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RESEARCH PAPER · Inorganic Chemistry · 2013

Large Mid-IR Second-Order Nonlinear-Optical Effects Designed by the Supramolecular Assembly of Different Bond Types without IR Absorption

Xiao‐Ming Jiang, Guan‐E Wang, Zhi‐Fa Liu, Ming‐Jian Zhang, Guo‐Cong Guo

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Large Mid-IR Second-Order Nonlinear-Optical Effects Designed by the Supramolecular Assembly of Different Bond Types without IR AbsorptionOriginalChemInform Abstract: Large Mid‐IR Second‐Order Nonlinear‐Optical Effects Designed by the Supramolecular Assembly of Different Bond Types Without IR Absorption.0Large and Fast Single‐Crystal Resistive Humidity Sensitivity of Metal Pnictide Halides Containing van der Waals Host–Guest Interactions10Hg5AsS2I3 – A Narrow‐Band‐Gap 2D Layered Compound with Different Trapped I– Anions4Unveiling NO2π···C C π–hole interactions: A combined computational and crystallographic study11Partial Geometric Frustration in Inorganic Supramolecular Spin Systems with One-Dimensional Trigonally Aligned Magnetic Chains ∞1(MCl4)2− (M = Fe2+, Co2+)4Recent achievements on middle and far-infrared second-order nonlinear optical materials433Metal-inorganic frameworks with pnictogen linkers17A new pnictidehalide with van der Waals host–guest interactions exhibiting both geometric spin frustration and resistive humidity sensitivity2Advantageous Units in Antimony Sulfides: Exploration and Design of Infrared Nonlinear Optical Materials95Adduct-Type IR Nonlinear-Optical Crystal SbI 3 ·(S 8 ) 3 with a Large Second-Harmonic Generation and a High Laser-Induced Damage Threshold59Intriguing Structural Transition Inducing Variable Birefringences in ABa2MS4Cl (A = Rb, Cs; M = Ge, Sn)32Recent advances and future perspectives on infrared nonlinear optical metal halides223Structural modulation induced by M IIIA metals in Ba 3 MQ 4 X (M = Al, Ga, In; Q = S, Se; X = Cl, Br): an experimental and computational analysis7Balanced Second-Order Nonlinear Optical Properties of Adducts CHI3·(S8)3 and AsI3·(S8)3: A Systematic Survey48Mixed-Anion Inorganic Compounds: A Favorable Candidate for Infrared Nonlinear Optical Materials140Second-order nonlinear optical-active selenide borate Zn8Se2(BO2)12: Experimental and theoretical analysis9Second-order nonlinear optical and photoelectric properties of Zn4B6O12S20A Series of Pentanary Salt-Inclusion Chalcogenoborates Containing a B12Q12 (Q = S, Se) Cluster Exhibiting a Kleinman-Forbidden Frequency-Doubling Effect25Introduction of Li into Ag-Based Noncentrosymmetric Sulfides for High-Performance Infrared Nonlinear Optical Materials40SnPQ3 (Q = S, Se, S/Se): A Series of Lone-Pair Cationic Chalcogenophosphates Exhibiting Balanced NLO Activity Originating from SnQ8 Units49Noncentrosymmetric chalcohalide K2Ba3Ge3S9Cl2: A new nonlinear optical material with remarkable laser-induced damage threshold17Symmetry breaking of A 3 M 2 X 9 -type perovskite derivatives induced by polar quaternary ammonium cations: achieving efficient nonlinear optical properties28Material research from the viewpoint of functional motifs103First Investigation of Nonlinear Optical Oxychalcogenide with Three‐Dimensional Anionic Framework and Special Windmill‐Like Functional Motifs †28Quasi-linear CuX 2 (X = Cl, Br) motif-built hybrid copper halides realizing encouraging nonlinear optical activities28The first polyanion-substitution-driven centrosymmetric-to-noncentrosymmetric structural transformation realizing an excellent nonlinear optical supramolecule [Cd 4 P 2 ][CdBr 4 ]17(C 13 N 3 H 14 ) 2 MBr 4 (M = Zn, Cd): two novel hybrid metal halides with balanced integrated nonlinear optical performance31Halogen-assisted octet binding electrons construction of pnictogens towards wide-bandgap nonlinear optical pnictides17Centrosymmetric CaBaMF8 and Noncentrosymmetric Li2CaMF8 (M = Zr, Hf): Dimension Variation and Nonlinear Optical Activity Resulting from an Isovalent Cation Substitution-Oriented Design17Structural Symmetry and Mixed‐anion Engineering in Halopnictides for Extraordinary Second‐Harmonic Generation6Structural Symmetry and Mixed‐anion Engineering in Halopnictides for Extraordinary Second‐Harmonic Generation4Deep-Ultraviolet Transparent Zr/Hf Fluorides with Second-Harmonic Generation Effects Induced by Alkali-Metal Modulation2Beyond the bandgap bottleneck: structure–property design principles for infrared nonlinear optical phosphides0

