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RESEARCH PAPER · Angewandte Chemie · 2024

Molecular Crystals Constructed by Polar Molecular Cages: A Promising System for Exploring High‐performance Infrared Nonlinear Optical Crystals

Xin Lei Zhao, Chensheng Lin, Chao Wang, Haotian Tian, Tao Yan, Bingxuan Li, Ning Ye, Min Luo

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Molecular Crystals Constructed by Polar Molecular Cages: A Promising System for Exploring High‐performance Infrared Nonlinear Optical CrystalsOriginalP4Sn (n = 3, 5, 7): Large Birefringence Enhanced by 3D Aromaticity and Packing Effect Induced Directional π–π Noncovalent Interactions6Five-Membered [C 5 O 5 ] 2 – Rings as Birefringence-Active Genes for Ultrabirefringent Crystals27Reactive flux assisted metal oxide–boron–sulfur routine for syntheses of CsRESiS 4 (RE = Sm, Gd–Ho): featuring nonlinear optical activity and wide band gaps5Two-dimensional organic-inorganic molecular cocrystal1Positional Isomerism Controls Polarity and Nonlinear Optical Properties in One‐Dimensional Hybrid Germanium Halides0Mineral‐Inspired and Computation‐Assisted Rational Design of Polar Gittinsite‐Type Thiophosphates With Exceptional Nonlinear Optical Performance3

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  1. P4Sn (n = 3, 5, 7): Large Birefringence Enhanced by 3D Aromaticity and Packing Effect Induced Directional π–π Noncovalent Interactions

    Advanced Optical Materials · 2025-04-11

    Wei Wu, Yi‐Bing Huang, Si‐Fan Lu, Jia Gao, Yan Guo, Wei‐Qi Huang, Meng‐Na Jing, Xiao‐Ming Jiang, Guo‐Cong Guo

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  2. Five-Membered [C 5 O 5 ] 2 – Rings as Birefringence-Active Genes for Ultrabirefringent Crystals

    Journal of the American Chemical Society · 2025-09-16

    Jiachen Lu, Yang Li, Kang Min Ok

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  3. Reactive flux assisted metal oxide–boron–sulfur routine for syntheses of CsRESiS 4 (RE = Sm, Gd–Ho): featuring nonlinear optical activity and wide band gaps

    Inorganic Chemistry Frontiers · 2025-11-05

    Zhen-Cheng Wu, Fang-Xu Tian, Rui Xiao, Mao-Yin Ran, Wenlong Liu, Wen-Tong Chen, Sheng-Ping Guo

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  4. Two-dimensional organic-inorganic molecular cocrystal

    National Science Review · 2025-11-07

    Yiran Ma, Zhichen Xu, Haidi Liu, Xinliang Feng, Jie Liu, Decai Ouyang, Zongdong Sun, Huihui Ding, Lingyi Ao, Yue Hu, Hao Peng, Dehui Li, Ying‐Shuang Fu, Hongtao Yuan, Yongli Yan, Yuanping Yi, Meihui Wang, Tianyou Zhai

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  5. Positional Isomerism Controls Polarity and Nonlinear Optical Properties in One‐Dimensional Hybrid Germanium Halides

    Angewandte Chemie · 2026-04-29

    Shaohua Xiao, Xingxing Jiang, Kaining Duanmu, Chao Wu, Zheshuai Lin, Zhipeng Huang, Jinhu Yang, Mark Graeme Humphrey, C L Zhang

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  6. Mineral‐Inspired and Computation‐Assisted Rational Design of Polar Gittinsite‐Type Thiophosphates With Exceptional Nonlinear Optical Performance

    Advanced Functional Materials · 2026-08-06

    Mao‐Yin Ran, Shao-Peng Gui, Jian Cheng, Yu‐Xuan Zhang, Wen‐Dong Yao, Wenlong Liu, Sheng‐Ping Guo

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