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RESEARCH PAPER · Inorganic Chemistry Frontiers · 2022

KLi 2 CO 3 F: a beryllium-free KBBF-type deep-UV carbonate with an enhanced interlayer interaction and large birefringence

Qiang Wang, Wen Dong Song, Yang Lan, Liling Cao, Ling Huang, Daojiang Gao, Jian Bi, Guohong Zou

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KLi 2 CO 3 F: a beryllium-free KBBF-type deep-UV carbonate with an enhanced interlayer interaction and large birefringenceOriginalSn3B10O17Cl2 Achieving Birefringence Enhancement by Stereochemical Activity Lone Pair9Dramatically improved optical anisotropy by realizing stereochemically active lone pairs in a sulfate system, K 2 SO 4 ·HIO 323Achieving great optical anisotropy with the well-directed alignment of π-conjugated groups due to hydrogen bonds9Explorations of highly birefringent materials in the vanadium oxyfluoride–iodate system by fluoride ion modulation8KBa 3 M 2 F 14 Cl (M = Zr, Hf): novel short-wavelength mixed metal halides with the largest second-harmonic generation responses contributed by mixed functional moieties37The local state of hydrogen atoms and proton transfer in the crystal structure of natural berborite, Be2(BO3)(OH)‧H2O: Low-temperature single crystal X-ray analysis, IR and 1H NMR spectroscopy, and crystal chemistry and structural complexity of beryllium borates8Centrosymmetric CaBaMF8 and Noncentrosymmetric Li2CaMF8 (M = Zr, Hf): Dimension Variation and Nonlinear Optical Activity Resulting from an Isovalent Cation Substitution-Oriented Design17Sb2O2SeO3 and Sb2O(SeO3)2: Two-Layered Antimony(III) Selenites with Enhanced Birefringence10Amino substitution strategy achieves significant blue shift while preserving high optical anisotropy: A2(H3C3N4S2)2•H2O (A =NH4, K, Rb, Cs)6BaPb2(CO3)2F2: Enhancing Birefringence by a Multiunit Synergy Effect9Rational Design and Controlled Synthesis of High-Performance Inorganic Short-Wave UV Nonlinear Optical Materials150K 2 Na(I 3 O 8 ) 3 : a promising mid-infrared birefringent material with two different structures of octaoxotriiodate( v ) polyanions1K3[HCO3]2F: a new deep-UV birefringent crystal exhibiting strong optical anisotropy17A Promising Deep Ultraviolet Nonlinear Optical Crystal Activated by the Ordered Structure Design40A Promising Deep Ultraviolet Nonlinear Optical Crystal Activated by the Ordered Structure Design3Review of KBe2BO3F2-like second-order nonlinear optical materials and their structure-performance relationships13Hydrogen Bond-Assisted Structural Regulation Enables Large Birefringence in Two Antimony Oxalofluoride Crystals5Enhanced Birefringence in Hybrid Antimony Halides via π-Conjugated Organic Cation Design10Regulating KBBF-like structures via a charge-assisted hydrogen-bonded framework to enable easily grown ultraviolet nonlinear optical crystals0Synthesis and characterization of mixed carbonate and bicarbonate materials as candidates for deep-UV applications1

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  1. Sn3B10O17Cl2 Achieving Birefringence Enhancement by Stereochemical Activity Lone Pair

    Inorganic Chemistry · 2022-11-01

    Lihan Deng, Mengfan Wu, Zhihua Yang, Shujuan Han, Shilie Pan

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  2. Dramatically improved optical anisotropy by realizing stereochemically active lone pairs in a sulfate system, K 2 SO 4 ·HIO 3

    Inorganic Chemistry Frontiers · 2023-01-01

    Zhiyong Bai, Kang Min Ok

    Read original paper ↗ ·

  3. Achieving great optical anisotropy with the well-directed alignment of π-conjugated groups due to hydrogen bonds

    Journal of Saudi Chemical Society · 2023-12-16

    Chenhui Hu, Junjie Liu, Jiale Qu, Jinghui Hu, Xiangzhan Jiang

    Read original paper ↗ ·

  4. Explorations of highly birefringent materials in the vanadium oxyfluoride–iodate system by fluoride ion modulation

    Journal of Materials Chemistry C · 2024-01-01

    Yu Huang, Xueying Zhang, Sangen Zhao, Jiang‐Gao Mao, Bing‐Ping Yang

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  5. KBa 3 M 2 F 14 Cl (M = Zr, Hf): novel short-wavelength mixed metal halides with the largest second-harmonic generation responses contributed by mixed functional moieties

    Chemical Science · 2024-01-01

    Mei Yan, Chun‐Li Hu, Ru‐Ling Tang, Wen‐Dong Yao, Wenlong Liu, Sheng‐Ping Guo

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  6. The local state of hydrogen atoms and proton transfer in the crystal structure of natural berborite, Be2(BO3)(OH)‧H2O: Low-temperature single crystal X-ray analysis, IR and 1H NMR spectroscopy, and crystal chemistry and structural complexity of beryllium borates

