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RESEARCH PAPER · Crystal Growth & Design · 2009

Growth and Properties of Single Crystals of Noncentrosymmetric Na3VO2B6O11

Xiaoyun Fan, Shilie Pan, Xueling Hou, Xuelin Tian, Jian Wei Han, Jacob M. Haag, Kenneth Reinhard Poeppelmeier

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Growth and Properties of Single Crystals of Noncentrosymmetric Na3VO2B6O11OriginalMicrohardness properties of 4-methoxy benzaldehyde N-methyl 4-stilbazolium tosylate16A congruently melting and deep UV nonlinear optical material: Li3Cs2B5O10104Crystal growth and optical properties of a noncentrosymmetric haloid borate, K3B6O10Br91Synthesis, crystal structure and optical properties of a new lead fluoride borate with isolated [B9O21]15− unit25Li4Cs3B7O14: Synthesis, Crystal Structure, and Optical Properties84Top-Seeded Solution Growth, Morphology, and Properties of a Polar Crystal Cs2TeMo3O1277Growth, crystal structure and optical properties of layered dibarium cadmium diborate, Ba2Cd(BO3)217K3B6O10Cl: A New Structure Analogous to Perovskite with a Large Second Harmonic Generation Response and Deep UV Absorption Edge673Growth, structure and properties of the non-centrosymmetric hydrated borate CaN2B8O26H3210Thermal, optical, mechanical and dielectric properties of nonlinear optical crystal 4-methoxy benzaldehyde-N-methyl 4-stilbazolium tosylate33New bidentate non-centrosymmetric borate–malate: Synthesis, structure and characterization of RbB(dl-C4H4O5)2·H2O20A New Lithium Rubidium Borate Li6Rb5B11O22 with Isolated B11O22 Building Blocks72Polymorphism of BaTeMo 2 O 9 : A New Polar Polymorph and the Phase Transformation186Synthesis, crystal structure and optical properties of a new lead bismuth borate8Molecular Engineering Design to Resolve the Layering Habit and Polymorphism Problems in Deep UV NLO Crystals: New Structures in MM′Be2B2O6F (M═Na, M′═Ca; M═ K, M′═Ca, Sr)198Anisotropic thermal properties of the polar crystal Cs2TeMo3O1224A new noncentrosymmetric vanadoborate: synthesis, crystal structure and characterization of K2SrVB5O1222Li5Rb2B7O14: a new congruently melting compound with two kinds of B–O one-dimensional chains and short UV absorption edge25UV Nonlinear Optical Crystal Ba2[B6O9(OH)4] Featuring Unique Chiral Layers with a New B18O42 Circle Based on BO3 and BO4 Units97Structure, growth and properties of a novel polar material, KSr4B3O921Synthesis, crystal structure and properties of a new lead fluoride borate, Pb3OBO3F17Synthesis, crystal structure and properties of a new strontium cadmium diborate5Pb4VBO8: Synthesis, Crystal Structure, and Properties5Synthesis, crystal structure and properties of a new congruently melting compound, K3ZnB5O1016Synthesis, crystal structure and properties of a new lead calcium diborate7M2Cd3B16O28 (M = Rb, Cs): Two Isostructural Alkali Cadmium Borates with a New Type of Borate Layer29A combination of multiple chromophores enhances second-harmonic generation in a nonpolar noncentrosymmetric oxide: CdTeMoO681Na2Cd7B8O20: a new noncentrosymmetric compound with special [B3O7] units20New tartratoborates: synthesis, structure, and characterization of non-centrosymmetric ASr[C4H2O6B(OH)2]·4H2O (A = K+, Rb+)29Synthesis, crystal growth