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RESEARCH ARTICLE · Journal of Materials Chemistry C · 2017

A new cerium iodate infrared nonlinear optical material with a large second-harmonic generation response

Lei Xiao, Zhenbo Cao, Jiyong Yao, Zheshuai Lin, Zhanggui Hu

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A new cerium iodate infrared nonlinear optical material with a large second-harmonic generation responseOriginalCe(IO3)2F2⋅H2O: The First Rare‐Earth‐Metal Iodate Fluoride with Large Second Harmonic Generation Response66Synthesis and structure of a new mixed metal iodate Ba 3 Ga 2 (IO 3 ) 1217REI5O14 (RE=Y and Gd): Promising SHG Materials Featuring the Semicircle‐Shaped I5O143− Polyiodate Anion125REI5O14 (RE=Y and Gd): Promising SHG Materials Featuring the Semicircle‐Shaped I5O143− Polyiodate Anion62Synthesis, Characterization, and Crystal Structure Determination of a New Lithium Zinc Iodate Polymorph LiZn(IO3)320Incorporating rare-earth cations with moderate electropositivity into iodates for the optimized second-order nonlinear optical performance17Synthesis, Crystal Structure, and Optical Properties of the First Alkali Metal Rare-Earth Iodate Fluoride: Li2Ce(IO3)4F222K2Na(IO3)2(I3O8) with Strong Second Harmonic Generation Response Activated by Two Types of Isolated Iodate Anions46Ba2[MoO3(OH)(IO3)2]IO3: A Promising SHG Material Featuring a Λ-Shaped Functional Motif Achieved by Universal Mono-Site Substitution50From Ce(IO 3 ) 4 to CeF 2 (IO 3 ) 2 : fluorinated homovalent substitution simultaneously enhances SHG response and bandgap for mid-infrared nonlinear optics26Pressure-dependent modifications in the optical and electronic properties of Fe(IO 3 ) 3 : the role of Fe 3d and I 5p lone–pair electrons15LaSiP3 and LaSi2P6: Two Excellent Rare‐Earth Pnictides with Strong SHG Responses as Mid‐ and Far‐Infrared Nonlinear Optical Crystals36Synthesis and Characterization of Novel Nanoparticles of Lithium Aluminum Iodate LiAl(IO3)4, and DFT Calculations of the Crystal Structure and Physical Properties6CaCe(IO 3 ) 3 (IO 3 F)F: a promising nonlinear optical material containing both IO 3 − and IO 3 F 2− anions22Pressure-induced phase transition and increase of oxygen-iodine coordination in magnesium iodate16General relationship between the band-gap energy and iodine-oxygen bond distance in metal iodates15A review on the advancements in the characterization of the high-pressure properties of iodates44ε-La(IO3)3: A Polar Iodate with High Thermal Stability and a Large Second-Harmonic-Generation Response Obtained by a Supercritical Hydrothermal Method8Ce(IO3)3F and Ce(IO3)2(NO3): Two Mixed-Anion Cerium Iodates with Good Nonlinear Optical and Birefringent Properties14Ln 2 F 2 (OH 2 )(MoO 3 ) 2 (SeO 3 ) 2 : Promising Multifunctional Nonlinear Optical Materials Created by Partial Fluorination Strategy under Corrosion Resistant Supercritical Reactions25Novel cesium cerium( iv ) iodate Cs 2 Ce(IO 3 ) 6 : hydrothermal synthesis, crystal structures and thermal stability2Prediction of lanthanide-containing ternary compounds2Ce-centered polyhedral arrangement pattern and optical performance in Ce-based nonlinear optical materials3Negative linear compressibility and phonon softening in Mg ( IO 3 ) 2 under pressure1BiCe(SO 4 ) 3 (H 2 O) 3 : a non-centrosymmetric bismuth cerium( iii ) sulfate with second-order nonlinear optical activity arising from strategic heterovalent cationic substitution0Strategic Oxygen‐Substitution in Perfluorinated Ce(IV) Coordination Frameworks Triggers Dual‐Wavelength Nonlinear Optical Materials With Exceptional Performances3Strategic Oxygen‐Substitution in Perfluorinated Ce(IV) Coordination Frameworks Triggers Dual‐Wavelength Nonlinear Optical Materials With Exceptional Performances33Ternary Anion‐Engineered Rare Earth Crystals for Broadband UV Transparency and Enhanced Second‐Harmonic Generation1A Polar Cerium Iodate Ce 2 (IO 3 ) 6 (H 2 O) with a Strong Second-Harmonic Generation Response in Trivalent Ce-Based Materials1High ionic thermoelectric performance in gel thermocells via the I−/IO3- redox couple0

