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RESEARCH PAPER · Advanced Optical Materials · 2021

Eu 2+ Stabilized at Octahedrally Coordinated Ln 3+ Site Enabling Red Emission in Sr 3 LnAl 2 O 7.5 (Ln = Y or Lu) Phosphors

Tao Hu, Yan Na Gao, Мaxim S. Моlokeev, Zhiguo Xia, Qinyuan Zhang

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Eu 2+ Stabilized at Octahedrally Coordinated Ln 3+ Site Enabling Red Emission in Sr 3 LnAl 2 O 7.5 (Ln = Y or Lu) PhosphorsOriginalDesign principles for achieving red emission in Eu2+/Eu3+ doped inorganic solids83Photoluminescence tuning in Ba3ScB3O9:Eu2+ phosphor by crystal-site engineering17Li + Ion Induced Full Visible Emission in Single Eu 2+ ‐Doped White Emitting Phosphor: Eu 2+ Site Preference Analysis, Luminescence Properties, and WLED Applications93Bismuth activated blue phosphor with high absorption efficiency for white LEDs55Realization of non-rare earth doped blue-emitting phosphor Ba2Y5B5O17: Sb by selective site excitation, and its application in n-UV excited wLEDs3Giant Red‐Shifted Emission in (Sr,Ba)Y 2 O 4 :Eu 2+ Phosphor Toward Broadband Near‐Infrared Luminescence230A novel differential display material: K3LuSi2O7: Tb3+/Bi3+ phosphor with thermal response, time resolution and luminescence color for optical anti-counterfeiting56Full-visible-spectrum lighting enabled by site-selective occupation in the high efficient and thermal stable (Rb, K)2CaPO4F: Eu2+ solid-solution phosphors58A new class of battery-free, mechanically powered, piezoelectric Ca 5 Ga 6 O 14 :Tb 3+ phosphors with self-recoverable luminescence46A novel red-emitting phosphor with an unusual concentration quenching effect for near-UV-based WLEDs40Stable Tunable Luminescence of Hetero-valent Eu Ion Activated Ba2InTaO6 Phosphors Synthesized by Defect-Induced Self-Reduction in the Molten-Salt Method16Tendentious multiple sites occupation towards white light emission in single-phase Ba2(1-/3)Ca(1-/3)Sr B2Si4O14:Eu2+ phosphors16Competitive Site Occupation toward Improved Quantum Efficiency of SrLaScO 4 :Eu Red Phosphors for Warm White LEDs103Eu2+ Doping Concentration-Induced Site-Selective Occupation and Photoluminescence Tuning in KSrScSi2O7:Eu2+ Phosphor77Luminescence properties and thermal stability of Dy3+/Eu3+co-doped single-component BaZn2(PO4)2 glass-ceramic phosphors32Synthesis of the Red-Emitting (Ba, Ca)2ScAlO5:Eu3+ Phosphors with Photoluminescence Properties30Far-red-emitting LaSrRO4:Mn4+ (R = Al and Ga) phosphor: Synthesis and optical properties11Dual-mode optical thermometry design in K 3 YSi 2 O 7 :Eu multi-site phosphor8Sr-substitution-guided Eu2+ site engineering of Ca9Nd(PO4)7:Eu2+ for high-efficiency white light-emitting diodes9Blue-light-excited red emission in a CaO:Eu phosphor17Recent progress in Ce 3+ /Eu 2+ -activated LEDs and persistent phosphors: focusing on the local structure and the electronic structure137Site-selective occupation of Cr3+ ions toward ultra-broadband near-infrared emission stannate phosphors23A multi-centre activated single-phase white light phosphor with high efficiency for near-UV based WLEDs69Ba 3 LuGa 2 O 7.5 :Bi 3+ phosphors with potential application in full-spectrum WLEDs and temperature sensing73Broadband emitting phosphor Sr 6 Sc 2 Al 4 O 15 :Cr 3+ for near-infrared LEDs31Ceramics phosphor powders4Eu 2+ luminescence in CaYGaO 4 olivine: a new efficient red phosphor for warm illumination47Spectral properties and self-reduction of Eu 3+ to Eu 2+ in aluminosilicate oxyfluoride glass30Effects of structural phase changes on the luminescence of Eu-doped (1-x)BaTiO3-xCaZrO311Efficient, stable, broadband cyan‐emitting Ca‐substituted Ba 9 Lu 2 Si 6 O 24 :Eu 2+ with multisite luminescence for NUV‐wLEDs7Synthesis, structure, and luminescence properties of melilite Dy3+:Lu CaLa0.98–Ga3O7 phosphors for use in yellow light-emitting devices22Site Occupation Engineering toward Giant Red-Shifted Photoluminescence in (Ba,Sr)2LaGaO5:Eu2+ Phosphors63Improved thermal stability and quantum efficiency of novel cyan phosphors toward full-visible-spectrum lighting15Millimeter-Sized K2MnF6:Si4+, NH4+ Red-Luminescent Crystals with High Absorption Efficiency (AEmax of 