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RESEARCH PAPER · Chemistry of Materials · 2022

One-Side Capping in Two-Dimensional WO 3 -Type Materials Leading to Strong Second-Harmonic Response

Haonan Liu, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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One-Side Capping in Two-Dimensional WO 3 -Type Materials Leading to Strong Second-Harmonic ResponseOriginalBa 2 [WO 3 F(IO 3 )][WO 3 F 2 ]: the first polar fluorinated tungsten iodate featuring a direct W–O–I bond7Cd 2 (IO 3 )(PO 4 ) and Cd 1.62 Mg 0.38 (IO 3 )(PO 4 ): metal iodate-phosphates with large SHG responses and wide band gaps28ZrF2(IO3)2 and RbGaF3(IO3): Two Promising Birefringent Crystals Featuring 1D Metal-Fluoride Cationic Chains and Wide Bandgaps22[M(OH) 2 ] 3 (IO 3 )(SeO 4 )·H 2 O (M = Ga and In): metal iodate–selenate nonlinear optical materials with a hexagonal tungsten oxide-type topology20Recent advances in F-containing iodate nonlinear optical materials6Alignment of Λ-Shaped Basic Building Units to Construct One New KMoO3(IO3) Polar Polymorph11Designing a Strong Second-Harmonic Generation Polar Iodate by the Structure-Directing Properties of the “Tumbler-like” [Zn(IO3)(I2O5(OH))] Polyanions20Cd2Nb2Te4O15: A Novel Pseudo‐Aurivillius‐Type Tellurite with Unprecedented Nonlinear Optical Properties and Excellent Stability40A selenite containing unusual [Ga2F(Se2O5)4(HSeO3)2]5- clusters with the polarization ‘lighted’ by F− anions15(NH 4 ) 2 (I 5 O 12 )(IO 3 ) and K 1.03 (NH 4 ) 0.97 (I 5 O 12 )(IO 3 ): Mixed‐Valent Polyiodates with Unprecedented I 5 O 12 − Unit Exhibiting Strong Second‐Harmonic Generation Responses and Giant Birefringence22LiGa(IO3)4: An Excellent NLO Material with Unprecedented 2D [Ga(IO3)4]∞− Layer Synthesized by Aliovalent Substitution20A potassium lead 2-methylmalonate-iodide nonlinear optical crystal with strong second-harmonic generation response and large birefringence2Ba 2 Ga 2 F 6 (IO 3 )(PO 4 ): the first fluoride-containing iodate-phosphate with a 1D [Ga 2 F 6 (IO 3 )(PO 4 )] 4− helix chain2From NaGa(IO3)3F to NaGa(IO3)2F2 and NaGa(IO3)4: The Effects of Chemical Substitution between F– Anions and IO3– Groups on the Structures and Properties of Gallium Iodates13C(NH2)3MoO3(IO3): A Molybdenyl Iodate with Giant Birefringence Designed via a Cation–Anion Synergetic Interaction Strategy36Unveiling the Twisted Aromatic Donor Effect on the Nonlinear Response of D‐ π ‐A Type Malononitrile‐Derived Chromophores10π-Lone pair synergy in (C7H4NO4)(IO3): Optimal balance among SHG, birefringence, and bandgap performance29(C10N2H10)(HI2O6)(HIO3)(IO3): A Birefringent Material Featuring Large π-Conjugated Organic Cation and Two Types of Iodate Anions2Chemical Substitution‐Driven Design of a High‐Performance Noncentrosymmetric Bismuth Molybdenum Selenite10Hetero‐Anionic Oxychalcogenides with Structures and Properties Tuned by the O:S Ratio14The birefringence in orthorhombic and triclinic lead-iodates and the functional basic units' contribution: A first-principles investigation3pH‐Regulated Ring‐Opening/Closing Transformation in Polyoxometalates Enables High‐Performance Nonlinear Optical Crystals1pH‐Regulated Ring‐Opening/Closing Transformation in Polyoxometalates Enables High‐Performance Nonlinear Optical Crystals13Recent achievements of d0 transition-metal-based oxyfluorides: Crystal chemistry and application in second-order NLO materials10Halogen-ion-driven polymorphs for high-performance nonlinear optical crystalline materials3Stable lead succinate-iodides with strong second-harmonic generation response and large birefringence0LiMn(IO 3 ) 3 : A Noncentrosymmetric Iodate Synthesized by Polyhedral Volume Ratio Modulation0Advances in metal selenite nonlinear optical materials: halogens directed structure modulation and property optimization0Coordination-Mode-Modulated Symmetry Breaking for Nonlinear Optical Crystals0

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29 direct citing papers saved.

