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RESEARCH PAPER · Crystal Growth & Design · 2016

Oxygen Anion Solubility as a Factor in Molten Flux Crystal Growth, Synthesis, and Characterization of Four New Reduced Lanthanide Molybdenum Oxides: Ce4.918(3)Mo3O16, Pr4.880(3)Mo3O16, Nd4.910(3)Mo3O16, and Sm4.952(3)Mo3O16

Anthony J. Cortese, Dileka Abeysinghe, Branford O. Wilkins, Mark D. Smith, Vitaly A. Rassolov, Hans‐Conrad zur Loye

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Oxygen Anion Solubility as a Factor in Molten Flux Crystal Growth, Synthesis, and Characterization of Four New Reduced Lanthanide Molybdenum Oxides: Ce4.918(3)Mo3O16, Pr4.880(3)Mo3O16, Nd4.910(3)Mo3O16, and Sm4.952(3)Mo3O16OriginalSynthetic Access to Cubic Rare Earth Molybdenum Oxides RE6MoO12−δ(RE = Tm–Lu) Representing a New Class of Ion Conductors20Effects of Alkali Cations and Sulfate/Chloride Anions on the Flux Growth of {001}-Faceted β-Li2TiO3 Crystals17Complex tunnel structure of new La 6 (Mo 2 O 7 )(MoO 4 ) 8 : crystal growth from flux and high structural complexity5Growth of {100}-faceted NaFeTiO 4 crystals with a tunable aspect ratio from a NaCl–Na 2 SO 4 binary flux7In Situ Neutron Diffraction Studies of the Flux Crystal Growth of the Reduced Molybdates La 4 Mo 2 O 11 and Ce 4 Mo 2 O 11 : Revealing Unexpected Mixed-Valent Transient Intermediates and Determining the Sequence of Events during Crystal Growth19Effect of Sodium and Fluorine Co‐Doping on the Properties of Fluorite‐Like Rare‐Earth Molybdates of Nd5Mo3O16 Type9Fluorite‐like Li x Ln 5– x Mo 3 O 16.5–1.5 x F x (Ln = La, Pr, Nd) compounds isostructural with Nd 5 Mo 3 O 1612Underlying limitations behind impedance rise and capacity fade of single crystalline Ni-rich cathodes synthesized via a molten-salt route28Substitutions in Nd5−xTbxMo3O16+δ Series: Phase Formation, Atomistic Modeling, and Crystal Structure of Nd5Mo3O16+δ-Based Solid Solutions2Solid-State Synthesis and Phase Transitions in the RE 2 (MoO 4 ) 3 Family Monitored by Thermodiffraction13Investigation of the Crystal Structure of Nd5Mo3O16 + δ in the Pressure Range 0–5.9 GPа0On the Crystal Structure of Nd5Mo3O16 + δ in the Pressure Range 0–5.9 GPа2Growth of Fe-Substituted Sr6Co5O15 Hexagonal Perovskite Single Crystals by a Flux Method10Solid-state and sol-gel synthesis of neodymium molybdate Nd5Mo3O16+δ and study of their crystal structure in the temperature range of 300–700 K by the neutron diffraction7Fluorite-like phases in the La2MoO6 – Sm2MoO6 – MoO3 system: Homogeneity region, crystal structure, and conductive properties9

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  1. Synthetic Access to Cubic Rare Earth Molybdenum Oxides RE6MoO12−δ(RE = Tm–Lu) Representing a New Class of Ion Conductors

    Chemistry of Materials · 2016-09-22

    Daniel Schildhammer, Gerda Fuhrmann, Lucas L. Petschnig, Simon Penner, Michaela Kogler, Thomas Götsch, Andreas Schaur, Nikolaus Weinberger, Andreas Saxer, Herwig Schottenberger, Hubert Huppertz

    Read original paper ↗ ·

  2. Effects of Alkali Cations and Sulfate/Chloride Anions on the Flux Growth of {001}-Faceted β-Li2TiO3 Crystals

    Crystal Growth & Design · 2017-01-11

    Xiong Ye Xiao, Fumitaka Hayashi, Kunio Yubuta, Annabella Selloni, Katsuya Teshima

