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RESEARCH PAPER · Crystal Growth & Design · 2017

Nonlinear Optical Crystal Rb 4 Sn 3 Cl 2 Br 8 : Synthesis, Structure, and Characterization

Pifu Gong, Siyang Luo, Yi Jin Yang, Fei Liang, Shengzi Zhang, Sangen Zhao, Junhua Luo, Zheshuai Lin

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Nonlinear Optical Crystal Rb 4 Sn 3 Cl 2 Br 8 : Synthesis, Structure, and CharacterizationOriginalAir-Stable Direct Bandgap Perovskite Semiconductors: All-Inorganic Tin-Based Heteroleptic Halides AxSnClyIz (A = Cs, Rb)92Extended First Hyperpolarizability of Quasi-Octupolar Molecules by Halogenated Methylation: Whether the Iodine Atom is the Best Choice50Recent advances and future perspectives on infrared nonlinear optical metal halides223Synthesis and anticancer property of Zn(II) compounds nanoparticles based on tetrazole carboxylate ligands15Synthesis, crystal structures and nonlinear optical properties of β-RbCdI 3 ·H 2 O and CsCdI 3 ·H 2 O8ASbF3Cl (A = Rb, Cs): Structural Evolution from Centrosymmetry to Noncentrosymmetry16Mixed-Anion Inorganic Compounds: A Favorable Candidate for Infrared Nonlinear Optical Materials140Five New Silver Rare‐Earth Iodates, AgLn(IO3)4 (Ln=Pr, Sm, Dy, Er and Tm): Synthesis, Structures and Properties6In[Ba 3 Cl 3 F 6 ]: a novel infrared-transparent molecular sieve constructed by halides6Lead-Free Tin(IV)-Based Organic–Inorganic Metal Halide Hybrids with Excellent Stability and Blue-Broadband Emission137Theoretical Framework of 1,3-Thiazolium-5-Thiolates Mesoionic Compounds: Exploring the Nature of Photophysical Property and Molecular Nonlinearity35Structural Evolution and Optical Property Tunability by Halogen Substitution in [N(CH3)4]MX2 (M = Ga+, In+, X = Cl, Br): A Family of Organically Templated Metal Halides8Cs4FeBiBr10: An Example of a New-Type A4BB′X10 Lead-Free Metal Halide Perovskite Single Crystal3Halonitrides Zn 2 NX (X=Cl,Br): Novel Mid-Infrared Nonlinear Optical Materials30Sn7Br10S2: The First Ternary Halogen‐Rich Chalcohalide Exhibiting a Chiral Structure and Pronounced Nonlinear Optical Properties24Sn7Br10S2: The First Ternary Halogen‐Rich Chalcohalide Exhibiting a Chiral Structure and Pronounced Nonlinear Optical Properties146AIn 4 S 6 Cl (A = Rb and Cs) and Pb 5 Sn 3 Q 10 Cl 2 (Q = S and Se): quaternary chalcohalides with mixed anionic coordination exhibit photocurrent responses11K6Sn4F12I2•0.5H2O: a zero-dimensional alkali metal tin mixed halide compound exhibiting color change due to crystal water loss0From CsKTaF7 to CsNaTaF7: Alkali Metal Cations Regulation to Generate SHG Activity**22Effects of external field wavelength and solvation on the photophysical property and optical nonlinearity of 1,3-thiazolium-5-thiolates mesoionic compound9ASn(C10H12N2O8)Cl·H2O (A = K, Rb): Nonlinear optical crystals with new distorted Sn(IV)-centered nitrogen-oxygen-chloride polyhedron and wide band gaps6Photoluminescence and Nonlinear Optical Properties of Two Terpyridine-Based Hybrid Zn/Cd Halides25Rational Design of the Alkali Metal Sn‐Based Mixed Halides with Large Birefringence and Wide Transparent Range45Equivalent cation-tuning to realize a new Ce( iv ) fluoride with excellent comprehensive nonlinear optical performances12Novel antimony-based mixed halides exhibiting an excellent SHG response and a broad transmission range20Hydrothermal growth and characterization of large Rb 2 SnBr 6 double perovskite crystals: a promising semiconductor material for photocatalysis and optoelectronics8Design and Synthesis of Two Sn-Centered Mixed Halide Crystals with Enhanced Birefringence8One-Dimensional Perovskite RbGeI3 with Large Optical Anisotropy3Planar [HgCl 3 ] and V‑Shaped [HgCl 2 ] Units Synergistically Creating a Prominent Halide Birefringent Crystal β ‐CsHg 2 Cl 5 with Wide‐Spectrum7Designing High-Performance Short-Wave UV Tellurium-Based Mixed Halides Birefringent Crystals via Halogen Substitution Engineering4Advances in metal selenite nonlinear optical materials: halogens directed structure modulation and property optimization0Entropy‐Driven Precursor Symmetry Breaking for Phase‐Selective Synthesis of Noncentrosymmetric Rb 2 CdCl 2 I 20

