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RESEARCH PAPER · Journal of Materials Chemistry · 2005

Polar ordering of polar octahedra in [C2N2H10][VOF4(H2O)]

Nicholas F. Stephens, Manfred Buck, Philip Lightfoot

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Polar ordering of polar octahedra in [C2N2H10][VOF4(H2O)]OriginalA second polymorph of [H3N(CH2)3NH3][V4O10]2Hydrothermal chemistry of oligomeric vanadium oxyfluorides57The role of temperature in the solvothermal synthesis of hybrid vanadium oxyfluorides41Novel Vanadium(IV) Oxyfluorides with ‘Spin-Ladder'-Like Structures, and Their Relationship to (VO)2P2O751Hydrothermal Vanadium Fluoride Chemistry: Four New V3+ Chain Structures29A new hybrid framework based on a ‘superoctahedral’ [V7O6F30]14− polyanion14A Luminescent Microporous Metal−Organic Framework for the Recognition and Sensing of Anions1014Hydrothermal Synthesis of Vanadium Oxyfluoride Chains Incorporating Covalently Bound Copper Coordination Complexes35Crystallisation of some mixed Na/V and K/V fluorides by solvothermal methods36Organic–inorganic hybrid chains and layers constructed from copper-amine cations and early transition metal (Nb, Mo) oxyfluoride anions21Novel building units with bimetallic rings in inorganic/organic hybrid chains and layers2Solvatothermal chemistry of organically-templated vanadium fluorides and oxyfluorides21Hydrothermal synthesis and structural characterization of bimetallic organic–inorganic hybrid materials: Copper vanadate–1,4-Carboxy-phenylphosphonate phases15Increasing the dimensionality of hybrid vanadium oxyfluorides using ionothermal synthesis31Structural chemistry of organically-templated metal fluorides61Hydrothermal synthesis and structure of a two-dimensional bimetallic copper–molybdophosphonate, [{Cu4(H2O)2(phenbisterpy)2(HO3P(CH2)4PO3H)}(Mo4FO12)2{O3P(CH2)4PO3}]·4H2O, constructed from {Mo4FO12}1− clusters and copper-ligand chains (phenbisterpy = 1,4-bis(2,2′:6′,2′′-terpyridin-4′-yl)benzene)15A new chain structure:catena-poly[4,4′-(ethane-1,2-diyl)dipyridinium bis[[aquadifluoridooxidovanadate]-μ-fluorido]]0A three-dimensional heterometallic CuI/VIV1,2-bis(1,2,4-triazol-4-yl)ethane framework: a new insight into the structure of vanadium oxyfluoride coordination hybrids2Multiferroic magnetoelectric fluorides: why are there so many magnetic ferroelectrics?130Hydrothermal syntheses and structures of vanadium oxyfluorides templated by organic and metal organic cations9The Role of Polar, Lamdba (Λ)-Shaped Building Units in Noncentrosymmetric Inorganic Structures139Inducing polarity in [VO3]nn− chain compounds using asymmetric hydrogen-bonding networks17The Dimeric [V2O4F6]4– Vanadium Oxide‐Fluoride Anion in Na2(M(H2O)2)(V2O4F6) (M = Co2+, Ni2+, and Cu2+)8AgI/VV Heterobimetallic Frameworks Generated from Novel-Type {Ag2(VO2F2)2(triazole)4} Secondary Building Blocks: A New Aspect in the Design of SVOF Hybrids59Influence of Hydrofluoric Acid Formation on Lithium Ion Insertion in Nanostructured V2O516Solid state coordination chemistry: Structural consequences of varying diphosphonate tether length and fluoride incorporation in the copper–bisterpy/oxomolybdenum/organodiphosphonate system (bisterpy = 2,2′:4′,4″:2″,2″′-quarterpyridyl-6′,6″-di-2-pyridine)16Structural consequences of fluoride incorporation into oxovanadium-xylyldiphosphonates with charge compensating copper(II)-imine components13Synthesis, Crystal Structure, Vibrational and Optical Properties of (Hdea)4(V7O19F)∙0.42H2O, an Original (V7O19F)4− Cluster Oxyfluoride9Syntheses of Two Vanadium Oxide–Fluoride Materials That Differ in Phase Matchability46A New Vanadium (V) Coordination Based on [(H2C4O4)VO2F] n 2n− Polymeric Chains and Diethylammonium Cations, Synthesis, Crystal Structure, Vibrational and Optical Properties2Synthetic strategies for new vanadium oxyfluorides containing novel building blocks: structures of V( iv ) and V( v ) containing Sr 4 V 3 O 5 F 13 , Pb 7 V 4 O 8 F 18 , Pb 2 VO 2 F 5 , and Pb 2 VOF 617Synthesis, Bonding, and Reactivity of Vanadium(IV) Oxido–Fluorido Compounds with Neutral Chelate Ligands of the General Formula cis-[VIV(═O)(F)(LN–N)2]+7Nature of phase transitions in ammonium oxofluorovanadates, a vibrational spectroscopy study of (NH4)3VO2F4 and (NH4)3VOF57Orientational disorder and phase transitions in ammonium oxofluorovanadates, (NH4)3VOF5 and (NH4)3VO2F41Design and Assembly of Covalently Functionalised Polyoxofluorovanadate Molecular Hybrids10Effect of Deuteration on Phase Transitions in Vanadium Dioxotetrafluoride2Crystal structure of tetrakis[μ-3-carboxy-1-(1,2,4-triazol-4-yl)adamantane-κ2 N 1:N 2]tetrafluoridodi-μ2-oxido-dioxidodisilver(I)divanadium(V) tetrahydrate3Hydrogen-Bond-Assisted Alignment of [MCu(SeO 3 ) 4 Cl(H 2 O)] 4– (M = Fe, Ga) Anionic Layers to Form Two Polar Oxychlorides: Pb 2 MCu(SeO 3 ) 4 Cl(H 2 O)10A Combined Experimental and Theoretical Investigation of Oxidation Catalysis by cis-[VIV(O)(Cl/F)(N4)]+ Species Mimicking the Active Center of Metal-Enzymes3Construction of Ideal One-Dimensional Spin Chains by Topochemical Dehydration/Rehydration Route13