93.5%) and External Quantum Efficiency (EQEmax of 68.9%) Grown by Cooling-Induced Crystallization11Synthesis and luminescent properties of a new cyan Ca18Li6-3xYx(PO4)14:0.1Eu phosphors and PVA-based composite films for multifunctional applications11A polymorphic SrGa 2 O 4 :Eu 2+ red phosphor for warm illumination and operando visualization of H 2 O 2 catalytic reaction4Structure tailoring and defect engineering of a highly thermally stable red emitting phosphor22An efficient and thermally stable red emitting Eu2+ doped oxide for rechargeable portable flashlight62Pure-red phosphor Ca3Si2O7:Eu2+ obtained by the CO reduction strategy13A new yellowish‐green‐emitting phosphor: Eu 2+ ‐doped Ba 3 YAl 2 O 7.55Unlocking Chlorine Oxide‐Based Ultra‐Wideband Near‐Infrared Phosphor and Advancing Spectral Performance via Lattice Engineering43Achieving Eu 2+ Luminescence at Trivalent Lattice Site in Rb 3 Y(PO 4 ) 2 :Eu toward Multicolor Emissions by Carbon and Hydrogen Coreduction23Development of Mg2TiO4:Mn4+ phosphors for enhanced red LED emission and forensic fingerprint analysis21Sunlight‐Activated Eu2+‐Doped Red Persistent Luminescence Material for Night‐Vision Signage, Anti‐Counterfeiting and Location Detection30Controllable multicolored optical glass-ceramics based on nanostructure strategies and dopants0Cation substitution strategy realizing controllable spectral shape and multiple applications in a novel blue-cyan emitting KBaScSi2O7:Bi3+ phosphor4Calcium vacancy enhanced self-reduction of Ce4+ for single-phase full-spectrum lighting and information encryption2Compositional engineering of phase-stable and highly efficient deep-red emitting phosphor for advanced plant lighting systems94Recent progress of inorganic phosphors in artificial plant cultivation LEDs46A novel red emitting phosphor CaSc2O4:Eu2+ for the warm white LEDs8A review of recent advances in Ce3+-activated garnet phosphors for blue-chip-pumped pc-WLEDs81Sunlight-activated Sr3Ga4O9:Eu2+ orange-red persistent luminescence material for convenient anti-counterfeiting and nighttime warning signs applications2Eu 2+ Doping Driven Polymorphic Transition in Sr 2 SiO 4 Glass Ceramic for Optical Property Tailoring and Multifunctional Photonic Applications2Synthesis and luminescent properties of novel red-emitting K3GdSi2O7: Eu2+ phosphors for warm white leds0Synergistic optimization of luminescence in feldspar-structured blue-cyan phosphors via heterovalent K+ substitution coupled with bandgap engineering0A novel Eu-doped broadband orange-red phosphor SrLaGaO4 with high thermal stability for WLEDs and anti-counterfeiting inks3A Novel Dual-Ratio Optical Probe Based on Europium-Doped Carbon Dots for the Detection of Tetracycline3Preparation of Eu(III) Luminescent Hybrid Nanomaterials via Oxidation Induced by Gas-Phase Vacuum Evaporation Approach and Their Anti-Counterfeiting Applications0Site-selective Eu2+ occupation in multi-polyhedral Ca3Al2O6 for tunable high-color-purity blue and red emission0Enhanced thermal stability red-emitting phosphors for multifunctional applications: LED illumination, smoke-penetrating lighting, and data encryption computing0Be Aware of Impurity Phases: Red Emission in Europium‐Doped CaYGaO 4 Caused by Unintentionally Formed CaS:Eu 2+0

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  7. A novel differential display material: K3LuSi2O7: Tb3+/Bi3+ phosphor with thermal response, time resolution and luminescence color for optical anti-counterfeiting

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  15. Luminescence properties and thermal stability of Dy3+/Eu3+co-doped single-component BaZn2(PO4)2 glass-ceramic phosphors

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  17. Far-red-emitting LaSrRO4:Mn4+ (R = Al and Ga) phosphor: Synthesis and optical properties

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  18. Dual-mode optical thermometry design in K 3 YSi 2 O 7 :Eu multi-site phosphor

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  19. Sr-substitution-guided Eu2+ site engineering of Ca9Nd(PO4)7:Eu2+ for high-efficiency white light-emitting diodes

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