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  1. Air-Stable Direct Bandgap Perovskite Semiconductors: All-Inorganic Tin-Based Heteroleptic Halides AxSnClyIz (A = Cs, Rb)

    Chemistry of Materials · 2018-06-20

    Jiangwei Li, Constantinos C. Stoumpos, Giancarlo G. Trimarchi, In Jae Chung, Lingling Mao, Michelle Chen, Michael R. Wasielewski, Liduo Wang, Mercouri G. Kanatzidis

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  2. Extended First Hyperpolarizability of Quasi-Octupolar Molecules by Halogenated Methylation: Whether the Iodine Atom is the Best Choice

    The Journal of Physical Chemistry C · 2018-08-28

    Zeyu Liu, Shugui Hua, Guohua Wu

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  3. Recent advances and future perspectives on infrared nonlinear optical metal halides

    Coordination Chemistry Reviews · 2018-10-23

    Pifu Gong, Fei Liang, Lei Kang, Xingguo Chen, Jingui Qin, Yicheng Wu, Zheshuai Lin

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  4. Synthesis and anticancer property of Zn(II) compounds nanoparticles based on tetrazole carboxylate ligands

    Inorganica Chimica Acta · 2018-12-05

    Ting Zhu, Tian Yu Wu, Jing Ao Ren, Su Jian Qian, Yan Li, Wan Ting Su, Deng Feng Zou, Qiao Yun Li, Jie Yang

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  5. Synthesis, crystal structures and nonlinear optical properties of β-RbCdI 3 ·H 2 O and CsCdI 3 ·H 2 O

    Dalton Transactions · 2019-01-01

    Qi Wu, Xian Liu, Siran Xu, Hongbing Pi, Xue Han, Yang Liu, Yanjun Li

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  6. ASbF3Cl (A = Rb, Cs): Structural Evolution from Centrosymmetry to Noncentrosymmetry

    Crystal Growth & Design · 2019-01-24

    Pifu Gong, Yi Jin Yang, Fengguang You, Xinyuan Zhang, Gaomin Song, Shengzi Zhang, Qian Huang, Zheshuai Lin

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  7. Mixed-Anion Inorganic Compounds: A Favorable Candidate for Infrared Nonlinear Optical Materials

    Crystal Growth & Design · 2019-06-07

    Yanyan Li, Wenjing Wang, Hui Wang, Hua Lin, Li‐Ming Wu

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  8. Five New Silver Rare‐Earth Iodates, AgLn(IO3)4 (Ln=Pr, Sm, Dy, Er and Tm): Synthesis, Structures and Properties

    ChemistrySelect · 2019-08-06

    Qi Wu, Xian Liu, Siran Xu, Hongbing Pi, Yanjun Li

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  9. In[Ba 3 Cl 3 F 6 ]: a novel infrared-transparent molecular sieve constructed by halides

