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RESEARCH PAPER · Chemistry of Materials · 2021

Learning from Mineral Structures toward New Luminescence Materials for Light-Emitting Diode Applications

Xinquan Zhou, Jianwei Qiao, Zhiguo Xia

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Learning from Mineral Structures toward New Luminescence Materials for Light-Emitting Diode ApplicationsOriginalCaY 2 Al 4 SiO 12 :Ce 3+ ,Mn 2+ : a single component phosphor to produce high color rendering index WLEDs with a blue chip53Design of highly efficient deep-red emission in the Mn 4+ doped new-type structure CaMgAl 10 O 17 for plant growth LED light22Efficient energy transfer from Bi 3+ to Mn 2+ in CaZnOS for WLED application28Local Structure Modulation Induced Highly Efficient Red-Emitting Ba 2Gd 1-xY xNbO 6:Mn 4+ Phosphors for Warm WLEDs0Narrow-band red emitting oxonitridosilicate phosphor La 4−x Sr 2+x Si 5 N 12−x O x :Pr 3+ ( x ≈ 1.69)17Pb 2 TiFO(SeO 3 ) 2 Br: a new polar compound with the strongest second harmonic generation in the selenite bromide family29Samarium and manganese incorporation to improve color rendering of LuAG:Ce 3+ phosphor ceramics for laser-driven lighting: a Color-tunable and energy transfer study17Expanding the Toolbox of Inorganic Mechanoluminescence Materials166A new solid solution Bi1.48Eu0.52Pb0·5Sr0·5B2O7 and luminescent properties of the Bi2-xPb0.5Sr0·5B2O7:xEu3+ phosphors7Design principles for achieving red emission in Eu2+/Eu3+ doped inorganic solids83A Study of Tb 3+ → Eu 3+ Energy Transfer in Tb 3+ /Eu 3+ Codoped Y 2 Mg 2 Al 2 Si 2 O 12 Phosphors8Photoluminescence tuning in Ba3ScB3O9:Eu2+ phosphor by crystal-site engineering17Novel double-perovskite SrLaLiTeO6:Mn4+ far-red phosphor with superior thermal stability for indoor plant growth LED58Hydroxyfluorooxoborate Na[B3O3F2(OH)2]⋅[B(OH)3]: Optimizing the Optical Anisotropy with Heteroanionic Units for Deep Ultraviolet Birefringent Crystals146Hydroxyfluorooxoborate Na[B3O3F2(OH)2]⋅[B(OH)3]: Optimizing the Optical Anisotropy with Heteroanionic Units for Deep Ultraviolet Birefringent Crystals16CsBaB9O15: a high performance ultraviolet nonlinear optical material activated by the peculiar double layered configuration80Realization of non-rare earth doped blue-emitting phosphor Ba2Y5B5O17: Sb by selective site excitation, and its application in n-UV excited wLEDs3An efficient garnet-structured Na3Al2Li3F12:Cr3+ phosphor with excellent photoluminescence thermal stability for near-infrared LEDs157Structural Diversity and Incompatibility Induced Complex Phase Formation Behavior in the Stuffed Tridymites Ca 1– x Sr x Ga 2 O 47Ca[B 8 O 11 (OH) 4 ] : Eu 2+ – A Highly Efficient Deep Blue‐Emitting Phosphor Prepared by Low‐Temperature Self‐reduction12Understanding the β –K 2 CO 3 -Type Na(Na 0.5 Sc 0.5 )BO 3 :Ce 3 + Phosphor2Luminescence properties and tunable emission of Ca3MgSi2O8:Eu3+, Bi3+ phosphor with Bi3+ → Eu3+ energy transfer21Multi-responsive deep-ultraviolet emission in praseodymium-doped phosphors for microbial sterilization77Cyan-Emitting Sialon-Polytypoid Phosphor Discovered by a Single-Particle-Diagnosis Approach5Local Structure Modulation-Induced Highly Efficient Red-Emitting Ba 2 Gd 1– x Y x NbO 6 :Mn 4+ Phosphors for Warm WLEDs45Study on the luminescence properties and energy transfer of Na4CaSi3O9:Ce3+, Sm3+ phosphor55Site-selective and cooperative doping of Gd 3 Al 5 O 12 :Ce garnets for structural stabilization and warm WLED lighting of low CCT and high CRI26Multifunctional Ca9NaZn1-Mg (PO4)7:Eu2+ phosphor for full-spectrum lighting, optical thermometry and pressure sensor applications112Tailoring Bi2MoO6 by Eu3+ incorporation for enhanced photoluminescence emissions20Locally-ordered A-site vacancy assisted photoluminescence enhancement in simply rare-earth doped perovskite oxide13Perovskite fiber-shaped optoelectronic devices for wearable applications39Reducing the cyan-cavity: Lu 2 MAl 4 SiO 12 :Ce 3+ (M = Mg, Ca, Sr and Ba) phosphor-in-glass film towards full-spectrum laser-driven lighting24Remarkable structure and luminescence regulation of a Gd 2 LuAl 5 O 12 :Ce garnet phosphor with a Ca 2+ /Si 4+ pair for high-quality w-WLED lighting8Study on luminescence characterizations of SrMg2La2W2O12:Eu3+ red-emitting phosphor63Suppression of charge imbalance via Li+-Mn4+ co-incorporated Sr2YSbO6 red phosphors for warm w-LEDs43Regulation of Local Site Structures to Stabilize Mixed-Valence Eu2+/3+ under a Reducing Atmosphere for Multicolor Photoluminescence23Inverse‐Tunable Red Luminescence and Electronic Properties of Nitridoberylloaluminates Sr2−xBax[BeAl3N5]:Eu2+ (x=0–2)3Anti-Defect engineering toward high luminescent efficiency in whitlockite phosphors53Photoluminescence and conductive properties of CaEuNbMoO 8 solid‐solution ceramics4Temperature-Responsive Photoluminescence and Elastic Properties of 1D Lead Halide Perovskites R- and S-(Methylbenzylamine)PbBr36Novel Cr3+-activated far-red emitting phosphors with β-Ca3(PO4)2-type structure for indoor plant cultivation37Near-UV excited green-emission enhancement by efficient energy transfer in Na1.8Mg0.9Si1.1O4:Ce3+,Tb3+ phosphor for solid-state lighting applications13Simultaneous Spectral Tuning and Thermal Stability Adjustment in Ca8ZnGa(1–x)Lax(PO4)7:Eu2+ Phosphors23Eu2+ Doping Concentration-Induced Site-Selective Occupation and Photoluminescence Tuning in KSrScSi2O7:Eu2+ Phosphor77Effect of ionic couple substitution on the enhanced photoluminescence properties of (BaMg)1-x(KxAl10+x)O17:Eu2+ phosphor for white LEDs application7Intense Luminescence and Good Thermal Stability in a Mn2+-Activated Mg-Based Phosphor with Self-Reduction27Recent research progress of luminescent materials with apatite structure: A review16Challenges and Strategies to Design Phosphors for Future White Light Emitting Diodes104Activators lattice migration strategy customized for tunable luminescence of Ce3+ doped β-Ca3(PO4)226Investigation on Ba2(Y1-x, Lux)5B5O17: y at.% Bi as a new type of N-UV excited high efficient blue phosphor for wLED6Modulating the emission spectrum of Ca2La8(SiO4)6O2:Eu(2+,3+) phosphor through Mn2+ ion doping3Manipulating concentration quenching and thermal stability of Eu3+-activated NaYbF4 nanoparticles via phase transition strategy toward diversified applications25Tunable photoluminescence of LiNbO3: RE3+ (RE3+ = Dy3+, Sm3+, Dy3+/Sm3+) single-phase phosphors for warm white LEDs78An investigation on luminescence properties of La2CaO4:Sm3+ red-emitting phosphor8Photoluminescence, site occupation and optical thermometry of Ba2La6Y2(SiO4)6O2: Eu3+ phosphors with high thermal stability14Environment-Dependent Eu2+-Activated Ba3CaK(PO4)3 toward White-Light Emission by Chemical Cosubstitution of the (BO3)3– Anion Group19Color-tunable blue-emitting Na2MgSiO4:Ce3+ phosphors for white light-emitting diodes33Oxide-Based Red Emitting Phosphors with High Color Purity and Their Versatile Applications: Synthesis, Structure, and Luminescence Properties23Tuning emission color of Eu2+-activated phosphor through phase segregation22A single-phase white-emitting La(BO3,PO4):Dy3+ phosphor with high thermostability35Luminescent Materials Based on Aluminates: A Review14Finding a Deep‐UV Borate BaZnB4O8 with Edge‐sharing [BO4] Tetrahedra and Strong Optical Anisotropy20Effect of ambient temperature on optical performances of Eu 2+ /Ho 3+ co-doped Ba 2 SiO 4 phosphors0Novel Sm3+-activated YCa4O(BO3)3 phosphors with high quantum efficiency and thermal stability for red-backlight display and indoor illumination27Enhanced luminescence of Mn4+ equivalently doped fluoride phosphors by reducing defects and impurities16Highly Efficient Narrow‐Band Green Emission in LaZn 1 ‐ x Mn x Al 11 O 19 Magnetoplumbite Phosphors toward White LED Application and Optical Thermometer46Highly efficient and tunable broadband UV excitable Ba9Lu2Si6O24:Eu2+, Mn2+ single-phase white-light-emitting phosphors21A novel narrow-band blue-emitting phosphor with high efficiency and thermal stability for WLEDs and FEDs31Achieving excellent thermostable red emission in singly Mn 2+ -doped near-zero thermal expansion (NZTE) material Li 2 Zn 3 (P 2 O 7 ) 26Exploring dual-emission properties in Mn 4+ distinctively activated BaTaF 7 red emitting phosphor21Fundamentals of ceramics for photonics applications3Introduction to properties of aluminates and its scope0Recent progress in trivalent europium (Eu 3+ )-based inorganic phosphors for solid-state lighting: an overview72Remarkably enhanced upconversion