2018

[C5H12N]SnCl3: A Tin Halide Organic–Inorganic Hybrid as an Above‐Room‐Temperature Solid‐State Nonlinear Optical Switch

Xitao Liu, Chengmin Ji, Zhenyue Wu, Lina Li, Shiguo Han, Yuyin Wang, Zhihua Sun, Junhua Luo

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[C5H12N]SnCl3: A Tin Halide Organic–Inorganic Hybrid as an Above‐Room‐Temperature Solid‐State Nonlinear Optical SwitchOriginalRedox-switching of ternary Ni( ii ) and Cu( ii ) complexes: synthesis, experimental and theoretical studies along with second-order nonlinear optical properties17A DFT probe on the linear and nonlinear optical characteristics of some star‐shaped DI‐π‐DII‐Atype acetylene‐bridged rigid triazines7(C 3 H 9 NI) 4 AgBiI 8 : a direct-bandgap layered double perovskite based on a short-chain spacer cation for light absorption66Above room-temperature dielectric switching and semiconducting properties of a layered organic–inorganic hybrid compound: (C 6 H 12 N) 2 Pb(NO 3 ) 418Tin based organic–inorganic hybrid semiconductors with reversible phase transition and dielectric anomaly29Switchable Dielectric Behavior and Order‐Disorder Phase Transition in a New Organic‐Inorganic Hybrid Compound: (CH3NH3)4[InCl6]Cl15Lead-Free Tin(IV)-Based Organic–Inorganic Metal Halide Hybrids with Excellent Stability and Blue-Broadband Emission137Phase transition, dielectric switching property of an In (III)-based organic-inorganic hybrid compound: (C5H16N2)InBr529Polar Molecule-Based Material with Optic–Electric Switching Constructed by Polar Anions21Three-Dimensional Perovskite Methylhydrazinium Lead Chloride with Two Polar Phases and Unusual Second-Harmonic Generation Bistability above Room Temperature173Molecule-based nonlinear optical switch with highly tunable on-off temperature using a dual solid solution approach102Revisiting a Perovskite-like Copper-Formate Framework NH4[Cu(HCOO)3]: Order–Disorder Transition Influenced by Jahn-Teller Distortion and above Room-Temperature Switching of the Nonlinear Optical Response between Two SHG-Active States30Exploring a Fatigue‐Free Layered Hybrid Perovskite Ferroelectric for Photovoltaic Non‐Volatile Memories51Exploring a Fatigue‐Free Layered Hybrid Perovskite Ferroelectric for Photovoltaic Non‐Volatile Memories0Stepwise Dielectric Switching Occurs in Two Photo-Responsive Complexes Possessing Two-Dimensional Structures12Tunable phase transition, band gap and SHG properties by halogen replacement of hybrid perovskites [(thiomorpholinium)PbX3, X = Cl, Br, I]75A Photochromic Zinc–Viologen Framework with a High-Contrast Nonlinear Optical Switchable Behavior24Hybrid Metal‐Halide Infrared Nonlinear Optical Crystals of (TMEDA)MI5 (M = Sb, Bi) with High Stability36Near-Infrared Phosphorescent Hybrid Organic–Inorganic Perovskite with High-Contrast Dielectric and Third-Order Nonlinear Optical Switching Functionalities74A one-dimensional perovskite with ferroelectric and switchable nonlinear optical properties: [azetidinium]CdCl 334Near-room-temperature reversible switching of quadratic optical nonlinearities in a one-dimensional perovskite-like hybrid24Symmetry breaking of A 3 M 2 X 9 -type perovskite derivatives induced by polar quaternary ammonium cations: achieving efficient nonlinear optical properties28Chiral Hybrid Copper(I) Halides for High Efficiency Second Harmonic Generation with a Broadband Transparency Window112Chiral Hybrid Copper(I) Halides for High Efficiency Second Harmonic Generation with a Broadband Transparency Window13A promising nonlinear optics and optical limiting attributes in single organic coumarin-based compounds5Cooperative Enhancement of Second Harmonic