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RESEARCH PAPER · Inorganic Chemistry Frontiers · 2022

CaCe(IO 3 ) 3 (IO 3 F)F: a promising nonlinear optical material containing both IO 3 − and IO 3 F 2− anions

Nan Ma, Chun‐Li Hu, Jin Chen, Zhi Gang Fang, Yu Huang, Bingxuan Li, Jiang‐Gao Mao

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CaCe(IO 3 ) 3 (IO 3 F)F: a promising nonlinear optical material containing both IO 3 − and IO 3 F 2− anionsOriginalA new polar alkaline earth–rare earth iodate: Ba 2 Ce(IO 3 ) 8 (H 2 O)10A series of novel phosphites/phosphates with deep-ultraviolet cut-off edges from 0D polar to 3D non-polar architectures13Recent advances in F-containing iodate nonlinear optical materials6(NH 4 ) 2 (I 5 O 12 )(IO 3 ) and K 1.03 (NH 4 ) 0.97 (I 5 O 12 )(IO 3 ): Mixed‐Valent Polyiodates with Unprecedented I 5 O 12 − Unit Exhibiting Strong Second‐Harmonic Generation Responses and Giant Birefringence22A survey of stereoactive oxysalts for linear and nonlinear optical applications40Ce(IO3)3F and Ce(IO3)2(NO3): Two Mixed-Anion Cerium Iodates with Good Nonlinear Optical and Birefringent Properties14Optically Anisotropic Mixed-Metal Fluoroiodate Ba2[GaF5(IO3F)] with a Wide Optical Transparent Window and a Moderate Birefringence6New iodate fluoride Rb 2 Ce(IO 3 ) 5 F with nonlinear optical properties12Novel cesium cerium( iv ) iodate Cs 2 Ce(IO 3 ) 6 : hydrothermal synthesis, crystal structures and thermal stability2Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units66(C10N2H10)(HI2O6)(HIO3)(IO3): A Birefringent Material Featuring Large π-Conjugated Organic Cation and Two Types of Iodate Anions2Achieving balanced UV SHG responses, optical band gaps and birefringence in rare earth compounds Ln(IO 3 )(SO 4 )·3H 2 O (Ln = Y, Gd, Er, Ho, Dy, Eu)4Unveiling the Intrinsic Superior SHG Performance of Ce 4+ Fluoride Masked by Subtle Ce 3+ Impurity and Its Effective Removal13Unveiling the Intrinsic Superior SHG Performance of Ce4+ Fluoride Masked by Subtle Ce3+ Impurity and Its Effective Removal2LiAgCe2F10(H2O)2: Focusing on the Cation Size Effect to Reasonably Design a Nonlinear Optical Hydrated Cerium(IV) Fluoride10Cs2CdV2O6Br2: A Mid-Infrared Nonlinear Optical Vanadate Containing Both d0/d10 Transition Metal Cations and Bromine Anions5Optimizing the Hydrogen-Bond Network Drives Cadmium Ce(IV) Fluoride Hydrate with Significantly Enhanced Optical Anisotropy8Ce-centered polyhedral arrangement pattern and optical performance in Ce-based nonlinear optical materials3Ba2CrIO3F6: a magnetic alkaline-earth chromium fluoroiodate with ferromagnetic exchange interactions1Strategic Oxygen‐Substitution in Perfluorinated Ce(IV) Coordination Frameworks Triggers Dual‐Wavelength Nonlinear Optical Materials With Exceptional Performances3Strategic Oxygen‐Substitution in Perfluorinated Ce(IV) Coordination Frameworks Triggers Dual‐Wavelength Nonlinear Optical Materials With Exceptional Performances33Exploration of the influence of exchange-correlation functionals and hydrostatic pressure on the physical properties of recently synthesized nonlinear optical material Na2CeF60

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  1. A new polar alkaline earth–rare earth iodate: Ba 2 Ce(IO 3 ) 8 (H 2 O)

