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RESEARCH PAPER · Science China Chemistry · 2021

Two SbX5-based isostructural polar 1D hybrid antimony halides with tunable broadband emission, nonlinear optics, and semiconductor properties

Zhikai Qi, Yali Chen, Huizhi Gao, Fuqiang Zhang, Shi-Li Li, Xian‐Ming Zhang

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Two SbX5-based isostructural polar 1D hybrid antimony halides with tunable broadband emission, nonlinear optics, and semiconductor propertiesOriginalModulating photoelectron localization degree to achieve controllable photoluminescence quenching and activation of 0D hybrid antimony perovskites53Organic–Inorganic Hybrid Antimony(III) Halides for Second Harmonic Generation34Blue Light-Excitable Broadband Yellow Emission in a Zero-Dimensional Hybrid Bismuth Halide with Type-II Band Alignment39Characteristics of structure, thermal stability and optical properties for a novel NLO crystal (C5H12NO)H2PO48From H 12 C 4 N 2 CdI 4 to H 11 C 4 N 2 CdI 3 : a highly polarizable CdNI 3 tetrahedron induced a sharp enhancement of second harmonic generation response and birefringence50Singlet exciton and singlet/triplet self-trapped excitons for ultra-broadband white-light emission in a zero-dimensional cadmium bromide hybrid25Zero-dimensional antimony halides with tunable photoluminescence via halogen ligand modulation16Second-Harmonic Generation in Homochiral Antimony Halides Directed by l -Histidine24Luminescent Behavior of Sb3+-Activated Luminescent Metal Halide26Broadband blue light emissions of one-dimensional hybrid Cu( i ) halides with ultrahigh anti -water stability12The role of halogens in structural diversity and chirality enhancement of 1D chiral hybrid metal halides8Zero-dimensional hybrid tin halides with stable broadband light emissions14A New centrosymmetric supramolecular Hybrid Antimony (III)-based material :X-ray characterization, vibrational studies, theoretical (DFT and TD-DFT) studies, thermal behavior, opto-electric properties and atomic Hirshfeld surface analysis.3CPL-active hybrid copper(I) halides enabled by cation inclusion with chiral crown-ether11A new zero-dimensional hybrid antimony halide of (C25H46N)2SbCl5 with dual-emission and high quantum-efficiency for light-emitting application17Manganese-manganese distance modulation in zero-dimensional hybrid manganese halides using pyridine quaternary ammonium salts as templates14Photoluminescent chain-of-dimer anion in a novel hybrid halometallate (C 5 H 14 N 2 ) 3 {Sb 2 Br 9 } 2 : atypical behavior in one-dimensional anionic systems5Strong second-harmonic generation response in an organic–inorganic hybrid antimony bromide1Zero-dimensional organic–inorganic hybrid antimony bromide with efficient broadband orange emission and nonlinear optical response17Tetracoordinated Manganese(II) Halide with Multimode Thermochromic Luminescence for Anticounterfeiting and Encryption11Rearrangement of Sb···Br Secondary Bonds Resulting in Reversible Transformation between Dimeric and Chain-Like Antimony Bromide Hybrid Materials: Tunability of Electron Self-Trapped Luminescence and Proton Conductivity2Advanced Optoelectronic Properties of Sb(III) based Metal Halides: Opportunities and Challenges25Investigation of structural characterization, vibrationaland optical properties of a novel 1D semiconductor antimony(III) halide incorporating 3-chloro-6-methylpyridazine1Designing Hybrid Sb-Based Nonlinear Optical Crystals with Large Birefringence by Combining the Lone Pair and π-Conjugated Genes10Multi-aromatic organic cation engineering unlocks high-efficient photoluminescence and dual-mode mechanoluminescence of zero-dimensional [Sb2Cl8]2− dimer10A one-dimensional hybrid ferroelectric exhibiting lone pair stereoactivity based on square pyramids1Luminescence tuning in a zero-dimensional organic–inorganic hybrid metal halide family of (C 7 H 18 N 2 )MBr 4 (M = Cd, Zn, and Mn)3Second-harmonic generation in two hybrid organic–inorganic metal chlorides based on l -thioproline ligand1Syntheses, structures and optical properties of two new cadmium antimonites: Cs 4 Cd(SbF 5 ) 3 (H 2 O) 2 and Cd[Sb 7 O 10 (OH)](SO 4 )0Structural Tuning via Chain Length for Emergent Second Harmonic Generation in Hybrid Metal Halides1Unlocking Strong SHG Response and Large Birefringence in Hybrid Antimony Halides via a Three-in-One Strategy7[Sb2I10]4− Chains, I2 Molecules and I− ions coexisting in a narrow bandgap iodoantimonate hybrid: Structure, characterization, electrical conductivity and theoretical insight2V-Shaped Pseudo-Chains Coupled with Lone-Pair-Distorted [GeX 3 ] − Units Enable Large Birefringence in Ge(II) Hybrid Halides2Organic–inorganic hybrid antimony halides: Optical properties design toward advanced optoelectronic applications2

