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RESEARCH PAPER · Chemical Communications · 2019

ABaSbQ 3 (A = Li, Na; Q = S, Se): diverse arrangement modes of isolated SbQ 3 ligands regulating the magnitudes of birefringences

Ailijiang Abudurusuli, Kui Wu, Abudukadi Tudi, Zhihua Yang, Shilie Pan

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ABaSbQ 3 (A = Li, Na; Q = S, Se): diverse arrangement modes of isolated SbQ 3 ligands regulating the magnitudes of birefringencesOriginalFrom BiF 3 to BiF 3 ·H 2 O: diverse Bi( iii ) coordination for structural transformation and birefringence regulation14The solvothermal synthesis and characterization of quaternary arsenic chalcogenides CsTMAsQ 3 (TM = Hg, Cd; Q = S, Se) using Cs + as a structure directing agent: from 1D anionic chains to 2D anionic layers15Functional Chalcogenide Na2HgSn2Se6 and K2MnGe2Se6 Exhibiting Flexible Chain Structure and Intriguing Birefringence Tunability16First non-centrosymmetric antimony chalcogenides containing mixed cations of alkali and alkaline-Earth: Ba14Na4Sb11S31Cl3 featuring unique disorded 43 helical chains of [Sb5S18]21–5Chalcophosphates: A Treasure House of Infrared Nonlinear Optical Materials75Ba3[LiSbS2(S2)2Cl2]: The first zero-dimensional (0D) lithium metal thioantimonate featuring molecular anions of [LiSbS2(S2)2Cl2]6–3Intriguing Dimensional Transition Inducing Variable Birefringence in K2Na2Sn3S8 and Rb3NaSn3Se828Design and synthesis of Ba 3 SiSe 5 with suitable birefringence modulated via M IV atoms in the Ba–M IV –Q (M IV = Si, Ge; Q = S, Se) system3Facile syntheses of silver thioantimonates exhibiting second-harmonic generation responses and large birefringence18Structural diversities in centrosymmetric La 8 S 4 Cl 8 La 12 S 8 Cl 4 [SbS 3 ] 8 and non-centrosymmetric Ln 12 S 8 Cl 8 [SbS 3 ] 4 (Ln = La and Ce): syntheses, crystal and electronic structures, and optical properties10Synthesis, characterization and theoretical investigation of a new chalcohalide, Ba 4 GaS 4 F 311Synthesis, crystal structure, photocatalysis, photocurrent response: one-dimensional K 2 HgSnSe 4 and three-dimensional Na 6 Cu 8 Sn 3 Se 1323Preparation of 0–2 dimensional organic-decorated quaternary TM-Cd-Sb-Se (TM = Zn, Mn, Fe) compounds by solvothermal method: Syntheses, crystal structures and properties9Two ternary antimony-chalcogenides of Cs4Sb4S8 and Cs3Sb5Se913Cs2ZnSn3S8: A Sulfide Compound Realizes a Large Birefringence by Modulating the Dimensional Structure24Solvothermal synthesis and properties of three antimony chalcogenides containing transition metal zinc13Solvothermal Syntheses of Three-Dimensional Open-Framework Thioantimonates Displaying Nonlinear Optical Responses5Synthesis and Characterizations of Two Tellurides β-BaGa2Te4 and Ba5Ga2Ge3Te12 with Flexible Chain Structure16Solvothermal syntheses and characterization of three quaternary selenidoarsenates containing mercury [TM(en)3][HgAs2Se4](TM Mn, Ni, Zn)5CsCu 3 SbS 4 : rational design of a two-dimensional layered material with giant birefringence derived from Cu 3 SbS 442Ba 6 In 2 Ge 2 Te 15 : a THz birefringent material with an intriguing quasi-[Te 5 ] 4− chain possessing large optical anisotropy and an ultrawide transmission range7LiSrSbS 3 : parallel