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RESEARCH PAPER · Materials Horizons · 2025

Optimizing optical anisotropy in low-dimensional structures via intralayer hydrogen bonding modulation and anionic substitution

Muhammad Sharjeel Arif, Xu Liu, Hangwei Jia, Zhihua Yang, Xueling Hou, Shilie Pan

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Optimizing optical anisotropy in low-dimensional structures via intralayer hydrogen bonding modulation and anionic substitutionOriginal新型非线性光学晶体和双折射晶体的研究进展（特邀）4Metal Cation Engineered UV Birefringent Crystals in π‐Conjugated Sulfonates with Record‐High Optical Anisotropy17[CON3H6BF4]: An Efficient Metal‐Free Borate with Optimized Birefringence Achieved by Structural Design Strategy15A novel metal-free crystal demonstrating superior birefringence attributed to the synergistic interaction of dual π-conjugated units8Optimizing the Hydrogen-Bond Network Drives Cadmium Ce(IV) Fluoride Hydrate with Significantly Enhanced Optical Anisotropy8Chiral Bismuth Halide Crystals: Polarizability-Driven Birefringence and Wave Plate Functionality4Effect of Multiple Hydrogen Bonding on the π-Conjugated Groups and Optical Properties in Molecular Crystals5Hybrid Zinc‒Based Halides with Giant Optical Anisotropy via Protonation‒Engineered π ‒Conjugated Organic Group24Achieving Ultra‐High Optical Anisotropy via Structural Regulation and Coplanar Engineering of Extended π‐Conjugated [H 2–x C 3 N 3 S 3 ] (x = 1, 2) Groups3Crystal structures and optical properties of two layered lead halide phosphites Pb 3 (HPO 3 )Cl 4 ·H 2 O and Pb 3 (HPO 3 ) 2 Cl 2 ·H 2 O0CsB(OH) 4 (H 2 O) 2 and Na(NH 4 ) 2 B 10 O 16 OH(H 2 O): a hydroxylation modification strategy regulates the borate structures and optical properties0Protonation‐Triggered Structural Transformations in 4‐Hydroxypyridinium Halides for Solar‐Blind UV Functional Crystals3Protonation‐Triggered Structural Transformations in 4‐Hydroxypyridinium Halides for Solar‐Blind UV Functional Crystals8Noncovalent Assembly Engineering Achieves Excellent Birefringence in Crystals0Redox‐Driven Strategy Enabling Leapfrog Enhancement of Birefringence in Layered Tin‐Based Optical Crystals1Mineral‐Inspired and Computation‐Assisted Rational Design of Polar Gittinsite‐Type Thiophosphates With Exceptional Nonlinear Optical Performance3Decoupling Contributions of Distinct Strategies for Enhancing Polarizability Anisotropy in Crystals Containing π-Conjugated Groups0

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17 direct citing papers saved.

  1. 新型非线性光学晶体和双折射晶体的研究进展（特邀）

    Chinese Journal of Lasers · 2025-01-01

    韩树娟 Han Shujuan, 杨志华 Yang Zhihua, 张方方 Zhang Fangfang, 李广卯 Li Guangmao, 李俊杰 Li Junjie, 吴雅博 Wu Yabo, 储冬冬 Chu Dongdong, 程孟 Cheng Meng, 张文彬 Zhang Wenbin, 丁文 Ding Wen, 潘世烈 Pan Shilie

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  2. Metal Cation Engineered UV Birefringent Crystals in π‐Conjugated Sulfonates with Record‐High Optical Anisotropy

    Small · 2025-04-07

    Zichang Wang, Qing‐Yu Liu, Zhihua Yang, Xueling Hou, Minqiang Gai

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  3. [CON3H6BF4]: An Efficient Metal‐Free Borate with Optimized Birefringence Achieved by Structural Design Strategy

    Small · 2025-05-23

    Muhammad Arif, Xu Liu, Hangwei Jia, Zhihua Yang, Xueling Hou, Shilie Pan

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  4. A novel metal-free crystal demonstrating superior birefringence attributed to the synergistic interaction of dual π-conjugated units

    Science China Materials · 2025-07-07

    Die-Xue Yang, Ru‐Ling Tang, Yi‐Lei Lv, Bing-Wei Miao, Wenlong Liu, Sheng‐Ping Guo

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  5. Optimizing the Hydrogen-Bond Network Drives Cadmium Ce(IV) Fluoride Hydrate with Significantly Enhanced Optical Anisotropy