    Journal of Physics and Chemistry of Solids · 2024-02-22

    Sergey M. Aksenov, Nikita V. Chukanov, Viktor P. Tarasov, Daria A. Banaru, Stephanie A. Mackley, A. M. Banaru, Sergey V. Krivovichev, Peter Carman Burns

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  7. Centrosymmetric CaBaMF8 and Noncentrosymmetric Li2CaMF8 (M = Zr, Hf): Dimension Variation and Nonlinear Optical Activity Resulting from an Isovalent Cation Substitution-Oriented Design

    Inorganic Chemistry · 2024-03-06

    Mei Yan, Ru‐Ling Tang, Wei Xu, Wenlong Liu, Sheng‐Ping Guo

    Read original paper ↗ ·

  8. Sb2O2SeO3 and Sb2O(SeO3)2: Two-Layered Antimony(III) Selenites with Enhanced Birefringence

    Inorganic Chemistry · 2024-06-04

    Han Luo, Yu Zhang, Tingyu Wang, Ling Huang, Liling Cao, Xuehua Dong, Guohong Zou

    Read original paper ↗ ·

  9. Amino substitution strategy achieves significant blue shift while preserving high optical anisotropy: A2(H3C3N4S2)2•H2O (A =NH4, K, Rb, Cs)

    Chinese Chemical Letters · 2024-11-10

    Shuang Zhao, Fei Jia, Kaibei Zhan, Rui‐Xi Wang, Pengfei Tan, Lin Shen, Li‐Ming Wu, Ling Chen

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  10. BaPb2(CO3)2F2: Enhancing Birefringence by a Multiunit Synergy Effect

    Inorganic Chemistry · 2024-12-02

    Yuan Hua Lin, Rongfang Zhang, Yucheng Hao, Ming-Yang Cao, Xuanlin Pan, Jiang‐Gao Mao

    Read original paper ↗ ·

  11. Rational Design and Controlled Synthesis of High-Performance Inorganic Short-Wave UV Nonlinear Optical Materials

    Accounts of Chemical Research · 2024-12-12

    Xuehua Dong, Ling Huang, Guohong Zou

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  12. K 2 Na(I 3 O 8 ) 3 : a promising mid-infrared birefringent material with two different structures of octaoxotriiodate( v ) polyanions

    New Journal of Chemistry · 2025-01-01

    Min-Quan Lin, M. Duan, Jiang-Gao Mao, Bing‐Ping Yang

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  13. K3[HCO3]2F: a new deep-UV birefringent crystal exhibiting strong optical anisotropy

    Science China Materials · 2025-03-03

    Wenbin Zhang, Yabo Wu, Zhihua Yang, Shujuan Han, Shilie Pan

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  14. A Promising Deep Ultraviolet Nonlinear Optical Crystal Activated by the Ordered Structure Design

    Angewandte Chemie International Edition · 2025-03-11

    Haonan Liu, Xuming Zhai, Xinru Li, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  15. A Promising Deep Ultraviolet Nonlinear Optical Crystal Activated by the Ordered Structure Design

    Angewandte Chemie · 2025-03-11

    Haonan Liu, Xuming Zhai, Xinru Li, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  16. Review of KBe2BO3F2-like second-order nonlinear optical materials and their structure-performance relationships

    Coordination Chemistry Reviews · 2025-04-06

    Junben Huang, Chenglong Zhang, Siying Chen, Ailijiang Abudurusuli

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  17. Hydrogen Bond-Assisted Structural Regulation Enables Large Birefringence in Two Antimony Oxalofluoride Crystals

    Inorganic Chemistry · 2025-08-05

    Tingyu Wang, Dan Wang, Bailiang Li, Ling Huang, Liling Cao, Xuehua Dong, Guohong Zou

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  18. Enhanced Birefringence in Hybrid Antimony Halides via π-Conjugated Organic Cation Design

    Crystal Growth & Design · 2025-09-02

    Luli Wang, Han Luo, Siyu Chen, Ling Huang, Liling Cao, Xuehua Dong, Guohong Zou

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  19. Regulating KBBF-like structures via a charge-assisted hydrogen-bonded framework to enable easily grown ultraviolet nonlinear optical crystals

    Chemical Science · 2026-01-01

    Mingshu Zhang, Shuya Zhao, Zhen‐Cheng Wu, Yue Yin, Zheyu Zhang, Jiafeng Chen, Sheng‐Ping Guo, Yan Zhou

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  20. Synthesis and characterization of mixed carbonate and bicarbonate materials as candidates for deep-UV applications

    Chemical Communications · 2026-01-01

    Muhammad Mujahid Iqbal, Hussin Elkik, Changyou Liu, Aqsa Munawar, Zilong Chen, Zhihua Yang, Fangfang Zhang, Shilie Pan

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