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RESEARCH PAPER · Accounts of Materials Research · 2021

Toward the Enhancement of Critical Performance for Deep-Ultraviolet Frequency-Doubling Crystals Utilizing Covalent Tetrahedra

Miriding Mutailipu, Zhihua Yang, Shilie Pan

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Toward the Enhancement of Critical Performance for Deep-Ultraviolet Frequency-Doubling Crystals Utilizing Covalent TetrahedraOriginalA new acentric borate–nitrate Cs 3 B 8 O 13 (NO 3 ) with interpenetrating porous 3D covalent and ionic lattices8BaZn 3 (BO 3 ) 2 F 2 : a new beryllium-free zincoborate with a KBBF-type structure11Enhanced birefringence and suppressed second harmonic generation response mechanism in nonlinear optical materials via structural fine-tuning9Hg 3 (Te 3 O 8 )(SO 4 ): a new sulfate tellurite with a novel structure and large birefringence explored from d 10 metal compounds39Na 2 La 2 B 10 O 19 : a new lanthanum sodium borate with infinite 2D layer 2∞[B 10 O 19 ] 8− and moderate birefringence4Systematic centricity control using a chiral template: novel noncentrosymmetric polar niobium oxyfluorides and tantalum fluorides directed by chiral histidinium cations, [( l -hisH 2 )NbOF 5 ], [( d -hisH 2 )NbOF 5 ], [( l -hisH 2 )TaF 7 ], and [( d -hisH 2 )TaF 7 ]8RbMT3(BO3)2O3 (M=Ba, Sr; T=Al, Ga): New Double‐Layered Oxyborates Constructed from [BO3] Triangles and [TO4] Tetrahedra13Cs4B4O3F10: First Fluorooxoborate with [BF4] Involving Heteroanionic Units and Extremely Low Melting Point18Hydrogen‐Bond‐Driven Synergistically Enhanced Hyperpolarizability: Chiral Coordination Polymers with Nonpolar Structures Exhibiting Unusually Strong Second‐Harmonic Generation87Hydrogen‐Bond‐Driven Synergistically Enhanced Hyperpolarizability: Chiral Coordination Polymers with Nonpolar Structures Exhibiting Unusually Strong Second‐Harmonic Generation19Hydroxyfluorooxoborate Na[B3O3F2(OH)2]⋅[B(OH)3]: Optimizing the Optical Anisotropy with Heteroanionic Units for Deep Ultraviolet Birefringent Crystals146Hydroxyfluorooxoborate Na[B3O3F2(OH)2]⋅[B(OH)3]: Optimizing the Optical Anisotropy with Heteroanionic Units for Deep Ultraviolet Birefringent Crystals16Structural Origin of Very Large Second-Harmonic Generation of a Layered Perovskite, Na0.5Bi2.5Nb2O921Finding a Series of BaBOF3 Fluorooxoborate Polymorphs with Tunable Symmetries: A Simple but Flexible Case37Two SbX5-based isostructural polar 1D hybrid antimony halides with tunable broadband emission, nonlinear optics, and semiconductor properties34AMoO3(IO3) (A = Na and K): Two promising optical materials via properly assembling the Λ-shaped basic building units19Ba2B13O19(OH)5·5H2O: A promising nonlinear optical material with a unique 2[B13O19(OH)5]∞ two-dimensional layer9K3BaTeB7O15: A new borotellurite with mixed metal cations5Guanidinium Fluorooxoborates as Efficient Metal-free Short-Wavelength Nonlinear Optical Crystals140Phase Matchability Transformation in the Infrared Nonlinear Optical Materials with Diamond‐Like Frameworks63(N 2 H 6 )[HPO 3 F] 2 : maximizing the optical anisotropy of deep-ultraviolet fluorophosphates33Band gap modulation and nonlinear optical properties