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  1. Ce(IO3)2F2⋅H2O: The First Rare‐Earth‐Metal Iodate Fluoride with Large Second Harmonic Generation Response

    Chemistry - A European Journal · 2018

    Tushagu Abudouwufu, Min Zhang, Shichao Cheng, Zhihua Yang, Shilie Pan

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  2. Synthesis and structure of a new mixed metal iodate Ba 3 Ga 2 (IO 3 ) 12

    CrystEngComm · 2019

    Lei Xiao, Fengguang You, Pifu Gong, Zhanggui Hu, Zheshuai Lin

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  3. REI5O14 (RE=Y and Gd): Promising SHG Materials Featuring the Semicircle‐Shaped I5O143− Polyiodate Anion

    Angewandte Chemie International Edition · 2019

    Jin Chen, Chun‐Li Hu, Fei‐Fei Mao, Bing‐Ping Yang, Xiao‐Han Zhang, Jiang‐Gao Mao

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  4. REI5O14 (RE=Y and Gd): Promising SHG Materials Featuring the Semicircle‐Shaped I5O143− Polyiodate Anion

    Angewandte Chemie · 2019

    Jin Chen, Chun‐Li Hu, Fei‐Fei Mao, Bing‐Ping Yang, Xiaohan Zhang, Jiang‐Gao Mao

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  5. Synthesis, Characterization, and Crystal Structure Determination of a New Lithium Zinc Iodate Polymorph LiZn(IO3)3

    Crystals · 2019

    Zoulikha Hebboul, Christine Galez, Djamal Benbertal, Sandrine Beauquis, Yannick Mugnier, Abdelnour Benmakhlouf, M. Bouchenafa, Daniel Errandonea

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  6. Incorporating rare-earth cations with moderate electropositivity into iodates for the optimized second-order nonlinear optical performance

    Inorganic Chemistry Frontiers · 2020

    Lin Lin, Longhua Li, Chao Wu, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  7. Synthesis, Crystal Structure, and Optical Properties of the First Alkali Metal Rare-Earth Iodate Fluoride: Li2Ce(IO3)4F2

    Crystal Growth & Design · 2020

    Changcheng Tang, Xingxing Jiang, Shu Hai Guo, Ruixin Guo, Lijuan Liu, Mingjun Xia, Qian Huang, Zheshuai Lin, Xiaoyang Wang

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  8. K2Na(IO3)2(I3O8) with Strong Second Harmonic Generation Response Activated by Two Types of Isolated Iodate Anions

    Chemistry of Materials · 2020

    Tushagu Abudouwufu, Min Zhang, Shichao Cheng, Hao Zeng, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  9. Ba2[MoO3(OH)(IO3)2]IO3: A Promising SHG Material Featuring a Λ-Shaped Functional Motif Achieved by Universal Mono-Site Substitution

    Chemistry of Materials · 2020

    Q. Huang, Chun‐Li Hu, Bing‐Ping Yang, Ru‐Ling Tang, Jin Chen, Zhi Gang Fang, Bingxuan Li, Jiang‐Gao Mao

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  10. From Ce(IO 3 ) 4 to CeF 2 (IO 3 ) 2 : fluorinated homovalent substitution simultaneously enhances SHG response and bandgap for mid-infrared nonlinear optics

