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RESEARCH PAPER · The Journal of Physical Chemistry C · 2016

Synthesis, Characterization, and Theoretical Studies of (Pb4O)Pb2B6O14: A New Lead(II) Borate with Isolated Oxygen-Centered Pb4O Tetrahedra and Large Second Harmonic Generation Response

Fangfang Zhang, Fangyuan Zhang, Bing‐Hua Lei, Zhihua Yang, Shilie Pan

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Synthesis, Characterization, and Theoretical Studies of (Pb4O)Pb2B6O14: A New Lead(II) Borate with Isolated Oxygen-Centered Pb4O Tetrahedra and Large Second Harmonic Generation ResponseOriginalNonlinear optical response mechanism of noncentrosymmetric lead borate Pb 6 [B 4 O 7 (OH) 2 ] 3 with three crystallographically independent [B 4 O 7 (OH) 2 ] 4− chains8Hydrothermal synthesis of a new lead(II) borate (Pb4O)Pb2B6O14-II5Experimental and ab initio studies of two UV nonlinear optical materials15Crystal structure of the solid solution Ba8.35Pb0.65(B3O6)63[O2Pb3]2(BO3)Br: An Oxidoborate Oxide Bromide with the ∞1[O2Pb3] Double Chains Based on Edge‐sharing OPb4 Tetrahedra2Synthesis, crystal structure, and properties of new lead barium borate with B 3 O 6 plane hexagonal rings2Pb@Pb8 Basket-like-Cluster-Based Lead Tellurate–Nitrate Kleinman-Forbidden Nonlinear-Optical Crystal: Pb9Te2O13(OH)(NO3)326Controlled synthesis of anisotropic lead borate crystals and its co-shielding of neutron and gamma radiations24Syntheses, crystal structure and luminescent properties of polyborates PbLnB7O13 (Ln = Gd, Sm) with a 2D [B7O13]∞ framework13Flexible coordination of Pb atoms and variable zinc–borate frameworks to construct three Pb 5 Zn 4 B 6 O 18 polymorphs8NH 4 B 11 O 16 (OH) 2 : a new ammonium borate with wavy-shaped polycyclic 2∞[B 11 O 16 (OH) 2 ] layers27The first lead fluorooxoborate PbB 5 O 8 F: achieving the coexistence of large birefringence and deep-ultraviolet cut-off edge75Synthesis, spectroscopic and X-ray structural characterization of two novel mixed-ligand lead(II) complexes4Pb4B6O13: A Polar Lead Oxyborate with Uncommon ∞(B6O12)6– Layers Exhibiting a Large Second Harmonic Generation Response15A facile route to prepare lead borate crystals for jointly shielding neutron and gamma rays6[O 2 Pb 3 ] 2 (BO 3 )I: a new lead borate iodide with 1∞[O 2 Pb 3 ] double chains6Crystal structure, theoretical studies and luminescent properties of a new borate Na 3 GdB 8 O 15 with one-dimensional broad-banded anionic framework13Synthesis, characterization and crystal structure of a new mixed alkali and alkaline-earth metal borate Rb 9 Ba 24 (BO 3 ) 196α-, β-Pb4B2O7 and α-, β-Pb4B6O13: Polymorphism drives changes in structure and performance15PbB5O7F3: A High-Performing Short-Wavelength Nonlinear Optical Material120Crystal growth, structural characteristics and electronic structure of Ba1-xPbxFe12O19 (x = 0.23–0.80) hexaferrites27Sr5[BO2(OH)]3(OH)3F: First hydroxyborate fluoride with the [BO2(OH)]2− unit2KSnI 3 ⋅ H 2 O: A New Compound with One‐Dimensional SnI 3 Chains of Pyramidal SnI 5 Polyhedra2Borates: A Rich Source for Optical Materials1089Ba 2.5 Pb 1.5 B 12 O 22 : structural transformation from a centrosymmetric to a noncentrosymmetric space group by introducing Pb into Ba 2 B 6 O 117Surface Transformations of Lead Oxides and Carbonates Using First-Principles and Thermodynamics Calculations18Sr2Pb(BeB5O10)(BO3): An Excellent Ultraviolet Nonlinear-Optical Beryllium Borate by the Pb-Modified Construction of a Conjugated System and Lone-Pair Effect14Na 2 SrB 16 O 26 : a new borate with independent interpenetrating B–O networks and deep-ultraviolet cutoff edge4Two lead borate-nitrates with anion-centered [OPb 4 ] tetrahedra and two types of π-conjugated planar units showing large birefringence20Effect of bond valence sum on the structural modeling of lead borate glass2CaBO2F: A novel deep-UV structural template with high nonlinear optical performance induced by electron delocalization25Ba1.09Pb0.91Be2(BO3)2F2: The First Pb-Containing Beryllium Borate Fluoride with Trigonal Prismatic PbO6 and 2D [Be3B3O6F3]∞ Layers7Mixed Rare-Earth Chalcogenide Borate Eu9–xRExMgS2B20O41 (RE = Sm, Gd) Featuring a 3D {[B20O41]22–}∞ Framework Connected by [B6O9(O0.5)6]6– and [B7O13(O0.5)3]8– Clusters7Dimensionality Effect of the “Free-Oxygen” Motif on the Crystal Field Splitting in Rare-Earth Crystals5New antimony fluorooxoborates with strong birefringence and unprecedented structural characterisation19Composition‐dependent structural role of lead in aluminoborate and galloborate glasses: A solid‐state NMR study7Alternating built-in electric field enhances the charge pairs separation in PbB4O7 piezocatalyst for pollutant degradation1Hydrogen‐Bond‐Directed Modular Assembly of Polar Chains for Rational Construction of UV Nonlinear Optical Crystals14Hydrogen‐Bond‐Directed Modular Assembly of Polar Chains for Rational Construction of UV Nonlinear Optical Crystals3Promising UV/DUV nonlinear optical materials with X-membered (X = multiples of 6) rings in anhydrous inorganic borates20Ab Initio Molecular Dynamics Insights Into the Atomic‐Scale Structure in PbO–B 2 O 3 –ZnO Glasses Containing PbBiO 2 I0