    Read original paper ↗ ·

  3. Complex tunnel structure of new La 6 (Mo 2 O 7 )(MoO 4 ) 8 : crystal growth from flux and high structural complexity

    Mendeleev Communications · 2017-11-01

    Marie Colmont, Bastien Leclercq, Olivier Mentré, Pascal Roussel

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  4. Growth of {100}-faceted NaFeTiO 4 crystals with a tunable aspect ratio from a NaCl–Na 2 SO 4 binary flux

    CrystEngComm · 2017-12-01

    Tomohito Sudare, Daiki Kawaura, Kunio Yubuta, Fumitaka Hayashi, Katsuya Teshima

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  5. In Situ Neutron Diffraction Studies of the Flux Crystal Growth of the Reduced Molybdates La 4 Mo 2 O 11 and Ce 4 Mo 2 O 11 : Revealing Unexpected Mixed-Valent Transient Intermediates and Determining the Sequence of Events during Crystal Growth

    Chemistry of Materials · 2018-01-10

    Dileka Abeysinghe, Ashfia Huq, Jeongho Yeon, Mark D. Smith, Hans‐Conrad zur Loye

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  6. Effect of Sodium and Fluorine Co‐Doping on the Properties of Fluorite‐Like Rare‐Earth Molybdates of Nd5Mo3O16 Type

    European Journal of Inorganic Chemistry · 2019-01-30

    Valentina I. Voronkova, Elena P. Kharitonova, Ekaterina Orlova, A. Kežionis, Dalius Petrulionis

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  7. Fluorite‐like Li x Ln 5– x Mo 3 O 16.5–1.5 x F x (Ln = La, Pr, Nd) compounds isostructural with Nd 5 Mo 3 O 16

    Journal of the American Ceramic Society · 2020-07-27

    Valentina I. Voronkova, Elena P. Kharitonova, Ekaterina Orlova, E. D. Baldin, Nikolay V. Gorshkov, Vladimir Georgievich Goffman, Sergei A. Chernyak

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  8. Underlying limitations behind impedance rise and capacity fade of single crystalline Ni-rich cathodes synthesized via a molten-salt route

    Journal of Power Sources · 2022-08-17

    Luqman Azhari, Zifei Meng, Zhenzhen Yang, Guanhui Gao, Yimo Han, Yan Wang

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  9. Substitutions in Nd5−xTbxMo3O16+δ Series: Phase Formation, Atomistic Modeling, and Crystal Structure of Nd5Mo3O16+δ-Based Solid Solutions

    Journal of Chemistry · 2023-01-25

    Konstantin A. Chebyshev, N. I. Selikova, Lyudmila V. Pasechnik, Aleksey V. Ignatov

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  10. Solid-State Synthesis and Phase Transitions in the RE 2 (MoO 4 ) 3 Family Monitored by Thermodiffraction

    Crystal Growth & Design · 2023-03-14

    Iván da Silva, Gerardo Gil de Cos, Cristina González-Silgo, Javier López-Solano, Andrés Mujica, Nivaria R. Ramírez-Rodríguez, Manuel E. Torres

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  11. Investigation of the Crystal Structure of Nd5Mo3O16 + δ in the Pressure Range 0–5.9 GPа

    Поверхность Рентгеновские синхротронные и нейтронные исследования · 2023-04-01

    Konstantin A. Chebyshev, В. А. Турченко, Sergey E. Kichanov

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  12. On the Crystal Structure of Nd5Mo3O16 + δ in the Pressure Range 0–5.9 GPа

    Journal of Surface Investigation X-ray Synchrotron and Neutron Techniques · 2023-04-01

    Konstantin A. Chebyshev, В. А. Турченко, Sergey E. Kichanov

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  13. Growth of Fe-Substituted Sr6Co5O15 Hexagonal Perovskite Single Crystals by a Flux Method

    Crystal Growth & Design · 2023-04-05

    Yuhu Huang, Han‐Shu Xu

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  14. Solid-state and sol-gel synthesis of neodymium molybdate Nd5Mo3O16+δ and study of their crystal structure in the temperature range of 300–700 K by the neutron diffraction

    Solid State Sciences · 2024-01-10

    Konstantin A. Chebyshev, Tatiana S. Berezhnaya, В. А. Турченко

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  15. Fluorite-like phases in the La2MoO6 – Sm2MoO6 – MoO3 system: Homogeneity region, crystal structure, and conductive properties

    Ceramics International · 2024-09-25

    Tatiana S. Berezhnaya, Konstantin A. Chebyshev

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