    Inorganic Chemistry · 2025-07-25

    Wen-Ye Gao, Siyu Ma, Bing-Wei Miao, Wenfeng Zhou, Wenlong Liu, Ru‐Ling Tang

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  6. Chiral Bismuth Halide Crystals: Polarizability-Driven Birefringence and Wave Plate Functionality

    Inorganic Chemistry · 2025-10-14

    Quanlin Chen, Zhiqiang Huang, Xiaoting Liao, Miao Ren, Xiaohui Huang, Shao‐Ming Ying

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  7. Effect of Multiple Hydrogen Bonding on the π-Conjugated Groups and Optical Properties in Molecular Crystals

    Inorganic Chemistry · 2025-11-03

    Hangwei Jia, Xiangrong Song, Muhammad Arif, Yaqi Jin, Feng Yu, Xueling Hou

    Read original paper ↗ ·

  8. Hybrid Zinc‒Based Halides with Giant Optical Anisotropy via Protonation‒Engineered π ‒Conjugated Organic Group

    Advanced Functional Materials · 2025-11-20

    Ruo‐Nan Li, Zhen‐Cheng Wu, Wen‐Dong Yao, Yi‐Fan Fu, Yu‐Mei Zhang, Wenlong Liu, Jiajing Wu, Sheng‐Ping Guo

    Read original paper ↗ ·

  9. Achieving Ultra‐High Optical Anisotropy via Structural Regulation and Coplanar Engineering of Extended π‐Conjugated [H 2–x C 3 N 3 S 3 ] (x = 1, 2) Groups

    Advanced Functional Materials · 2025-12-12

    Muhammad Arif, Xu Liu, Hangwei Jia, Zhihua Yang, Xueling Hou, Shilie Pan

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  10. Crystal structures and optical properties of two layered lead halide phosphites Pb 3 (HPO 3 )Cl 4 ·H 2 O and Pb 3 (HPO 3 ) 2 Cl 2 ·H 2 O

    Dalton Transactions · 2026-01-01

    Zong-Jie Zhao, Yu-Zheng Yan, Jia-Jian Fu, Hongyan Wu, Jian‐Han Zhang

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  11. CsB(OH) 4 (H 2 O) 2 and Na(NH 4 ) 2 B 10 O 16 OH(H 2 O): a hydroxylation modification strategy regulates the borate structures and optical properties

    Dalton Transactions · 2026-01-01

    Kelibinuer Wulamu, Ziting Yan, Dongdong Chu, Juanjuan Lu, Yanhui Zhang, Hong Du

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  12. Protonation‐Triggered Structural Transformations in 4‐Hydroxypyridinium Halides for Solar‐Blind UV Functional Crystals

    Angewandte Chemie · 2026-01-04

    Jing Lu, Xin Liu, Shuangxiong Zhao, Xuebing Deng, Qundong Fu, Jingyu Guo, Zheng Liu, Li‐Ming Wu, Ling Chen

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  13. Protonation‐Triggered Structural Transformations in 4‐Hydroxypyridinium Halides for Solar‐Blind UV Functional Crystals

    Angewandte Chemie International Edition · 2026-01-04

    Jing Lu, Xin Liu, Shuangxiong Zhao, Xuebing Deng, Qundong Fu, Jingyu Guo, Zheng Liu, Li‐Ming Wu, Ling Chen

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  14. Noncovalent Assembly Engineering Achieves Excellent Birefringence in Crystals

    Inorganic Chemistry · 2026-04-24

    Mengqing Wu, Yiman Yang, Xinyi Wang, Yaoguo Shen

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  15. Redox‐Driven Strategy Enabling Leapfrog Enhancement of Birefringence in Layered Tin‐Based Optical Crystals

    Advanced Functional Materials · 2026-06-01

    Hangwei Jia, Yaqi Jin, Muhammad Arif, Bailin Chen, Zhihua Yang, Xueling Hou, Shilie Pan

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  16. Mineral‐Inspired and Computation‐Assisted Rational Design of Polar Gittinsite‐Type Thiophosphates With Exceptional Nonlinear Optical Performance

    Advanced Functional Materials · 2026-08-06

    Mao‐Yin Ran, Shao-Peng Gui, Jian Cheng, Yu‐Xuan Zhang, Wen‐Dong Yao, Wenlong Liu, Sheng‐Ping Guo

    Read original paper ↗ ·

  17. Decoupling Contributions of Distinct Strategies for Enhancing Polarizability Anisotropy in Crystals Containing π-Conjugated Groups

    Inorganic Chemistry · 2026-08-23

    Haoran Liu, Chenhui Hu, Xueli Du, Qingyu Liu, Xiaona Li, Zhihua Yang, Min Zhang

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