of quaternary tellurates Li 2 GeTeO 613Hexameric poly-fluoroberyllophosphate Na 4 Be 2 PO 4 F 5 with moderate birefringence and deep-ultraviolet transmission as a potential zero-order-waveplate crystal17K 2 S 4 O 6 : improving birefringence and nonlinear optical properties with the [O 3 S–S–S–SO 3 ] 2− group5KLi 2 CO 3 F: a beryllium-free KBBF-type deep-UV carbonate with an enhanced interlayer interaction and large birefringence20Na 2 SrB 16 O 26 : a new borate with independent interpenetrating B–O networks and deep-ultraviolet cutoff edge4PNO: a promising deep-UV nonlinear optical material with the largest second harmonic generation effect17α-LiMB 9 O 15 (M = Sr, Pb): flexible [B 3 O 7 ] units leading to the low temperature phase of β-LiMB 9 O 15 (M = Sr, Pb)11Review of Heteroleptic Tetrahedra as Birefringent or Nonlinear Optical Motifs17Potential optical functional crystals with large birefringence: Recent advances and future prospects322“Removing Center”─An Effective Structure Design Strategy for Nonlinear Optical Crystals37Finding the First Squarates Nonlinear Optical Crystal NaHC4O4·H2O with Strong Second Harmonic Generation and Giant Birefringence56Strong Nonlinearity Induced by Coaxial Alignment of Polar Chain and Dense [BO3] Units in CaZn2(BO3)212Strong Nonlinearity Induced by Coaxial Alignment of Polar Chain and Dense [BO3] Units in CaZn2(BO3)2212Double‐Modification Oriented Design of a Deep‐UV Birefringent Crystal Functionalized by [B12O16F4(OH)4] Clusters9Double‐Modification Oriented Design of a Deep‐UV Birefringent Crystal Functionalized by [B12O16F4(OH)4] Clusters139Enhancement of Birefringence in Borophosphate Pushing Phase-Matching into the Short-Wavelength Region150(NH4)3B11PO19F3: a deep-UV nonlinear optical crystal with unique [B5PO10F]∞ layers142Bright Green Emission from Self-Trapped Excitons Triggered by Sb3+ Doping in Rb4CdCl6145Difluoro(oxalato)borates as Short-Wavelength Optical Crystals with Bifunctional [BF 2 C 2 O 4 ] Units38Rearrangement of [B2O5] Dimers within [B7O14] Clusters Enables Enhanced Optical Anisotropy in Li3Cs6Al2B14O28F4Dual-Ligand-Oriented Design of Noncentrosymmetric Complexes with Nonlinear-Optical Activity11NaK5Zn2(B5O10)2 and β-K3ZnB5O10: Two Zincoborates with Deep-UV Cutoff Edge9Ba6Zn6(B3O6)6(B6O12): Barium Zinc Borate Contains π-Conjugated [B3O6]3– Anions and [B6O12]6– Anion with Edge-Sharing BO4 Tetrahedra36Local Polarity-Induced Assembly of Second-Order Nonlinear Optical Materials128M(NH2SO3)2·xH2O (M = Ca, Pb, x = 0, 1, 4): Effect of Hydrogen Bonding on Structural Transformations and Second Harmonic Generation of Metal Sulfamates26Aluminoborates as Nonlinear Optical Materials79Aluminoborates as Nonlinear Optical Materials14Effects of Pr3+ doping concentration on optical properties of LaF3 crystal10Anisotropic structure building unit involving diverse chemical bonds: a new opportunity for high-performance second-order NLO materials181Discovery of SrZn 2 B 6 O 12 with an unprecedented quadruple-layered configuration0Dramatically improved optical anisotropy by realizing stereochemically active lone pairs in a sulfate system, K 2 SO 4 ·HIO 323From H 12 C 4 N 2 CdI 4 to H 11 C 4 N 2 CdI 3 : a highly