    Journal of Materials Chemistry C · 2021

    Tianhui Wu, Xingxing Jiang, Chao Wu, Hongyuan Sha, Zujian Wang, Zheshuai Lin, Zhipeng Huang, Xifa Long, Mark Graeme Humphrey, Chi Zhang

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  11. Pressure-dependent modifications in the optical and electronic properties of Fe(IO 3 ) 3 : the role of Fe 3d and I 5p lone–pair electrons

    Inorganic Chemistry Frontiers · 2021

    Akun Liang, Plácida Rodríguez-Hernández, Alfonso Muñoz, Saqib Rahman, Alfredo Segura, Daniel Errandonea

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  12. LaSiP3 and LaSi2P6: Two Excellent Rare‐Earth Pnictides with Strong SHG Responses as Mid‐ and Far‐Infrared Nonlinear Optical Crystals

    Advanced Optical Materials · 2021

    Yingshuang Sun, Jindong Chen, Shunda Yang, Bingxuan Li, Guoliang Chai, Chensheng Lin, Min Luo, Ning Ye

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  13. Synthesis and Characterization of Novel Nanoparticles of Lithium Aluminum Iodate LiAl(IO3)4, and DFT Calculations of the Crystal Structure and Physical Properties

    Nanomaterials · 2021

    Rihab Chikhaoui, Zoulikha Hebboul, Mohamed Abdelilah Fadla, Kévin Bredillet, Akun Liang, Daniel Errandonea, Sandrine Beauquis, Ali Benghia, Jean-Christophe Marty, Ronan Le Dantec, Yannick Mugnier, Enrico Bandiello

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  14. CaCe(IO 3 ) 3 (IO 3 F)F: a promising nonlinear optical material containing both IO 3 − and IO 3 F 2− anions

    Inorganic Chemistry Frontiers · 2022

    Nan Ma, Chun‐Li Hu, Jin Chen, Zhi Gang Fang, Yu Huang, Bingxuan Li, Jiang‐Gao Mao

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  15. Pressure-induced phase transition and increase of oxygen-iodine coordination in magnesium iodate

    Physical review. B./Physical review. B · 2022

    Akun Liang, Robin Turnbull, Cătălin Popescu, Francisco Javier Manjon, Enrico Bandiello, Plácida Rodríguez-Hernández, Alfonso Muñoz, Ibraheem Yousef, Zoulikha Hebboul, Daniel Errandonea

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  16. General relationship between the band-gap energy and iodine-oxygen bond distance in metal iodates

    Physical Review Materials · 2022

    Akun Liang, Robin Turnbull, Plácida Rodríguez-Hernández, Alfonso Muñoz, M. Jasmin, Lan-Ting Shi, Daniel Errandonea

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  17. A review on the advancements in the characterization of the high-pressure properties of iodates

    Progress in Materials Science · 2023

    Akun Liang, Robin Turnbull, Daniel Errandonea

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  18. ε-La(IO3)3: A Polar Iodate with High Thermal Stability and a Large Second-Harmonic-Generation Response Obtained by a Supercritical Hydrothermal Method

    Inorganic Chemistry · 2023

    Dandan Wang, Xinyuan Zhang, Pifu Gong, Zheshuai Lin, Zhanggui Hu, Yicheng Wu

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  19. Ce(IO3)3F and Ce(IO3)2(NO3): Two Mixed-Anion Cerium Iodates with Good Nonlinear Optical and Birefringent Properties

    Inorganic Chemistry · 2023

    Nan Ma, Yu Hong Huang, Chun‐Li Hu, Mingzhi Zhang, Bingxuan Li, Jiang‐Gao Mao

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  20. Ln 2 F 2 (OH 2 )(MoO 3 ) 2 (SeO 3 ) 2 : Promising Multifunctional Nonlinear Optical Materials Created by Partial Fluorination Strategy under Corrosion Resistant Supercritical Reactions

