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RESEARCH PAPER · Journal of Materials Chemistry C · 2022

Cs 2 VOF 4 (IO 2 F 2 ): Rationally designing a noncentrosymmetric early-transition-metal fluoroiodate

Mengmeng Ding, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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Cs 2 VOF 4 (IO 2 F 2 ): Rationally designing a noncentrosymmetric early-transition-metal fluoroiodateOriginalA new birefringent material, HfF2(IO3)2, with a large birefringence and improved overall performances achieved by the integration of functional groups19MIO 3 F (M = Co and Ni): Magnetic Iodate Fluorides with Zigzag Chains16Recent advances in F-containing iodate nonlinear optical materials6C(NH2)3(I3O8)(HI3O8)(H2I2O6)(HIO3)4·3H2O: An Unprecedented Asymmetric Guanidinium Polyiodate with a Strong Second-Harmonic-Generation Response and a Wide Band Gap16Polar Bismuth Selenite Iodate Oxide BiSeIO6 with Three Types of Lone Pair Cations in One Structure6CsHfF4(IO3): A Hafnium Iodate Exhibiting a Strong Second-Harmonic-Generation Effect and a Wide Band Gap Achieved by Mixed-Ligand Acentric Coordination8Designing a Strong Second-Harmonic Generation Polar Iodate by the Structure-Directing Properties of the “Tumbler-like” [Zn(IO3)(I2O5(OH))] Polyanions20Advances in aliovalent substitution strategy for the design and synthesis of nonlinear optical materials: d0 transition metal/gallium iodates and selenites70Li2RbSO4Cl with a Short Ultraviolet Absorption Edge and an Acentric Structure through Assembling Heteroleptic [LiO3Cl] Tetrahedra2A survey of stereoactive oxysalts for linear and nonlinear optical applications40Optically Anisotropic Mixed-Metal Fluoroiodate Ba2[GaF5(IO3F)] with a Wide Optical Transparent Window and a Moderate Birefringence6Ba 2 Ga 2 F 6 (IO 3 )(PO 4 ): the first fluoride-containing iodate-phosphate with a 1D [Ga 2 F 6 (IO 3 )(PO 4 )] 4− helix chain2Explorations of highly birefringent materials in the vanadium oxyfluoride–iodate system by fluoride ion modulation8From NaGa(IO3)3F to NaGa(IO3)2F2 and NaGa(IO3)4: The Effects of Chemical Substitution between F– Anions and IO3– Groups on the Structures and Properties of Gallium Iodates13Guanidinium Vanadate [C(NH2)3]3VO4·2H2O Revealing Enhanced Second-Harmonic Generation and Wide Band Gaps13A congruent-melting rubidium zinc vanadium oxychloride exhibiting strong mid-infrared second-harmonic generation and high laser-induced damage threshold6π-Lone pair synergy in (C7H4NO4)(IO3): Optimal balance among SHG, birefringence, and bandgap performance29(C10N2H10)(HI2O6)(HIO3)(IO3): A Birefringent Material Featuring Large π-Conjugated Organic Cation and Two Types of Iodate Anions2Assisting the Effective Design of an SBBO-Like Vanadium-Iodate Crystal with Mixed Metal Cations2Symmetry Breaking via Anion-Molecule Synergy: Fluorine and Crystalline Water Directed Construction of Noncentrosymmetric Sr(IO2F2)2·2H2O0Cs2CdV2O6Br2: A Mid-Infrared Nonlinear Optical Vanadate Containing Both d0/d10 Transition Metal Cations and Bromine Anions5Recent achievements of d0 transition-metal-based oxyfluorides: Crystal chemistry and application in second-order NLO materials10Bonding-type-driven structural transformation toward novel fluoroiodosulfates: Achieving non-centrosymmetry and enhanced optical properties in K2(IO3F)SO30LiMn(IO 3 ) 3 : A Noncentrosymmetric Iodate Synthesized by Polyhedral Volume Ratio Modulation0

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  1. A new birefringent material, HfF2(IO3)2, with a large birefringence and improved overall performances achieved by the integration of functional groups