luminescence in Na + codoped spinel nanoparticles for photothermal cancer therapy and SPECT imaging16Single-component full-color emitting Ca 6 Y 2 Na 2 (PO 4 ) 6 F 2 :Eu 2+ ,Tb 3+ ,Mn 2+ phosphors with superior performance: color-tunable and energy transfer study4Site Occupation Regulation of Eu2+ by the Introduction of (Bo3)3- Group Towards Full-Visible-Spectrum Emission in a Singly Doped K2basr(Po4)2:Eu2+ Phosphor0Superlattice-stabilized structure and charge transfer assisted photoluminescence enhancement in a samarium-doped high entropy perovskite oxide17Structure and Luminescence Studies of a Ce3+-Activated Ba5La3MgAl3O15 Green-Emitting Phosphor31Cu2+ and Cr3+ doped borate glasses and glass-ceramics as light conversion materials for plant photosynthesis9Ultrahighly Efficient Narrowband Red Luminescence of Uniquely Distorted Mn 4+ Octahedron in the Feldspar‐Type LED Phosphor47Simultaneous realization of tunable luminescence and enhanced thermal stability in Eu2+-based blue-green phosphors for multifunctional applications16Structure and photoluminescence studies of Rb3GdSi2O7: Eu2+ phosphor used for NUV converted white LEDs10Crystal structure and luminescence characterizations of Eu3+-doped Sr2GaTaO6 phosphors with high color purity for w-LEDs7Luminescence Performance of Mn4+ Activated BaLa2Al2O7 Phosphors2Crystal Structures and Luminescence Properties of RE6Si11N20O:Ce3+ (RE = Lu, Y)1A novel broad-band red K2MgSiO4:Eu2+ phosphor and defect-induced tunable emission from red to yellow20A novel red BaLaInO4: Eu3+ phosphor for WLEDs32Synthesis, spectral characteristics and energy transfer of SrLa2Al2O7:Mn4+, Dy3+31Fluorescence properties and thermal stability of Sr2Gd1-xNbO6: xEu3+ with dual-wavelength excitation response5Anomalous thermal quenching behavior of novel orange-red SrLa1-xNaTeO6:xSm3+ phosphors for optical temperature sensing8Novel Sm3+ doped YCa4O(BO3)3 phosphors: Structural and, low and room temperature luminescent insights30Anomalous 5D0→7F4 Transition of Eu3+‐Doped BaLaGaO4 Phosphors for WLEDs and Plant Growth Applications95Energy transfer and optical properties of NaLaMgWO6:Dy3+, Tb3+ phosphors9Fluorination strategy toward chemical and functional modification65Temperature/electric field induced photoluminescence-modulation effect in dysprosium-doped barium titanate ferroelectric ceramics16Achieving high sensing sensitivity in a Dy 3+ doped garnet phosphor toward optical thermometry32Achieving white emission by site-selective occupation of Eu 2+ in K 2 BaSr(PO 4 ) 2− x (BO 3 ) x :Eu 2+12Effect of phase structure on the photoluminescence properties of Er 3+ -doped CaWO 4 mineral materials7Photochromic apatite skeletal structure materials: recent advances and potential applications14Charge compensation effect of alkali metal ions on luminescence enhancement and negative thermal quenching of Sr1-xLaNaTeO6:xEu3+ red phosphors18Thermally-stable and color-tunable novel single phase phosphor Ca2GaTaO6:Dy3+, Sm3+ for indoor lighting applications49Dy3+ → Eu3+ energy transfer induced tunable luminescence in disordered La3Ga5SiO14:Dy3+/Eu3+ phosphors7Multicolor regulation of trivalent lanthanide ions-codoped boggildite-type phosphor toward superb warm white luminescence for white light-emitting diodes13Upconversion Luminescence Properties and Temperature Sensing Characteristics of Tm3+, Yb3+-codoped SrAl2Si2O8 Phosphors with High Thermometric Sensitivities5Broadband Green-Yellow KGaSi2O6:Eu2+ Phosphor with Excellent Thermal Stability for Near Ultraviolet-Pumped White-Light-Emitting Diodes1Highly efficient broadband near-infrared-emitting (Sr,Ba)3ZnTa2O9:Cr3+ phosphors based on crystal-field engineering toward veins imaging and night vision applications16Mn-Doped Ca14Mg4Ga12O36 with the Tululite Mineral Structure for Color-Tunable Emission14Realizing golden ultraviolet C emission of 265 nm by oxygen vacancies engineering for 100 % sterilization efficiency13Novel single phase warm white-emitting phosphor BaLaGaO4:Dy3+,Sm3+ with high thermal stability and color stability26A novel highly thermal-stable Ca2GaNbO6: Sm3+ phosphor with excellent color purity for high CRI wLEDs and security ink51Crystal Field Engineering Inducing Transformation from Narrow Band of Eu3+ to Broadband of