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  1. ChemInform Abstract: Large Mid‐IR Second‐Order Nonlinear‐Optical Effects Designed by the Supramolecular Assembly of Different Bond Types Without IR Absorption.

    ChemInform · 2013-09-12

    Xiao‐Ming Jiang, Guan‐E Wang, Zhi‐Fa Liu, Mingjian Zhang, Guo‐Cong Guo

    Read original paper ↗ ·

  2. Large and Fast Single‐Crystal Resistive Humidity Sensitivity of Metal Pnictide Halides Containing van der Waals Host–Guest Interactions

    Chemistry - An Asian Journal · 2014-08-08

    Xiao‐Ming Jiang, Zhi‐Bo Yan, Dan Liu, Ke‐Feng Wang, Guo‐Cong Guo, Shaozhen Li, Jun‐Ming Liu

    Read original paper ↗ ·

  3. Hg5AsS2I3 – A Narrow‐Band‐Gap 2D Layered Compound with Different Trapped I– Anions

    European Journal of Inorganic Chemistry · 2015-04-14

    Yong Liu, Hui‐Yi Zeng, Bin‐Wen Liu, Geng‐E Wang, Guo‐Cong Guo

    Read original paper ↗ ·

  4. Unveiling NO2π···C C π–hole interactions: A combined computational and crystallographic study

    Chemical Physics Letters · 2015-06-13

    Antonio Bauzá, Antonio Frontera

    Read original paper ↗ ·

  5. Partial Geometric Frustration in Inorganic Supramolecular Spin Systems with One-Dimensional Trigonally Aligned Magnetic Chains ∞1(MCl4)2− (M = Fe2+, Co2+)

    Scientific Reports · 2015-12-09

    Xiao‐Ming Jiang, Xiao‐Guo Li, Ming‐Jian Zhang, Zhi‐Fa Liu, Yong Liu, Jun‐Ming Liu, Guo‐Cong Guo

    Read original paper ↗ ·

  6. Recent achievements on middle and far-infrared second-order nonlinear optical materials

    Coordination Chemistry Reviews · 2016-12-27

    Sheng‐Ping Guo, Yang Chi, Guo‐Cong Guo

    Read original paper ↗ ·

  7. Metal-inorganic frameworks with pnictogen linkers

    Russian Chemical Reviews · 2017-10-31

    Tatiana A. Shestimerova, Аndrei V. Shevelkov

    Read original paper ↗ ·

  8. A new pnictidehalide with van der Waals host–guest interactions exhibiting both geometric spin frustration and resistive humidity sensitivity

    New Journal of Chemistry · 2017-12-15

    Siyan Peng, Liusai Yang, Ming‐Shui Yao, Leshu Yu

    Read original paper ↗ ·

  9. Advantageous Units in Antimony Sulfides: Exploration and Design of Infrared Nonlinear Optical Materials

    ACS Applied Materials & Interfaces · 2018-07-12

    Cong Hu, Bingbing Zhang, Bing‐Hua Lei, Shilie Pan, Zhihua Yang

    Read original paper ↗ ·

  10. Adduct-Type IR Nonlinear-Optical Crystal SbI 3 ·(S 8 ) 3 with a Large Second-Harmonic Generation and a High Laser-Induced Damage Threshold