Generation in an Organic–Inorganic Hybrid Antimony Halide63Dimethylaniline-Based Hybrid Compounds of Cadmium Diiodide: Synthesis, Crystal Structure, and Physical Properties5Organic Cation Modulation Triggered Second Harmonic Response in Manganese Halides with Bright Fluorescence46Lead-free 3D hybrid perovskites based on an aziridinium cation17Quasi-linear CuX 2 (X = Cl, Br) motif-built hybrid copper halides realizing encouraging nonlinear optical activities28Schottky construction of bimetallic Au-Cu alloy@TiO2 hollow nanoboxes embedded optical switch for enhancing photocatalytic and selective adsorption activities via one-pot deposition-precipitation strategy15Multi‐Stimuli Responsive Luminescence and Domino Phase Transition of Hybrid Copper Halides with Nonlinear Optical Switching Behavior20Multi‐Stimuli Responsive Luminescence and Domino Phase Transition of Hybrid Copper Halides with Nonlinear Optical Switching Behavior126Achiral Fluorinated Aromatic Ligands Based Chiral Hybrid Antimony Halides with High‐Efficiency Second‐Harmonic Generation18Centimeter-sized single crystal of a lead-free halide double perovskite with ferroelastic phase transition-triggered switchable dielectric properties11A review of the relationship between the structure and nonlinear optical properties of organic-inorganic hybrid materials150Oxidation-Induced Dissolution Recrystallization Structural Transformation Strategy Enhanced Nonlinear Optical Effect of Hybrid Chiral Tin Bromide Single Crystals7(C 13 N 3 H 14 ) 2 MBr 4 (M = Zn, Cd): two novel hybrid metal halides with balanced integrated nonlinear optical performance31Amine-directed synthesis, valence state control, and optical properties of two new organic–inorganic tin chlorides7Li+(3)Mg−: A new alkaline earthide with large nonlinear optical response0Phase Transitions and Dynamics in Mixed Three- and Low-Dimensional Lead Halide Perovskites134Alkali Metal–Substitution–Induced Confinement Effect for Designing High Phase–Transition–Temperature Molecular–Based Compounds Exhibiting Strong Photoluminescence1Warm white-light emission from self-trapped excitons in double-chain metal halide hybrid2Advanced Organic–Inorganic Hybrid Materials for Optoelectronic Applications222Enhanced phase transition temperature achieved by CH3/H substitution in Sn-based perovskite3Tetrachloro-(acetylacetonato)stannate(IV) and tri-iodocadmate(II) stabilized by a heptacyclic cation: Synthesis, characterization, and crystal structure0Enhanced second harmonic generation in a Fdd 2 polymorph of C 12 H 8 N 2 O 4 Zn for UV nonlinear optical applications1Toward the Strongest Nonlinear Optical Response and Largest Birefringence in Solvent‐Free Organic–Inorganic Metal Halides by Hydrogen Bond Engineering39Unravelling the impact of octahedral distortion and non-covalent interactions on the hyperpolarizabilities of Co(II) and Ni(II) coordination complexes with uridine nucleotide11Halogen-ion-driven polymorphs for high-performance nonlinear optical crystalline materials3Noncentrosymmetric hybrid gallium halides built from non-polar inorganic units3Exploring the Effect of Electronic Symmetry on the Hyperpolarizabilities of Co(II) and Ni(II) Coordination Complexes with Cytidine Nucleotide7Halogen Engineering and Orbital Origins of Large Second-Harmonic Generation in Organic–Inorganic Hybrid Metal Halides2Mixed Cation-Ordering-Driven Ferroelastic Phase Transition in Hybrid Lead Halide Enabling Large Switchable Birefringence04-Bromopyridinium trichloridostannate(II)0Structural-Dynamic Synergy in Hydrogen-Bond Reconfiguration Enables Room-Temperature Tunable Nonlinear Optical Materials0