    Scripta Materialia · 2022-10-10

    Yu Huang, Zhi Gang Fang, Bing‐Ping Yang, Xueying Zhang, Jiang‐Gao Mao

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  2. MIO 3 F (M = Co and Ni): Magnetic Iodate Fluorides with Zigzag Chains

    Inorganic Chemistry · 2022-10-26

    Hang Liu, Yanhong Wang, Ya-Dong Zhou, Shuang Li, Yaling Dou, Tao Wang, Hongcheng Lu

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  3. Recent advances in F-containing iodate nonlinear optical materials

    Chinese Journal of Structural Chemistry · 2023-01-01

    Dong Gao, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  4. C(NH2)3(I3O8)(HI3O8)(H2I2O6)(HIO3)4·3H2O: An Unprecedented Asymmetric Guanidinium Polyiodate with a Strong Second-Harmonic-Generation Response and a Wide Band Gap

    Inorganic Chemistry · 2023-01-19

    Dong Yan, Meng-Meng Ren, Fei‐Fei Mao, Yu Ma, Ru‐Ling Tang, Bingbing Zhang, Yao Ma, Xiu‐Du Zhang, Shu‐Fang Li

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  5. Polar Bismuth Selenite Iodate Oxide BiSeIO6 with Three Types of Lone Pair Cations in One Structure

    Inorganic Chemistry · 2023-01-27

    Lei Geng, Wenfei Li, Baozhu Zhu, Shihua Ma, Baotong Liu, Kaiyue Jiang, Hong‐Yan Lu, Chang‐Yu Meng

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  6. CsHfF4(IO3): A Hafnium Iodate Exhibiting a Strong Second-Harmonic-Generation Effect and a Wide Band Gap Achieved by Mixed-Ligand Acentric Coordination

    Inorganic Chemistry · 2023-02-15

    Yu Huang, Bingxuan Li, Chun‐Li Hu, Bing‐Ping Yang, Jiang‐Gao Mao

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  7. Designing a Strong Second-Harmonic Generation Polar Iodate by the Structure-Directing Properties of the “Tumbler-like” [Zn(IO3)(I2O5(OH))] Polyanions

    ACS Materials Letters · 2023-05-08

    Jiale Chen, Pengcheng Yang, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongping Wu

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  8. Advances in aliovalent substitution strategy for the design and synthesis of nonlinear optical materials: d0 transition metal/gallium iodates and selenites

    Coordination Chemistry Reviews · 2023-05-22

    Zhiyong Bai, Kang Min Ok

    Read original paper ↗ ·

  9. Li2RbSO4Cl with a Short Ultraviolet Absorption Edge and an Acentric Structure through Assembling Heteroleptic [LiO3Cl] Tetrahedra

    Inorganic Chemistry · 2023-08-08

    Huanhuan Cheng, Fuming Li, Juanjuan Lu, Xueling Hou

    Read original paper ↗ ·

  10. A survey of stereoactive oxysalts for linear and nonlinear optical applications

    Materials Today Physics · 2023-08-12

    Pengfei Li, Jiang‐Gao Mao, Fang Kong

    Read original paper ↗ ·

  11. Optically Anisotropic Mixed-Metal Fluoroiodate Ba2[GaF5(IO3F)] with a Wide Optical Transparent Window and a Moderate Birefringence

    Inorganic Chemistry · 2023-10-17

    Yuhang Wang, Fu-Ying Li, Dong‐Xue Jiao, Qi Wei, Li Wei, Guo‐Yu Yang

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  12. Ba 2 Ga 2 F 6 (IO 3 )(PO 4 ): the first fluoride-containing iodate-phosphate with a 1D [Ga 2 F 6 (IO 3 )(PO 4 )] 4− helix chain

    Dalton Transactions · 2024-01-01

    Miao‐Bin Xu, Jiajia Li, Huai‐Yu Wu, Nan Ma, Ning Yu, Mo-Fan Zhuo, Jin Chen, Ke‐Zhao Du