    Chemical Communications · 2020-01-01

    Xiaoqing Jiang, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  10. Lead-Free Tin(IV)-Based Organic–Inorganic Metal Halide Hybrids with Excellent Stability and Blue-Broadband Emission

    The Journal of Physical Chemistry Letters · 2020-02-03

    Gaomin Song, Mingze Li, Yi Jin Yang, Fei Liang, Qian Huang, Xiaomeng Liu, Pifu Gong, Zhiguo Xia, Zheshuai Lin

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  11. Theoretical Framework of 1,3-Thiazolium-5-Thiolates Mesoionic Compounds: Exploring the Nature of Photophysical Property and Molecular Nonlinearity

    The Journal of Physical Chemistry A · 2020-06-15

    Zeyu Liu, Ziqi Tian, Tian Lu, Shugui Hua

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  12. Structural Evolution and Optical Property Tunability by Halogen Substitution in [N(CH3)4]MX2 (M = Ga+, In+, X = Cl, Br): A Family of Organically Templated Metal Halides

    Inorganic Chemistry · 2020-07-15

    Xian Liu, Wan Ya, Qi Wu, Fei Liang, Jun Zhang

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  13. Cs4FeBiBr10: An Example of a New-Type A4BB′X10 Lead-Free Metal Halide Perovskite Single Crystal

    Crystal Growth & Design · 2020-12-18

    Muhammad Usman, Qingfeng Yan

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  14. Halonitrides Zn 2 NX (X=Cl,Br): Novel Mid-Infrared Nonlinear Optical Materials

    Chemistry of Materials · 2021-02-02

    Xin Lei Zhao, Chensheng Lin, Jindong Chen, Min Luo, Feng Xu, Shunda Yang, Shuangshuang Shi, Bingxuan Li, Ning Ye

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  15. Sn7Br10S2: The First Ternary Halogen‐Rich Chalcohalide Exhibiting a Chiral Structure and Pronounced Nonlinear Optical Properties

    Angewandte Chemie · 2021-12-24

    Xiaohui Li, Zhi‐Hui Shi, Mei Yang, Wenlong Liu, Sheng‐Ping Guo

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  16. Sn7Br10S2: The First Ternary Halogen‐Rich Chalcohalide Exhibiting a Chiral Structure and Pronounced Nonlinear Optical Properties

    Angewandte Chemie International Edition · 2021-12-24

    Xiaohui Li, Zhi‐Hui Shi, Mei Yang, Wenlong Liu, Sheng‐Ping Guo

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  17. AIn 4 S 6 Cl (A = Rb and Cs) and Pb 5 Sn 3 Q 10 Cl 2 (Q = S and Se): quaternary chalcohalides with mixed anionic coordination exhibit photocurrent responses

    Dalton Transactions · 2022-01-01

    Lin‐Tao Jiang, Mingze Li, Xiao‐Ming Jiang, Bin‐Wen Liu, Guo‐Cong Guo

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  18. K6Sn4F12I2•0.5H2O: a zero-dimensional alkali metal tin mixed halide compound exhibiting color change due to crystal water loss

    Microstructures · 2022-01-01

    Pifu Gong, Siyang Luo, Zheshuai Lin

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  19. From CsKTaF7 to CsNaTaF7: Alkali Metal Cations Regulation to Generate SHG Activity**

    Chemistry - A European Journal · 2022-06-21

    Ru‐Ling Tang, Xin Lian, Xiaohui Li, Lei Huai, Wenlong Liu, Sheng‐Ping Guo

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  20. Effects of external field wavelength and solvation on the photophysical property and optical nonlinearity of 1,3-thiazolium-5-thiolates mesoionic compound

    Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy · 2022-12-09

    Shugui Hua, Xia Wang, Zeyu Liu, Tian Lu, Mengdi Zhao

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  21. ASn(C10H12N2O8)Cl·H2O (A = K, Rb): Nonlinear optical crystals with new distorted Sn(IV)-centered nitrogen-oxygen-chloride polyhedron and wide band gaps

