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RESEARCH PAPER · ACS Materials Au · 2022

Eu2+ Doping Concentration-Induced Site-Selective Occupation and Photoluminescence Tuning in KSrScSi2O7:Eu2+ Phosphor

Shunqi Lai, Ming Zhao, Yifei Zhao, Мaxim S. Моlokeev, Zhiguo Xia

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Eu2+ Doping Concentration-Induced Site-Selective Occupation and Photoluminescence Tuning in KSrScSi2O7:Eu2+ PhosphorOriginalA novel blue-emitting Tm3+ and Tb3+ co-doped Ca9Nd(PO4)7 phosphor for white light-emitting diodes1Investigation into the Eu2+ ions occupations and the coordination environments in components modulated Sr3MgSi2O81Recent progress in Ce 3+ /Eu 2+ -activated LEDs and persistent phosphors: focusing on the local structure and the electronic structure137Site-selective occupation of Cr3+ ions toward ultra-broadband near-infrared emission stannate phosphors23Fluorescence modulation in Pr3+-doped MGd2O4 (M = Sr, Ba) by the site engineering strategy4Stabilization of Eu 2+ in Li 2 B 4 O 7 with the BO 3 network through U 6+ co-doping and defect engineering8Highly-efficient Eu 2+ -activated Sr 8 Si 4 O 12 Cl 8 cyan-emitting phosphors with zero-thermal quenching luminescence for versatile applications16Synthesis, structure, and luminescence properties of Europium/Cerium/Terbium doped strontium-anorthite-type green phosphor for solid state lighting8Temperature dependent luminescence properties of Mn2+ ions for site preference of NaCa2GeO4F: Mn2+, Fe3+ phosphor9Simultaneous realization of tunable luminescence and enhanced thermal stability in Eu2+-based blue-green phosphors for multifunctional applications16Towards efficient blue Eu2+ activated pyrophosphate phosphor for warm white LED applications13Divalent ansa-Octaphenyllanthanocenes: Synthesis, Structures, and EuII Luminescence9Regulation of Bi3+ emission in Ca3Ga4O9 phosphors through doping concentration and solid-solution component design15Luminescence properties of Eu2+/3+ co-activated La6Sr4(SiO4)6F2 polychromatic phosphors towards white light-emitting diodes and anti-counterfeiting8A novel red BaLaInO4: Eu3+ phosphor for WLEDs32Mechanoluminescence and afterglow modulation of Zr and Mg doped strontium aluminate3On the luminescence properties of Eu2+ with multiple-site occupancy in silicate K2MgSi3O83Anomalous 5D0→7F4 Transition of Eu3+‐Doped BaLaGaO4 Phosphors for WLEDs and Plant Growth Applications95GPT-Assisted Learning of Structure–Property Relationships by Graph Neural Networks: Application to Rare-Earth-Doped Phosphors16A theoretical spectroscopy study of the photoluminescence properties of narrow band Eu 2+ -doped phosphors containing multiple candidate doping centers. Prediction of an unprecedented narrow band red phosphor10Synthesis and photoluminescence properties of high-quality reddish-orange emitting Ca 4 Nb 2 O 9 :Eu 3+ phosphors for WLEDs and anti-counterfeiting18Blue-emitting Bi3+-doped K2MGeO5 (M = Hf, Zr) phosphors for full-spectrum WLED: Crystal structure, electronic structure and luminescent properties12Thermally-stable and color-tunable novel single phase phosphor Ca2GaTaO6:Dy3+, Sm3+ for indoor lighting applications49Superior Quantum Efficiency Blue‐Emitting Phosphors with High Thermal Stability toward Multipurpose LED Applications57Zero-thermal-quenching broadband yellow-emitting Bi3+-activated phosphors based on metal to metal charge transfer27Eu2+ doping and Mg2+-coupled Zn2+, Ca2+ and Sr2+ cations induce tunable orange-blue luminescence in cordierite3Crystal-Site Engineering of Novel Na3KMg7(PO4)6–x(BO3)x:Eu2+ Phosphors for Full-Spectrum Lighting10Codoping Eu3+ with Sc3+ and La3+ in CaSnO3 for possible site selective doping: Is size selection in site selective doping really effective?3Multi-sites induced ultra-broadband luminescence based on Eu2+ doped whitlockite-type phosphor for full-spectrum WLEDs9Luminescence Dynamics of BaAl2O4:Eu2+ Phosphor5Novel single phase warm white-emitting phosphor BaLaGaO4:Dy3+,Sm3+ with high thermal stability and color stability26A novel thermally-stable Ca2GaTaO6:Sm3+ phosphor and its application in WLEDs and anti-counterfeit inks30Structural, phosphorescence, thermal, and dielectric properties of SrAl4O7: Eu3+ nano phosphors7Unlocking Chlorine Oxide‐Based Ultra‐Wideband Near‐Infrared Phosphor and Advancing Spectral Performance via Lattice Engineering43Achieving Eu 2+ Luminescence at Trivalent Lattice Site in Rb 3 Y(PO 4 ) 2 :Eu toward Multicolor Emissions by Carbon and Hydrogen Coreduction23Oxide phosphors1A novel KSrScSi2O7:xCr silicate phosphor, luminescence/chromaticity, and applications in NIR pc-LED and stable green ceramic pigments17Construction of an artificial-intelligence agent for the discovery of next-generation white-LED phosphors0High-sensitivity optical thermometer based on the luminescence of divalent and trivalent thulium ions in CaAl 4 O 7 :Tm 2+/3+ operating in cryogenic and high temperature ranges7Phosphor-converted light-emitting diodes