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34 direct citing papers saved.

  1. Modulating photoelectron localization degree to achieve controllable photoluminescence quenching and activation of 0D hybrid antimony perovskites

    Journal of Materials Chemistry C · 2022-01-01

    Dongyang Li, Yu Cheng, Yu-Han Hou, Junhua Song, Chuan‐Ju Sun, Cheng‐Yang Yue, Zhihong Jing, Xiao‐Wu Lei

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  2. Organic–Inorganic Hybrid Antimony(III) Halides for Second Harmonic Generation

    Crystal Growth & Design · 2022-10-14

    Siming Qi, Puxin Cheng, Xiao Han, Fei Ge, Rongchao Shi, Liang Xu, Geng Li, Jialiang Xu

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  3. Blue Light-Excitable Broadband Yellow Emission in a Zero-Dimensional Hybrid Bismuth Halide with Type-II Band Alignment

    Inorganic Chemistry · 2022-11-16

    Zhikai Qi, Huizhi Gao, Xudong Zhu, Zhuo‐Ya Lu, Xian‐Ming Zhang

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  4. Characteristics of structure, thermal stability and optical properties for a novel NLO crystal (C5H12NO)H2PO4

    Optical Materials · 2022-11-27

    Duanliang Wang, Xiangsheng Meng, Nana Zhang, Defu Sun, Ruoxian Hou, Hanzhang Chen, Xiaobing Liu

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  5. From H 12 C 4 N 2 CdI 4 to H 11 C 4 N 2 CdI 3 : a highly polarizable CdNI 3 tetrahedron induced a sharp enhancement of second harmonic generation response and birefringence

    Chemical Science · 2023-01-01

    Huai‐Yu Wu, Chun‐Li Hu, Miao‐Bin Xu, Qianqian Chen, Nan Ma, Xiao‐Ying Huang, Ke‐Zhao Du, Jin Chen

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  6. Singlet exciton and singlet/triplet self-trapped excitons for ultra-broadband white-light emission in a zero-dimensional cadmium bromide hybrid

    Journal of Materials Chemistry C · 2023-01-01

    Huizhi Gao, Zhuo‐Ya Lu, Xingxing Zhao, Ke Zhang, Xudong Zhu, Rixin Cheng, Shi-Li Li, Zhikai Qi, Xian‐Ming Zhang

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  7. Zero-dimensional antimony halides with tunable photoluminescence via halogen ligand modulation

    Journal of Materials Chemistry C · 2023-01-01

    Zhaohui Huang, Enzhi Zhao, Ping Qi, Aixin Song

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  8. Second-Harmonic Generation in Homochiral Antimony Halides Directed by l -Histidine

    Inorganic Chemistry · 2023-10-02

    Juan Cheng, Peiqi Qian, Meng Yang, Ling Huang, Hongmei Zeng, Guohong Zou, Zhien Lin

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  9. Luminescent Behavior of Sb3+-Activated Luminescent Metal Halide

    Nanomaterials · 2023-10-29

    Tao Huang, Bingsuo Zou

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  10. Broadband blue light emissions of one-dimensional hybrid Cu( i ) halides with ultrahigh anti -water stability

    Dalton Transactions · 2024-01-01

    Na Lin, Yunxia Li, Yu Liu, Kai-Qi Sun, Hong-Yan Zhang, Xiao‐Wu Lei, Zhiwei Chen

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  11. The role of halogens in structural diversity and chirality enhancement of 1D chiral hybrid metal halides

    Journal of Materials Chemistry C · 2024-01-01

    Jing‐Meng Zhang, Xiang‐Bin Han, Wei Qiang Wang, Ming‐Liang Jin, Chang‐Qing Jing, Chao‐Yang Chai, Chengdong Liu, Wen Zhang