polarizable CdNI 3 tetrahedron induced a sharp enhancement of second harmonic generation response and birefringence50Hydroxyfluorooxoborate (NH 4 )[C(NH 2 ) 3 ][B 3 O 3 F 4 (OH)] for exploring the effects of cation substitution on structure and optical properties26K 5 [B 3 O 3 F 4 (OH)] 2 (NO 3 ): the first hydroxyfluorooxoborate-nitrate with a short ultraviolet cutoff edge and large birefringence18LiCs 3 AlB 7 O 14 : achieving enhanced optical anisotropy via [AlO 4 ] tetrahedron introduction to rearrange the anionic framework5Low temperature molten salt synthesis of noncentrosymmetric (NH 4 ) 3 SbF 3 (NO 3 ) 3 and centrosymmetric (NH 4 ) 3 SbF 4 (NO 3 ) 234Tetrahedron-based deep-ultraviolet nonlinear optical crystal with optimized KBe 2 BO 3 F 2 -like structure and disordered cations2Two Acentric Aluminoborates Incorporated d10 Cations: Syntheses, Structures, and Nonlinear Optical Properties24SbI3·3S8: A Novel Promising Inorganic Adducts Crystal for Second Harmonic Generation5Fluorooxoborates: A precious treasure of deep-ultraviolet nonlinear optical materials24A Rare‐Earth Selenite with Unexpectedly Well‐Balanced Ultraviolet Nonlinear Optical Functionality, Sc(HSeO 3 ) 331Li3B8O13X (X = Cl and Br): Two New Noncentrosymmetric Crystals with Large Birefringence Induced by BO3 Units18Rational Design, Stabilities and Nonlinear Optical Properties of Non-Conventional Transition Metalides; New Entry into Nonlinear Optical Materials8Two Ultraviolet Optical Crystals K6B12O19F4 and K12B28O48: The Effects of Metal Cations Size and the F Ions on the Structure6Advances in aliovalent substitution strategy for the design and synthesis of nonlinear optical materials: d0 transition metal/gallium iodates and selenites70Target-Oriented Synthesis of Borate Derivatives Featuring Isolated [B3O3] Six-Membered Rings as Structural Features20Recent Progress in Crystalline Borates with Edge-Sharing BO4 Tetrahedra21Design Principles for Noncentrosymmetric Materials23Fluorooxoborate Promoting the Exploration of Short-Wavelength Linear and Nonlinear Optical Crystals with Expected Properties and Versatile Structures27Introduction of the [B–O/F] Units Enhances the Band Gap and Birefringence from Na6Mg3B10O18F6 to K3NaB10O16F211Photophysics of corroles and closely related systems for emergent solar energy, medicinal, and materials science applications39Rare-Earth Scandium Borate Fluoride with a Deep-Ultraviolet Cutoff Edge12Unveiling The Role of Cu+ Doping in Rb2AgBr3 Scintillators toward Enhanced Photoluminescence Quantum Efficiency and Light Yield34Hydroxyl-Driven Enhanced Birefringence in Borophosphates3Rb 3 MgB 5 O 10 and LiBaAl(BO 3 ) 2 : covalent tetrahedra MO 4 -containing borates with deep-ultraviolet cutoff edges9Fluorination strategy toward chemical and functional modification65A bifunctional primitive strategy induces enhancements of large second harmonic generation and wide UV transmittance in rare-earth borates containing [B 5 O 10 ] groups22Ba 5 Y 12 Zn[O(SiO 4 )] 8 : a novel non-centrosymmetric silicate with a short ultraviolet cut-off edge featuring [ZnSi 4 O 16 ] and [SiO 4 ] units3Designing promising ultraviolet (UV) birefringent crystals with different hydrogen-bonded