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RESEARCH PAPER · iScience · 2021

Li/Na substitution and Yb3+ co-doping enabling tunable near-infrared emission in LiIn2SbO6:Cr3+ phosphors for light-emitting diodes

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Li/Na substitution and Yb3+ co-doping enabling tunable near-infrared emission in LiIn2SbO6:Cr3+ phosphors for light-emitting diodesOriginalLuminescent properties and LED Application of Broadband Near-Infrared Emitting NaInGe2O6: Cr3+ phosphors89A General Ammonium Salt Assisted Synthesis Strategy for Cr3+‐Doped Hexafluorides with Highly Efficient Near Infrared Emissions212Efficient and Tunable Luminescence in Ga 2– x In x O 3 :Cr 3+ for Near-Infrared Imaging172Composition modification for tuning the luminescent property in Sr19(Mg,Mn)2(PO4)14: Eu2+ phosphors12A highly efficient and suitable spectral profile Cr3+-doped garnet near-infrared emitting phosphor for regulating photomorphogenesis of plants278Photoluminescence origin and non-contact thermometric properties in Pb2+-activated CaZrO3 perovskite phosphor20Achieving an ultra-broadband infrared emission through efficient energy transfer in LiInP2O7: Cr3+, Yb3+ phosphor80Efficient Broadband Near‐Infrared Emission in the GaTaO4:Cr3+ Phosphor191Octahedron-dependent near-infrared luminescence in Cr3+-activated phosphors99Efficient Ultra‐Broadband Ga 4 GeO 8 :Cr 3+ Phosphors with Tunable Peak Wavelengths from 835 to 980 nm for NIR pc‐LED Application134Ultra-broadband NIR luminescence in chromium doped magnesium aluminosilicate glass as future light sources for spectroscopy applications25Accessing High-Power Near-Infrared Spectroscopy Using Cr3+-Substituted Metal Phosphate Phosphors114A simple and generic post-treatment strategy for highly efficient Cr 3+ -activated broadband NIR emitting phosphors for high-power NIR light sources45Achieving a tunable and ultra-broadband near-infrared emission in the Ga 2−2 x Zn x Ge x O 3 :Cr 3+ phosphor16Chemical unit co-substitution enabling broadband and tunable near-infrared emission in garnet-type Lu3Sc2Ga3O12:Cr3+ phosphors22Consequence of optimal bonding on cation ordering and enhanced near-infrared luminescence in Cr 3+ -doped pyroxene oxides49Cr 3+ -Doped double perovskite antimonates: efficient and tunable phosphors from NIR-I to NIR-II78Cr3+ and Eu3+ Co-Activated Al2w3o12 Phosphor for Ratiometric Temperature Sensing0Efficient and thermally stable broadband near-infrared emission in a garnet Gd 3 In 2 Ga 3 O 12 :Cr 3+ phosphor44Synthesis of broadband NIR garnet phosphor Ca 4 ZrGe 3 O 12 : Cr 3+ , Yb 3+ for NIR pc-LED applications148A broadband near‐infrared Sc 1 − x (PO 3 ) 3 : X Cr 3+ phosphor with enhanced thermal stability and quantum yield by Yb 3+ codoping28Structural Rigidity Control toward Cr3+-Based Broadband Near-Infrared Luminescence with Enhanced Thermal Stability243Broadband NIR Garnet Phosphors with Improved Thermal Stability via Energy Transfer49Efficient and Thermally Stable Broad-Band Near-Infrared Emission in a KAlP 2 O 7 :Cr 3+ Phosphor for Nondestructive Examination191Efficient Visible Light Charging for Rare Earth‐Free Persistent Phosphor35Dopant and Compositional Modulation Triggered Broadband and Tunable Near-Infrared Emission in Cs2Ag1–xNaxInCl6:Cr3+ Nanocrystals131Broadband near-infrared emission in the NaInP2O7:Cr3+ phosphor for light-emitting-diode applications50Highly efficient Fe3+-doped A2BB′O6 (A = Sr2+, Ca2+; B, B′ = In3+, Sb5+, Sn4+) broadband near-infrared-emitting phosphors for spectroscopic analysis251Blue LED-pumped intense short-wave infrared luminescence based on Cr3+-Yb3+-co-doped phosphors294Multiple Strategies to Approach High-Efficiency Luminescence Controllable in Blue/Cyan/Green-Emitting Bi 3+ -Activated Phosphors30Modulation of Thermally Stable Photoluminescence in Cr 3+ -Based Near-Infrared Phosphors201Novel broadband near-infrared emitting long afterglow phosphor MgGeO3: Cr3+33Blue LED‐Pumped Broadband Short‐Wave Infrared Emitter Based on LiMgPO4:Cr3+,Ni2+ Phosphor97Enhancement of Near‐Infrared Phosphor Luminescence Properties via Construction of Stable and Compact Energy Transfer Paths54Near-Infrared Broadband ZnTa2O6:Cr3+ Phosphor for pc-LEDs and Its Application to Nondestructive Testing64Ultra‐Wide Vis–NIR Mg2Al4Si5O18:Eu2+,Cr3+ Phosphor Containing Unusual NIR Luminescence Induced by Cr3+ Occupying Tetrahedral Coordination for Hyperspectral Imaging66Molten Salt Synthesis of Broad-Band Near-Infrared InBO 3 :Cr 3+ Submicron Phosphor and Its Luminescent Enhancement by Lanthanide Ion Codoping23Advances in Chromium‐Activated Phosphors for Near‐Infrared Light Sources489Broadband near-infrared luminescence in the NaAlP2O7:Cr3+ phosphor for spectroscopy applications19Enhanced Thermal Stability and Energy Transfer by Crystal‐Field Engineering in a Garnet Phosphor for Thermometry and NIR‐LED48The third biological window luminescence for tissue penetration through Cr–Er energy transfer6Dopant and compositional modulation triggered long-wavelength ultra-broadband and tunable NIR emission in MgO: Cr3+ phosphor for NIR spectroscopy applications53Ultra-broadband and high-efficiency phosphors to brighten NIR-II light source applications31A highly sensitive blue-LED-excitable self-calibrated luminescent thermometer based on Cr3+/Eu3+ Co-doped Al2W3O1218Producing Tunable Broadband Near-Infrared Emission through Co-Substitution in (Ga1–xMgx)(Ga1–xGex)O3:Cr3+77Engineering the local structure of ZnGa2O4: Cr3+ via Mg substitution to realize superior luminescence18Recent Advances in Chromium‐Doped Near‐Infrared Luminescent Materials: Fundamentals, Optimization Strategies, and Applications252Double‐Site Occupation Triggered Broadband and Tunable NIR‐I and NIR‐II Luminescence in AlNbO4:Cr3+ Phosphors15Simultaneous Absorption and Near‐Infrared Emission Enhancement of Cr 3+ Ions in MgGa 2 O 4 Spinel Oxide via Anionic F‐Substitution88Super Broadband Near‐Infrared Solid Solution Phosphors with Adjustable Peak Wavelengths from 1165 to 875 nm for NIR Spectroscopy Applications41A reliable and stable ratiometric luminescence thermometer based on dual near-infrared emission in a Cr 3+ -doped LaSr 2 Ga 11 O 20 phosphor22Achieving excellent thermostable red emission in singly Mn 2+ -doped near-zero thermal expansion (NZTE) material Li 2 Zn 3 (P 2 O 7 ) 26An efficient and thermally stable near-infrared phosphor derived from the Ln 3 ScInGa 3 O 12 :Cr 3+ (Ln = La, Gd, Y, and Lu) garnet family18Blue-light-excitable pure and efficient short-wave infrared luminescence via Cr 3+ → Yb 3+ energy transfer in a KYbP 2 O 7 :Cr 3+ phosphor24Broadening of the near-infrared emission band of the Mg 2 Al 4 Si 5 O 18 :Cr 3+ phosphor for illumination emission applications12Efficient and ultra-broadband Cr 3+ /Ni 2+ co-doped phosphors for light-emitting diodes with spectral output over NIR-I and NIR-II regions37Highly