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  12. Zero-dimensional hybrid tin halides with stable broadband light emissions

    Dalton Transactions · 2024-01-01

    Jing-Ning Lv, Jie Zhang, Yu-Meng Liu, Shaoya Zhang, Xiang-Yuan Deng, Man Xu, Xiao‐Wu Lei, Zhiwei Chen, Cheng‐Yang Yue

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  13. A New centrosymmetric supramolecular Hybrid Antimony (III)-based material :X-ray characterization, vibrational studies, theoretical (DFT and TD-DFT) studies, thermal behavior, opto-electric properties and atomic Hirshfeld surface analysis.

    Journal of Molecular Structure · 2024-06-07

    Nour Elleuch, Sameh Sellami, Lobna Jlail, Jérôme Lhoste, Mohamed Boujelbene

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  14. CPL-active hybrid copper(I) halides enabled by cation inclusion with chiral crown-ether

    Science China Chemistry · 2024-08-22

    Peng Fan, Li‐Xuan Cai, Xiao‐Fang Duan, Fan Yin, Chenchen Li, Zhonghua Deng, Xiaozhen Li, Qing‐Fu Sun

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  15. A new zero-dimensional hybrid antimony halide of (C25H46N)2SbCl5 with dual-emission and high quantum-efficiency for light-emitting application

    Materials Today Chemistry · 2024-08-28

    Xixi Cheng, Bobo Yang, Shiliang Mei, Wenfang Peng, Yuanyuan Wang, Changran Zheng, Yang Li, Rongrong Hu, Jiang Li, Jun Zou

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  16. Manganese-manganese distance modulation in zero-dimensional hybrid manganese halides using pyridine quaternary ammonium salts as templates

    Materials Today Chemistry · 2024-10-28

    Haiming Cheng, Xudong Hu, Chi Cao, Haiping Xu, Xiaoyi Liu, Xiaoming Li, Huiyan Wang, Keke Huang, Wensheng Yang, Dayang Wang, Renguo Xie

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  17. Photoluminescent chain-of-dimer anion in a novel hybrid halometallate (C 5 H 14 N 2 ) 3 {Sb 2 Br 9 } 2 : atypical behavior in one-dimensional anionic systems

    Dalton Transactions · 2024-11-27

    Andrey V. Bykov, Tatiana A. Shestimerova, M. A. Bykov, Victoria E. Gontcharenko, Konstantin Alexandrovich Lyssenko, Mikhail T. Metlin, Il'ya Viktorovich Taydakov, Anastasia V. Grigorieva, Аndrei V. Shevelkov

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  18. Strong second-harmonic generation response in an organic–inorganic hybrid antimony bromide

    Dalton Transactions · 2025-01-01

    Xuemei Wen, Gangji Yi, Qinglan Zhong, Caihong Guo, Hongmei Zeng, Guohong Zou, Zhien Lin

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  19. Zero-dimensional organic–inorganic hybrid antimony bromide with efficient broadband orange emission and nonlinear optical response

    RSC Advances · 2025-01-01

    Zhao Wang, Xiaoxue Xi, Xueli Chen

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  20. Tetracoordinated Manganese(II) Halide with Multimode Thermochromic Luminescence for Anticounterfeiting and Encryption

    Inorganic Chemistry · 2025-05-30

    Zhaohui Huang, Xiaoli Wang, Peng Du, Chuanqi Feng, Ping Niu, XU Dong-mei, Lumin Wang, Wei Gao, Aixin Song

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  21. Rearrangement of Sb···Br Secondary Bonds Resulting in Reversible Transformation between Dimeric and Chain-Like Antimony Bromide Hybrid Materials: Tunability of Electron Self-Trapped Luminescence and Proton Conductivity

    Inorganic Chemistry · 2025-06-02

    Jiantao Yuan, Nan Zhang, Jian Zhang, Xian‐Ming Zhang

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  22. Advanced Optoelectronic Properties of Sb(III) based Metal Halides: Opportunities and Challenges

    Advanced Functional Materials · 2025-07-06

    Tao Huang, Hui Peng, Ruosheng Zeng, Bingsuo Zou

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  23. Investigation of structural characterization, vibrationaland optical properties of a novel 1D semiconductor antimony(III) halide incorporating 3-chloro-6-methylpyridazine