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  1. Redox-switching of ternary Ni( ii ) and Cu( ii ) complexes: synthesis, experimental and theoretical studies along with second-order nonlinear optical properties

    New Journal of Chemistry · 2019-01-01

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  2. A DFT probe on the linear and nonlinear optical characteristics of some star‐shaped DI‐π‐DII‐Atype acetylene‐bridged rigid triazines

    Journal of Physical Organic Chemistry · 2019-11-14

    V.M. Vidya, Prabhakar Chetti

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  3. (C 3 H 9 NI) 4 AgBiI 8 : a direct-bandgap layered double perovskite based on a short-chain spacer cation for light absorption

    Chemical Communications · 2020-01-01

    Yunpeng Yao, Bo Kou, Peng Yu, Zhenyue Wu, Lina Li, Sasa Wang, Xinyuan Zhang, Xitao Liu, Junhua Luo

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  4. Above room-temperature dielectric switching and semiconducting properties of a layered organic–inorganic hybrid compound: (C 6 H 12 N) 2 Pb(NO 3 ) 4

    Dalton Transactions · 2020-01-01

    Jia‐Ying Jiang, Qi Xu, Jia‐Jun Ma, Zhi‐Xin Gong, Chao Yi Shi, Yi Zhang

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  5. Tin based organic–inorganic hybrid semiconductors with reversible phase transition and dielectric anomaly

    Dalton Transactions · 2020-01-01

    Xiuli You, Jiaojiao Yao, Zhenhong Wei

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  6. Switchable Dielectric Behavior and Order‐Disorder Phase Transition in a New Organic‐Inorganic Hybrid Compound: (CH3NH3)4[InCl6]Cl

    European Journal of Inorganic Chemistry · 2020-01-09

    Min Li, Guan‐Cheng Xu, Wen‐Bo Xin, Yin‐Qiang Zhang

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  7. Lead-Free Tin(IV)-Based Organic–Inorganic Metal Halide Hybrids with Excellent Stability and Blue-Broadband Emission

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    Gaomin Song, Mingze Li, Yi Jin Yang, Fei Liang, Qian Huang, Xiaomeng Liu, Pifu Gong, Zhiguo Xia, Zheshuai Lin

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  8. Phase transition, dielectric switching property of an In (III)-based organic-inorganic hybrid compound: (C5H16N2)InBr5

    Journal of Solid State Chemistry · 2020-03-22

    Min Li, Guan‐Cheng Xu, Yinqiang Zhang, Wen‐Bo Xin

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  9. Polar Molecule-Based Material with Optic–Electric Switching Constructed by Polar Anions

    Inorganic Chemistry · 2020-04-01

    Xuemei Zhao, Dong Li, Hai‐Xia Zhao, Yan‐Ping Ren, La‐Sheng Long, Lan‐Sun Zheng

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  10. Three-Dimensional Perovskite Methylhydrazinium Lead Chloride with Two Polar Phases and Unusual Second-Harmonic Generation Bistability above Room Temperature

    Chemistry of Materials · 2020-04-13

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  11. Molecule-based nonlinear optical switch with highly tunable on-off temperature using a dual solid solution approach

    Nature Communications · 2020-06-02

    Shi‐Yong Zhang, Xia Shu, Ying Zeng, Qing‐Yan Liu, Zi‐Yi Du, Chun‐Ting He, Wei‐Xiong Zhang, Xiao‐Ming Chen

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  12. Revisiting a Perovskite-like Copper-Formate Framework NH4[Cu(HCOO)3]: Order–Disorder Transition Influenced by Jahn-Teller Distortion and above Room-Temperature Switching of the Nonlinear Optical Response between Two SHG-Active States

    The Journal of Physical Chemistry C · 2020-08-02

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  13. Exploring a Fatigue‐Free Layered Hybrid Perovskite Ferroelectric for Photovoltaic Non‐Volatile Memories

    Angewandte Chemie International Edition · 2020-11-28

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  14. Exploring a Fatigue‐Free Layered Hybrid Perovskite Ferroelectric for Photovoltaic Non‐Volatile Memories