    Inorganic Chemistry · 2018-08-23

    Sheng‐Ping Guo, Zongdong Sun, Yang Chi, Huaiguo Xue

    Read original paper ↗ ·

  11. Intriguing Structural Transition Inducing Variable Birefringences in ABa2MS4Cl (A = Rb, Cs; M = Ge, Sn)

    Inorganic Chemistry · 2018-08-24

    Yu Chu, Kui Wu, Xin Su, Jian Wei Han, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  12. Recent advances and future perspectives on infrared nonlinear optical metal halides

    Coordination Chemistry Reviews · 2018-10-23

    Pifu Gong, Fei Liang, Lei Kang, Xingguo Chen, Jingui Qin, Yicheng Wu, Zheshuai Lin

    Read original paper ↗ ·

  13. Structural modulation induced by M IIIA metals in Ba 3 MQ 4 X (M = Al, Ga, In; Q = S, Se; X = Cl, Br): an experimental and computational analysis

    Dalton Transactions · 2019-01-01

    Abudukadi Tudi, Shujuan Han, Ailijiang Abudurusuli, Haohai Yu, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  14. Balanced Second-Order Nonlinear Optical Properties of Adducts CHI3·(S8)3 and AsI3·(S8)3: A Systematic Survey

    Inorganic Chemistry · 2019-03-15

    Zhen‐Tao Lu, Zongdong Sun, Yang Chi, Huaiguo Xue, Sheng‐Ping Guo

    Read original paper ↗ ·

  15. Mixed-Anion Inorganic Compounds: A Favorable Candidate for Infrared Nonlinear Optical Materials

    Crystal Growth & Design · 2019-06-07

    Yanyan Li, Wenjing Wang, Hui Wang, Hua Lin, Li‐Ming Wu

    Read original paper ↗ ·

  16. Second-order nonlinear optical-active selenide borate Zn8Se2(BO2)12: Experimental and theoretical analysis

    Journal of Solid State Chemistry · 2020-07-18

    Wenfeng Zhou, Xiaohui Li, Wen‐Dong Yao, Huaiguo Xue, Sheng‐Ping Guo

    Read original paper ↗ ·

  17. Second-order nonlinear optical and photoelectric properties of Zn4B6O12S

    Journal of Alloys and Compounds · 2021-02-03

    Wenfeng Zhou, Wen‐Dong Yao, Ru‐Ling Tang, Huaiguo Xue, Sheng‐Ping Guo

    Read original paper ↗ ·

  18. A Series of Pentanary Salt-Inclusion Chalcogenoborates Containing a B12Q12 (Q = S, Se) Cluster Exhibiting a Kleinman-Forbidden Frequency-Doubling Effect

    Inorganic Chemistry · 2021-02-09

    Shanshan Han, Wen‐Dong Yao, Su‐Xin Yu, Yueling Sun, Anhua Gong, Sheng‐Ping Guo

    Read original paper ↗ ·

  19. Introduction of Li into Ag-Based Noncentrosymmetric Sulfides for High-Performance Infrared Nonlinear Optical Materials

    Inorganic Chemistry · 2021-03-16

    Wenfeng Zhou, Wen‐Dong Yao, Qing Zhang, Huaiguo Xue, Sheng‐Ping Guo

    Read original paper ↗ ·

  20. SnPQ3 (Q = S, Se, S/Se): A Series of Lone-Pair Cationic Chalcogenophosphates Exhibiting Balanced NLO Activity Originating from SnQ8 Units

    Inorganic Chemistry · 2021-08-31

    Zhi‐Hui Shi, Mei Yang, Wen‐Dong Yao, Wenlong Liu, Sheng‐Ping Guo

    Read original paper ↗ ·

  21. Noncentrosymmetric chalcohalide K2Ba3Ge3S9Cl2: A new nonlinear optical material with remarkable laser-induced damage threshold

    Journal of Alloys and Compounds · 2021-11-13

    Wenfeng Zhou, Zhi‐Hui Shi, Wenlong Liu, Sheng‐Ping Guo

    Read original paper ↗ ·

  22. Symmetry breaking of A 3 M 2 X 9 -type perovskite derivatives induced by polar quaternary ammonium cations: achieving efficient nonlinear optical properties