  1. Ba 2 [WO 3 F(IO 3 )][WO 3 F 2 ]: the first polar fluorinated tungsten iodate featuring a direct W–O–I bond

    Dalton Transactions · 2022-01-01

    Ying Hou, Hongyi Li, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

    Read original paper ↗ ·

  2. Cd 2 (IO 3 )(PO 4 ) and Cd 1.62 Mg 0.38 (IO 3 )(PO 4 ): metal iodate-phosphates with large SHG responses and wide band gaps

    Chemical Communications · 2022-01-01

    Qianqian Chen, Chun‐Li Hu, Li-Jia Yao, Jin Chen, Ming‐Yang Cao, Bingxuan Li, Jiang‐Gao Mao

    Read original paper ↗ ·

  3. ZrF2(IO3)2 and RbGaF3(IO3): Two Promising Birefringent Crystals Featuring 1D Metal-Fluoride Cationic Chains and Wide Bandgaps

    Inorganic Chemistry · 2022-10-26

    Jin Chen, Ke‐Zhao Du

    Read original paper ↗ ·

  4. [M(OH) 2 ] 3 (IO 3 )(SeO 4 )·H 2 O (M = Ga and In): metal iodate–selenate nonlinear optical materials with a hexagonal tungsten oxide-type topology

    Inorganic Chemistry Frontiers · 2023-01-01

    Qianqian Chen, Chun‐Li Hu, Bingxuan Li, Jiang‐Gao Mao

    Read original paper ↗ ·

  5. Recent advances in F-containing iodate nonlinear optical materials

    Chinese Journal of Structural Chemistry · 2023-01-01

    Dong Gao, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

    Read original paper ↗ ·

  6. Alignment of Λ-Shaped Basic Building Units to Construct One New KMoO3(IO3) Polar Polymorph

    Inorganic Chemistry · 2023-02-22

    Qing Li, Haonan Liu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongping Wu

    Read original paper ↗ ·

  7. Designing a Strong Second-Harmonic Generation Polar Iodate by the Structure-Directing Properties of the “Tumbler-like” [Zn(IO3)(I2O5(OH))] Polyanions

    ACS Materials Letters · 2023-05-08

    Jiale Chen, Pengcheng Yang, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongping Wu

    Read original paper ↗ ·

  8. Cd2Nb2Te4O15: A Novel Pseudo‐Aurivillius‐Type Tellurite with Unprecedented Nonlinear Optical Properties and Excellent Stability

    Small · 2023-05-28

    Qiang Wang, Xuehua Dong, Ling Huang, Kang Min Ok, Zhien Lin, Guohong Zou

    Read original paper ↗ ·

  9. A selenite containing unusual [Ga2F(Se2O5)4(HSeO3)2]5- clusters with the polarization ‘lighted’ by F− anions

    Materials Today Physics · 2023-06-01

    Jingru Zhang, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongping Wu

    Read original paper ↗ ·

  10. (NH 4 ) 2 (I 5 O 12 )(IO 3 ) and K 1.03 (NH 4 ) 0.97 (I 5 O 12 )(IO 3 ): Mixed‐Valent Polyiodates with Unprecedented I 5 O 12 − Unit Exhibiting Strong Second‐Harmonic Generation Responses and Giant Birefringence

    Small · 2023-07-25

    Nan Ma, Jin Chen, Bingxuan Li, Chun‐Li Hu, Jiang‐Gao Mao

    Read original paper ↗ ·

  11. LiGa(IO3)4: An Excellent NLO Material with Unprecedented 2D [Ga(IO3)4]∞− Layer Synthesized by Aliovalent Substitution

    Small · 2023-09-07

    Shuoxing Yang, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

    Read original paper ↗ ·

  12. A potassium lead 2-methylmalonate-iodide nonlinear optical crystal with strong second-harmonic generation response and large birefringence

    Scripta Materialia · 2023-10-14

    Shuangcheng Li, Zilong Geng, Ruibiao Fu, Zuju Ma, Xin‐Tao Wu

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  13. Ba 2 Ga 2 F 6 (IO 3 )(PO 4 ): the first fluoride-containing iodate-phosphate with a 1D [Ga 2 F 6 (IO 3 )(PO 4 )] 4− helix chain

    Dalton Transactions · 2024-01-01

    Miao‐Bin Xu, Jiajia Li, Huai‐Yu Wu, Nan Ma, Ning Yu, Mo-Fan Zhuo, Jin Chen, Ke‐Zhao Du

    Read original paper ↗ ·

  14. From NaGa(IO3)3F to NaGa(IO3)2F2 and NaGa(IO3)4: The Effects of Chemical Substitution between F– Anions and IO3– Groups on the Structures and Properties of Gallium Iodates

    Inorganic Chemistry · 2024-01-01

    Shuoxing Yang, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

    Read original paper ↗ ·

  15. C(NH2)3MoO3(IO3): A Molybdenyl Iodate with Giant Birefringence Designed via a Cation–Anion Synergetic Interaction Strategy

