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RESEARCH PAPER · Chemical Engineering Journal · 2021

Full-visible-spectrum lighting enabled by site-selective occupation in the high efficient and thermal stable (Rb, K)2CaPO4F: Eu2+ solid-solution phosphors

Dewu Wu, Chen Shi, Jiangcong Zhou, Yuxin Gao, Yi-Ting Huang, Jianyan Ding, Quansheng Wu

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Full-visible-spectrum lighting enabled by site-selective occupation in the high efficient and thermal stable (Rb, K)2CaPO4F: Eu2+ solid-solution phosphorsOriginalEfficient violet-light-excitable blue-cyan phosphor for full-spectrum lighting48Excellent enhancement of thermal stability and quantum efficiency for Na2BaCa(PO4)2:Eu2+ phosphor based on Sr doping into Ca30Multiple Strategies to Approach High-Efficiency Luminescence Controllable in Blue/Cyan/Green-Emitting Bi 3+ -Activated Phosphors30Towards single broadband white emission in Rb0.5K1.5CaPO4(F, Cl): Eu2+ via selective site occupancy engineering for solid-state lighting applications42Efficient Er3+ doped single-component Cs2Ag(Na)In(Bi)Cl6 phosphors for full-spectrum light-emitting diodes16High-Efficiency Continuous-Luminescence-Controllable Performance and Antithermal Quenching in Bi 3+ -Activated Phosphors35Ultra‐Broadband Green‐Emitting Phosphors without Cyan Gap Based on Double‐Heterovalent Substitution Strategy for Full‐Spectrum WLED Lighting89Environment-Dependent Eu2+-Activated Ba3CaK(PO4)3 toward White-Light Emission by Chemical Cosubstitution of the (BO3)3– Anion Group19Design of novel cyan phosphor Ca7NaLu(PO4)6:Eu2+ for full-visible-spectrum white LED: enhanced thermal stability and tuned emission by neighbor cation effect30Design of Eu 2+ ‐activated broadband orange‐emitting phosphors with excellent luminescent performance for warm WLEDs10Highly efficient and tunable broadband UV excitable Ba9Lu2Si6O24:Eu2+, Mn2+ single-phase white-light-emitting phosphors21A multi-centre activated single-phase white light phosphor with high efficiency for near-UV based WLEDs69Achieving efficient violet-light-excited blue phosphors by nitridation for violet-chip-based full-spectrum lighting47Exclusive confinement of Bi 3+ -activators in the triangular prism enabling efficient and thermally stable green emission in the tridymite-type phosphor CaBaGa 4 O 8 :Bi 3+13Site-selective occupation, optical spectrum regulation and photoluminescence property investigation of Eu 2+ -activated blue light-excited yellow-orange emitting phosphors5Deep blue, cyan, orange-red, and white multicolor emissions generated by Bi3+/Eu3+ activated KBaYSi2O7 luminescent materials for white light-emitting diodes19Strong energy transfer and color tunable emission in Eu2+ and Mn2+ co-doped Na2BaSr(PO4)2 phosphor14Dual luminescent peaks, energy transfer and temperature sensor properties of a new Eu2+/Mn2+ co-doped phosphor13Cu2+ and Cr3+ doped borate glasses and glass-ceramics as light conversion materials for plant photosynthesis9Site‐Engineering for Controlling Multiple‐Excitation and Emission in Eu2+‐Activated CaSrSiO4 Phosphors in Marine Fisheries21Designing multicolor luminescence in Tb3+/Eu3+-codoped KGd2F7 nanoparticles through energy transfer engineering for warm white light-emitting diode5Cation substitution induced highly symmetric crystal structure in cyan-green-emitting Ca2La1-xLuxHf2Al3O12:Ce3+ solid-solution phosphors with enhanced photoluminescence emission and thermal stability: Toward full-visible-spectrum white LEDs41Enhancing External Quantum Efficiency of Blue-Emitting Phosphor Ba(K)-β-Al2O3:Eu2+ by Lattice Site Engineering for Full-Spectrum Lighting40Hydrothermal synthesis and tunable luminescence of YPO4:Eu2+/Eu3+, Tb3+ nanocrystals17An Ultra‐Broadband Yellow‐Emitting Phosphor KRbCa0.8Mg0.2PO4F:Eu2+ for White Light‐Emitting Diodes with High Color Rendering Index38A new Na2BaCa(PO4)2: Eu3+ red-emitting phosphor