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  1. A second polymorph of [H3N(CH2)3NH3][V4O10]

    Acta Crystallographica Section C Crystal Structure Communications · 2006-10-31

    Nicholas F. Stephens, Philip Lightfoot

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  2. Hydrothermal chemistry of oligomeric vanadium oxyfluorides

    Dalton Transactions · 2007-01-01

    David W. Aldous, Nicholas F. Stephens, Philip Lightfoot

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  3. The role of temperature in the solvothermal synthesis of hybrid vanadium oxyfluorides

    Dalton Transactions · 2007-01-01

    David W. Aldous, Nicholas F. Stephens, Philip Lightfoot

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  4. Novel Vanadium(IV) Oxyfluorides with ‘Spin-Ladder'-Like Structures, and Their Relationship to (VO)2P2O7

    Inorganic Chemistry · 2007-01-26

    David W. Aldous, Richard J. Goff, John Paul Attfield, Philip Lightfoot

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  5. Hydrothermal Vanadium Fluoride Chemistry: Four New V3+ Chain Structures

    Inorganic Chemistry · 2007-04-21

    David W. Aldous, Nicholas F. Stephens, Philip Lightfoot

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  6. A new hybrid framework based on a ‘superoctahedral’ [V7O6F30]14− polyanion

    Chemical Communications · 2008-01-01

    Thushitha Mahenthirarajah, Philip Lightfoot

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  7. A Luminescent Microporous Metal−Organic Framework for the Recognition and Sensing of Anions

