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RESEARCH PAPER · Inorganic Chemistry Frontiers · 2022

Cd(NH 2 SO 3 ) 2 · x H 2 O ( x = 0, 2): new sulfamates with a unique coordination environment and reversible phase transitions

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Cd(NH 2 SO 3 ) 2 · x H 2 O ( x = 0, 2): new sulfamates with a unique coordination environment and reversible phase transitionsOriginalSr(NO 3 )(NH 2 SO 3 )·H 2 O: First Nitrate Sulfamate Revealing Remarkable Second Harmonic Generation and Optimized Birefringence25Sr(NH2SO3)(NO3)·H2O: An Ultraviolet Nonlinear Optical Material Exhibiting Strong Second-Harmonic Generation Response and Sufficient Birefringence10Designing Sulfate Crystals with Strong Optical Anisotropy through π‐Conjugated Tailoring51Designing Sulfate Crystals with Strong Optical Anisotropy through π‐Conjugated Tailoring11Deep‐Ultraviolet Transparent Mixed Metal Sulfamates with Enhanced Nonlinear Optical Properties and Birefringence11Deep‐Ultraviolet Transparent Mixed Metal Sulfamates with Enhanced Nonlinear Optical Properties and Birefringence75NaB(OH) 3 CH 3 : a deep-ultraviolet optical crystal with unprecedented methyl-modified [B(OH) 3 CH 3 ] units6Designing Strong Polarity and High Configurational Entropy Flexible Units toward Excellent Ultraviolet Nonlinear Optical Materials42Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering61Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering4Strategically designed anisotropic organic–inorganic metal halides (OIMHs) with superior balance between bandgap and birefringence13Metal Cation Engineered UV Birefringent Crystals in π‐Conjugated Sulfonates with Record‐High Optical Anisotropy17La(SO3NH2)2NO3·H2O: synergistic anion engineering of the first rare-earth nitrate sulfamate defying transparency-birefringence-nonlinearity trade-offs in ultraviolet nonlinear optics8Organic Halogen Substitution-Driven Halogen Bonding Induces Polar 3D Supramolecular Framework and Second-Harmonic-Generation Response7A[N(SO 2 NH 2 ) 2 ] (A = Na, K, Rb, and Cs): enhancing birefringence of non π-conjugated deep-ultraviolet crystals via novel dimeric disulfonamide [N(SO 2 NH 2 ) 2 ] − groups0Strategically designed deep-ultraviolet optical crystals with balanced properties by small heteroatom substitution1Synergistic Enhancement of Optical Anisotropy in Nitrate Sulfamate for UV Applications: Role of Functional Group Alignment and Hydrogen Bond Network1Cation-sulfur-driven dimensional reduction engineering for tailoring sulfonate birefringent crystals with enhanced anisotropy2Coordination-Mode-Modulated Symmetry Breaking for Nonlinear Optical Crystals0Assembly of dual π-conjugated units toward enhanced birefringence in a 2D organic sulfonate crystal0

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  1. Sr(NO 3 )(NH 2 SO 3 )·H 2 O: First Nitrate Sulfamate Revealing Remarkable Second Harmonic Generation and Optimized Birefringence

    Small Structures · 2023-09-13

    Xuefei Wang, Yang Li, Zilong Chen, Jihyun Lee, Fangfang Zhang, Kenneth Reinhard Poeppelmeier, Shilie Pan, Kang Min Ok

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  2. Sr(NH2SO3)(NO3)·H2O: An Ultraviolet Nonlinear Optical Material Exhibiting Strong Second-Harmonic Generation Response and Sufficient Birefringence

    Inorganic Chemistry · 2023-10-20

    Xia Hao, Chensheng Lin, Min Luo, Ning Ye

    Read original paper ↗ ·
  3. Designing Sulfate Crystals with Strong Optical Anisotropy through π‐Conjugated Tailoring

    Angewandte Chemie International Edition · 2023-10-27

    Zhiyong Bai, Kang Min Ok

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  4. Designing Sulfate Crystals with Strong Optical Anisotropy through π‐Conjugated Tailoring

    Angewandte Chemie · 2023-10-27

    Zhiyong Bai, Kang Min Ok

    Read original paper ↗ ·
  5. Deep‐Ultraviolet Transparent Mixed Metal Sulfamates with Enhanced Nonlinear Optical Properties and Birefringence

    Angewandte Chemie · 2023-11-17

    Xuefei Wang, Xudong Leng, Yunseung Kuk, Jihyun Lee, Qun Jing, Kang Min Ok

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  6. Deep‐Ultraviolet Transparent Mixed Metal Sulfamates with Enhanced Nonlinear Optical Properties and Birefringence

