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RESEARCH PAPER · Angewandte Chemie International Edition · 2019

Giant Enhancement of Second Harmonic Generation Accompanied by the Structural Transformation of 7‐Fold to 8‐Fold Interpenetrated Metal–Organic Frameworks (MOFs)

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Giant Enhancement of Second Harmonic Generation Accompanied by the Structural Transformation of 7‐Fold to 8‐Fold Interpenetrated Metal–Organic Frameworks (MOFs)OriginalRegulation of the Degree of Interpenetration in Metal–Organic Frameworks49From lamellar net to bilayered-lamella and to porous pillared-bilayer: reversible crystal-to-crystal transformation, CO 2 adsorption, and fluorescence detection of Fe 3+ , Al 3+ , Cr 3+ , MnO 4 − , and Cr 2 O 7 2− in water31Octacyanidometallates for multifunctional molecule-based materials164Tandem structural transformations from 4-fold to 5-fold interpenetrated Cd(II) metal-organic frameworks7Improving the Stability and Visualizing the Structural Transformation of the Stimuli-Responsive Metal–Organic Frameworks (MOFs)15Recent Progress in 2D Metal‐Organic Frameworks for Optical Applications149Crystal Structure, Polymorphism, and Anisotropic Thermal Expansion of α-Ca(CH3COO)230Coordination Polymers Based on Highly Emissive Ligands: Synthesis and Functional Properties112RETRACTED: Two Co(II) coordination polymers exhibit picric acid sensing property and treatment activity in nonalcoholic fatty liver disease by reducing intestinal Escherichia coli counts1N-Donor Auxiliary Ligand Influence on the Coordination Mode Variations of V-Shaped Triazole Dicarboxylic Acid Ligand Affording Seven New Luminescent Zn(II) Compounds with Variable Structural Motifs49Photofunctional metal-organic framework thin films for sensing, catalysis and device fabrication22Let the light be a guide: Chromophore communication in metal-organic frameworks60Crystal structure and electrochemical properties of an interpenetrating MOF constructed by 5-i-butoxyisophthalate and rigid N-donor ligands1Influence of conformational change of chain unit on the intrinsic negative thermal expansion of polymers20Electrochemical Synthesis of Large Area Two‐Dimensional Metal–Organic Framework Films on Copper Anodes200Electrochemical Synthesis of Large Area Two‐Dimensional Metal–Organic Framework Films on Copper Anodes12Engineering entangled photon pairs with metal–organic frameworks19Vibrational Sum-Frequency Generation Hyperspectral Microscopy for Molecular Self-Assembled Systems42Structural Variation and Switchable Nonlinear Optical Behavior of Metal–Organic Frameworks50Aggregation‐induced emission materials for nonlinear optics86Control of interpenetration and structural transformations in the interpenetrated MOFs166Crystalline Porous Materials for Nonlinear Optics91Solvent-Effected Coordination Variation of Flexible Ligands to Cu(II) for the Formation of 1D and 2D Secondary Building Units for Metal–Organic Frameworks23Photonic Metal‐Organic Frameworks31Millimeter-Scale Zn(3-ptz)2 Metal–Organic Framework Single Crystals: Self-Assembly Mechanism and Growth Kinetics19Heterobimetallic Cluster‐Based Coordination Polymers: Assembly, Structures and Third‐Order Nonlinear Optical Properties4Interpenetrated Metal-Porphyrinic Framework for Enhanced Nonlinear Optical Limiting200Construction and second‐order nonlinear optical properties of two 1D zigzag chains with crisscross and parallel arrangements0Transient Reflection Spectroscopy on Ultrafast Interlayer Charge Transfer Processes in a MoS2/WSe2van der Waals Heterojunction13Impact of the Structural Modification of Diamondoid Cd(II) MOFs on the Nonlinear Optical Properties38Interpenetrating dye-functionalized indium–organic frameworks for photooxidative cyanation and oxidative cyclization16The solvent influenced coordination variation of flexible ligands to Y( iii ) towards MOF structural diversity7Ultra-Fast Synthesis of Single-Crystalline Three-Dimensional Covalent Organic Frameworks and Their Applications in Polarized Optics36Efficient Strategy for Investigating the Third-Order Nonlinear Optical (NLO) Properties of Solid-State Coordination Polymers34One and Two‐Photon Excited Fluorescence Optimization of Metal–Organic Frameworks with Symmetry‐Reduced AIEgen‐Ligand37One and Two‐Photon Excited Fluorescence Optimization of Metal–Organic Frameworks with Symmetry‐Reduced AIEgen‐Ligand2Multiple Interpenetrating Metal–Organic Frameworks with Channel-Size-Dependent Behavior for Selective Gossypol Detection and Perovskite Quantum Dot Encapsulation36Anomalous thermal expansion of strontium squarate trihydrate induced by hydrogen-bond weakening2Chiral metal–organic frameworks for photonics133Dimensional expansion of 1D zigzag chains to a 2D two-fold interpenetrated metal–organic framework for adsorption of lanthanide cations and white light emission4Significant Improvement of Solid‐State One‐/Two‐Photon Excited Luminescence in HOFs via Constructing Hydrogen‐Bonded Solvate Model19Tuning of Second-Harmonic Generation in Zn-Based Metal–Organic Frameworks by Controlling the Structural Interpenetrations: A First-Principles Investigation15Enhancement in Two-Photon Absorption and Photoluminescence in Single Crystals of Cd(II) Metal Organic Frameworks30Solvothermal synthesis of binder free Ni-MOF thin films for supercapacitor electrodes100Nonlinear