phosphate frameworks18Galloborates as ultraviolet nonlinear optical crystals: advances and perspectives8Halide-driven polarity tuning and optimized SHG-bandgap balance in (C 4 H 11 N 2 )ZnX 3 (X = Cl, Br, I)34Hydrogen bonding bolstered head-to-tail ligation of functional chromophores in a 0D SbF 3 ·glycine adduct for a short-wave ultraviolet nonlinear optical material32Research progress in optical materials with cationic organic planar π-conjugated groups containing CN bonds34新型深紫外非线性光学晶体研究进展（特邀）9Synthesis and Characterization of Metal Iso-cyamelurate K0.5In0.5(H2C6N7O3)2·9H2O with Large Birefringence8Screening Large Birefringent Materials via Halogen Regulation in Ternary d0-Transition Metal Oxyhalides8Unleashing the potential of π-conjugated [B2O3(OH)2] to enhance birefringence in DUV crystals9Sr2[B5O8(OH)]2 ⋅ [B(OH)3] ⋅ H2O: A Strontium Borate That Shows Deep‐Ultraviolet‐Transparent Nonlinear Optical Properties17M6[Cd2(CO3)2(B12O18)(OH)6] (M = K, Rb): Borate–Carbonates with Two CdCO3 Embedded in a Cyclic Oxoboron Anion10Review on birefringence in borates based on birefringence-active functional groups and arrangements57Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units66A Rare-Earth-Based Borate Optical Crystal with Enlarged Dihedral Angles of Distinct [BO3] Groups Exhibiting a Wide UV Transparent Range8Screening Strategy Identifies an Overlooked Deep‐Ultraviolet Transparent Nonlinear Optical Crystal3Screening Strategy Identifies an Overlooked Deep‐Ultraviolet Transparent Nonlinear Optical Crystal45Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering61Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering4Na2B6SO13 with unprecedented [B6SO13]∞ double chains and largest birefringence among borosulfates induced by the uniform arrangement of [B3O7] units19C6N7(NH2)3·H3PO4: Strong Second Harmonic Generation and Giant Birefringence Benefiting from Amino Substitution Strategy24Tetrahedra Modification of Phosphates for Optical Anisotropy Enhancement13Constructing Ultraviolet Nonlinear Optical Crystals with Superior Thermal Stability Based on Organic π-Conjugated [HCOO] Groups6π-Lone pair synergy in (C7H4NO4)(IO3): Optimal balance among SHG, birefringence, and bandgap performance29Deep‐Ultraviolet Transparent Nonlinear Optical Phosphates: A New Alternative to Conventional Borates9Looking Back the Nonlinear Optical Crystals in a Functionalized Unit's Perspective109Structural elucidation, Quantum chemical and optoelectronic properties of novel N,N’-diphenylguanidinium-3,5-dinitrobenzoate single crystal2Coordinated assembly of alkali and alkaline earth metals with the perfluorinated [AlF 6 ] group to design deep-ultraviolet zero-order waveplate materials2Tailoring UV waveplate materials via rational assembly of functional motifs in scandium fluoride phosphate2Pb9Si8O22Cl6 and Pb3.07Ca1.93Si3O11: Two Ultraviolet Nonlinear Optical Materials Exhibit a Moderate Second Harmonic Generation Response1Highly Polarizable Phosphorus‐Centered Tetrahedra and π‐Conjugated Carbon‐Centered Triangular Moieties Inducing Large Anisotropy and Short‐Wavelength Phase‐Matching23K2PbB5P3O17: A Mixed-Coordinated Borophosphate with Enhanced Birefringence Driven