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RESEARCH PAPER · Angewandte Chemie International Edition · 2021

Simultaneous Broadening and Enhancement of Cr 3+ Photoluminescence in LiIn 2 SbO 6 by Chemical Unit Cosubstitution: Night‐Vision and Near‐Infrared Spectroscopy Detection Applications

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Simultaneous Broadening and Enhancement of Cr 3+ Photoluminescence in LiIn 2 SbO 6 by Chemical Unit Cosubstitution: Night‐Vision and Near‐Infrared Spectroscopy Detection ApplicationsOriginalCr 3+ -activated Na 3 X 2 Li 3 F 12 (X = Al, Ga, or In) garnet phosphors with broadband NIR emission and high luminescence efficiency for potential biomedical application124Broadband Short-Wave Infrared Light-Emitting Diodes Based on Cr 3+ -Doped LiScGeO 4 Phosphor147A highly efficient and suitable spectral profile Cr3+-doped garnet near-infrared emitting phosphor for regulating photomorphogenesis of plants278Improved thermal stability of the near‐infrared Al‐modulated Zn 3 Ga 2 GeO 8 : Cr 3+ phosphors for plant growth applications36Chromium Ion Pair Luminescence: A Strategy in Broadband Near-Infrared Light-Emitting Diode Design283Spectrally tunable and thermally stable near-infrared luminescence in Na 3 Sc 2 (PO 4 ) 3 :Cr 3+ phosphors by Ga 3+ co-doping for light-emitting diodes62Two Selective Sites Control of Cr3+‐Doped ABO4 Phosphors for Tuning Ultra‐Broadband Near‐Infrared Photoluminescence and Multi‐Applications124Efficient Ultra‐Broadband Ga 4 GeO 8 :Cr 3+ Phosphors with Tunable Peak Wavelengths from 835 to 980 nm for NIR pc‐LED Application134A new broadband near-infrared emitting Mg 2 Al 4 Si 5 O 18 :Cr 3+ phosphor for night-vision imaging29A novel near-infrared phosphor Mg 2 InSbO 6 :Cr 3+ with high quantum efficiency and considerable persistent luminescence duration29Achievement of high efficiency and thermally stable near-infrared phosphors by designing a chromium crystallographic environment for nondestructive testing and night vision15Broadband near-infrared luminescence from Fe 3+ -activated NaScSi 2 O 6 phosphors for luminescence thermometry and night-vision applications70Chemical unit co-substitution enabling broadband and tunable near-infrared emission in garnet-type Lu3Sc2Ga3O12:Cr3+ phosphors22Efficient broadband near-infrared emission induced by Nb 5+ substitution for Ta 5+ in GaTa 1− y Nb y O 4 :Cr 3+ phosphor50Efficient Cr 3+ -activated NaInP 2 O 7 phosphor for broadband near-infrared LED applications21Highly efficient and thermally stable broadband near-infrared emitting fluoride Cs 2 KGaF 6 :Cr 3+ for multiple LED applications33Investigation on the Luminescent Property and Application of In2BP3O12:