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RESEARCH PAPER · Inorganic Chemistry · 2022

NaHSO4·H2O: A Promising Deep-Ultraviolet Nonlinear-Optical Bisulfate with Large Birefringence and a Second-Harmonic-Generation Effect

Han Li, Haotian Tian, Chensheng Lin, Xin Lei Zhao, Chao Wang, Ning Ye, Min Luo

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NaHSO4·H2O: A Promising Deep-Ultraviolet Nonlinear-Optical Bisulfate with Large Birefringence and a Second-Harmonic-Generation EffectOriginalRecent progress of newly developed functional building units and corresponding nonlinear optical materials14Li2.9Cs1.1(SO4)2: An Ultraviolet Transparent Sulfate as a Nonlinear Optical Crystal16YSO4F·H2O: A Deep-Ultraviolet Birefringent Rare-Earth Sulfate Fluoride with Enhanced Birefringence Induced by Fluorinated Y-Centered Polyhedra19Exceptional Optical Anisotropy Enhancement Achieved Through Dual‐Ions Cosubstitution Strategy in Novel Hybrid Bismuth Halides23A Universal Design Strategy Achieving Large Birefringence and Short Phase‐Matching Capability of Optical Materials via Dissimilating Non‐π‐Conjugated Units6(C4H6N3O)(HSO4): A Cytosinium Bisulfate with Large Birefringence and Moderate Second Harmonic Generation Effect Produced via Combining a Promising Planar Nonlinear Optical-Active Motif with a Tetrahedral Group13A3Sc(SO4)3 (A = K, Rb, Cs): Three Deep‐Ultraviolet Transparent Alkali‐Scandium Sulfates with Strong Second‐Harmonic Generation Response and High Thermal Stability14NaK5La2(SO4)6: Enhanced Birefringence of Multiple-Alkali Metal Sulfate Systems via Rare Earth Metal-Centered Polyhedra5Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering61Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering4Sb2(TeO4)(SO4): An Anhydrous Tellurite Sulfate with Large Birefringence and Enhanced Thermal Stability8Multifunctional Cd‐based Hybrid with Large Birefringence Achieving Excellent Second Harmonic Generation and Reversible Temperature‐Activated Fluorescence for Anti‐counterfeiting16Hybrid Cd 2+ -Based Halide Birefringent Crystals Achieving Tunable Dual-Color Emission for Multifunctional LED and Anticounterfeiting Applications2RbLa(SO 4 ) 2 : A KBBF-like Deep-UV Transparent Rare Earth Sulfate with Strong SHG Response and High Thermal Stability Enabled by Multicomponent Structural Design2Rational Design of a Strong Nonlinear Optical Crystal With Ultrawide Bandgap via Fine‐Tuning of Channel Structures0A Hydrogen-Bonded Molecular Crystal with Strong Optical Anisotropy and Large Second-Harmonic Generation Response0

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  1. Recent progress of newly developed functional building units and corresponding nonlinear optical materials

    Chinese Journal of Structural Chemistry · 2023-05-11

    Wenjing Tan, Chenyang Zhang, Chenyang Zhang, Tingting Huang, Bingbing Zhang

    Read original paper ↗ ·

  2. Li2.9Cs1.1(SO4)2: An Ultraviolet Transparent Sulfate as a Nonlinear Optical Crystal

    Crystal Growth & Design · 2023-06-27

    Wen Zhi Yang, Lehui Liu, Lizhen Zhang, Yisheng Huang, Feifei Yuan, Zhoubin Lin

    Read original paper ↗ ·

  3. YSO4F·H2O: A Deep-Ultraviolet Birefringent Rare-Earth Sulfate Fluoride with Enhanced Birefringence Induced by Fluorinated Y-Centered Polyhedra

    Inorganic Chemistry · 2023-10-12

    Dong‐Xue Jiao, Huili Zhang, Xiao-Fei Li, Chao He, Jinhua Li, Qi Wei, Guo‐Yu Yang

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  4. Exceptional Optical Anisotropy Enhancement Achieved Through Dual‐Ions Cosubstitution Strategy in Novel Hybrid Bismuth Halides

    Small · 2024-01-17

    Zhiyong Bai, Kang Min Ok

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  5. A Universal Design Strategy Achieving Large Birefringence and Short Phase‐Matching Capability of Optical Materials via Dissimilating Non‐π‐Conjugated Units