efficient broadband NIR phosphor Y 2 CaHfScAl 3 O 12 :Cr 3+ ,Yb 3+ with superior thermal stability for spectroscopy applications45Non-destructive food-quality analysis using near-infrared luminescence from Mg 3 Gd 2 Ge 3 O 12 :Cr 3+32Quantifying rigidity for thermally stable Cr 3+ phosphors9Ultra-broadening near-infrared emission of Cr 3+ -activated pyroxene phosphors via chemical unit substitution and Yb 3+ co-doping17Regulating Eu 2+ Multisite Occupation through Structural Disorder toward Broadband Near-Infrared Emission91Energy transfer realizes efficient NIR emitting Ca2ScTaO6:Cr3+, Yb3+ perovskite-structured phosphors39Versatile Ca 2 LnSbO 6 :Eu 3+ /Mn 4+ (Ln = La, Y, Gd, and Lu) phosphors for temperature sensing and plant growth LED19Tunable broadband near-infrared emission in LiScO2:Cr3+ phosphor induced by the variation of chromium ion concentration26Two-site occupation in Cr3+-activated BaIn2(P2O7)2 phosphor for broadband near-infrared thermometry and LED applications30Enhanced and Broadened NIR Emission of CaZnGe2O6:Cr3+ by Yb3+ Codoping for NIR Applications11Introducing Jahn-Teller distortion to enhance the practicability of (Ga,Sc)2O3:Cr3+ near-infrared phosphor18The co-optimization of efficiency and emission bandwidth in GSAGG:Cr3+ NIR ceramic phosphors19Thermal Stability Improvement of Cr3+‐Activated Broadband Near‐Infrared Phosphors via State Population Optimization60Widened and enhanced near-infrared luminescence of Y2-Sc GaSbO7:Cr3+ phosphors31Minimizing Bond Angle Distortion to Improve Thermal Stability of Cr3+ Doped Near‐Infrared Phosphor44Research progress of rare earth/transition metal ions doped NIR luminescent materials6Ultra-broad Near-Infrared Emitting Phosphor LiInF4: Cr3+with Extremely Weak Crystal Field42Creating an efficient and tunable near-infrared emission by using [Mg2+-Sn4+] chemical unit co-substitution in Ga2O3:Cr3+ phosphor7Achieving an ultra-high absorption efficiency in a monoclinic LiAlP2O7:Cr3+ near-infrared phosphor16Achieving Ultra‐Broadband Near‐Infrared Emission in Cr3+‐Activated Cs2NaScCl6 Perovskite for Efficient Phosphor‐Converted Light‐Emitting Diodes42Efficient near-infrared luminescence in LiInO2:Cr3+ phosphor for light-emitting-diodes6Ultra-broadband near-infrared Cr3+-doped multi-phase glass-ceramics realized by the selective enrichment strategy for near-infrared spectroscopy applications14Selective enrichment strategy induces ultra-broadband NIR emission in Cr3+-doped multi-phase glass-ceramics for NIR spectroscopy applications10Broadband near-infrared luminescence in the novel Li3Cs2Sr2B3P6O24:Cr3+ phosphor for NIR pc-LED15Wide near-infrared II emissions and LED application of Y2Ti2O7: Cr3+/Yb3+/Nd3+ phosphors5An ultra broadband NIR phosphor LiScSnO4:Cr3+ with emission wavelength peaking at 900 nm for component analysis14Broadband emitting Fe 3+ ‐doped double perovskite‐type antimonates phosphors for NIR spectroscopy applications28Sr2(Ga/Al)TaO6:Cr3+ phosphor with tunable near-infrared emitting for light-emitting diodes and optical thermometer32Thermally stable broadband near-infrared emitting pyrochlore oxide phosphors codoped with Cr3+ and Yb3+ ions22CaLaLiTeO6: Mn4+, Tm3+ phosphors with multiband near-infrared emission towards multifunctional applications11From Ancient Blue Pigment to Unconventional NIR Phosphor: A Thermal-Stable Near-Infrared I/II Broadband Emission from Ca1–xSrxCuSi4O10 Solid Solution9Small Stokes Shift and Two‐Site