    Journal of Molecular Structure · 2025-07-15

    Eya Toumi, Nour Elleuch, Sergiu G. Shova, Mohamed Boujelbene

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  24. Designing Hybrid Sb-Based Nonlinear Optical Crystals with Large Birefringence by Combining the Lone Pair and π-Conjugated Genes

    Inorganic Chemistry · 2025-07-28

    Kang Yang, Duanliang Wang, Fangcong Liu, Chuanrui Zhu, Qiyao Wang, Kui Wu, Jiyang Wang, Chuanying Shen

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  25. Multi-aromatic organic cation engineering unlocks high-efficient photoluminescence and dual-mode mechanoluminescence of zero-dimensional [Sb2Cl8]2− dimer

    Chemical Engineering Journal · 2025-10-31

    Fu Wang, Siyu Zhang, Qiyu Zhao, Kangkang Wang, Zuobin Tang, Binbin Su, Jiaren Du, Hu Liu, Huidong Xie

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  26. A one-dimensional hybrid ferroelectric exhibiting lone pair stereoactivity based on square pyramids

    Dalton Transactions · 2026-01-01

    Ya-Juan Li, Yu-Qiao Tong, Shi-Qing Yin, Qian-Jun Gu, Peng-Peng Gong, Yi Guo, Bo Huang, Ai‐Xin Zhu

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  27. Luminescence tuning in a zero-dimensional organic–inorganic hybrid metal halide family of (C 7 H 18 N 2 )MBr 4 (M = Cd, Zn, and Mn)

    Inorganic Chemistry Frontiers · 2026-01-01

    Zhongliang Gong, Xiaodong Yi, Xi-Gui Gao, Huwenyu Huang, Yuxin Ma, Zi‐xuan Liu, Jingmei Zhao, Lijuan Feng, Cheng-Yang Yue

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  28. Second-harmonic generation in two hybrid organic–inorganic metal chlorides based on l -thioproline ligand

    CrystEngComm · 2026-01-01

    Yingjie Wang, Peiqi Qian, Xuemei Wen, Hongmei Zeng, Guohong Zou, Zhien Lin

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  29. Syntheses, structures and optical properties of two new cadmium antimonites: Cs 4 Cd(SbF 5 ) 3 (H 2 O) 2 and Cd[Sb 7 O 10 (OH)](SO 4 )

    Dalton Transactions · 2026-01-01

    Yi Yuan, Chun‐Li Hu, Dan-Dan Zhou, Jiang‐Gao Mao, Fang Kong

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  30. Structural Tuning via Chain Length for Emergent Second Harmonic Generation in Hybrid Metal Halides

    Inorganic Chemistry · 2026-02-02

    Yibo Cui, Jiawei Lin, Lei Gao, Yuhe Shao, Ruonan Yao, Zhongnan Guo, Jing Zhao, Quanlin Liu

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  31. Unlocking Strong SHG Response and Large Birefringence in Hybrid Antimony Halides via a Three-in-One Strategy

    Inorganic Chemistry · 2026-02-03

    Yuqi Xu, Yi-Fan Fu, Wen-Dong Yao, Yumei Zhang, Liming Kong, Wenlong Liu, Jiajing Wu

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  32. [Sb2I10]4− Chains, I2 Molecules and I− ions coexisting in a narrow bandgap iodoantimonate hybrid: Structure, characterization, electrical conductivity and theoretical insight

    Journal of Molecular Structure · 2026-02-12

    Shuyue Xie, Ya-Zhen Song, Hanhua Zhao, Jun Li, Yong Yan, Bo Zhang

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  33. V-Shaped Pseudo-Chains Coupled with Lone-Pair-Distorted [GeX 3 ] − Units Enable Large Birefringence in Ge(II) Hybrid Halides

    Crystal Growth & Design · 2026-02-28

    Tiantian Wang, Lu Liu, Gangji Yi, Xiangyu Han, Xuehua Dong, Hongmei Zeng, Zhien Lin, Guohong Zou

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  34. Organic–inorganic hybrid antimony halides: Optical properties design toward advanced optoelectronic applications

    Coordination Chemistry Reviews · 2026-04-30

    Jiaojiao Wei, Xiaodong Yi, Chongchong Chen, Tiantian Sun, Hongru Fu, Wei Zheng, Xueyuan Chen

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