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RESEARCH PAPER · Crystal Growth & Design · 2014

Observation of Multiple Crystal-to-Crystal Transitions in a New Reduced Vanadium Oxalate Hybrid Material, Ba3[(VO)2(C2O4)5(H2O)6]·(H2O)3, Prepared via a Mild, Two-Step Hydrothermal Method

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Observation of Multiple Crystal-to-Crystal Transitions in a New Reduced Vanadium Oxalate Hybrid Material, Ba3[(VO)2(C2O4)5(H2O)6]·(H2O)3, Prepared via a Mild, Two-Step Hydrothermal MethodOriginalSynthetic strategies for new vanadium oxyfluorides containing novel building blocks: structures of V( iv ) and V( v ) containing Sr 4 V 3 O 5 F 13 , Pb 7 V 4 O 8 F 18 , Pb 2 VO 2 F 5 , and Pb 2 VOF 617Crystal Growth of Four Oxovanadium(IV) Tartrates Prepared via a Mild Two-Step Hydrothermal Method: Observation of Spin-Dimer Behavior and Second Harmonic Generation28Synthesis, characterization, and properties of reduced europium molybdates and tungstates21Single-Crystal to Single-Crystal Reversible Transformations Induced by Thermal Dehydration in Keggin-Type Polyoxometalates Decorated with Copper(II)-Picolinate Complexes: The Structure Directing Role of Guanidinium6Single crystal growth and characterization of the first reduced lanthanum molybdenum oxychloride, La20Mo12O63Cl4, with an unusual trigonal prismatic MoO6 unit14High-Temperature Salt Flux Crystal Growth of New Lanthanide Molybdenum Oxides, Ln5Mo2O12 Ln = Eu, Tb, Dy, Ho, and Er: Magnetic Coupling within Mixed Valent Mo(IV/V) Rutile-Like Chains22Single crystal growth and characterization of NaxLn1−xMoO4, Ln=La, Ce, Pr, Nd, Sm, and Eu (x=0.397–0.499)9Understanding the Formation of Salt-Inclusion Phases: An Enhanced Flux Growth Method for the Targeted Synthesis of Salt-Inclusion Cesium Halide Uranyl Silicates61Oxygen Anion Solubility as a Factor in Molten Flux Crystal Growth, Synthesis, and Characterization of Four New Reduced Lanthanide Molybdenum Oxides: Ce4.918(3)Mo3O16, Pr4.880(3)Mo3O16, Nd4.910(3)Mo3O16, and Sm4.952(3)Mo3O1615Crystal growth, structure, and properties, of a new oxovanadium(IV) phosphate material, [H2en]4[V7P8O35(OH)6(H2O)]·3H2O prepared via a mild one step hydrothermal route4A Novel Copper Oxalate, Na2Cu(C2O4)24Application of a mild hydrothermal method to the synthesis of mixed transition-metal( ii )/uranium( iv ) fluorides18Where Do New Materials Come From? Neither the Stork nor the Birds and the Bees! In Search of the Next “First Material”1Na2Fe(C2O4)F2: A New Iron-Based Polyoxyanion Cathode for Li/Na Ion Batteries48A fresnoite-structure-related mixed valent titanium(III/IV) chlorosilicate, Ba3Ti2Si4O14Cl: A flux crystal growth route to Ti(III) containing oxides11One-step mild hydrothermal method to prepare low valent sodium vanadium(III) monohydrogenphosphate: NaV(HPO4)24Diverse Family of Layered Frustrated Magnets with Tailorable Interlayer Interactions24[Co(H2O)6]3[U2O4F7]2: A Model System for Understanding the Formation of Dimensionally Reduced Materials11Polyanionic Insertion Materials for Sodium‐Ion Batteries448Synthesis, crystal structure, thermal, photoluminescent and magnetic properties of a new material: Na2[Ni(C2O4)2(H2O)2].6H2O4Solvent-assisted structural conversion involving bimetallic complexes based on the tris(oxalato)ferrate( iii ) unit with the green → blue → red crystal color sequence13Utilizing an In Situ Reduction in the Synthesis of BaMoOF54Hybrid Inorganic‐Organic Frameworks: Synthesis and Crystal Structures of RbFe(SO4)(C2O4)0.5·H2O and CsM(SO4)(C2O4)0.5·H2O (M = Mn, Fe)2Structural conversion of three copper( ii ) complexes with snapshot observations based on the different crystal colours and morphology5Mild hydrothermal synthesis of potassium uranyl phosphates with layered and framework structures2Gladstone–Dale compatibility, electronic polarizability and vibrational spectroscopy of minerals and inorganic compounds with V 4+ O and V 4+ O 2 vanadyl groups1Synthesis, Crystal Structure, and Magnetism in Fluoride Sulfates, A2VF3(SO4) (A = K, Rb, Cs)2