and characterization of a new noncentrosymmetric borophosphate: RbPbBP2O836New Molybdenum(VI) Phosphates: Synthesis, Characterization, and Calculations of Centrosymmetric RbMoO2PO4and Noncentrosymmetric Rb4Mo5P2O2239Ba2Cd(B3O6)2: A Congruent‐Melting Compound with Isolated B3O6 Units8Sr3BeB6O13: A New Borate in the SrO/BeO/B2O3 System with Novel Tri-Six-Membered Ring (BeB6O15)10– Building Block22Exploration of a new compound in the M–B–O–X (M: alkali metals; X: halogen) system: Preparation, crystal and electronic structures, and optical properties of Na3B6O10Br20Effect of Rigid Units on the Symmetry of the Framework: Design and Synthesis of Centrosymmetric NaBa4(B5O9)2F2Cl and Noncentrosymmetric NaBa4(AlB4O9)2Br350Sr8MgB18O36: a New Alkaline-Earth Borate with a Novel Zero-Dimensional (B18O36)18– Anion Ring49Synthesis, crystal structure and optical properties of Ba5V3O12F18Li 0.8 Mg 2.1 B 2 O 5 F: the first borate fluoride with magnesium–oxygen–fluorine octahedral chains20Ca 3 Be 6 B 5 O 16 F: the first alkaline-earth beryllium borate with fluorine anions11Exploring the influence of cationic skeletons on the arrangement of isolated BO 3 groups based on RbMgBO 3 , CsZn 4 (BO 3 ) 3 and Cs 4 Mg 4 (BO 3 ) 422p–(p,π*) interaction mechanism revealing and accordingly designed new member in deep-ultraviolet NLO borates Li n M n−1 B 2n−1 O 4n−2 (M = Cs/Rb, n = 3, 4, 6)52SrBeB2O5: Growth, crystal structure and optical properties13Synthesis, Crystal Structure, and Characterization of a Congruent Melting Compound Magnesium Strontium Diborate MgSrB2O58(MMgBO3)n (n = 1, M = Li, Na, K, Rb and n = 4, M = Cs): An investigation on the structure transition and optical properties8Zn 4 B 3 O 9 C 2 H 8 N 2 : an organic–inorganic hybrid borate with a novel graphene-like layer8Synthesis, crystal structure, and properties of an interesting elliptical vanadoborate housing crystal: [Ni(en)2]6[(VO)12O6B18O39(OH)3]·5H2O12Effect of cation substitution on structural transition: synthesis, characterization and theoretical studies of NaCa 4 B 3 O 9 , NaCaBO 3 , NaSrBO 3 and Li 4 CaB 2 O 618Efficient photocatalytic dechlorination of chlorophenols over a nonlinear optical material Na 3 VO 2 B 6 O 11 under UV-visible light irradiation62Evidence of “new hot spots” from determining the nonlinear optical behavior of materials: mechanistic studies of the vanadium borate crystal, Na 3 VO 2 B 6 O 1116Two New Crystals in LimCsnBm+nO2(m+n) (m + n = 5, 7; m > n) Series: Noncentrosymmetric Li5Cs2B7O14 and Centrosymmetric Li4CsB5O1016Nonlinear optical response mechanism of noncentrosymmetric lead borate Pb 6 [B 4 O 7 (OH) 2 ] 3 with three crystallographically independent [B 4 O 7 (OH) 2 ] 4− chains8Role of the metal cation types around VO 4 groups on the nonlinear optical behavior of materials: experimental and theoretical analysis19High-temperature Raman spectroscopic study of vanadoborate Na3VO2B6O112Structure, Raman and infrared spectroscopic properties of new nonlinear optical material Na3VO2B6O1111Synthesis, structure and properties of nonlinear optical crystal Li(H 2 O) 4 B(OH) 4 ·2H 2 O5A new non-centrosymmetry compound: Synthesis, crystal structure and electronic structure study of hydrated sodium borate Na2[BO2(OH)]·H2O3M 3 V 2 B 10 O 23 (M = Ca, Sr): two new vanadoborates with [V 2 B 10 O 23 ] ∞ double layers11Two haloid borate crystals with large nonlinear optical response32Two tartratoborates with hybrid anionic groups from unusual condensation reactions9Phase-Matching in Nonlinear Optical Compounds: A Materials Perspective245Li3VO4: A Promising Mid-Infrared Nonlinear Optical Material with Large Laser Damage Threshold51Optical and laser damage threshold studies on 1, 3, 5-triphenylbenzene scintillator crystal grown by Sankaranarayanan-Ramasamy (SR) technique8Pb 10 V 6 O 25 : A new lead vanadate with apatite structure3Flux Exploration, Growth, and Optical Spectroscopic Properties of Large Size LaBSiO5 and Eu3+-Substituted LaBSiO5 Crystals16Crystal Growth and Optical Properties of Beryllium-Free Nonlinear Optical Crystal K3Ba3Li2Al4B6O20F35Charge transfer from internal electrostatic fields is superior to surface defects for 2,4-dichlorophenol degradation in K 3−x Na x B 6 O 10 Br photocatalysts16Second-order nonlinear optical crystals with mixed anions251NaCa4V5O17 with isolated V2O7 dimer and V3O10 trimer exhibiting a large birefringence19BaV2O6·H2O: A nonlinear optical crystal with a large bandgap7Noncentrosymmetric Sulfide Oxide MZnSO (M = Ca or Sr) with Strongly Polar Structure as Novel Nonlinear Crystals43Mechanistic insights into efficient reversible hydrogen storage in ferrotitanium30Vanadoborates: cluster-based architectures, preparation and properties36Spatial separation of photo-induced charge carriers in a Na3VO2B6O11 polar material and its enhanced photocatalytic activity11A Theoretical Perspective on Strategies for Modeling High Performance Nonlinear Optical Materials92Growth and Characterization of a Nonlinear Optical Crystal Cd3Te2WO10 Decorated by WO4 Tetrahedra Showing a Large Band Gap9Synthesis and characterization of Cs 2 Zn 4 V 4 O 15 —a new vanadate in the Cs–Zn–V–O quaternary system5Synthesis and proton conducting ability of a crystalline 3-D vanadoborate with [V 6 B 20 ] architectures4Cd8(BO3)4SiO4: Metal Cation Inducing the Formation of Isolated [BO3] and [SiO4] Units in Borate Silicate15Three in one: a cadmium bismuth vanadate NLO crystal exhibiting a large second-harmonic generation response and enhanced birefringence12Two new 3-D vanadoborates incorporating rare polymeric K-O-K chain or network with photocatalytic properties8Research progress in the chemistry of novel vanadoborates with extended structures of heteropolyvanadates0Exploring quaternary vanadates containing alkali metals, alkaline earth metals, and [VO 4 ] in the quest for nonlinear optical materials1Analyzing second and third harmonic generation in multilayered quantum dots: Effects of alloy composition and layer structure6Promising UV/DUV nonlinear optical materials with X-membered (X = multiples of 6) rings in anhydrous inorganic borates20Substituted polyoxovanadates: a comprehensive review of synthetic strategies, structural evolution and multifunctional applications0Investigation on the crystal growth, spectroscopic, third harmonic generation studies and photocatalytic studies of organic–inorganic hybrid material complex single crystal0Enhanced third-harmonic generation in Al-based nanostructures: Implications for integrated optical device design0