with excellent thermal stability and high quantum efficiency for WLEDs11A Novel Cyan Phosphor (K,Rb) 3 GdSi 2 O 7 :Ce 3+ for Full‐Spectrum Lighting through Local Structure Tailoring48Abnormal Bi3+ activated NIR phosphor toward multifunctional LED applications19K2CaPO4F:Eu2+,RE3+ for pc-WLEDs: Cationic substitution inducing tunable emission and anti-thermal quenching8Phase transitions and optical properties of Tb3+ activated NaY(WO4)2 phosphors16Progress of Ce 3+ /Eu 2+ doped phosphors for violet chip based full-spectra lighting42Structure and photoluminescence of Mn 2+/4+ -activated doubly ordered spinel Mg 4 (Ga/Al)SbO 8 : site-selective Al 3+ -to-Ga 3+ substitution enabling Mn 4+ accumulation, excellent anti-thermal quenching of Mn 2+ green emission, and optical thermometry17Unlocking color-tunable emission of Eu 2+ -activated phosphors through doping-free exploration of hidden sites3Controllable multipoint tunable luminescence of Ca8.96Al1-Gd (PO4)7:0.04Eu2+ based on crystal lattice engineering7An efficient and thermally stable red emitting Eu2+ doped oxide for rechargeable portable flashlight62Deep‐Red (Sr,Ba)Lu2O4: Eu2+ Phosphor for Full‐Spectrum Lighting7Superior Quantum Efficiency Blue‐Emitting Phosphors with High Thermal Stability toward Multipurpose LED Applications57Super thermally stable Rb-β-Al2O3:Eu blue phosphor for full-spectra lighting4Heterostructure anion-groups guided design enabling customizable Eu2+ spectrum behavior in borophosphate7Efficient violet-light-excitable blue-cyan-emitting Ca2YHf2GaAl2O12:Ce3+ garnet phosphors enable high-color-rendering full-spectrum warm-white LEDs44Color‐Tunable Emission via Site‐Selective Occupation of Eu2+ Activators in Silicate Phosphors17Customized Cyan Phosphors for Efficient Full‐Spectrum Illumination and Fingerprint Detection22Modulating optical properties through cation substitution: composition-property relationships in MI3M III P 3 O 9 N:Eu 2+ (M I = Na, K; M III = Al, Ga, In)2Unlocking dual Mn 3+ /Mn 4+ emissions in garnet phosphors for WLED and plant growth lighting applications15Tunable photoluminescence in Eu2+-activated KCaLa(PO4)2 phosphor through structural disorder3Effect of Ca2+ partial substitution with Mg2+ on luminescence enhancement of Ca3Ga4O9:Bi3+ cyan-emitting phosphors for warm WLEDs4Site-selective occupancy of Ca6BaP4O17:Eu2+ phosphor and its potential optical thermometry applications0Enhancing spectral uniformity in full-spectrum white LEDs using an SiO 2 aerogel encapsulant1Wavelength-Tunable of Broad Red to Near-Infrared Emission in (Sr,Ba)3Sc4O9 :Eu2+ Phosphors: Crystal Field Effects and Thermal Stability6Site‐Selective Occupation of Mn 2+ Activators for Tunable Luminescence in Well‐Designed CaZnGe 2 O 6 Phosphors7Glass network engineering of yellow-emitting Ba 2 Sc 2 B 4 O 11 :Ce 3+ glass ceramics for full-spectrum lighting22Thermal‐Robust and Glass‐Compatible K 1.3 Al 9 Ga 2 O 17.15 :Eu for Laser‐Driven Lighting and Underwater Optical Communication3Resolving energy transfer dynamics in Eu²⁺-activated multi-site phosphors via metaheuristic optimization and physics-informed neural networks1Sb5+-Nb5+ substitution driven structural tuning and luminescence enhancement of Mn4+-activated double perovskite phosphors1Polarization tuning of ferroelectric photocatalysts: From conventional selection to AI-guided design for efficient CO2-to-C1 conversion5Tunable Broadband Red-To-Near-Infrared Emission in Eu 2+ -Activated Sr 1– x Ba x La 2 Sc 2 O 7 Phosphors via Site-Selective Occupation and Cation Substitution3Multisite-selective occupancy enabled luminescence tuning in aluminate-gallate solid solutions for solid-state lighting0Regulating cyan luminescence in Ca9ZnK(PO4)7: Eu2+ phosphors through Ca/Sr solid solution toward full-spectrum WLEDs0

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  1. Efficient violet-light-excitable blue-cyan phosphor for full-spectrum lighting