by the [B2O5] Unit5Inch‐sized K[NH2(CH2COO)2]: a High‐Performance UV Nonlinear Optical Crystal Enabled by Novel Flexible π‐Conjugated Building Units, [NH2(CH2COO)2]−13Review of KBe2BO3F2-like second-order nonlinear optical materials and their structure-performance relationships13Bridging the Interlayer Binding to Ordered π‐Conjugated Units for Constructing High‐Performing Light Polarization Crystals8Bridging the Interlayer Binding to Ordered π‐Conjugated Units for Constructing High‐Performing Light Polarization Crystals48Recent progress in structural design strategies of high-birefringence optical crystals54[C( NH2 )3] 2SiF6 : Design of Deep Ultraviolet Crystals with Large Birefringence Based on a Fluorination‐Oriented Strategy13A Promising Short-Wave UV NLO Crystal with an Optimized KBBF-like Structure and Well-Balanced Properties Achieved via a Chemical Substitution Strategy6Breaking the Birefringence Barrier in B–O Crystals via B–C π-scaffolding36Synthesis and Characterization of (H7C5N2)6(V10O28)·2H2O with Edge-Sharing VO6 Octahedra Exhibiting Large Birefringence2La(SO3NH2)2NO3·H2O: synergistic anion engineering of the first rare-earth nitrate sulfamate defying transparency-birefringence-nonlinearity trade-offs in ultraviolet nonlinear optics8Unlocking Advanced UV NLO Crystals in Rare‐Earth Metal Borate Fluorides via [B 3 O 6 ]‐Mediated Structural Modulation18Design and Synthesis of a Rare Earth Borate Ultraviolet Nonlinear Optical Crystal K 3 Lu 2 (BO 3 ) 38Maximizing the second-harmonic generation response via coordination-induced localization of nonbonding electrons12High‐Throughput Discovery of Large Birefringence Materials in Mixed‐N Hf‐O Systems0High precision thermal healing of large aperture crystal optics in ultrahigh energy lasers via laser–solid–thermal–fluid multiphysics0Charge-order-induced directional enhancement of non-diagonal second-order nonlinear optical tensor components2Growth of Pr3+:CaYAl3O7 crystal and its spectral properties with excellent thermal stability for visible laser0Synergistic dual-modification strategy of π-conjugated cations and tetrahedra: rational design of ultraviolet high-birefringence monofluorophosphates0Synthesis and characterization of mixed carbonate and bicarbonate materials as candidates for deep-UV applications1Tailoring linear and nonlinear optical properties of 2D Sc 2 C MXenes via surface termination modulation0The condensation of π-conjugated units: a new paradigm for designing high-performance optical crystals4Constructing Deep‐Ultraviolet Nonlinear Optical Crystals via Synergistic Combination of Fluorinated Polyhedra and Polymerized BO 3 Units15Ba 5 Zn 4 (B 3 O 6 ) 2 (B 12 O 24 ): A Borate with Edge-Sharing [BO 4 ] Tetrahedral Connection by Introducing Zn into β-BaB 2 O 42NH 4 B 3 PO 6 (OH) 3 : A Hydroxyborophosphate with Short DUV Cutoff Edge and Large Birefringence2Regulating B‐O Arrangement Boosts Anisotropy in a Simple Rubidium Borate, Leading to a High‐Performance UV NLO Crystal0Growth of Pr3+:CaYAl3O7 crystal and its spectral properties with excellent thermal stability for visible laser0Dual‐Role BF 3 Anchoring Enables Giant Birefringence in Short‐Wave UV‐Transparent Fluoroborates0