Occupation in the ANb2O6:Cr3+ (A = Zn/Mg) Phosphors Toward Highly Efficient Ultra‐Broadband Near‐Infrared Emission for Multifunctional Applications24Blue light-excited broadband NIR-II-emitting Li 2 ZnSn 3 O 8 :Cr 3+ ,Ni 2+ phosphor for multifunctional optical applications42Broadband short-wave infrared Mg 4 Nb 2 O 9 :Cr 3+ ,Li + phosphor for nondestructive safety detection and biomedical imaging17Broadband short-wave near-infrared-emitting phosphor MgNb 2 O 6 :Cr 3+ for pc -LED applications9Creating a blue-light-excitable, ultra-broadband and relatively long-wavelength near-infrared emission in Cr 3+ -activated garnet by controlling cationic disorder15High performance NIR-I to NIR-II emission of a Cr 3+ -doped Cs 2 NaLuCl 6 phosphor with an IQE and EQE of up to 92.9% and 60.75%44Highly efficient and thermostable far-red phosphor for promoting root growth in plants11Tunable luminescence via Cr 3+ –Yb 3+ /Nd 3+ energy transfer in Cr 3+ and Yb 3+ /Nd 3+ coactivated NIR phosphors for non-destructive analysis22Tunable near-infrared phosphor LiSc 2 SbO 6 :Cr 3+ by Mg 2+ substitution and Yb 3+ co-doping for phosphor-converted light-emitting diodes4Unlocking non-characteristic near-infrared emission of rare earth ions for photosynthetic bacteria cultivation and vein imaging applications4Tunable broadband near-infrared emission from environmentally friendly Fe3+-activated lead-free perovskites for spectral analysis and rapid nighttime recognition25Pr3+ ions, another alternative near-infrared luminescence emitter though energy transfer from Eu2+ for NIR pc-LEDs18Laser-driven broadband near-infrared light source with watt-level output280A Novel Near‐Infrared Emitting Sr 2 LuSbO 6 :Fe 3+ Phosphor with Persistent Luminescence Performance76Efficient broadband NIR garnet phosphor Ca2LuScGa2Si2O12:Cr3+,Yb3+ for NIR pc-LED applications17Advances in Fe3+-activated luminescent materials for near-infrared light sources64Extending Near-Infrared Emission Beyond 900 nm in Cr3+-Activated Niobate Double Perovskites10Cr3+ and Yb3+ co-doped perovskite-like phosphor with improved thermal stability by efficient energy transfer14Developing the Na2CaZr2Ge3O12:Cr3+ Garnet Phosphor for Advanced NIR pc-LEDs in Night Vision and Bioimaging87Highly thermally stable SrLaMgTaO6: Cr3+ double-perovskite phosphors for night-vision applications23Improved broadband luminescence in Gd2GaSb1-Ta O7:Cr3+,Yb3+ pyrochlore phosphors: Near-infrared spectroscopic applications and dual-mode optical thermometry11Remarkable broadband NIR emission of BaCa2MgSi2O8:Cr3+ phosphors and Eu2+ co-doping modulation7A High-Efficiency NIR-II Emitting LiAlSiO4:Cr/Ni Phosphors through Violet Excitation for NIR pc-LED Application12Long-Wavelength Broadband Near-Infrared ZrTe3O8:Cr3+, Ti4+ Phosphor of High Luminescence Quantum Yield and Excellent Thermal Stability9A novel KSrScSi2O7:xCr silicate phosphor, luminescence/chromaticity, and applications in NIR pc-LED and stable green ceramic pigments17Spectroscopic analysis of NIR emitting phosphors based on NaLaMgWO6 doped with Nd3+ and Er3+19Enhancement of luminescence properties of broadband NIR Cr3+-activated phosphate phosphors through cationic substitution11Improving the luminescence performance of the near-infrared phosphor La 3 SnGa 5 O 14 :Cr 3+ ,Yb 3+ via energy transfer and its application in fingerprint detection and night vision6Broadening near-infrared emission and enhancing thermal stability of