    Journal of the American Chemical Society · 2008-05-01

    Banglin Chen, Liangbo Wang, Fatima Zapata, Guodong Qian, Emil B. Lobkovsky

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  8. Hydrothermal Synthesis of Vanadium Oxyfluoride Chains Incorporating Covalently Bound Copper Coordination Complexes

    Inorganic Chemistry · 2008-08-19

    Thushitha Mahenthirarajah, Yang Li, Philip Lightfoot

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  9. Crystallisation of some mixed Na/V and K/V fluorides by solvothermal methods

    Solid State Sciences · 2008-10-01

    David W. Aldous, Philip Lightfoot

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  10. Organic–inorganic hybrid chains and layers constructed from copper-amine cations and early transition metal (Nb, Mo) oxyfluoride anions

    Dalton Transactions · 2009-01-01

    Thushitha Mahenthirarajah, Yang Li, Philip Lightfoot

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  11. Novel building units with bimetallic rings in inorganic/organic hybrid chains and layers

    Journal of Solid State Chemistry · 2009-09-10

    Thushitha Mahenthirarajah, Yang Li, Philip Lightfoot

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  12. Solvatothermal chemistry of organically-templated vanadium fluorides and oxyfluorides

    Inorganica Chimica Acta · 2009-10-15

    P. DeBurgomaster, W. Ouellette, Hongxue Liu, Charles J. O’Connor, G.T. Yee, Jon A. Zubieta

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  13. Hydrothermal synthesis and structural characterization of bimetallic organic–inorganic hybrid materials: Copper vanadate–1,4-Carboxy-phenylphosphonate phases

    Inorganica Chimica Acta · 2009-10-30

    P. DeBurgomaster, Hongxue Liu, Charles J. O’Connor, Jon A. Zubieta

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  14. Increasing the dimensionality of hybrid vanadium oxyfluorides using ionothermal synthesis

    Dalton Transactions · 2010-01-01

    Farida Himeur, Phoebe K. Allan, Simon J. Teat, Richard J. Goff, Russell E. Morris, Philip Lightfoot

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  15. Structural chemistry of organically-templated metal fluorides

    Dalton Transactions · 2010-01-01

    Karim Adil, M. Leblanc, V. Maisonneuve, Philip Lightfoot

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  16. Hydrothermal synthesis and structure of a two-dimensional bimetallic copper–molybdophosphonate, [{Cu4(H2O)2(phenbisterpy)2(HO3P(CH2)4PO3H)}(Mo4FO12)2{O3P(CH2)4PO3}]·4H2O, constructed from {Mo4FO12}1− clusters and copper-ligand chains (phenbisterpy = 1,4-bis(2,2′:6′,2′′-terpyridin-4′-yl)benzene)

    Inorganic Chemistry Communications · 2010-02-05

    Stephanie Jones, Hongxue Liu, W. Ouellette, Katherine Schmidtke, Charles J. O’Connor, Jon A. Zubieta

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  17. A new chain structure:catena-poly[4,4′-(ethane-1,2-diyl)dipyridinium bis[[aquadifluoridooxidovanadate]-μ-fluorido]]

    Acta Crystallographica Section C Crystal Structure Communications · 2010-04-13

    David W. Aldous, Alexandra M. Z. Slawin, Philip Lightfoot

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  18. A three-dimensional heterometallic CuI/VIV1,2-bis(1,2,4-triazol-4-yl)ethane framework: a new insight into the structure of vanadium oxyfluoride coordination hybrids

    Acta Crystallographica Section C Crystal Structure Communications · 2010-08-27

    Olena V. Sharga, A.B. Lysenko, Harald Krautscheid, K.V. Domasevitch

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  19. Multiferroic magnetoelectric fluorides: why are there so many magnetic ferroelectrics?