    Advanced Science · 2023

    Yun‐Xiang Ma, Pengfei Li, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  21. Novel cesium cerium( iv ) iodate Cs 2 Ce(IO 3 ) 6 : hydrothermal synthesis, crystal structures and thermal stability

    CrystEngComm · 2024

    Oksana P. Grigorieva, Larisa Victorovna Shvanskaya, Т. Б. Шаталова, Andrey A. Zolotarev, Peter S. Berdonosov, В. А. Долгих

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  22. Prediction of lanthanide-containing ternary compounds

    Computational Materials Science · 2025

    Huaijun Sun, Chao Zhang, Jianbo Huang, Xingdu Fan, Weiyi Xia, Ling Tang, Renhai Wang, Renhai Wang, Kunpeng Cui, Cai‐Zhuang Wang

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  23. Ce-centered polyhedral arrangement pattern and optical performance in Ce-based nonlinear optical materials

    Chinese Chemical Letters · 2025

    Xuan Li, Tianhui Wu, Meiqi Liu, Yang Zhao, Jiahang Liu, Miao Zhang, Weiwei Cao, Jianmin Gu, Desong Wang

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  24. Negative linear compressibility and phonon softening in Mg ( IO 3 ) 2 under pressure

    Physical review. B./Physical review. B · 2025

    F. Bodo, E. Kraka, A. Erba

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  25. BiCe(SO 4 ) 3 (H 2 O) 3 : a non-centrosymmetric bismuth cerium( iii ) sulfate with second-order nonlinear optical activity arising from strategic heterovalent cationic substitution

    Chemical Communications · 2026

    Zheng-Yu Yang, C. Z. Chen, Bing-Wei Miao, Yi‐Lei Lv, Wenfeng Zhou, Ming‐Yang Cao, Ru‐Ling Tang

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  26. Strategic Oxygen‐Substitution in Perfluorinated Ce(IV) Coordination Frameworks Triggers Dual‐Wavelength Nonlinear Optical Materials With Exceptional Performances

    Angewandte Chemie · 2026

    Ru‐Ling Tang, Wen‐Ye Gao, Guo-Ren Zhu, Yang Chi, Liang Ma, Wenlong Liu, Sheng‐Ping Guo

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  27. Strategic Oxygen‐Substitution in Perfluorinated Ce(IV) Coordination Frameworks Triggers Dual‐Wavelength Nonlinear Optical Materials With Exceptional Performances

    Angewandte Chemie International Edition · 2026

    Ru‐Ling Tang, Wen‐Ye Gao, Guo-Ren Zhu, Yang Chi, Liang Ma, Wenlong Liu, Sheng‐Ping Guo

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  28. Ternary Anion‐Engineered Rare Earth Crystals for Broadband UV Transparency and Enhanced Second‐Harmonic Generation

    Chinese Journal of Chemistry · 2026

    Xiaohui Zhang, Ye Tao, Qianshuang Lu, Jiarui Tan, Chenglong Xu, Yingjie Li, Yi Chen, Jianke Pan, F. H. Su, Tingchao He, Haifeng Dong, Heng Wang, Zhi Chen, Xiujun Yu, Xiaopeng Li

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  29. A Polar Cerium Iodate Ce 2 (IO 3 ) 6 (H 2 O) with a Strong Second-Harmonic Generation Response in Trivalent Ce-Based Materials

    Inorganic Chemistry · 2026

    Jiahang Liu, Miao Zhang, Shizheng Li, Ziyang Wang, Yang Zhao, NianRui Qu, Weiwei Cao, Jianmin Gu, Tianhui Wu

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  30. High ionic thermoelectric performance in gel thermocells via the I−/IO3- redox couple

    Journal of Power Sources · 2026

    Manqi Chen, Luoting Wu, Wenjun He, Guimei Li, Suyu Chen, Jiawei Luo, Chunxia Xie, Cheng‐Gong Han, Kai Zhou, Li Niu

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