    Chemistry of Materials · 2024-02-08

    Wei Zeng, Yao Tian, Xuehua Dong, Ling Huang, Hongmei Zeng, Zhien Lin, Guohong Zou

    Read original paper ↗ ·

  16. Unveiling the Twisted Aromatic Donor Effect on the Nonlinear Response of D‐ π ‐A Type Malononitrile‐Derived Chromophores

    Chemistry - A European Journal · 2024-07-20

    Xiangzhao Zhu, Songhua Chen, Jia-Bei Xu, Jianhua Huang, Jianfeng Yan, Yaofeng Yuan

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  17. π-Lone pair synergy in (C7H4NO4)(IO3): Optimal balance among SHG, birefringence, and bandgap performance

    Chinese Chemical Letters · 2024-09-27

    Miao‐Bin Xu, Qianqian Chen, Qian-Qian Chen, Bingxuan Li, Ke-Zhao Du, Jin Chen

    Read original paper ↗ ·

  18. (C10N2H10)(HI2O6)(HIO3)(IO3): A Birefringent Material Featuring Large π-Conjugated Organic Cation and Two Types of Iodate Anions

    Inorganic Chemistry · 2024-10-19

    Yuhang Wang, De-Xuan Jiang, De‐Xuan Liu, Fu-Ying Li, He Zhao, Jie Pan, Qi Wei, Li Wei, Guo‐Yu Yang

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  19. Chemical Substitution‐Driven Design of a High‐Performance Noncentrosymmetric Bismuth Molybdenum Selenite

    Advanced Optical Materials · 2025-01-17

    Hieu Minh Ngo, Yunseung Kuk, Jihyun Lee, Jiachen Lu, Zhiyong Bai, Chun‐Li Hu, Kang Min Ok

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  20. Hetero‐Anionic Oxychalcogenides with Structures and Properties Tuned by the O:S Ratio

    Advanced Functional Materials · 2025-01-17

    Shaoxin Cui, Shuoxing Yang, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  21. The birefringence in orthorhombic and triclinic lead-iodates and the functional basic units' contribution: A first-principles investigation

    Chemical Physics Letters · 2025-02-22

    Jialong Wang, Enshen Wang, Xiuhua Cui, Peng Li, Qun Jing, Zhaohui Chen

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  22. pH‐Regulated Ring‐Opening/Closing Transformation in Polyoxometalates Enables High‐Performance Nonlinear Optical Crystals

    Angewandte Chemie · 2025-11-06

    Wei Zeng, Jing Zhang, Yao Tian, Hongmei Zeng, Zhien Lin, Liujiang Zhou, Kang Min Ok, Guohong Zou

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  23. pH‐Regulated Ring‐Opening/Closing Transformation in Polyoxometalates Enables High‐Performance Nonlinear Optical Crystals

    Angewandte Chemie International Edition · 2025-11-06

    Wei Zeng, Jing Zhang, Yao Tian, Hongmei Zeng, Zhien Lin, Liujiang Zhou, Kang Min Ok, Guohong Zou

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  24. Recent achievements of d0 transition-metal-based oxyfluorides: Crystal chemistry and application in second-order NLO materials

    Coordination Chemistry Reviews · 2025-11-06

    Tianhui Wu, Jiahang Liu, Meiqi Liu, Xuan Li, Miao Zhang, Weiwei Cao, Jianmin Gu, Desong Wang

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  25. Halogen-ion-driven polymorphs for high-performance nonlinear optical crystalline materials

    Chemical Science · 2026-01-01

    Yuwei Kang, Can Hui Yang, Yunjie Wang, Qi Wu

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  26. Stable lead succinate-iodides with strong second-harmonic generation response and large birefringence

    Inorganic Chemistry Frontiers · 2026-01-01

    Yulu Wu, Jialin Zeng, Rui Biao Fu, Wen Jing Yang, Zilong Geng, Senfu Lei, Yiting Luo, Xiaofan Tong, Zuju Ma

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  27. LiMn(IO 3 ) 3 : A Noncentrosymmetric Iodate Synthesized by Polyhedral Volume Ratio Modulation

    Inorganic Chemistry · 2026-05-26

    Ruilan Kong, Weitong Wang, Shuoxing Yang, S W, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yizhi Wu, HS Wu

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  28. Advances in metal selenite nonlinear optical materials: halogens directed structure modulation and property optimization

    Coordination Chemistry Reviews · 2026-08-14

    Dan-Dan Zhou, Tian-Tian He, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  29. Coordination-Mode-Modulated Symmetry Breaking for Nonlinear Optical Crystals

    Inorganic Chemistry · 2026-08-24

    Lan Wang, Zhen Qin, Shu‐Fang Li, Xin-Ran Hao, Chu Chu, Bingbing Zhang, Dong Yan

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