Metal–Organic Framework Crystals for Efficient Multicolor Coherent Optical Emission39Zn(II) Metal–Organic Frameworks with a Long Spacer Ligand and a Tricarboxylate Coligand1Gigantic blue shift of two‐photon–induced photoluminescence of interpenetrated metal–organic framework (MOF)17Dynamically responsive photonic metal–organic frameworks23Desolvation of metal complexes to construct metal–organic framework glasses63UiO-66 metal organic framework as stable platform for non-linear optical applications9Detection of extreme temperatures via emission from MOFs of a varied structure1Crystallographic and Spectroscopic Snapshots of Multi‐Stimuli‐Responsive Dinuclear Cobalt Metal−Organic Frameworks10First-principles screening of metal–organic frameworks for entangled photon pair generation5Grayscale to Multicolor Laser Writing Inside a Label‐Free Metal‐Organic Frameworks13Photophysical properties and photonic applications of porphyrin-based MOFs99Cobalt-based metal–organic framework (Co-MOF) thin films with high capacitance for supercapacitor electrode32Giant Second‐Order Nonlinearity and Anisotropy of Large‐Sized Few‐Layer SnS with Ferroelectric Stacking15Harvesting Multicolor Photoluminescence in Nonaromatic Interpenetrated Metal–Organic Framework Nanocrystals via Pressure‐Modulated Carbonyls Aggregation26Two dimensional Co-based metal organic framework for selective adsorption of Congo red from wastewater67Optical Phenomena in Molecule-Based Magnetic Materials154Stretchable Tb–Tb Distance Regulates the Piezofluorochromic Behavior of Chiral Tb(III)-MOF upon Compression10Reversible Phase Transformations in a Double-Walled Diamondoid Coordination Network with a Stepped Isotherm for Methane20Metal–organic frameworks for nonlinear optics and lasing17Zn(II)/Cd(II) MOFs based on 2,5-thiophenedicarboxylic acid and bis(Imidazole) linkers for highly selective and sensitive detection of Fe3+ and Cr2O72-17Efficient generation of polarization-entangled photons in metal-organic framework waveguides0Strain-Mediated Second Harmonic Generation Enhancement of Bimetallic Metal–Organic Frameworks6Theoretical Study on Second-Order Nonlinear Optical Responses of Pyrazine-carbazole Derivatives in Gas, Solution, and Crystal States7Strain Control of Third Harmonic Generation in Nb2SiTe4 Driven by Tuneable Anisotropic Characteristics5Achiral and chiral metal-organic frameworks (MOFs) as an efficient catalyst for organic synthesis47Transformation of 3D Metal–Organic Frameworks into Nanosheets with Enhanced Memristive Behavior for Electronic Data Processing8Supersaturation‐Controlled Single‐Crystal Growth of Covalent Organic Frameworks with Binary Solvents10Phenanthroline coordination-triggered structural transformation into 2D mixed-ligand lanthanide MOFs: Top-down exfoliation and sequential ratiometric sensing of Eu3+ and tetracycline2Cavity Controlled Nonlinear Optical Filtering of Second Harmonic Signal in Metal Organic Framework Single Crystals4Breathing Behaviors and CO 2 -Related Separation of Two Flexible Interpenetrating Zn 5 Cluster-Based Metal–Organic Frameworks6Metal–Organic Frameworks with a Crystal System Switch for Optical Tuning4Tunable interpenetration in anionic In-MOFs via solvent regulation: A function platform for nitroaromatic compounds detection and organic dye separation3Structure–property relationships in noncentrosymmetric solid‐state materials7Advancements in Entangled Photon Pairs in 2D Van der Waal Materials for On‐Chip Quantum Device Applications3Halogenated Metal–Organic Frameworks for Entangled Photon Pair Generation0An insight into Fe-HKUST-1@viscose composite spunlaced nonwoven material for organic dye adsorption1Metal–organic frameworks (MOFs) for nonlinear optical properties: design principles, DFT insights, and future directions for photonic applications1MOF-assisted achieving and maintaining alignment of chromophore: a strategy for simultaneously enhancing poling efficiency and long-term stability of second-order nonlinear materials0Stepwise spin transition tuned by solvent ratios in an atypical 2-fold interpenetrated PtS-type framework0The dynamic adaptability of mixed-ligand zinc MOFs: from fundaments to applications18Deconstructing and Rationalizing Interpenetration in Pillar-Layered Metal–Organic Frameworks6Coordination Geometry-Directed Optical Anisotropy and Phase-Matched Nonlinear Optics in Chiral Metal–Organic Frameworks2C 6 H 7 NCl·X (X = Cl, Br): Outstanding Multifunctional Nonlinear Optical and Birefringent Crystals Enabled by Incorporation of π‐Conjugated Moieties2MOF-assisted achieving and maintaining alignment of chromophore: a strategy for simultaneously enhancing poling efficiency and long-term stability of second-order nonlinear materials0Reversible Transformations of Topology and Partial Interpenetrations in Metal‐Organic Frameworks Triggered by Solid‐State Photo/Thermal Reactions0Metal–organic framework-based second-order nonlinear optical materials: From structural design to functional applications0Properties and applications of porphyrin-based coordination polymers and networks5Dual-Function Fluorescence Sensors Based on Interpenetrated Isomeric Cd-MOFs: Selective Detection of 2,4,6-Trinitrophenol and Nitrofurazone2Interpenetration Transformation of Diacetylene Metal–Organic Frameworks for Topochemical Polymerization0

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