    Scripta Materialia · 2023-08-30

    Ya-Hui Zhu, Zilong Geng, Hong‐Xin Tang, Ruibiao Fu, Zuju Ma, Xin‐Tao Wu

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  22. Photoluminescence and Nonlinear Optical Properties of Two Terpyridine-Based Hybrid Zn/Cd Halides

    Inorganic Chemistry · 2023-12-12

    Sihan Wang, Zhengli Liang, Xinluan Song, Xin Huang, Lehui Liu, Xingxing Jiang, Zheshuai Lin, Hongming Liu

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  23. Rational Design of the Alkali Metal Sn‐Based Mixed Halides with Large Birefringence and Wide Transparent Range

    Small · 2023-12-15

    Jun-Bo Wang, Mengmeng Zhu, Yaoqing Chu, Jindan Tian, Lili Liu, Bingbing Zhang, P. Shiv Halasyamani

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  24. Equivalent cation-tuning to realize a new Ce( iv ) fluoride with excellent comprehensive nonlinear optical performances

    Inorganic Chemistry Frontiers · 2024-01-01

    Beibei Zhang, Wen‐Ye Gao, Wei Lin Xu, L. Ma, Wenlong Liu, Ru‐Ling Tang, Sheng‐Ping Guo

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  25. Novel antimony-based mixed halides exhibiting an excellent SHG response and a broad transmission range

    Inorganic Chemistry Frontiers · 2024-12-05

    Luli Wang, Han Luo, Siyu Chen, Ling Huang, Liling Cao, Xuehua Dong, Guohong Zou

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  26. Hydrothermal growth and characterization of large Rb 2 SnBr 6 double perovskite crystals: a promising semiconductor material for photocatalysis and optoelectronics

    Dalton Transactions · 2025-01-01

    Rahidul Hasan, Hafiz Zohaib Aslam, Rutva Joshi, Roger A. Lalancette, Georgiy Akopov

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  27. Design and Synthesis of Two Sn-Centered Mixed Halide Crystals with Enhanced Birefringence

    Inorganic Chemistry · 2025-01-21

    Hongkun Liu, Gangji Yi, Jiarong Lv, Xuehua Dong, Hongmei Zeng, Ling Huang, Zhien Lin, Guohong Zou

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  28. One-Dimensional Perovskite RbGeI3 with Large Optical Anisotropy

    Inorganic Chemistry · 2025-02-12

    Huige Chen, Deshuai Xiao, Pifu Gong, Xinyuan Zhang, Zheshuai Lin, Lei Kang

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  29. Planar [HgCl 3 ] and V‑Shaped [HgCl 2 ] Units Synergistically Creating a Prominent Halide Birefringent Crystal β ‐CsHg 2 Cl 5 with Wide‐Spectrum

    Advanced Optical Materials · 2025-06-03

    Yi‐Lei Lv, Ru‐Ling Tang, Cheng Chen, Liang Ma, Wenlong Liu, Sheng‐Ping Guo

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  30. Designing High-Performance Short-Wave UV Tellurium-Based Mixed Halides Birefringent Crystals via Halogen Substitution Engineering

    Crystal Growth & Design · 2025-06-24

    Xiang Mao, Yu Yan, Yingzi Zhang, Xuehua Dong, Ling Huang, Liling Cao, Daojiang Gao, Guohong Zou

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  31. Advances in metal selenite nonlinear optical materials: halogens directed structure modulation and property optimization

    Coordination Chemistry Reviews · 2026-08-14

    Dan-Dan Zhou, Tian-Tian He, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  32. Entropy‐Driven Precursor Symmetry Breaking for Phase‐Selective Synthesis of Noncentrosymmetric Rb 2 CdCl 2 I 2

    Advanced Optical Materials · 2026-08-17

    Sheng Lv, Liangcheng Song, Yanling Xu, Jiahao Zhou, Chongqiang Zhu, Chunhui Yang

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