    Journal of Physics Condensed Matter · 2011-03-01

    James Floyd Scott, R. Blinc

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  20. Hydrothermal syntheses and structures of vanadium oxyfluorides templated by organic and metal organic cations

    Inorganica Chimica Acta · 2011-09-10

    Tiffany M. Smith, Michael Tichenor, Jose Marcelo Vargas, Charles J. O’Connor, Jon A. Zubieta

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  21. The Role of Polar, Lamdba (Λ)-Shaped Building Units in Noncentrosymmetric Inorganic Structures

    Journal of the American Chemical Society · 2012-02-15

    Martin D. Donakowski, Romain Gautier, Jeongho Yeon, Donald T. Moore, Juan C. Nino, P. Shiv Halasyamani, Kenneth Reinhard Poeppelmeier

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  22. Inducing polarity in [VO3]nn− chain compounds using asymmetric hydrogen-bonding networks

    Journal of Solid State Chemistry · 2012-02-21

    Matthew D. Smith, Samuel M. Blau, Kelvin B. Chang, T. Thao Tran, Mat­thias Zeller, P. Shiv Halasyamani, Joshua Schrier, Alexander J. Norquist

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  23. The Dimeric [V2O4F6]4– Vanadium Oxide‐Fluoride Anion in Na2(M(H2O)2)(V2O4F6) (M = Co2+, Ni2+, and Cu2+)

    Zeitschrift für anorganische und allgemeine Chemie · 2012-06-27

    Martin D. Donakowski, Anastasiya I. Vinokur, Kenneth Reinhard Poeppelmeier

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  24. AgI/VV Heterobimetallic Frameworks Generated from Novel-Type {Ag2(VO2F2)2(triazole)4} Secondary Building Blocks: A New Aspect in the Design of SVOF Hybrids

    Inorganic Chemistry · 2012-07-25

    Ganna A. Senchyk, Valerii Bukhanko, A.B. Lysenko, Harald Krautscheid, Eduard B. Rusanov, A.N. Chernega, Mirosław Karbowiak, K.V. Domasevitch

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  25. Influence of Hydrofluoric Acid Formation on Lithium Ion Insertion in Nanostructured V2O5

    The Journal of Physical Chemistry C · 2012-09-12

    Jing Wu, Nellymar Membreño, Wen‐Yueh Yu, Jaclyn D. Wiggins-Camacho, David W. Flaherty, Charles Buddie Mullins, Keith J. Stevenson

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  26. Solid state coordination chemistry: Structural consequences of varying diphosphonate tether length and fluoride incorporation in the copper–bisterpy/oxomolybdenum/organodiphosphonate system (bisterpy = 2,2′:4′,4″:2″,2″′-quarterpyridyl-6′,6″-di-2-pyridine)

    Inorganica Chimica Acta · 2012-11-02

    Stephanie Jones, Jose Marcelo Vargas, Steven Pellizzeri, Charles J. O’Connor, Jon A. Zubieta

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  27. Structural consequences of fluoride incorporation into oxovanadium-xylyldiphosphonates with charge compensating copper(II)-imine components

    Inorganica Chimica Acta · 2013-11-28

    Tiffany M. Smith, Luke Strauskulage, Kathryn Perrin, Diona Symester, Steve R. Freund, Jose Marcelo Vargas, Leonard Spînu, Jon A. Zubieta

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  28. Synthesis, Crystal Structure, Vibrational and Optical Properties of (Hdea)4(V7O19F)∙0.42H2O, an Original (V7O19F)4− Cluster Oxyfluoride

    Journal of Cluster Science · 2014-08-14

    Issam Omri, Mohsen Graia, Tahar Mhiri

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  29. Syntheses of Two Vanadium Oxide–Fluoride Materials That Differ in Phase Matchability

    Inorganic Chemistry · 2014-08-19

    Martin D. Donakowski, Romain Gautier, Hongcheng Lu, T. Thao Tran, Jacqueline Cantwell, P. Shiv Halasyamani, Kenneth Reinhard Poeppelmeier