    Angewandte Chemie International Edition · 2023-11-17

    Xuefei Wang, Xudong Leng, Yunseung Kuk, Jihyun Lee, Qun Jing, Kang Min Ok

    Read original paper ↗ ·
  7. NaB(OH) 3 CH 3 : a deep-ultraviolet optical crystal with unprecedented methyl-modified [B(OH) 3 CH 3 ] units

    Journal of Materials Chemistry C · 2024-01-01

    Chenhui Hu, Huimin Li, Jian Wei Han, Xueling Hou, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·
  8. Designing Strong Polarity and High Configurational Entropy Flexible Units toward Excellent Ultraviolet Nonlinear Optical Materials

    Advanced Functional Materials · 2024-04-15

    Haotian Tian, Chensheng Lin, Bingxuan Li, Xin Lei Zhao, Tao Yan, Ning Ye, Min Luo

    Read original paper ↗ ·
  9. Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering

    Angewandte Chemie International Edition · 2024-08-15

    Huan Zhou, Meng Cheng, Dongdong Chu, Xu Liu, Ran An, Shilie Pan, Shilie Pan, Zhihua Yang

    Read original paper ↗ ·
  10. Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering

    Angewandte Chemie · 2024-08-15

    Huan Zhou, Meng Cheng, Dongdong Chu, Xu Liu, Ran An, Shilie Pan, Zhihua Yang

    Read original paper ↗ ·
  11. Strategically designed anisotropic organic–inorganic metal halides (OIMHs) with superior balance between bandgap and birefringence

    Inorganic Chemistry Frontiers · 2024-12-16

    Mingchang Wang, Huaiyu Wu, Miao‐Bin Xu, Jiajia Li, Ke‐Zhao Du, Jin Chen

    Read original paper ↗ ·
  12. Metal Cation Engineered UV Birefringent Crystals in π‐Conjugated Sulfonates with Record‐High Optical Anisotropy

    Small · 2025-04-07

    Zichang Wang, Qing‐Yu Liu, Zhihua Yang, Xueling Hou, Minqiang Gai

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  13. La(SO3NH2)2NO3·H2O: synergistic anion engineering of the first rare-earth nitrate sulfamate defying transparency-birefringence-nonlinearity trade-offs in ultraviolet nonlinear optics

    Science China Chemistry · 2025-08-08

    Huan Zhou, Meng Cheng, Shilie Pan, Zhihua Yang

    Read original paper ↗ ·
  14. Organic Halogen Substitution-Driven Halogen Bonding Induces Polar 3D Supramolecular Framework and Second-Harmonic-Generation Response

    Inorganic Chemistry · 2025-09-17

    Mingchang Wang, Jiajia Li, Yan Chen, Ke‐Zhao Du, Jin Chen

    Read original paper ↗ ·
  15. A[N(SO 2 NH 2 ) 2 ] (A = Na, K, Rb, and Cs): enhancing birefringence of non π-conjugated deep-ultraviolet crystals via novel dimeric disulfonamide [N(SO 2 NH 2 ) 2 ] − groups

    Inorganic Chemistry Frontiers · 2026-01-01

    Yuchen Yan, Xin Wen, Jindong Chen, Jiyang Wang, Zhanggui Hu, Ning Ye, Guang Peng

    Read original paper ↗ ·
  16. Strategically designed deep-ultraviolet optical crystals with balanced properties by small heteroatom substitution

    Inorganic Chemistry Frontiers · 2026-01-01

    Mei Hu, Zhencheng Wu, Xin Su, Hongheng Chen, Qun Jing, Zhaohui Chen, Ming‐Hsien Lee

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  17. Synergistic Enhancement of Optical Anisotropy in Nitrate Sulfamate for UV Applications: Role of Functional Group Alignment and Hydrogen Bond Network

    Small · 2026-04-09

    Xiaotian Ma, Hongyuan Sha, Qianzhen Zhang, Ruyi Niu, Xiya Wen, Xifa Long, Shilie Pan, Yun Mo Yang

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  18. Cation-sulfur-driven dimensional reduction engineering for tailoring sulfonate birefringent crystals with enhanced anisotropy

    Chinese Journal of Structural Chemistry · 2026-05-02

    Hanjing Huang, Longyun Xu, Wenli Zhao, Huijian Zhao, Xianghao Kong, Ning Ye, Zhanggui Hu, Conggang Li

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  19. Coordination-Mode-Modulated Symmetry Breaking for Nonlinear Optical Crystals

    Inorganic Chemistry · 2026-08-24

    Lan Wang, Zhen Qin, Shu‐Fang Li, Xin-Ran Hao, Chu Chu, Bingbing Zhang, Dong Yan

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  20. Assembly of dual π-conjugated units toward enhanced birefringence in a 2D organic sulfonate crystal

    Science China Chemistry · 2026-09-15

    Longyun Xu, Hanjing Huang, Conggang Li, Huijian Zhao, Conghe Liu, Kaidong Xu, Jina Wang, Ning Ye, Zhanggui Hu

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