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  1. A new acentric borate–nitrate Cs 3 B 8 O 13 (NO 3 ) with interpenetrating porous 3D covalent and ionic lattices

    Dalton Transactions · 2021-01-01

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  2. BaZn 3 (BO 3 ) 2 F 2 : a new beryllium-free zincoborate with a KBBF-type structure

    Dalton Transactions · 2021-01-01

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  3. Enhanced birefringence and suppressed second harmonic generation response mechanism in nonlinear optical materials via structural fine-tuning

    Materials Chemistry Frontiers · 2021-01-01

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  4. Hg 3 (Te 3 O 8 )(SO 4 ): a new sulfate tellurite with a novel structure and large birefringence explored from d 10 metal compounds

    Chemical Communications · 2021-01-01

    Pengfei Li, Chun‐Li Hu, Ya-Ping Gong, Fang Kong, Jiang‐Gao Mao

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  5. Na 2 La 2 B 10 O 19 : a new lanthanum sodium borate with infinite 2D layer 2∞[B 10 O 19 ] 8− and moderate birefringence

    New Journal of Chemistry · 2021-01-01

    Chengfa Wu, Junwei Feng, Feng Yu

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  6. Systematic centricity control using a chiral template: novel noncentrosymmetric polar niobium oxyfluorides and tantalum fluorides directed by chiral histidinium cations, [( l -hisH 2 )NbOF 5 ], [( d -hisH 2 )NbOF 5 ], [( l -hisH 2 )TaF 7 ], and [( d -hisH 2 )TaF 7 ]

    Inorganic Chemistry Frontiers · 2021-01-01

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  7. RbMT3(BO3)2O3 (M=Ba, Sr; T=Al, Ga): New Double‐Layered Oxyborates Constructed from [BO3] Triangles and [TO4] Tetrahedra

    Chemistry - A European Journal · 2021-04-08

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  8. Cs4B4O3F10: First Fluorooxoborate with [BF4] Involving Heteroanionic Units and Extremely Low Melting Point

    Chemistry - A European Journal · 2021-05-03

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  9. Hydrogen‐Bond‐Driven Synergistically Enhanced Hyperpolarizability: Chiral Coordination Polymers with Nonpolar Structures Exhibiting Unusually Strong Second‐Harmonic Generation

    Angewandte Chemie International Edition · 2021-06-07

    Joonhyuk Kee, Kang Min Ok

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  10. Hydrogen‐Bond‐Driven Synergistically Enhanced Hyperpolarizability: Chiral Coordination Polymers with Nonpolar Structures Exhibiting Unusually Strong Second‐Harmonic Generation

    Angewandte Chemie · 2021-06-07

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  11. Hydroxyfluorooxoborate Na[B3O3F2(OH)2]⋅[B(OH)3]: Optimizing the Optical Anisotropy with Heteroanionic Units for Deep Ultraviolet Birefringent Crystals

    Angewandte Chemie International Edition · 2021-06-21

    Congcong Jin, Xuping Shi, Hao Zeng, Shujuan Han, Zhen Chen, Zhihua Yang, Miriding Mutailipu, Shilie Pan

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  12. Hydroxyfluorooxoborate Na[B3O3F2(OH)2]⋅[B(OH)3]: Optimizing the Optical Anisotropy with Heteroanionic Units for Deep Ultraviolet Birefringent Crystals

    Angewandte Chemie · 2021-06-21

    Congcong Jin, Xuping Shi, Hao Zeng, Shujuan Han, Zhen Chen, Zhihua Yang, Miriding Mutailipu, Shilie Pan

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  13. Structural Origin of Very Large Second-Harmonic Generation of a Layered Perovskite, Na0.5Bi2.5Nb2O9

    Chemistry of Materials · 2021-08-04

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  14. Finding a Series of BaBOF3 Fluorooxoborate Polymorphs with Tunable Symmetries: A Simple but Flexible Case

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  15. Two SbX5-based isostructural polar 1D hybrid antimony halides with tunable broadband emission, nonlinear optics, and semiconductor properties

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  16. AMoO3(IO3) (A = Na and K): Two promising optical materials via properly assembling the Λ-shaped basic building units

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  17. Ba2B13O19(OH)5·5H2O: A promising nonlinear optical material with a unique 2[B13O19(OH)5]∞ two-dimensional layer

    Journal of Alloys and Compounds · 2021-12-09

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  18. K3BaTeB7O15: A new borotellurite with mixed metal cations

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  19. Guanidinium Fluorooxoborates as Efficient Metal-free Short-Wavelength Nonlinear Optical Crystals

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  20. Phase Matchability Transformation in the Infrared Nonlinear Optical Materials with Diamond‐Like Frameworks

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  21. (N 2 H 6 )[HPO 3 F] 2 : maximizing the optical anisotropy of deep-ultraviolet fluorophosphates

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  22. Band gap modulation and nonlinear optical properties of quaternary tellurates Li 2 GeTeO 6

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  23. Hexameric poly-fluoroberyllophosphate Na 4 Be 2 PO 4 F 5 with moderate birefringence and deep-ultraviolet transmission as a potential zero-order-waveplate crystal