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  1. Nonlinear optical response mechanism of noncentrosymmetric lead borate Pb 6 [B 4 O 7 (OH) 2 ] 3 with three crystallographically independent [B 4 O 7 (OH) 2 ] 4− chains

    RSC Advances · 2016-01-01

    Xuefei Wang, Fangfang Zhang, Bing‐Hua Lei, Zhihua Yang, Shilie Pan

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  2. Hydrothermal synthesis of a new lead(II) borate (Pb4O)Pb2B6O14-II

    Zeitschrift für Naturforschung B · 2016-10-12

    Sandra Schönegger, Klaus Wurst, Günter Heymann, Hubert Huppertz

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  3. Experimental and ab initio studies of two UV nonlinear optical materials

    RSC Advances · 2017-01-01

    Juanjuan Lu, Guoqiang Q. Shi, Hongping Wu, Ming Wen, Dianwei Hou, Zhihua Yang, Fangfang Zhang, Shilie Pan

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  4. Crystal structure of the solid solution Ba8.35Pb0.65(B3O6)6

    Acta Crystallographica Section E Crystallographic Communications · 2017-02-14

    Wenwu Zhao

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  5. [O2Pb3]2(BO3)Br: An Oxidoborate Oxide Bromide with the ∞1[O2Pb3] Double Chains Based on Edge‐sharing OPb4 Tetrahedra

    Zeitschrift für anorganische und allgemeine Chemie · 2017-03-03

    Lingyun Dong, Jiao Yang, Shigang Shen, Zhenzhen Liu, Xiaojing Chen, Sufang Sun

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  6. Synthesis, crystal structure, and properties of new lead barium borate with B 3 O 6 plane hexagonal rings

    Journal of Molecular Structure · 2017-04-15

    Wenwu Zhao

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  7. Pb@Pb8 Basket-like-Cluster-Based Lead Tellurate–Nitrate Kleinman-Forbidden Nonlinear-Optical Crystal: Pb9Te2O13(OH)(NO3)3

    Inorganic Chemistry · 2017-06-26

    Yi-Gang Chen, Nan Qing Yang, Xingxing Jiang, Yao Guo, Xian‐Ming Zhang

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  8. Controlled synthesis of anisotropic lead borate crystals and its co-shielding of neutron and gamma radiations

    Journal of Alloys and Compounds · 2017-08-25

    You Shi Wu, Quan‐Ping Zhang, Dong Zhou, Yuanlin Zhou, Jian Zheng

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  9. Syntheses, crystal structure and luminescent properties of polyborates PbLnB7O13 (Ln = Gd, Sm) with a 2D [B7O13]∞ framework