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  15. Stepwise Dielectric Switching Occurs in Two Photo-Responsive Complexes Possessing Two-Dimensional Structures

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  16. Tunable phase transition, band gap and SHG properties by halogen replacement of hybrid perovskites [(thiomorpholinium)PbX3, X = Cl, Br, I]

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  17. A Photochromic Zinc–Viologen Framework with a High-Contrast Nonlinear Optical Switchable Behavior

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  18. Hybrid Metal‐Halide Infrared Nonlinear Optical Crystals of (TMEDA)MI5 (M = Sb, Bi) with High Stability

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  19. Near-Infrared Phosphorescent Hybrid Organic–Inorganic Perovskite with High-Contrast Dielectric and Third-Order Nonlinear Optical Switching Functionalities

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  20. A one-dimensional perovskite with ferroelectric and switchable nonlinear optical properties: [azetidinium]CdCl 3

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  21. Near-room-temperature reversible switching of quadratic optical nonlinearities in a one-dimensional perovskite-like hybrid

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  22. Symmetry breaking of A 3 M 2 X 9 -type perovskite derivatives induced by polar quaternary ammonium cations: achieving efficient nonlinear optical properties

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  23. Chiral Hybrid Copper(I) Halides for High Efficiency Second Harmonic Generation with a Broadband Transparency Window

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  25. A promising nonlinear optics and optical limiting attributes in single organic coumarin-based compounds

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  26. Cooperative Enhancement of Second Harmonic Generation in an Organic–Inorganic Hybrid Antimony Halide

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  27. Dimethylaniline-Based Hybrid Compounds of Cadmium Diiodide: Synthesis, Crystal Structure, and Physical Properties

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  28. Organic Cation Modulation Triggered Second Harmonic Response in Manganese Halides with Bright Fluorescence

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  29. Lead-free 3D hybrid perovskites based on an aziridinium cation

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  30. Quasi-linear CuX 2 (X = Cl, Br) motif-built hybrid copper halides realizing encouraging nonlinear optical activities

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  31. Schottky construction of bimetallic Au-Cu alloy@TiO2 hollow nanoboxes embedded optical switch for enhancing photocatalytic and selective adsorption activities via one-pot deposition-precipitation strategy

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  32. Multi‐Stimuli Responsive Luminescence and Domino Phase Transition of Hybrid Copper Halides with Nonlinear Optical Switching Behavior

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  33. Multi‐Stimuli Responsive Luminescence and Domino Phase Transition of Hybrid Copper Halides with Nonlinear Optical Switching Behavior

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  34. Achiral Fluorinated Aromatic Ligands Based Chiral Hybrid Antimony Halides with High‐Efficiency Second‐Harmonic Generation

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  35. Centimeter-sized single crystal of a lead-free halide double perovskite with ferroelastic phase transition-triggered switchable dielectric properties

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  36. A review of the relationship between the structure and nonlinear optical properties of organic-inorganic hybrid materials

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  37. Oxidation-Induced Dissolution Recrystallization Structural Transformation Strategy Enhanced Nonlinear Optical Effect of Hybrid Chiral Tin Bromide Single Crystals

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  38. (C 13 N 3 H 14 ) 2 MBr 4 (M = Zn, Cd): two novel hybrid metal halides with balanced integrated nonlinear optical performance

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  39. Amine-directed synthesis, valence state control, and optical properties of two new organic–inorganic tin chlorides

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  43. Warm white-light emission from self-trapped excitons in double-chain metal halide hybrid

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  47. Enhanced second harmonic generation in a Fdd 2 polymorph of C 12 H 8 N 2 O 4 Zn for UV nonlinear optical applications

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  48. Toward the Strongest Nonlinear Optical Response and Largest Birefringence in Solvent‐Free Organic–Inorganic Metal Halides by Hydrogen Bond Engineering

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  50. Halogen-ion-driven polymorphs for high-performance nonlinear optical crystalline materials

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