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  2. Excellent enhancement of thermal stability and quantum efficiency for Na2BaCa(PO4)2:Eu2+ phosphor based on Sr doping into Ca

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  3. Multiple Strategies to Approach High-Efficiency Luminescence Controllable in Blue/Cyan/Green-Emitting Bi 3+ -Activated Phosphors

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  4. Towards single broadband white emission in Rb0.5K1.5CaPO4(F, Cl): Eu2+ via selective site occupancy engineering for solid-state lighting applications

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  5. Efficient Er3+ doped single-component Cs2Ag(Na)In(Bi)Cl6 phosphors for full-spectrum light-emitting diodes

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  6. High-Efficiency Continuous-Luminescence-Controllable Performance and Antithermal Quenching in Bi 3+ -Activated Phosphors

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  7. Ultra‐Broadband Green‐Emitting Phosphors without Cyan Gap Based on Double‐Heterovalent Substitution Strategy for Full‐Spectrum WLED Lighting

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  8. Environment-Dependent Eu2+-Activated Ba3CaK(PO4)3 toward White-Light Emission by Chemical Cosubstitution of the (BO3)3– Anion Group

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  9. Design of novel cyan phosphor Ca7NaLu(PO4)6:Eu2+ for full-visible-spectrum white LED: enhanced thermal stability and tuned emission by neighbor cation effect

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  10. Design of Eu 2+ ‐activated broadband orange‐emitting phosphors with excellent luminescent performance for warm WLEDs

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  11. Highly efficient and tunable broadband UV excitable Ba9Lu2Si6O24:Eu2+, Mn2+ single-phase white-light-emitting phosphors

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  12. A multi-centre activated single-phase white light phosphor with high efficiency for near-UV based WLEDs

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  13. Achieving efficient violet-light-excited blue phosphors by nitridation for violet-chip-based full-spectrum lighting

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  14. Exclusive confinement of Bi 3+ -activators in the triangular prism enabling efficient and thermally stable green emission in the tridymite-type phosphor CaBaGa 4 O 8 :Bi 3+

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  15. Site-selective occupation, optical spectrum regulation and photoluminescence property investigation of Eu 2+ -activated blue light-excited yellow-orange emitting phosphors

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  16. Deep blue, cyan, orange-red, and white multicolor emissions generated by Bi3+/Eu3+ activated KBaYSi2O7 luminescent materials for white light-emitting diodes

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  17. Strong energy transfer and color tunable emission in Eu2+ and Mn2+ co-doped Na2BaSr(PO4)2 phosphor

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  18. Dual luminescent peaks, energy transfer and temperature sensor properties of a new Eu2+/Mn2+ co-doped phosphor

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  19. Cu2+ and Cr3+ doped borate glasses and glass-ceramics as light conversion materials for plant photosynthesis

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  20. Site‐Engineering for Controlling Multiple‐Excitation and Emission in Eu2+‐Activated CaSrSiO4 Phosphors in Marine Fisheries

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  21. Designing multicolor luminescence in Tb3+/Eu3+-codoped KGd2F7 nanoparticles through energy transfer engineering for warm white light-emitting diode

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  23. Enhancing External Quantum Efficiency of Blue-Emitting Phosphor Ba(K)-β-Al2O3:Eu2+ by Lattice Site Engineering for Full-Spectrum Lighting

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  24. Hydrothermal synthesis and tunable luminescence of YPO4:Eu2+/Eu3+, Tb3+ nanocrystals

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  26. A new Na2BaCa(PO4)2: Eu3+ red-emitting phosphor with excellent thermal stability and high quantum efficiency for WLEDs

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  30. Phase transitions and optical properties of Tb3+ activated NaY(WO4)2 phosphors

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  31. Progress of Ce 3+ /Eu 2+ doped phosphors for violet chip based full-spectra lighting

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  32. Structure and photoluminescence of Mn 2+/4+ -activated doubly ordered spinel Mg 4 (Ga/Al)SbO 8 : site-selective Al 3+ -to-Ga 3+ substitution enabling Mn 4+ accumulation, excellent anti-thermal quenching of Mn 2+ green emission, and optical thermometry

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  33. Unlocking color-tunable emission of Eu 2+ -activated phosphors through doping-free exploration of hidden sites

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  35. An efficient and thermally stable red emitting Eu2+ doped oxide for rechargeable portable flashlight

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  45. Tunable photoluminescence in Eu2+-activated KCaLa(PO4)2 phosphor through structural disorder

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