    Journal of Luminescence · 2017-10-12

    Dan Zhao, Fa‐Xue Ma, Baozhong Liu, Mingjie Ma, Peigao Duan, Lina Zhang, Weilong Zhang

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  10. Flexible coordination of Pb atoms and variable zinc–borate frameworks to construct three Pb 5 Zn 4 B 6 O 18 polymorphs

    Inorganic Chemistry Frontiers · 2018-01-01

    Xiaobo Pan, Hongping Wu, Ming Wen, Bingbing Zhang, Zhihua Yang, Shilie Pan

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  11. NH 4 B 11 O 16 (OH) 2 : a new ammonium borate with wavy-shaped polycyclic 2∞[B 11 O 16 (OH) 2 ] layers

    New Journal of Chemistry · 2018-01-01

    Chunmei Huang, Fangfang Zhang, Bingbing Zhang, Zhihua Yang, Shilie Pan

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  12. The first lead fluorooxoborate PbB 5 O 8 F: achieving the coexistence of large birefringence and deep-ultraviolet cut-off edge

    Chemical Communications · 2018-01-01

    Miriding Mutailipu, Min Zhang, Bingbing Zhang, Zhihua Yang, Shilie Pan

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  13. Synthesis, spectroscopic and X-ray structural characterization of two novel mixed-ligand lead(II) complexes

    Journal of Molecular Structure · 2018-08-03

    Gholamhossein Sh. Mohammadnezhad, Fariba Nasimpour, Mostafa M. Amini, Ezzatollah Najafi, Helmar Görls, Winfried Plass, Mohammad R. Sabzalian

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  14. Pb4B6O13: A Polar Lead Oxyborate with Uncommon ∞(B6O12)6– Layers Exhibiting a Large Second Harmonic Generation Response

    Inorganic Chemistry · 2019-01-14

    Lingyun Dong, Ying Wang, Bingbing Zhang, Zhihua Yang, Xusheng Ge, Kai Liu, Shigang Shen

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  15. A facile route to prepare lead borate crystals for jointly shielding neutron and gamma rays

    Inorganic Chemistry Communications · 2019-12-09

    Guilin Li, Quan‐Ping Zhang, Jia-Le Li, Xingtao Zhao, Wei‐Di Xu, Maoxin Wang, Duigong Xu, Yuanlin Zhou

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  16. [O 2 Pb 3 ] 2 (BO 3 )I: a new lead borate iodide with 1∞[O 2 Pb 3 ] double chains

    Dalton Transactions · 2020-01-01

    Kuan Li, Alimujiang Yalikun, Zhi Su

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  17. Crystal structure, theoretical studies and luminescent properties of a new borate Na 3 GdB 8 O 15 with one-dimensional broad-banded anionic framework

    Dalton Transactions · 2020-01-01

    Dan Zhao, Yanan Li, Yan-Ping Fan, Baozhong Liu, Shirui Zhang, Ruijuan Zhang

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  18. Synthesis, characterization and crystal structure of a new mixed alkali and alkaline-earth metal borate Rb 9 Ba 24 (BO 3 ) 19

    New Journal of Chemistry · 2020-01-01

    Xiaowen Niu, Li Wang

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  19. α-, β-Pb4B2O7 and α-, β-Pb4B6O13: Polymorphism drives changes in structure and performance

    Science China Materials · 2020-01-20

    Chunmei Huang, Fangfang Zhang, Shichao Cheng, Zhihua Yang, Shilie Pan

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  20. PbB5O7F3: A High-Performing Short-Wavelength Nonlinear Optical Material

    Chemistry of Materials · 2020-02-11

    Shujuan Han, Miriding Mutailipu, Abudukadi Tudi, Zhihua Yang, Shilie Pan

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  21. Crystal growth, structural characteristics and electronic structure of Ba1-xPbxFe12O19 (x = 0.23–0.80) hexaferrites

    Journal of Alloys and Compounds · 2020-06-20

    Д.А. Винник, Igor P. Prosvirin, Vladimir E. Zhivulin, Naizheng Wang, Xingxing Jiang, Evgeny Alekseevich Trofimov, O.V. Zaitseva, Svetlana A. Gudkova, Sandra Nemrava, Dmitry A. Zherebtsov, Rainer Niewa, Victor V. Atuchin∥⊥, Zheshuai Lin

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  22. Sr5[BO2(OH)]3(OH)3F: First hydroxyborate fluoride with the [BO2(OH)]2− unit