configurations of lone pair electrons inducing a large birefringence16Unprecedented mid-infrared nonlinear optical materials achieved by crystal structure engineering, a case study of (KX)P 2 S 6 (X = Sb, Bi, Ba)59From Cc to P 6 3 mc : Structural Variation in La 3 S 2 Cl 2 [SbS 3 ] and La 3 OSCl 2 [SbS 3 ] Induced by the Isovalent Anion Substitution22Potential optical functional crystals with large birefringence: Recent advances and future prospects322Ba4cd2ge2te9: A Promising Infrared Functional Crystal with Large Birefringent And Photoluminescent Properties0Heteroanion-introduction-driven birefringence enhancement in oxychalcogenide Ba 3 M II Ge 3 O 2 S 8 (M II = Mn, Cd)19Honeycomb layered topology construction for exceptional long-wave infrared nonlinear optical crystals29Stereochemically active lone-pair-driven giant enhancement of birefringence from three-dimensional CsZn 4 Ga 5 Se 12 to two-dimensional CsZnAsSe 319Improved Birefringence Activated by Tetrahedra Decorated with a Single Linear Unit38Improved Birefringence Activated by Tetrahedra Decorated with a Single Linear Unit1Hydrazine-thermal syntheses, structures, and photocatalytic properties of tellurostannate hybrids with iron (II) complex unit2AGe2O4Q (A = Ba, Sr; Q = S, Se): A series of heteroanionic oxychalcogenides with large birefringence9Hg 3 AsS 4 X (X = Cl and Br): two Hg-based chalcogenides as long-wave infrared nonlinear optical crystals with superior comprehensive performances33Hydrazine-Assisted Synthesis, Structures, Photoelectricity, and Photocatalysis of Ternary Mercury–Tellurostannate Hybrids with Transition-Metal Complexes4From [Ba3S][GeS4] to [Ba3CO3][MS4] (M = Ge, Sn): Enhancing optical anisotropy in IR birefringent crystals via functional group implantation11NaCaGa 3 S 6 : a mixed alkali metal and alkaline earth metal sulfide with a distinctive [Ga 5 S 10 ] ∞ layered framework0P4Sn (n = 3, 5, 7): Large Birefringence Enhanced by 3D Aromaticity and Packing Effect Induced Directional π–π Noncovalent Interactions6Recent progress in structural design strategies of high-birefringence optical crystals54[TeSeS 2 ] 2− : The First Heterotriple‐Chalcogenide Motifs Decode Giant Mid‐Far Infrared Birefringence18[TeSeS 2 ] 2− : The First Heterotriple‐Chalcogenide Motifs Decode Giant Mid‐Far Infrared Birefringence4Research progress and future prospect of chalcogenides with large optical anisotropy46First-principles study of ABSe₃ (A = Li, Na) Perselenoborates: A Promising Family of Nonlinear Optical Materials1CaYIIIS 4 (III = Ga, In): Two Olivine-Type Compounds Exhibiting Exceptional Birefringence Properties1CsGaGe₃Se₈: Enhanced optical anisotropy and bandgap via cation-substitution-driven dimensionality reduction0Synthesis, crystal structure, and optical property of La2Cl3[SbS3]2Optimal three-dimensional [Ag 4 P 2 S 6 ]-framework assembly directed by a threefold roto-inversion axis for enhanced birefringence0Anion-Centered Engineering for Simultaneously Enhancing Birefringence and Band Gap in Chalcogenides1Achieving High‐Birefringence Thiophosphates From Low Polarizability Anisotropy Units by an Axial Linear Matching Strategy1Domino‐Effect Amplification via Covalent‐Chain Engineering for Giant Birefringence in NaAsQ 2 (Q = S, Se) Crystals0