    Advanced Optical Materials · 2024-04-18

    Huan Zhou, Shan Shu, Abudukadi Tudi, Wenqi Jin, Shilie Pan, Zhihua Yang

    Read original paper ↗ ·

  6. (C4H6N3O)(HSO4): A Cytosinium Bisulfate with Large Birefringence and Moderate Second Harmonic Generation Effect Produced via Combining a Promising Planar Nonlinear Optical-Active Motif with a Tetrahedral Group

    Inorganic Chemistry · 2024-05-31

    Meng-Han Lv, Shu‐Fang Li, Jing Wang, Jiaxin Wang, Ru‐Ling Tang, Hongbo Huang, Bingbing Zhang, Dong Yan

    Read original paper ↗ ·

  7. A3Sc(SO4)3 (A = K, Rb, Cs): Three Deep‐Ultraviolet Transparent Alkali‐Scandium Sulfates with Strong Second‐Harmonic Generation Response and High Thermal Stability

    Advanced Optical Materials · 2024-07-16

    Zilong Geng, Ruibiao Fu, Zuju Ma, Xintao Wu

    Read original paper ↗ ·

  8. NaK5La2(SO4)6: Enhanced Birefringence of Multiple-Alkali Metal Sulfate Systems via Rare Earth Metal-Centered Polyhedra

    Inorganic Chemistry · 2024-07-22

    Lehui Liu, Feifei Yuan, Lizhen Zhang, Yisheng Huang, Zhoubin Lin

    Read original paper ↗ ·

  9. Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering

    Angewandte Chemie International Edition · 2024-08-15

    Huan Zhou, Meng Cheng, Dongdong Chu, Xu Liu, Ran An, Shilie Pan, Shilie Pan, Zhihua Yang

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  10. Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering

    Angewandte Chemie · 2024-08-15

    Huan Zhou, Meng Cheng, Dongdong Chu, Xu Liu, Ran An, Shilie Pan, Zhihua Yang

    Read original paper ↗ ·

  11. Sb2(TeO4)(SO4): An Anhydrous Tellurite Sulfate with Large Birefringence and Enhanced Thermal Stability

    Inorganic Chemistry · 2025-04-08

    Xi-Ming Dong, Kai Huang, Hui‐Yan Zhao, Chao He, Xing‐Tao An, Qi Wei, Guo‐Yu Yang

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  12. Multifunctional Cd‐based Hybrid with Large Birefringence Achieving Excellent Second Harmonic Generation and Reversible Temperature‐Activated Fluorescence for Anti‐counterfeiting

    Advanced Optical Materials · 2025-05-21

    Duanliang Wang, Qiwei Xing, Defu Sun, Chuanrui Zhu, Kui Wu, Bingbing Zhang, Guangxia Liu, Jiyang Wang, Chuanying Shen

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  13. Hybrid Cd 2+ -Based Halide Birefringent Crystals Achieving Tunable Dual-Color Emission for Multifunctional LED and Anticounterfeiting Applications

    ACS Applied Materials & Interfaces · 2026-01-14

    Duanliang Wang, Qiwei Xing, Zhengao Xie, Xunwang Yan, Chuanrui Zhu, Bingbing Zhang, Xiao‐Wu Lei, Chuanying Shen

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  14. RbLa(SO 4 ) 2 : A KBBF-like Deep-UV Transparent Rare Earth Sulfate with Strong SHG Response and High Thermal Stability Enabled by Multicomponent Structural Design

    Inorganic Chemistry · 2026-02-02

    Ye Tao, Xiaohui Zhang, Chenglong Xu, Qianshuang Lu, J. N. Tan, Yingjie Li, Junzi Li, Jianke Pan, Feng Su, Tingchao He, Haifeng Dong, Heng Wang, Zhi Chen, Chengmin Ji, Xiujun Yu, Xiaopeng Li

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  15. Rational Design of a Strong Nonlinear Optical Crystal With Ultrawide Bandgap via Fine‐Tuning of Channel Structures

    Laser & Photonics Review · 2026-08-15

    Zilong Geng, Zuju Ma, Ruibiao Fu, Xin-Tao Wu

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  16. A Hydrogen-Bonded Molecular Crystal with Strong Optical Anisotropy and Large Second-Harmonic Generation Response

    Inorganic Chemistry · 2026-09-21

    Ning Yang, Li Shen, Wenting Lin, Zhenchao Bai, Xitong Song

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