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  1. Microhardness properties of 4-methoxy benzaldehyde N-methyl 4-stilbazolium tosylate

    Materials Letters · 2010-09-19

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  2. A congruently melting and deep UV nonlinear optical material: Li3Cs2B5O10

    Journal of Materials Chemistry · 2011-01-01

    Yun Mo Yang, Shilie Pan, Xueling Hou, Chuanyi Wang, Kenneth Reinhard Poeppelmeier, Zhaohui Chen, Hongping Wu, Zhongxiang Zhou

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  3. Crystal growth and optical properties of a noncentrosymmetric haloid borate, K3B6O10Br

    CrystEngComm · 2011-01-01

    Min Zhang, Shi-Lie Pan, Xiao-Yun Fan, Zhou Zhong-Xiang, Kenneth Reinhard Poeppelmeier, Yun Mo Yang

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  4. Synthesis, crystal structure and optical properties of a new lead fluoride borate with isolated [B9O21]15− unit

    Inorganic Chemistry Communications · 2011-02-04

    Wenwu Zhao, Shilie Pan, Jian Wei Han, Zhongxiang Zhou, Xuelin Tian, Junjie Li

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  5. Li4Cs3B7O14: Synthesis, Crystal Structure, and Optical Properties

    Inorganic Chemistry · 2011-02-21

    Yun Mo Yang, Shilie Pan, Hongyi Li, Jian Wei Han, Zhaohui Chen, Wenwu Zhao, Zhongxiang Zhou

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  6. Top-Seeded Solution Growth, Morphology, and Properties of a Polar Crystal Cs2TeMo3O12

    Crystal Growth & Design · 2011-03-25

    Junjie Zhang, Xutang Tao, Youxuan Sun, Zhonghan Zhang, Chengqian Zhang, Zeliang Gao, Haibing Xia, Sheng‐Qing Xia

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  7. Growth, crystal structure and optical properties of layered dibarium cadmium diborate, Ba2Cd(BO3)2

    Journal of Alloys and Compounds · 2011-04-15

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  8. K3B6O10Cl: A New Structure Analogous to Perovskite with a Large Second Harmonic Generation Response and Deep UV Absorption Edge

    Journal of the American Chemical Society · 2011-05-02

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  9. Growth, structure and properties of the non-centrosymmetric hydrated borate CaN2B8O26H32

    Materials Chemistry and Physics · 2011-05-11

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  10. Thermal, optical, mechanical and dielectric properties of nonlinear optical crystal 4-methoxy benzaldehyde-N-methyl 4-stilbazolium tosylate

    Journal of Physics and Chemistry of Solids · 2011-05-24

    Amirdha Sher Gill, S. Kalainathan

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  11. New bidentate non-centrosymmetric borate–malate: Synthesis, structure and characterization of RbB(dl-C4H4O5)2·H2O

    Materials Chemistry and Physics · 2011-06-18

    Zhaohui Chen, Shilie Pan, Hongping Wu, Yun Mo Yang, Xiaoyun Fan

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  12. A New Lithium Rubidium Borate Li6Rb5B11O22 with Isolated B11O22 Building Blocks

    Crystal Growth & Design · 2011-07-15

    Yun Mo Yang, Shilie Pan, Jian Wei Han, Xueling Hou, Zhongxiang Zhou, Wenwu Zhao, Zhaohui Chen, Min Zhang

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  13. Polymorphism of BaTeMo 2 O 9 : A New Polar Polymorph and the Phase Transformation

    Chemistry of Materials · 2011-07-25

    Junjie Zhang, Zhonghan Zhang, Weiguo Zhang, Qingxin Zheng, Youxuan Sun, Chengqian Zhang, Xutang Tao

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  14. Synthesis, crystal structure and optical properties of a new lead bismuth borate

    Inorganica Chimica Acta · 2011-10-16

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  15. Molecular Engineering Design to Resolve the Layering Habit and Polymorphism Problems in Deep UV NLO Crystals: New Structures in MM′Be2B2O6F (M═Na, M′═Ca; M═ K, M′═Ca, Sr)

    Chemistry of Materials · 2011-11-17

    Hongwei Huang, Jiyong Yao, Zheshuai Lin, Xiaoyang Wang, Ran He, Wenjiao Yao, Naixia Zhai, Chuangtian Chen

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  16. Anisotropic thermal properties of the polar crystal Cs2TeMo3O12

    Journal of Solid State Chemistry · 2011-12-22

    Junjie Zhang, Zhonghan Zhang, Youxuan Sun, Chengqian Zhang, Xutang Tao

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  17. A new noncentrosymmetric vanadoborate: synthesis, crystal structure and characterization of K2SrVB5O12