    Dalton Transactions · 2023-01-01

    Xueying Zhang, Xiaohan Zhang, Bing‐Ping Yang, Jiang‐Gao Mao

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  2. A series of novel phosphites/phosphates with deep-ultraviolet cut-off edges from 0D polar to 3D non-polar architectures

    CrystEngComm · 2023-01-01

    Yucheng Hao, Yang Zhang, Yuying Zhang, Zixiang Fu, Chunyang Heng, Junjie Li, Jiatian You, Kunhong Hu, Yuan Hua Lin, Haijian Li

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  3. Recent advances in F-containing iodate nonlinear optical materials

    Chinese Journal of Structural Chemistry · 2023-01-01

    Dong Gao, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  4. (NH 4 ) 2 (I 5 O 12 )(IO 3 ) and K 1.03 (NH 4 ) 0.97 (I 5 O 12 )(IO 3 ): Mixed‐Valent Polyiodates with Unprecedented I 5 O 12 − Unit Exhibiting Strong Second‐Harmonic Generation Responses and Giant Birefringence

    Small · 2023-07-25

    Nan Ma, Jin Chen, Bingxuan Li, Chun‐Li Hu, Jiang‐Gao Mao

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  5. A survey of stereoactive oxysalts for linear and nonlinear optical applications

    Materials Today Physics · 2023-08-12

    Pengfei Li, Jiang‐Gao Mao, Fang Kong

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  6. Ce(IO3)3F and Ce(IO3)2(NO3): Two Mixed-Anion Cerium Iodates with Good Nonlinear Optical and Birefringent Properties

    Inorganic Chemistry · 2023-09-07

    Nan Ma, Yu Hong Huang, Chun‐Li Hu, Mingzhi Zhang, Bingxuan Li, Jiang‐Gao Mao

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  7. Optically Anisotropic Mixed-Metal Fluoroiodate Ba2[GaF5(IO3F)] with a Wide Optical Transparent Window and a Moderate Birefringence

    Inorganic Chemistry · 2023-10-17

    Yuhang Wang, Fu-Ying Li, Dong‐Xue Jiao, Qi Wei, Li Wei, Guo‐Yu Yang

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  8. New iodate fluoride Rb 2 Ce(IO 3 ) 5 F with nonlinear optical properties

    Dalton Transactions · 2024-01-01

    Oksana P. Grigorieva, Т. Б. Шаталова, Alexey N. Kuznetsov∥, Peter S. Berdonosov, Sergey Yu. Stefanovich, Konstantin Alexandrovich Lyssenko, В. А. Долгих

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  9. Novel cesium cerium( iv ) iodate Cs 2 Ce(IO 3 ) 6 : hydrothermal synthesis, crystal structures and thermal stability

    CrystEngComm · 2024-01-01

    Oksana P. Grigorieva, Larisa Victorovna Shvanskaya, Т. Б. Шаталова, Andrey A. Zolotarev, Peter S. Berdonosov, В. А. Долгих

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  10. Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units

    Coordination Chemistry Reviews · 2024-07-03

    Bo Zhang, Mao‐Yin Ran, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  11. (C10N2H10)(HI2O6)(HIO3)(IO3): A Birefringent Material Featuring Large π-Conjugated Organic Cation and Two Types of Iodate Anions

    Inorganic Chemistry · 2024-10-19

    Yuhang Wang, De-Xuan Jiang, De‐Xuan Liu, Fu-Ying Li, He Zhao, Jie Pan, Qi Wei, Li Wei, Guo‐Yu Yang

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  12. Achieving balanced UV SHG responses, optical band gaps and birefringence in rare earth compounds Ln(IO 3 )(SO 4 )·3H 2 O (Ln = Y, Gd, Er, Ho, Dy, Eu)