Eu2+2Broadband NIR‐II Emission Generated by Tetrahedral Cr3+/Cr4+ in SrLaGa3O724Synthesis and tunable luminescence of BaLaGa3O7:Bi3+/Eu3+ phosphors1Mn2+ activated Boroaluminosilicate glass-ceramics with Al4B2O9 nanocrystals for tunable Emission1Accelerating Materials Discovery of Novel Europium(II)-Activated Phosphors through Machine Learning Classification of Europium Valences11Oxide phosphors1Sr 8 MgSc(PO 4 ) 7 :Eu 2+ phosphor: d–f transition driven applications for solid-state lighting and extreme environment multimode sensing investigations18Electronic structure analysis, a large Stokes shift of Bi 3+ in BiSr 3 (YO) 3 (BO 3 ) 4 and color-tunable emissions by energy transfer to Eu 3+ dopants0Emerging perovskite photochromic materials: recent advances, mechanisms, and applications8Multiple Applications of Sr8znin(1- M )Lu M (Po4)7:Eu2+/Mn2+ Through Thermal Stability Adjustment, Spectral Tuning, and Resonance Energy Transfer1Innovations in phosphate phosphors: Bridging structure-property gaps for enhanced luminescence27365 nm UV light excitable broadband cyan-blue emitting KSrScSi2O7: xCe3+ phosphor and its application in high color rendering pc-WLED7Multiple optical thermometry and dynamic anti‐counterfeiting based on multicolor emission in Y 2 GaSbO 7 :Bi 3+ ,Er 3+ phosphor9Ca3Lu2Si3O12:Ce3+, Tb3+: A dual-emitting garnet phosphor with high efficiency and thermo-sensitive for WLED and optical thermometer17Ca9-zMzCsLu0.667(PO4)7:Eu2+ (M = Mg2+, Sr2+): β-Ca3(PO4)2-based LED phosphors with improved thermal stability and standard white light3Ultrabroadband (Vis‐NIR) Emission in Single‐Component Perovskite LEDs via Tailored Multi‐Exciton Energy Transfer Pathways26Multiple applications of Sr8ZnIn(1-)Lu (PO4)7:Eu2+/Mn2+ through thermal stability adjustment, spectral tuning, and resonance energy transfer5Luminescence properties of multi-site Eu2+ emission in Ca9MgNa(PO4)7 phosphors with cation substitution5Structural regulation and optical characteristics of Ca8.95Al1-Gd (PO4)7:0.05Ce3+ phosphor through crystal lattice engineering0Develop Superior Green‐Emitting K‐Rich Eu 2+ ‐Activated Nepheline Phosphors for n‐UV‐Driven Pc‐WLEDs1The Synthesis and Photoluminescence Properties of Novel Sr 8 (Al 12 O 24 )(WO 4 ) 2 : Eu 2+ Green‐Emitting Phosphors for White LEDs0Research progress on feldspar-based phosphors: structural design, luminescence properties, and emerging applications4A novel single phase multifunctional Sr8ZnIn0.6Sc0.4(PO4)7: Eu2+/Mn2+ phosphor with good thermal stability for optical thermometers, fingerprint detection and WLEDs applications8Preparation and application of high stability yellow CDs fluorescence conversion materials for marine lighting0Orange-red emission in BaSc2O4:Sm3+ toward near-ultraviolet-LED-driven white lighting with high color rendering index0Efficient and thermal stable broadband near-infrared emitting Gd2CaAl3GaZrO12:Cr3+ garnet phosphor: structure, luminescence, and pc-LED application9Preparation and photoluminescence of high-monochromaticity green-emitting Ca9Tb(PO4)5(SiO4)F2:Ce3+ phosphor with high quantum efficiency and excellent thermal stability for WLEDs application1Composition-based machine learning for predicting and designing Mn 4+ -doped phosphors3Enhanced broadband near-infrared emission based on cation substitution in Cr3+ ion doped YGdScSbO7 phosphor0Crystal structure and photophysical analysis of red emitting Eu3+ doped vanadate based nanomaterials for innovative optoelectronic devices and latent fingerprinting applications2Novel thermally-stable Sr2AlTaO6: Sm3+ phosphors: synthesis, optical properties and applications in WLEDs and anti-counterfeiting1Tungstate Multifunctional Photochromic Material for Unlimited Optical Information Storage: Using Alkaline Earth Metal Ions to Regulate Photochromic Effect2Broadband‐Emitting NaGdSiO 4 :Eu 2+/3+ Phosphor for White Light‐Emitting Diodes0Regulating cyan luminescence in Ca9ZnK(PO4)7: Eu2+ phosphors through Ca/Sr solid solution toward full-spectrum WLEDs0Recent Progress in Lanthanide-Activated Halo-Phosphors for White Light-Emitting Diodes and Photovoltaic Efficiency Enhancement: A Comprehensive Review0Boosting nUV/blue emission of Ba3Sc(BO3)3:Ce3+ via Mg2+ induced charge compensation and site redistribution0