    Dalton Transactions · 2012-01-01

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  18. Li5Rb2B7O14: a new congruently melting compound with two kinds of B–O one-dimensional chains and short UV absorption edge

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    Yun Mo Yang, Shilie Pan, Xueling Hou, Xiaoyu Dong, Xin Su, Zhihua Yang, Min Zhang, Wenwu Zhao, Zhaohui Chen

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  19. UV Nonlinear Optical Crystal Ba2[B6O9(OH)4] Featuring Unique Chiral Layers with a New B18O42 Circle Based on BO3 and BO4 Units

    Inorganic Chemistry · 2012-01-19

    Li Wang, Shilie Pan, Li‐Xian Chang, Jianyang Hu, Hongwei Yu

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  20. Structure, growth and properties of a novel polar material, KSr4B3O9

    Journal of Solid State Chemistry · 2012-01-20

    Wenwu Zhao, Shilie Pan, Yongjiang Wang, Zhihua Yang, Xian Wang, Jian Wei Han

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  21. Synthesis, crystal structure and properties of a new lead fluoride borate, Pb3OBO3F

    Materials Research Bulletin · 2012-02-01

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  22. Synthesis, crystal structure and properties of a new strontium cadmium diborate

    Inorganica Chimica Acta · 2012-03-16

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  23. Pb4VBO8: Synthesis, Crystal Structure, and Properties

    Chemistry Letters · 2012-04-01

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  24. Synthesis, crystal structure and properties of a new congruently melting compound, K3ZnB5O10

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  25. Synthesis, crystal structure and properties of a new lead calcium diborate

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    Jian Hua Cao, Shilie Pan, Junyu Gao, Zhenjun Huang, Xiaoyu Dong, Min Zhang

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  26. M2Cd3B16O28 (M = Rb, Cs): Two Isostructural Alkali Cadmium Borates with a New Type of Borate Layer

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  27. A combination of multiple chromophores enhances second-harmonic generation in a nonpolar noncentrosymmetric oxide: CdTeMoO6

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  28. Na2Cd7B8O20: a new noncentrosymmetric compound with special [B3O7] units

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  29. New tartratoborates: synthesis, structure, and characterization of non-centrosymmetric ASr[C4H2O6B(OH)2]·4H2O (A = K+, Rb+)

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  30. Synthesis, crystal growth and characterization of a new noncentrosymmetric borophosphate: RbPbBP2O8

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  31. New Molybdenum(VI) Phosphates: Synthesis, Characterization, and Calculations of Centrosymmetric RbMoO2PO4and Noncentrosymmetric Rb4Mo5P2O22

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  32. Ba2Cd(B3O6)2: A Congruent‐Melting Compound with Isolated B3O6 Units

    Zeitschrift für anorganische und allgemeine Chemie · 2013-04-26

    Xiaoyu Dong, Liang Cui, Yunjing Shi, Shilie Pan, Zhongxiang Zhou, Zhihua Yang, Bingbing Zhang, Xiangzhan Jiang, Yun Mo Yang, Zhaohui Chen, Zhenjun Huang

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  33. Sr3BeB6O13: A New Borate in the SrO/BeO/B2O3 System with Novel Tri-Six-Membered Ring (BeB6O15)10– Building Block

    Inorganic Chemistry · 2013-05-03

    Wenjiao Yao, Hongwei Huang, Jiyong Yao, Tao Xu, Xingxing Jiang, Zheshuai Lin, Chuangtian Chen

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  34. Exploration of a new compound in the M–B–O–X (M: alkali metals; X: halogen) system: Preparation, crystal and electronic structures, and optical properties of Na3B6O10Br

    Inorganica Chimica Acta · 2013-05-06

    Zhaohui Chen, Shilie Pan, Xiaoyu Dong, Zhihua Yang, Min Zhang, Xin Su

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  35. Effect of Rigid Units on the Symmetry of the Framework: Design and Synthesis of Centrosymmetric NaBa4(B5O9)2F2Cl and Noncentrosymmetric NaBa4(AlB4O9)2Br3