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  1. Synthetic strategies for new vanadium oxyfluorides containing novel building blocks: structures of V( iv ) and V( v ) containing Sr 4 V 3 O 5 F 13 , Pb 7 V 4 O 8 F 18 , Pb 2 VO 2 F 5 , and Pb 2 VOF 6

    CrystEngComm · 2015-01-01

    Jeongho Yeon, Justin B. Felder, Mark D. Smith, Gregory W. Morrison, Hans‐Conrad zur Loye

    Read original paper ↗ ·
  2. Crystal Growth of Four Oxovanadium(IV) Tartrates Prepared via a Mild Two-Step Hydrothermal Method: Observation of Spin-Dimer Behavior and Second Harmonic Generation

    Inorganic Chemistry · 2015-03-31

    Anthony J. Cortese, Branford O. Wilkins, Mark D. Smith, Jeongho Yeon, Gregory W. Morrison, T. Thao Tran, P. Shiv Halasyamani, Hans‐Conrad zur Loye

    Read original paper ↗ ·
  3. Synthesis, characterization, and properties of reduced europium molybdates and tungstates

    Journal of Solid State Chemistry · 2015-05-18

    Dileka Abeysinghe, Birgit Gerke, Gregory W. Morrison, Chun H. Hsieh, Mark D. Smith, Rainer Pöttgen, Thomas M. Makris, Hans‐Conrad zur Loye

    Read original paper ↗ ·
  4. Single-Crystal to Single-Crystal Reversible Transformations Induced by Thermal Dehydration in Keggin-Type Polyoxometalates Decorated with Copper(II)-Picolinate Complexes: The Structure Directing Role of Guanidinium

    Inorganics · 2015-05-27

    Aroa Pache, Santiago Reinoso, Leire San Felices, Amaia Iturrospe, Luis M. Lezama, Juan Manuel Gutierrez-Zorrilla

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  5. Single crystal growth and characterization of the first reduced lanthanum molybdenum oxychloride, La20Mo12O63Cl4, with an unusual trigonal prismatic MoO6 unit

    Solid State Sciences · 2015-07-30

    Anthony J. Cortese, Branford O. Wilkins, Mark D. Smith, Gregory W. Morrison, Hans‐Conrad zur Loye

    Read original paper ↗ ·
  6. High-Temperature Salt Flux Crystal Growth of New Lanthanide Molybdenum Oxides, Ln5Mo2O12 Ln = Eu, Tb, Dy, Ho, and Er: Magnetic Coupling within Mixed Valent Mo(IV/V) Rutile-Like Chains

    Inorganic Chemistry · 2015-12-02

    Anthony J. Cortese, Dileka Abeysinghe, Branford O. Wilkins, Mark D. Smith, Gregory W. Morrison, Hans‐Conrad zur Loye

    Read original paper ↗ ·
  7. Single crystal growth and characterization of NaxLn1−xMoO4, Ln=La, Ce, Pr, Nd, Sm, and Eu (x=0.397–0.499)

    Journal of Solid State Chemistry · 2016-05-09

    Anthony J. Cortese, Dileka Abeysinghe, Mark D. Smith, Hans‐Conrad zur Loye

    Read original paper ↗ ·
  8. Understanding the Formation of Salt-Inclusion Phases: An Enhanced Flux Growth Method for the Targeted Synthesis of Salt-Inclusion Cesium Halide Uranyl Silicates

    Journal of the American Chemical Society · 2016-05-24

    Gregory W. Morrison, Mark D. Smith, Hans‐Conrad zur Loye

    Read original paper ↗ ·
  9. Oxygen Anion Solubility as a Factor in Molten Flux Crystal Growth, Synthesis, and Characterization of Four New Reduced Lanthanide Molybdenum Oxides: Ce4.918(3)Mo3O16, Pr4.880(3)Mo3O16, Nd4.910(3)Mo3O16, and Sm4.952(3)Mo3O16

    Crystal Growth & Design · 2016-07-06

    Anthony J. Cortese, Dileka Abeysinghe, Branford O. Wilkins, Mark D. Smith, Vitaly A. Rassolov, Hans‐Conrad zur Loye

    Read original paper ↗ ·
  10. Crystal growth, structure, and properties, of a new oxovanadium(IV) phosphate material, [H2en]4[V7P8O35(OH)6(H2O)]·3H2O prepared via a mild one step hydrothermal route

    Solid State Sciences · 2016-08-07

    Anthony J. Cortese, Mark D. Smith, Hans‐Conrad zur Loye

    Read original paper ↗ ·
  11. A Novel Copper Oxalate, Na2Cu(C2O4)2

    Zeitschrift für anorganische und allgemeine Chemie · 2016-10-28

    Wenjiao Yao, Anthony Robert Armstrong, Philip Lightfoot

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  12. Application of a mild hydrothermal method to the synthesis of mixed transition-metal( ii )/uranium( iv ) fluorides

    Inorganic Chemistry Frontiers · 2017-01-01

    Justin B. Felder, Jeongho Yeon, Mark D. Smith, Hans‐Conrad zur Loye

    Read original paper ↗ ·
  13. Where Do New Materials Come From? Neither the Stork nor the Birds and the Bees! In Search of the Next “First Material”