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    Chemical Engineering Journal · 2022-01-14

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  40. Temperature-Responsive Photoluminescence and Elastic Properties of 1D Lead Halide Perovskites R- and S-(Methylbenzylamine)PbBr3

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  42. Near-UV excited green-emission enhancement by efficient energy transfer in Na1.8Mg0.9Si1.1O4:Ce3+,Tb3+ phosphor for solid-state lighting applications

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  43. Simultaneous Spectral Tuning and Thermal Stability Adjustment in Ca8ZnGa(1–x)Lax(PO4)7:Eu2+ Phosphors

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  44. Eu2+ Doping Concentration-Induced Site-Selective Occupation and Photoluminescence Tuning in KSrScSi2O7:Eu2+ Phosphor

    ACS Materials Au · 2022-02-24

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  45. Effect of ionic couple substitution on the enhanced photoluminescence properties of (BaMg)1-x(KxAl10+x)O17:Eu2+ phosphor for white LEDs application

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  46. Intense Luminescence and Good Thermal Stability in a Mn2+-Activated Mg-Based Phosphor with Self-Reduction

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  47. Recent research progress of luminescent materials with apatite structure: A review

    Open Ceramics · 2022-04-15

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  48. Challenges and Strategies to Design Phosphors for Future White Light Emitting Diodes

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  49. Activators lattice migration strategy customized for tunable luminescence of Ce3+ doped β-Ca3(PO4)2

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  50. Investigation on Ba2(Y1-x, Lux)5B5O17: y at.% Bi as a new type of N-UV excited high efficient blue phosphor for wLED

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