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    Hongwei Yu, Shilie Pan, Hongping Wu, Zhihua Yang, Lingyun Dong, Xin Su, Bingbing Zhang, Hongyi Li

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  36. Sr8MgB18O36: a New Alkaline-Earth Borate with a Novel Zero-Dimensional (B18O36)18– Anion Ring

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  37. Synthesis, crystal structure and optical properties of Ba5V3O12F

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  38. Li 0.8 Mg 2.1 B 2 O 5 F: the first borate fluoride with magnesium–oxygen–fluorine octahedral chains

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  39. Ca 3 Be 6 B 5 O 16 F: the first alkaline-earth beryllium borate with fluorine anions

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  40. Exploring the influence of cationic skeletons on the arrangement of isolated BO 3 groups based on RbMgBO 3 , CsZn 4 (BO 3 ) 3 and Cs 4 Mg 4 (BO 3 ) 4

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  41. p–(p,π*) interaction mechanism revealing and accordingly designed new member in deep-ultraviolet NLO borates Li n M n−1 B 2n−1 O 4n−2 (M = Cs/Rb, n = 3, 4, 6)

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  42. SrBeB2O5: Growth, crystal structure and optical properties

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  43. Synthesis, Crystal Structure, and Characterization of a Congruent Melting Compound Magnesium Strontium Diborate MgSrB2O5

    Zeitschrift für anorganische und allgemeine Chemie · 2014-03-25

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  44. (MMgBO3)n (n = 1, M = Li, Na, K, Rb and n = 4, M = Cs): An investigation on the structure transition and optical properties

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  45. Zn 4 B 3 O 9 C 2 H 8 N 2 : an organic–inorganic hybrid borate with a novel graphene-like layer

    New Journal of Chemistry · 2014-09-30

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  46. Synthesis, crystal structure, and properties of an interesting elliptical vanadoborate housing crystal: [Ni(en)2]6[(VO)12O6B18O39(OH)3]·5H2O

    Journal of Alloys and Compounds · 2014-11-07

    Xiangzhan Jiang, Xiaoyu Dong, Shilie Pan, Jian Wei Han, Yun Mo Yang, Fangyuan Zhang, Hongwei Yu

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  47. Effect of cation substitution on structural transition: synthesis, characterization and theoretical studies of NaCa 4 B 3 O 9 , NaCaBO 3 , NaSrBO 3 and Li 4 CaB 2 O 6

    Physical Chemistry Chemical Physics · 2015-01-01

    Yun Mo Yang, Xin Su, Shilie Pan, Zhihua Yang

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  48. Efficient photocatalytic dechlorination of chlorophenols over a nonlinear optical material Na 3 VO 2 B 6 O 11 under UV-visible light irradiation

    Journal of Materials Chemistry A · 2015-01-01

    Xiaoyun Fan, Kangrong Lai, Lichang Wang, Hengshan Qiu, Jiao Yin, Pengjun Zhao, Shilie Pan, Jinbao Xu, Chuanyi Wang

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  49. Evidence of “new hot spots” from determining the nonlinear optical behavior of materials: mechanistic studies of the vanadium borate crystal, Na 3 VO 2 B 6 O 11

    Physical Chemistry Chemical Physics · 2015-01-01

    Xin Su, Zhihua Yang, Ming‐Hsien Lee, Shilie Pan, Ying Wang, Xiaoyun Fan, Zhenjun Huang, Bingbing Zhang

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  50. Two New Crystals in LimCsnBm+nO2(m+n) (m + n = 5, 7; m > n) Series: Noncentrosymmetric Li5Cs2B7O14 and Centrosymmetric Li4CsB5O10

    Inorganic Chemistry · 2015-07-21

    Lin Li, Shujuan Han, Bing‐Hua Lei, Xiaoyu Dong, Hongping Wu, Zhongxiang Zhou, Zhihua Yang, Shilie Pan

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