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  1. From BiF 3 to BiF 3 ·H 2 O: diverse Bi( iii ) coordination for structural transformation and birefringence regulation

    CrystEngComm · 2020-01-01

    Xian Liu, Can Yang, Qi Wu, Juan Sun, Fei Liang

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  2. The solvothermal synthesis and characterization of quaternary arsenic chalcogenides CsTMAsQ 3 (TM = Hg, Cd; Q = S, Se) using Cs + as a structure directing agent: from 1D anionic chains to 2D anionic layers

    RSC Advances · 2020-01-01

    Xinyu Tian, Cui-Xia Du, Zhaori Getu, Muge Shele, Yong‐Sheng Bao, Menghe Baiyin

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  3. Functional Chalcogenide Na2HgSn2Se6 and K2MnGe2Se6 Exhibiting Flexible Chain Structure and Intriguing Birefringence Tunability

    Inorganic Chemistry · 2020-05-15

    Zhuang Li, Youquan Liu, Shengzi Zhang, Wenhao Xing, Wenlong Yin, Zheshuai Lin, Jiyong Yao, Yicheng Wu

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  4. First non-centrosymmetric antimony chalcogenides containing mixed cations of alkali and alkaline-Earth: Ba14Na4Sb11S31Cl3 featuring unique disorded 43 helical chains of [Sb5S18]21–

    Journal of Solid State Chemistry · 2020-06-26

    Hua‐Jun Zhao, Biao Qin

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  5. Chalcophosphates: A Treasure House of Infrared Nonlinear Optical Materials

    Crystal Growth & Design · 2020-10-23

    Zhuang Li, Jiyong Yao, Yicheng Wu

    Read original paper ↗ ·

  6. Ba3[LiSbS2(S2)2Cl2]: The first zero-dimensional (0D) lithium metal thioantimonate featuring molecular anions of [LiSbS2(S2)2Cl2]6–

    Journal of Solid State Chemistry · 2020-11-24

    Hua‐Jun Zhao, Pengfei Liu

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  7. Intriguing Dimensional Transition Inducing Variable Birefringence in K2Na2Sn3S8 and Rb3NaSn3Se8

    Inorganic Chemistry · 2020-12-23

    Xiao Ji, Hongping Wu, Bingbing Zhang, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  8. Design and synthesis of Ba 3 SiSe 5 with suitable birefringence modulated via M IV atoms in the Ba–M IV –Q (M IV = Si, Ge; Q = S, Se) system

    Dalton Transactions · 2021-01-01

    Huanhuan Cheng, Abudukadi Tudi, Peng Wang, Kewang Zhang, Zhihua Yang, Shilie Pan

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  9. Facile syntheses of silver thioantimonates exhibiting second-harmonic generation responses and large birefringence

    Dalton Transactions · 2021-01-01

    Gang Yang, Xingxing Jiang, Chao Wu, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  10. Structural diversities in centrosymmetric La 8 S 4 Cl 8 La 12 S 8 Cl 4 [SbS 3 ] 8 and non-centrosymmetric Ln 12 S 8 Cl 8 [SbS 3 ] 4 (Ln = La and Ce): syntheses, crystal and electronic structures, and optical properties

    Dalton Transactions · 2021-01-01

    Hua‐Jun Zhao, Pengfei Liu, Li‐Ming Wu

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  11. Synthesis, characterization and theoretical investigation of a new chalcohalide, Ba 4 GaS 4 F 3

    Dalton Transactions · 2021-01-01

    Hongbo Gao, Ruijiao Chen, Kewang Zhang, Ailijiang Abudurusuli, Kangrong Lai, Junjie Li

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  12. Synthesis, crystal structure, photocatalysis, photocurrent response: one-dimensional K 2 HgSnSe 4 and three-dimensional Na 6 Cu 8 Sn 3 Se 13

    CrystEngComm · 2021-01-01

    Gele Teri, Na Li, Sagala Bai, E. Namila, Menghe Baiyin

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  13. Preparation of 0–2 dimensional organic-decorated quaternary TM-Cd-Sb-Se (TM = Zn, Mn, Fe) compounds by solvothermal method: Syntheses, crystal structures and properties

    Journal of Solid State Chemistry · 2021-01-08

    Muge Shele, Fei-Yan Qi, Xinyu Tian, Yong‐Sheng Bao, Menghe Baiyin

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  14. Two ternary antimony-chalcogenides of Cs4Sb4S8 and Cs3Sb5Se9

    Inorganic Chemistry Communications · 2021-04-28

    Fei-Yan Qi, Muge Shele, Menghe Baiyin

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  15. Cs2ZnSn3S8: A Sulfide Compound Realizes a Large Birefringence by Modulating the Dimensional Structure

    Inorganic Chemistry · 2021-06-16

    Tian Tian, Zefen Li, Naizheng Wang, Sangen Zhao, Jiayue Xu, Zheshuai Lin, Dajiang Mei

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  16. Solvothermal synthesis and properties of three antimony chalcogenides containing transition metal zinc

    Journal of Solid State Chemistry · 2021-07-01

    Muge Shele, Xinyu Tian, Menghe Baiyin

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  17. Solvothermal Syntheses of Three-Dimensional Open-Framework Thioantimonates Displaying Nonlinear Optical Responses