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  24. K 2 S 4 O 6 : improving birefringence and nonlinear optical properties with the [O 3 S–S–S–SO 3 ] 2− group

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  25. KLi 2 CO 3 F: a beryllium-free KBBF-type deep-UV carbonate with an enhanced interlayer interaction and large birefringence

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  26. Na 2 SrB 16 O 26 : a new borate with independent interpenetrating B–O networks and deep-ultraviolet cutoff edge

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  27. PNO: a promising deep-UV nonlinear optical material with the largest second harmonic generation effect

    Chemical Communications · 2022-01-01

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  28. α-LiMB 9 O 15 (M = Sr, Pb): flexible [B 3 O 7 ] units leading to the low temperature phase of β-LiMB 9 O 15 (M = Sr, Pb)

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  29. Review of Heteroleptic Tetrahedra as Birefringent or Nonlinear Optical Motifs

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  30. Potential optical functional crystals with large birefringence: Recent advances and future prospects

    Coordination Chemistry Reviews · 2022-02-08

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  31. “Removing Center”─An Effective Structure Design Strategy for Nonlinear Optical Crystals

    Chemistry of Materials · 2022-02-15

    Shuzhao Huang, Yun Mo Yang, Jianbang Chen, Wenqi Jin, Shichao Cheng, Zhihua Yang, Shilie Pan

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  32. Finding the First Squarates Nonlinear Optical Crystal NaHC4O4·H2O with Strong Second Harmonic Generation and Giant Birefringence

    ACS Materials Letters · 2022-03-02

    Xiaodong Zhang, Dong-Xu Cao, Daqing Yang, Ying Wang, Kui Wu, Ming‐Hsien Lee, Bingbing Zhang

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  33. Strong Nonlinearity Induced by Coaxial Alignment of Polar Chain and Dense [BO3] Units in CaZn2(BO3)2

    Angewandte Chemie · 2022-03-08

    Miriding Mutailipu, Fuming Li, Congcong Jin, Zhihua Yang, Kenneth Reinhard Poeppelmeier, Shilie Pan

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  34. Strong Nonlinearity Induced by Coaxial Alignment of Polar Chain and Dense [BO3] Units in CaZn2(BO3)2

    Angewandte Chemie International Edition · 2022-03-08

    Miriding Mutailipu, Fuming Li, Congcong Jin, Zhihua Yang, Kenneth Reinhard Poeppelmeier, Shilie Pan

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  35. Double‐Modification Oriented Design of a Deep‐UV Birefringent Crystal Functionalized by [B12O16F4(OH)4] Clusters

    Angewandte Chemie · 2022-05-11

    Congcong Jin, Fuming Li, Bingliang Cheng, Haotian Qiu, Zhihua Yang, Shilie Pan, Miriding Mutailipu

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  36. Double‐Modification Oriented Design of a Deep‐UV Birefringent Crystal Functionalized by [B12O16F4(OH)4] Clusters

    Angewandte Chemie International Edition · 2022-05-11

    Congcong Jin, Fuming Li, Bingliang Cheng, Haotian Qiu, Zhihua Yang, Shilie Pan, Miriding Mutailipu

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  37. Enhancement of Birefringence in Borophosphate Pushing Phase-Matching into the Short-Wavelength Region

    Journal of the American Chemical Society · 2022-05-13

    Wenbin Zhang, Junben Huang, Shujuan Han, Zhihua Yang, Shilie Pan

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  38. (NH4)3B11PO19F3: a deep-UV nonlinear optical crystal with unique [B5PO10F]∞ layers

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  44. Ba6Zn6(B3O6)6(B6O12): Barium Zinc Borate Contains π-Conjugated [B3O6]3– Anions and [B6O12]6– Anion with Edge-Sharing BO4 Tetrahedra

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  45. Local Polarity-Induced Assembly of Second-Order Nonlinear Optical Materials

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