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  13. Explorations of highly birefringent materials in the vanadium oxyfluoride–iodate system by fluoride ion modulation

    Journal of Materials Chemistry C · 2024-01-01

    Yu Huang, Xueying Zhang, Sangen Zhao, Jiang‐Gao Mao, Bing‐Ping Yang

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  14. From NaGa(IO3)3F to NaGa(IO3)2F2 and NaGa(IO3)4: The Effects of Chemical Substitution between F– Anions and IO3– Groups on the Structures and Properties of Gallium Iodates

    Inorganic Chemistry · 2024-01-01

    Shuoxing Yang, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  15. Guanidinium Vanadate [C(NH2)3]3VO4·2H2O Revealing Enhanced Second-Harmonic Generation and Wide Band Gaps

    Inorganic Chemistry · 2024-02-05

    Zhiyong Bai, Yunseung Kuk, Jihyun Lee, Heewon Kim, Kang Min Ok

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  16. A congruent-melting rubidium zinc vanadium oxychloride exhibiting strong mid-infrared second-harmonic generation and high laser-induced damage threshold

    Journal of Alloys and Compounds · 2024-04-14

    Lei Geng, Wenfei Li, Chang‐Yu Meng, You‐Zhao Lan, Baozhu Zhu, Shihua Ma, Qi Wu

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  17. π-Lone pair synergy in (C7H4NO4)(IO3): Optimal balance among SHG, birefringence, and bandgap performance

    Chinese Chemical Letters · 2024-09-27

    Miao‐Bin Xu, Qianqian Chen, Qian-Qian Chen, Bingxuan Li, Ke-Zhao Du, Jin Chen

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  18. (C10N2H10)(HI2O6)(HIO3)(IO3): A Birefringent Material Featuring Large π-Conjugated Organic Cation and Two Types of Iodate Anions

    Inorganic Chemistry · 2024-10-19

    Yuhang Wang, De-Xuan Jiang, De‐Xuan Liu, Fu-Ying Li, He Zhao, Jie Pan, Qi Wei, Li Wei, Guo‐Yu Yang

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  19. Assisting the Effective Design of an SBBO-Like Vanadium-Iodate Crystal with Mixed Metal Cations

    Crystal Growth & Design · 2025-05-22

    Xia Hao, Xuan Liu, Ruijie Wang, Chensheng Lin, Min Luo, Guang Peng, Tao Yan, Ning Ye

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  20. Symmetry Breaking via Anion-Molecule Synergy: Fluorine and Crystalline Water Directed Construction of Noncentrosymmetric Sr(IO2F2)2·2H2O

    Inorganic Chemistry · 2025-06-09

    Peng Jiang, Wenhu Wang, Juhui Cui, Ping Bai, Hongli Wu, Minqiang Gai

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  21. Cs2CdV2O6Br2: A Mid-Infrared Nonlinear Optical Vanadate Containing Both d0/d10 Transition Metal Cations and Bromine Anions

    Inorganic Chemistry · 2025-06-30

    Lei Geng, Baozhu Zhu, You‐Zhao Lan, Chang‐Yu Meng, Qi Wu

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  22. Recent achievements of d0 transition-metal-based oxyfluorides: Crystal chemistry and application in second-order NLO materials

    Coordination Chemistry Reviews · 2025-11-06

    Tianhui Wu, Jiahang Liu, Meiqi Liu, Xuan Li, Miao Zhang, Weiwei Cao, Jianmin Gu, Desong Wang

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  23. Bonding-type-driven structural transformation toward novel fluoroiodosulfates: Achieving non-centrosymmetry and enhanced optical properties in K2(IO3F)SO3

    Materials Today Chemistry · 2026-01-16

    Juhui Cui, Junwei Feng, Feng Xia Yu, Minqiang Gai

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  24. LiMn(IO 3 ) 3 : A Noncentrosymmetric Iodate Synthesized by Polyhedral Volume Ratio Modulation

    Inorganic Chemistry · 2026-05-26

    Ruilan Kong, Weitong Wang, Shuoxing Yang, S W, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yizhi Wu, HS Wu

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