    Crystal Growth & Design · 2021-07-22

    Chao Wu, Lin Lin, Tianhui Wu, Wenyan Dan, Zhipeng Huang, Chi Zhang

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  18. Synthesis and Characterizations of Two Tellurides β-BaGa2Te4 and Ba5Ga2Ge3Te12 with Flexible Chain Structure

    Inorganic Chemistry · 2021-09-16

    Mengran Sun, Xingyu Zhang, Wenhao Xing, Zhuang Li, Wenhao Liu, Zheshuai Lin, Wenlong Yin, Jiyong Yao

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  19. Solvothermal syntheses and characterization of three quaternary selenidoarsenates containing mercury [TM(en)3][HgAs2Se4](TM Mn, Ni, Zn)

    Inorganic Chemistry Communications · 2021-10-05

    Gele Teri, Ling Ling, Na Li, Menghe Baiyin

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  20. CsCu 3 SbS 4 : rational design of a two-dimensional layered material with giant birefringence derived from Cu 3 SbS 4

    Inorganic Chemistry Frontiers · 2021-12-01

    Chang Liu, Shenghua Zhou, Chao Zhang, Yaying Shen, Xiaoyan Liu, Hua Lin, Yi Liu

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  21. Ba 6 In 2 Ge 2 Te 15 : a THz birefringent material with an intriguing quasi-[Te 5 ] 4− chain possessing large optical anisotropy and an ultrawide transmission range

    Inorganic Chemistry Frontiers · 2022-01-01

    Mengran Sun, Xingyu Zhang, Wenhao Xing, Ece Uykur, Wenlong Yin, Zheshuai Lin, Jiyong Yao

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  22. LiSrSbS 3 : parallel configurations of lone pair electrons inducing a large birefringence

    Dalton Transactions · 2022-01-01

    Alimujiang Yalikun, Kewang Zhang, Jian Wei Han, Zhihua Yang

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  23. Unprecedented mid-infrared nonlinear optical materials achieved by crystal structure engineering, a case study of (KX)P 2 S 6 (X = Sb, Bi, Ba)

    Chemical Science · 2022-01-01

    Vivian Nguyen, Bingheng Ji, Kui Wu, Bingbing Zhang, Jian Wang

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  24. From Cc to P 6 3 mc : Structural Variation in La 3 S 2 Cl 2 [SbS 3 ] and La 3 OSCl 2 [SbS 3 ] Induced by the Isovalent Anion Substitution

    Crystal Growth & Design · 2022-01-17

    Hua‐Jun Zhao, Hedi Yang, Pengfei Liu, Hua Lin

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  25. Potential optical functional crystals with large birefringence: Recent advances and future prospects

    Coordination Chemistry Reviews · 2022-02-08

    Abudukadi Tudi, Shujuan Han, Zhihua Yang, Shilie Pan

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  26. Ba4cd2ge2te9: A Promising Infrared Functional Crystal with Large Birefringent And Photoluminescent Properties

    SSRN Electronic Journal · 2023-01-01

    Mengran Sun, Haojian Su, Wenhao Liu, Jiyong Yao

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  27. Heteroanion-introduction-driven birefringence enhancement in oxychalcogenide Ba 3 M II Ge 3 O 2 S 8 (M II = Mn, Cd)

    Inorganic Chemistry Frontiers · 2023-01-01

    Shenghua Zhou, Mao‐Yin Ran, Wenbo Wei, A-Yang Wang, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  28. Honeycomb layered topology construction for exceptional long-wave infrared nonlinear optical crystals

    Materials Horizons · 2023-01-01

    Jindong Chen, Chensheng Lin, Xiaotian Jiang, Guangsai Yang, Min Luo, Xin Zhao, Bingxuan Li, Guang Peng, Ning Ye, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  29. Stereochemically active lone-pair-driven giant enhancement of birefringence from three-dimensional CsZn 4 Ga 5 Se 12 to two-dimensional CsZnAsSe 3

    Inorganic Chemistry Frontiers · 2023-01-01

    Chao Zhang, Mao‐Yin Ran, Xin Chen, Shenghua Zhou, Hua Lin, Yi Liu

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  30. Improved Birefringence Activated by Tetrahedra Decorated with a Single Linear Unit

    Angewandte Chemie International Edition · 2023-06-29

    Wenlong Xie, Fuming Li, Jianbang Chen, Zhihuang Yang, Guangmao Li, Shilie Pan

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  31. Improved Birefringence Activated by Tetrahedra Decorated with a Single Linear Unit