    Journal of Molecular Structure · 2020-08-11

    Yingxuan Dong, Le Gao, Zhi Su

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  23. KSnI 3 ⋅ H 2 O: A New Compound with One‐Dimensional SnI 3 Chains of Pyramidal SnI 5 Polyhedra

    ChemistrySelect · 2020-11-18

    Kuan Li, Junwei Feng, Zhi Su

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  24. Borates: A Rich Source for Optical Materials

    Chemical Reviews · 2020-12-14

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  25. Ba 2.5 Pb 1.5 B 12 O 22 : structural transformation from a centrosymmetric to a noncentrosymmetric space group by introducing Pb into Ba 2 B 6 O 11

    Dalton Transactions · 2021-01-01

    Kaitong Liu, Jian Wei Han, Shilie Pan

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  26. Surface Transformations of Lead Oxides and Carbonates Using First-Principles and Thermodynamics Calculations

    Inorganic Chemistry · 2021-01-06

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  27. Sr2Pb(BeB5O10)(BO3): An Excellent Ultraviolet Nonlinear-Optical Beryllium Borate by the Pb-Modified Construction of a Conjugated System and Lone-Pair Effect

    Inorganic Chemistry · 2021-06-18

    Zhe Dai, Yi-Gang Chen, Yao Guo, Fang Wang, Yuanyu Yang, Xian‐Ming Zhang

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  28. Na 2 SrB 16 O 26 : a new borate with independent interpenetrating B–O networks and deep-ultraviolet cutoff edge

    Dalton Transactions · 2022-01-01

    Zhikang Chen, Kewang Zhang, Bei Zhang, Jun Zhang

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  29. Two lead borate-nitrates with anion-centered [OPb 4 ] tetrahedra and two types of π-conjugated planar units showing large birefringence

    Dalton Transactions · 2022-01-01

    Shuo Bai, Daqing Yang, Bingbing Zhang, Ling Li, Ying Wang

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  30. Effect of bond valence sum on the structural modeling of lead borate glass

    Journal of Non-Crystalline Solids · 2022-06-22

    Masaaki Nagao, Shinichi Sakida, Yasuhiko Benino, Tokuro Nanba, Atsushi Mukunoki, Tamotsu Chiba, Takahiro Kikuchi, Tomofumi Sakuragi, Hitoshi Owada

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  31. CaBO2F: A novel deep-UV structural template with high nonlinear optical performance induced by electron delocalization

    Science China Materials · 2022-11-09

    Chenchen Tu, Abudukadi Tudi, Wenqi Jin, Congwei Xie, Zhihua Yang

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  32. Ba1.09Pb0.91Be2(BO3)2F2: The First Pb-Containing Beryllium Borate Fluoride with Trigonal Prismatic PbO6 and 2D [Be3B3O6F3]∞ Layers

    Inorganic Chemistry · 2023-02-20

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  33. Mixed Rare-Earth Chalcogenide Borate Eu9–xRExMgS2B20O41 (RE = Sm, Gd) Featuring a 3D {[B20O41]22–}∞ Framework Connected by [B6O9(O0.5)6]6– and [B7O13(O0.5)3]8– Clusters

    Inorganic Chemistry · 2023-05-06

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  34. Dimensionality Effect of the “Free-Oxygen” Motif on the Crystal Field Splitting in Rare-Earth Crystals

    The Journal of Physical Chemistry C · 2023-07-25

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  35. New antimony fluorooxoborates with strong birefringence and unprecedented structural characterisation

    Chemical Communications · 2024-01-01

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  36. Composition‐dependent structural role of lead in aluminoborate and galloborate glasses: A solid‐state NMR study

    Journal of the American Ceramic Society · 2024-02-09

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  37. Alternating built-in electric field enhances the charge pairs separation in PbB4O7 piezocatalyst for pollutant degradation

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  38. Hydrogen‐Bond‐Directed Modular Assembly of Polar Chains for Rational Construction of UV Nonlinear Optical Crystals

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  39. Hydrogen‐Bond‐Directed Modular Assembly of Polar Chains for Rational Construction of UV Nonlinear Optical Crystals

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  40. Promising UV/DUV nonlinear optical materials with X-membered (X = multiples of 6) rings in anhydrous inorganic borates

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  41. Ab Initio Molecular Dynamics Insights Into the Atomic‐Scale Structure in PbO–B 2 O 3 –ZnO Glasses Containing PbBiO 2 I

    Journal of the American Ceramic Society · 2026-05-28

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