    Dalton Transactions · 2022-01-01

    Jiajing Wu, Yue Guo, Wen‐Dong Yao, Wenlong Liu, Sheng‐Ping Guo

    Read original paper ↗ ·

  23. Material research from the viewpoint of functional motifs

    National Science Review · 2022-02-10

    Xiao‐Ming Jiang, Shuiquan Deng, Myung‐Hwan Whangbo, Guo‐Cong Guo

    Read original paper ↗ ·

  24. First Investigation of Nonlinear Optical Oxychalcogenide with Three‐Dimensional Anionic Framework and Special Windmill‐Like Functional Motifs †

    Chinese Journal of Chemistry · 2022-07-14

    Jia-Nuo Li, Xiaohui Li, Ying‐Xuan Xu, Wenlong Liu, Sheng‐Ping Guo

    Read original paper ↗ ·

  25. Quasi-linear CuX 2 (X = Cl, Br) motif-built hybrid copper halides realizing encouraging nonlinear optical activities

    Inorganic Chemistry Frontiers · 2023-01-01

    Jing‐Li Qi, Jiajing Wu, Yue Guo, Zhong-Ping Xu, Wenlong Liu, Sheng‐Ping Guo

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  26. The first polyanion-substitution-driven centrosymmetric-to-noncentrosymmetric structural transformation realizing an excellent nonlinear optical supramolecule [Cd 4 P 2 ][CdBr 4 ]

    Chemical Science · 2023-01-01

    Zhixin Qiu, Zhe-Xiong Zheng, Xiao‐Ming Jiang, Bin‐Wen Liu, Guo‐Cong Guo

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  27. (C 13 N 3 H 14 ) 2 MBr 4 (M = Zn, Cd): two novel hybrid metal halides with balanced integrated nonlinear optical performance

    Inorganic Chemistry Frontiers · 2024-01-01

    Jiajing Wu, Yi-Fan Fu, Wenlong Liu, Sheng‐Ping Guo

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  28. Halogen-assisted octet binding electrons construction of pnictogens towards wide-bandgap nonlinear optical pnictides

    Chinese Chemical Letters · 2024-01-22

    Lihua Gao, Yinglei Han, Chensheng Lin, Huikang Jiang, Guang Peng, Guangsai Yang, Jindong Chen, Ning Ye

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  29. Centrosymmetric CaBaMF8 and Noncentrosymmetric Li2CaMF8 (M = Zr, Hf): Dimension Variation and Nonlinear Optical Activity Resulting from an Isovalent Cation Substitution-Oriented Design

    Inorganic Chemistry · 2024-03-06

    Mei Yan, Ru‐Ling Tang, Wei Xu, Wenlong Liu, Sheng‐Ping Guo

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  30. Structural Symmetry and Mixed‐anion Engineering in Halopnictides for Extraordinary Second‐Harmonic Generation

    Angewandte Chemie International Edition · 2025-12-18

    Yi‐Bing Huang, Bin‐Wen Liu, Wei Wu, Xiao‐Ming Jiang, Xiyue Cheng, Guo‐Qiang Wang, Guo‐Cong Guo

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  31. Structural Symmetry and Mixed‐anion Engineering in Halopnictides for Extraordinary Second‐Harmonic Generation

    Angewandte Chemie · 2025-12-18

    Yi‐Bing Huang, Bin‐Wen Liu, Wei Wu, Xiao‐Ming Jiang, Xiyue Cheng, Guo‐Qiang Wang, Guo‐Cong Guo

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  32. Deep-Ultraviolet Transparent Zr/Hf Fluorides with Second-Harmonic Generation Effects Induced by Alkali-Metal Modulation

    Inorganic Chemistry · 2026-06-26

    Ling Wang, Mei Yan, Min Li, Zheng-Yu Yang, X X Li, Wenfeng Zhou, Ru‐Ling Tang

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  33. Beyond the bandgap bottleneck: structure–property design principles for infrared nonlinear optical phosphides

    Coordination Chemistry Reviews · 2026-09-22

    Zichang Wang, Dajiang Mei, Ximeng Lv, Shuchang Wu, Yang Liu, Jingdong Yan, Xiangran Kong, Hongwei Leng, Zuotao Lei, Chunhui Yang

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