Cr3+-activated SrLaGa3O7 phosphors via Yb3+ co-doping10Enhanced Short-Wave Infrared Luminescence in Yb 3+ -Doped Cr(PO 3 ) 3 Phosphor with over 60% External Quantum Efficiency9Simultaneously enhanced shortwave infrared emission and thermal stability enabled by efficient resonance energy transfer in Ca3ScHfAlSi2O12: Cr3+, Yb3+ towards emerging spectroscopy applications3Ultra-broadband NIR-I/II-emitting Ca4HfGe3O12:Cr³ ⁺, Yb³ ⁺ garnet phosphors for organic material analysis4β‐Ga4GeO8 Stability Under Extreme Conditions (up to 600 °C and 30 GPa)0Broadband near-infrared post-perovskite phosphor MgGe0.9Si0.1O3:Cr3+, A+ (A = Li, Na, and K) with peak emission beyond 820 nm for night vision applications43Broadband near-infrared long persistent luminescence in Cr3+-Doped CaY2Ga4GeO12 phosphors for advanced light source applications4Ultra-broadband near infrared phosphor with wide spectral range and long peak wavelength achieved by double-site occupation1Simultaneously enhancing long-wavelength broadband NIR luminescence and thermal stabilities in Cr3+-activated phosphate phosphors via partial cation substitution4Valence and Site Engineering Enable Efficient Broadband Near‐Infrared Emission at 960 nm in Cr 3+ ‐Activated Forsterite48Small Stokes Shift Induced Highly Efficient and Thermally Stable Broadband Near‐Infrared Antimonite Double Perovskite Emitters for Spectroscopy Applications8Enhancement of NIR Luminescence Properties in Li 3 Cs 2 Sr 2 B 3 P 6 O 24 : Cr 3+ Phosphor via Yb 3+ Co‐Doping for Spectroscopy Applications3Chromium Ion Pairs Induce Highly Efficient and Thermostable Broadband NIR Phosphor for Plant Lighting and Night Vision12Synthesis of transition metal-sensitized lanthanide near-infrared luminescent nanoparticles16Recent Advances and Emerging Applications of Lanthanide/Transition‐Metal‐Ion‐Doped Short‐Wave Infrared Luminescent Materials10d10 Metal s-Orbital-Derived Conduction Band Enables Efficient Charge Separation in LiIn2SbO6: A Combined Band Structure and Molecular Orbital Analysis2Machine-Learning-Assisted Discovery of Cr3+-Based Near-Infrared Phosphors16Highly Efficient and Stable Broadband NIR Phosphor Gd 3 MgGeGa 3 O 12 :Cr 3+ for Advanced pc‐LEDs Applications5A blue-light-excitable ultra-broadband near-infrared phosphor across the entire NIR-I and NIR-II windows5Antenna Effect for Enhanced Near‐Infrared Luminescence in Lanthanide‐Doped Nanoparticles: Mechanisms, Strategies, and Applications23Balancing efficiency and long-wavelength emission in the blue-light-excitable pyroxene NaInSi 2 O 6 :Cr 3+ near-infrared phosphor0Improved near infrared emission of Li 2 MgZrO 4 :Cr 3+ induced by Ga 3+ doping0Emergence of Unusual Cr 3+ Emission and Exceptional Thermal Stability in Ca 3 Ga 2 Ge 3 O 12 : Cr 3+ /Yb 3+ Garnet Phosphors for High-Performance Optical Thermometry and NIR pc-LEDs4Ultra-broadband emission spanning red to near-infrared range from Cr3+ doped Y2Mo3O12 with negative thermal expansion for high-performance plant lighting0Efficient Broadband Short‐Wave Infrared Luminescence at 1400 nm Enabled by Cr 3+ ‐Yb 3+ Energy Shuttle Design1Next‐Generation Short‐Wave Infrared LED Phosphors Based on Chromium Doped Rare Earth Sulfides5Enhanced luminescence of La2LiSbO6: Cr3+ by Bi3+ and Yb3+ doping0Near-infrared-emitting Cr3+–doped MgGa2O4 spinel phosphors via a sol-gel combustion route for night-vision imaging and food analysis0

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