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  30. A New Vanadium (V) Coordination Based on [(H2C4O4)VO2F] n 2n− Polymeric Chains and Diethylammonium Cations, Synthesis, Crystal Structure, Vibrational and Optical Properties

    Journal of Cluster Science · 2014-11-08

    Issam Omri, Tahar Mhiri, Mohsen Graia

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  31. Synthetic strategies for new vanadium oxyfluorides containing novel building blocks: structures of V( iv ) and V( v ) containing Sr 4 V 3 O 5 F 13 , Pb 7 V 4 O 8 F 18 , Pb 2 VO 2 F 5 , and Pb 2 VOF 6

    CrystEngComm · 2015-01-01

    Jeongho Yeon, Justin B. Felder, Mark D. Smith, Gregory W. Morrison, Hans‐Conrad zur Loye

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  32. Synthesis, Bonding, and Reactivity of Vanadium(IV) Oxido–Fluorido Compounds with Neutral Chelate Ligands of the General Formula cis-[VIV(═O)(F)(LN–N)2]+

    Inorganic Chemistry · 2016-01-21

    Stamatis S. Passadis, Constantinos G. Tsiafoulis, Chryssoula Drouza, Athanassios C. Tsipis, Haralampos N. Miras, Anastasios D. Keramidas, Themistoklis A. Kabanos

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  33. Nature of phase transitions in ammonium oxofluorovanadates, a vibrational spectroscopy study of (NH4)3VO2F4 and (NH4)3VOF5

    Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy · 2017-01-09

    Yu. V. Gerasimova, Aleksandr S. Oreshonkov, N. M. Laptash, Alexander N. Vtyurin, А. С. Крылов, N. P. Shestakov, A.A. Ershov, A. G. Kocharova

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  34. Orientational disorder and phase transitions in ammonium oxofluorovanadates, (NH4)3VOF5 and (NH4)3VO2F4

    Acta Crystallographica Section B Structural Science Crystal Engineering and Materials · 2017-11-15

    Anatoly A. Udovenko, Evgeny I. Pogoreltsev, Yuri Marchenko, N. M. Laptash

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  35. Design and Assembly of Covalently Functionalised Polyoxofluorovanadate Molecular Hybrids

    Chemistry - A European Journal · 2018-01-10

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  36. Effect of Deuteration on Phase Transitions in Vanadium Dioxotetrafluoride

    Physics of the Solid State · 2019-02-01

    Evgeniy V. Bogdanov, E.I. Pogoreltsev, М. В. Горев, Мaxim S. Моlokeev, I. N. Flërov

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  37. Crystal structure of tetrakis[μ-3-carboxy-1-(1,2,4-triazol-4-yl)adamantane-κ2 N 1:N 2]tetrafluoridodi-μ2-oxido-dioxidodisilver(I)divanadium(V) tetrahydrate

    Acta Crystallographica Section E Crystallographic Communications · 2019-05-17

    Ganna A. Senchyk, A.B. Lysenko, Eduard B. Rusanov, K.V. Domasevitch

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  38. Hydrogen-Bond-Assisted Alignment of [MCu(SeO 3 ) 4 Cl(H 2 O)] 4– (M = Fe, Ga) Anionic Layers to Form Two Polar Oxychlorides: Pb 2 MCu(SeO 3 ) 4 Cl(H 2 O)

    Inorganic Chemistry · 2020-12-30

    Lei Geng, Chang‐Yu Meng, Hong‐Yan Lu

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  39. A Combined Experimental and Theoretical Investigation of Oxidation Catalysis by cis-[VIV(O)(Cl/F)(N4)]+ Species Mimicking the Active Center of Metal-Enzymes

    Inorganic Chemistry · 2022-11-10

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  40. Construction of Ideal One-Dimensional Spin Chains by Topochemical Dehydration/Rehydration Route

    Journal of the American Chemical Society · 2024-03-15

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