    Dalton Transactions · 2025-01-01

    Shihua Ma, Lei Geng, Baozhu Zhu, Changyu Meng

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  13. Unveiling the Intrinsic Superior SHG Performance of Ce 4+ Fluoride Masked by Subtle Ce 3+ Impurity and Its Effective Removal

    Angewandte Chemie International Edition · 2025-02-18

    Mengyue Li, Xin Liu, Rui Wang, Li‐Ming Wu, Li‐Ming Wu, Ling Chen, Qi Wu, Qi Wu

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  14. Unveiling the Intrinsic Superior SHG Performance of Ce4+ Fluoride Masked by Subtle Ce3+ Impurity and Its Effective Removal

    Angewandte Chemie · 2025-02-18

    Mengyue Li, Xin Liu, Rui Wang, Li‐Ming Wu, Ling Chen, Qi Wu

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  15. LiAgCe2F10(H2O)2: Focusing on the Cation Size Effect to Reasonably Design a Nonlinear Optical Hydrated Cerium(IV) Fluoride

    Inorganic Chemistry · 2025-03-24

    Wen-Ye Gao, Yi‐Lei Lv, Siyu Ma, Cheng Chen, Wenlong Liu, Ru‐Ling Tang

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  16. Cs2CdV2O6Br2: A Mid-Infrared Nonlinear Optical Vanadate Containing Both d0/d10 Transition Metal Cations and Bromine Anions

    Inorganic Chemistry · 2025-06-30

    Lei Geng, Baozhu Zhu, You‐Zhao Lan, Chang‐Yu Meng, Qi Wu

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  17. Optimizing the Hydrogen-Bond Network Drives Cadmium Ce(IV) Fluoride Hydrate with Significantly Enhanced Optical Anisotropy

    Inorganic Chemistry · 2025-07-25

    Wen-Ye Gao, Siyu Ma, Bing-Wei Miao, Wenfeng Zhou, Wenlong Liu, Ru‐Ling Tang

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  18. Ce-centered polyhedral arrangement pattern and optical performance in Ce-based nonlinear optical materials

    Chinese Chemical Letters · 2025-11-01

    Xuan Li, Tianhui Wu, Meiqi Liu, Yang Zhao, Jiahang Liu, Miao Zhang, Weiwei Cao, Jianmin Gu, Desong Wang

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  19. Ba2CrIO3F6: a magnetic alkaline-earth chromium fluoroiodate with ferromagnetic exchange interactions

    Journal of Solid State Chemistry · 2025-12-24

    Shuaikun Li, Yanhong Wang, Haibo Li, Hang Liu, Yun Lv, Hongcheng Lu

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  20. Strategic Oxygen‐Substitution in Perfluorinated Ce(IV) Coordination Frameworks Triggers Dual‐Wavelength Nonlinear Optical Materials With Exceptional Performances

    Angewandte Chemie · 2026-01-16

    Ru‐Ling Tang, Wen‐Ye Gao, Guo-Ren Zhu, Yang Chi, Liang Ma, Wenlong Liu, Sheng‐Ping Guo

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  21. Strategic Oxygen‐Substitution in Perfluorinated Ce(IV) Coordination Frameworks Triggers Dual‐Wavelength Nonlinear Optical Materials With Exceptional Performances

    Angewandte Chemie International Edition · 2026-01-16

    Ru‐Ling Tang, Wen‐Ye Gao, Guo-Ren Zhu, Yang Chi, Liang Ma, Wenlong Liu, Sheng‐Ping Guo

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  22. Exploration of the influence of exchange-correlation functionals and hydrostatic pressure on the physical properties of recently synthesized nonlinear optical material Na2CeF6

    Results in Materials · 2026-05-04

    Jakiul Islam, Nur E-Elahi, Md. Mehedi Hasan, Md. Shahjahan Ali, Md. Kamrul Hassan Bhuiya, Shuvo Sen, Eshrat Zahan Eshita, Aka Talukder, Md. Saiful Alam, Mohasena Ahamed

    Read original paper ↗ ·
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