in the marine environment: current status and future trends40Synthesis and Luminescence Properties of Eu2+/TM (Cr3+, Fe3+, Co3+) Co-Doped CaMgSiO4 Phosphors0Tuning the Luminescence Properties of Mn-Cr Codoped Sr2mgal22o36 Phosphors Via Ultrahigh Energy Transfer between Mn2+ and Cr3+ for Wled Applications0365 nm UV light excitable broadband cyan-blue emitting KSrScSi2O7: xCe3+ phosphor and its application in high color rendering pc-WLED7Decoding the Hume–Rothery Rule in a Bifunctional Tetra-metallic Alloy for Alkaline Water Electrolysis15High-efficiency and thermally stable Cr3+-doped BaSiF6 fluoride phosphors for broadband near-infrared LED applications5Dynamic and Static Stress Sensing Based on Mechanical Quenching Phenomenon From CaZnOS:Cu+7Tailoring of Blue‐Cyan Luminescence in Rb 3 Y[(P 1‐ x Si x )O 4 ] 2 :Eu 2+ Phosphor via Si 4+ ‐P 5+ Heterovalent Substitution for Full‐Spectrum Healthy Lighting25Exploring the potential of KSr6ScSi4O16:Eu2+ phosphors for full-spectrum light emitting diodes9Database of Eu 2+ and Ce 3+ Doped Phosphors for Development of Violet-light Excited White LEDs0High-color-purity and full-spectrum white light emission of Sn2+/Mn2+ co-doped BaO-ZnO-P2O5 glasses and novel single-phase BaZnP2O7 glass-ceramics3Cation-tunable blue phosphor (Ba,Mg)(Y,Sc)4Si5O17:Eu2+: enhanced quantum yield and thermal stability8Divalent Europium-containing colloidal metal halide nanocrystals for light-emitting applications7Stable Blue-Cyan Photoluminescence from Tendentious Multisite Occupations of Bi3+ in NaBaScSi2O7 with Efficient Absorption in nUV for Application in “Healthy” Illumination and Field Emission Display4Synthesis and Characterization of Eu 2+ /Nd 3+ Activated CaSi 2 O 5 Phosphor for Bioimaging Applications6Red-emitting KSr6ScSi4O16:Eu3+ phosphors for white LEDs and latent fingerprint detection14Multi-site occupied Cs2Ba3(P2O7)2:Eu2+ phosphor with blue-green dual emission for full-spectrum lighting2Study on luminescence properties of Eu2+ doped K-β-Al2O3 blue phosphor and its anti-counterfeiting application1Ce3+ → Pr3+ energy transfer and traps boosting thermal stability of KSrScSi2O7: Ce3+, Pr3+ phosphor for full-spectrum solid-state lighting2Eu2+-doping induced phase transformation and blue–cyan luminescence in KAlSi3O8 phosphors5From Model to Material: Machine Learning Enabled Discovery of LED‐Compatible Phosphors4Photoluminescence modulation of red-emitting Sr2ScGaO5:Eu2+ phosphor via cation substitution for WLED and fingerprint identification9Sr2Sb2O7: A multifunctional oxide platform for cyan-compensated healthy lighting and near-infrared applications3A novel cyan-emitting Ca2LuZr2Al1.5Ga1.5O12:Ce3+ phosphor excited by violet light toward full-spectrum white LEDs1Te4+-doped K2ZrSi3O9 phosphor with rare-earth-free cyan emission0Improvement of electrochemical properties and hydrogen production by Ho-Eu-TiO2 nanotubes1Spectral tuning of K1-Na Al11O17: 0.06Eu2 + phosphors induced by crystal lattice engineering and its application in high color rendering full spectrum WLED1Synthesis and crystal structure analysis of three new sodium europium (II) scandium silicates0Synthesis and luminescence properties of oxyapatite-type ZnLa4(SiO4)3O:Dy3+ yellow-emitting phosphor for high thermal stability in WLED0Europium self-reduction and multimodal luminescence of Ca2PO4Cl:Eu2+ microcrystals synthesized in air0Precise optical thermometry achieved in ultra-wide yellow photoluminescent Ba3Sc2(BO3)4:Eu2+ phosphor2Cation substitution engineering persistent luminescence for dynamic optical anti-counterfeiting0Synthesis and photoluminescent mechanisms of Ce3+-Activated KSr6ScSi4O16 blue-emitting phosphors for advanced solid-state lighting0An ultra-broadband green-emitting phosphor K2ZnSi3O8:Eu2+ with excellent thermal recovery for high-quality WLEDs0Optimization of inorganic rare-earth afterglow materials and their optoelectronic applications0Evolution of lighting technologies: The central role of rare-earth-doped materials in advancing modern illumination0Thermally Robust Narrow‐Band Deep‐Blue Emission From Eu 2+ ‐Activated Zero‐Dimensional Cs 2 ZnBr 4 Nanocrystals0

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  5. Fluorescence modulation in Pr3+-doped MGd2O4 (M = Sr, Ba) by the site engineering strategy

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  16. Mechanoluminescence and afterglow modulation of Zr and Mg doped strontium aluminate

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  17. On the luminescence properties of Eu2+ with multiple-site occupancy in silicate K2MgSi3O8

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  18. Anomalous 5D0→7F4 Transition of Eu3+‐Doped BaLaGaO4 Phosphors for WLEDs and Plant Growth Applications

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  19. GPT-Assisted Learning of Structure–Property Relationships by Graph Neural Networks: Application to Rare-Earth-Doped Phosphors

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