    Angewandte Chemie · 2023-06-29

    Wenlong Xie, Fuming Li, Jianbang Chen, Zhihuang Yang, Guangmao Li, Shilie Pan

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  32. Hydrazine-thermal syntheses, structures, and photocatalytic properties of tellurostannate hybrids with iron (II) complex unit

    Polyhedron · 2023-08-07

    Xiao Yang, Taohong Ren, Jiahua Zhang, Dingxian Jia

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  33. AGe2O4Q (A = Ba, Sr; Q = S, Se): A series of heteroanionic oxychalcogenides with large birefringence

    Solid State Sciences · 2023-11-28

    Dong Gao, Fuqiang Chen, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu, P. Shiv Halasyamani

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  34. Hg 3 AsS 4 X (X = Cl and Br): two Hg-based chalcogenides as long-wave infrared nonlinear optical crystals with superior comprehensive performances

    Inorganic Chemistry Frontiers · 2024-01-01

    Feng Xu, Xiang Xu, Bingxuan Li, Ge Zhang, Chan Zheng, Jindong Chen, Ning Ye

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  35. Hydrazine-Assisted Synthesis, Structures, Photoelectricity, and Photocatalysis of Ternary Mercury–Tellurostannate Hybrids with Transition-Metal Complexes

    Inorganic Chemistry · 2024-04-01

    Xiao Yang, Taohong Ren, Hongjin Zhu, Dingxian Jia

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  36. From [Ba3S][GeS4] to [Ba3CO3][MS4] (M = Ge, Sn): Enhancing optical anisotropy in IR birefringent crystals via functional group implantation

    Chinese Journal of Structural Chemistry · 2024-10-24

    Yong‐Fang Shi, Shenghua Zhou, Zuju Ma, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  37. NaCaGa 3 S 6 : a mixed alkali metal and alkaline earth metal sulfide with a distinctive [Ga 5 S 10 ] ∞ layered framework

    Dalton Transactions · 2025-01-01

    Jiale Chen, Haipeng Zhou, Huimin Sha, Jinfeng Liu, Xiu Zhu, Guisheng Xu, Jiankang Wang

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  38. P4Sn (n = 3, 5, 7): Large Birefringence Enhanced by 3D Aromaticity and Packing Effect Induced Directional π–π Noncovalent Interactions

    Advanced Optical Materials · 2025-04-11

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  39. Recent progress in structural design strategies of high-birefringence optical crystals

    Coordination Chemistry Reviews · 2025-05-08

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  40. [TeSeS 2 ] 2− : The First Heterotriple‐Chalcogenide Motifs Decode Giant Mid‐Far Infrared Birefringence

    Angewandte Chemie International Edition · 2025-06-17

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  41. [TeSeS 2 ] 2− : The First Heterotriple‐Chalcogenide Motifs Decode Giant Mid‐Far Infrared Birefringence

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  42. Research progress and future prospect of chalcogenides with large optical anisotropy

    Coordination Chemistry Reviews · 2025-06-20

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  43. First-principles study of ABSe₃ (A = Li, Na) Perselenoborates: A Promising Family of Nonlinear Optical Materials

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  44. CaYIIIS 4 (III = Ga, In): Two Olivine-Type Compounds Exhibiting Exceptional Birefringence Properties

    Inorganic Chemistry · 2025-08-21

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  45. CsGaGe₃Se₈: Enhanced optical anisotropy and bandgap via cation-substitution-driven dimensionality reduction

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  46. Synthesis, crystal structure, and optical property of La2Cl3[SbS3]

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  47. Optimal three-dimensional [Ag 4 P 2 S 6 ]-framework assembly directed by a threefold roto-inversion axis for enhanced birefringence

    Inorganic Chemistry Frontiers · 2026-01-01

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  48. Anion-Centered Engineering for Simultaneously Enhancing Birefringence and Band Gap in Chalcogenides

    Chemistry of Materials · 2026-01-19

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  49. Achieving High‐Birefringence Thiophosphates From Low Polarizability Anisotropy Units by an Axial Linear Matching Strategy

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  50. Domino‐Effect Amplification via Covalent‐Chain Engineering for Giant Birefringence in NaAsQ 2 (Q = S, Se) Crystals

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