    Scholar Commons (University of South Carolina) · 2017-01-01

    Gregory W. Morrison, Dileka Abeysinghe, Justin B. Felder, Shani Egodawatte, Timothy Ferreira, Hans‐Conrad zur Loye

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  14. Na2Fe(C2O4)F2: A New Iron-Based Polyoxyanion Cathode for Li/Na Ion Batteries

    Chemistry of Materials · 2017-02-10

    Wenjiao Yao, Moulay Tahar Sougrati, Khang Hoang, Jianing Hui, Philip Lightfoot, Anthony Robert Armstrong

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  15. A fresnoite-structure-related mixed valent titanium(III/IV) chlorosilicate, Ba3Ti2Si4O14Cl: A flux crystal growth route to Ti(III) containing oxides

    Journal of Solid State Chemistry · 2017-03-31

    Dileka Abeysinghe, Mark D. Smith, Hans‐Conrad zur Loye

    Read original paper ↗ ·
  16. One-step mild hydrothermal method to prepare low valent sodium vanadium(III) monohydrogenphosphate: NaV(HPO4)2

    Solid State Sciences · 2017-05-04

    Dileka Abeysinghe, Mark D. Smith, Hans‐Conrad zur Loye

    Read original paper ↗ ·
  17. Diverse Family of Layered Frustrated Magnets with Tailorable Interlayer Interactions

    Chemistry of Materials · 2017-07-27

    Wenjiao Yao, Lucy Clark, Mingjun Xia, Teng Li, Stephen Lee, Philip Lightfoot

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  18. [Co(H2O)6]3[U2O4F7]2: A Model System for Understanding the Formation of Dimensionally Reduced Materials

    Crystal Growth & Design · 2018-01-09

    Justin B. Felder, Mark D. Smith, Hans‐Conrad zur Loye

    Read original paper ↗ ·
  19. Polyanionic Insertion Materials for Sodium‐Ion Batteries

    Advanced Energy Materials · 2018-04-20

    Prabeer Barpanda, Laura Lander, Shin‐ichi Nishimura, Atsuo Yamada

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  20. Synthesis, crystal structure, thermal, photoluminescent and magnetic properties of a new material: Na2[Ni(C2O4)2(H2O)2].6H2O

    Journal of Molecular Structure · 2018-10-06

    M. Narsimhulu, G. Anil Kumar, G. Bhargavi, B. Srinivas, K.A. Hussain

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  21. Solvent-assisted structural conversion involving bimetallic complexes based on the tris(oxalato)ferrate( iii ) unit with the green → blue → red crystal color sequence

    Dalton Transactions · 2019-01-01

    Tadeusz M. Muzioł, Natalia Tereba, Robert Podgajny, Dariusz Kędziera, Grzegorz Wrzeszcz

    Read original paper ↗ ·
  22. Utilizing an In Situ Reduction in the Synthesis of BaMoOF5

    Journal of Chemical Crystallography · 2019-01-02

    Justin B. Felder, Mark D. Smith, Hans‐Conrad zur Loye

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  23. Hybrid Inorganic‐Organic Frameworks: Synthesis and Crystal Structures of RbFe(SO4)(C2O4)0.5·H2O and CsM(SO4)(C2O4)0.5·H2O (M = Mn, Fe)

    Zeitschrift für anorganische und allgemeine Chemie · 2019-05-17

    Xiaofang Li, Yuandong Wu, Dajiang Mei, Thomas Doert

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  24. Structural conversion of three copper( ii ) complexes with snapshot observations based on the different crystal colours and morphology

    RSC Advances · 2020-01-01

    Hao Su, Zhongkui Li, Junrui Tan, Hongwei Ma, Li Yan, Hui Li

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  25. Mild hydrothermal synthesis of potassium uranyl phosphates with layered and framework structures

    Journal of Solid State Chemistry · 2021-06-10

    Gregory W. Morrison, Kristen A. Pace, Hans‐Conrad zur Loye

    Read original paper ↗ ·
  26. Gladstone–Dale compatibility, electronic polarizability and vibrational spectroscopy of minerals and inorganic compounds with V 4+ O and V 4+ O 2 vanadyl groups

    Acta Crystallographica Section B Structural Science Crystal Engineering and Materials · 2023-07-04

    Н. В. Чуканов, R. X. Fischer, Olga N. Kazheva, Sergey M. Aksenov

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  27. Synthesis, Crystal Structure, and Magnetism in Fluoride Sulfates, A2VF3(SO4) (A = K, Rb, Cs)

    Crystal Growth & Design · 2024-05-28

    Yanling Jin, Suheon Lee, Xinan Zhang, Dan Chen, Wenxuan Zhu, Yaping Li, Qingqing Huang, Eundeok Mun, Kwang‐Yong Choi, Minfeng Lü

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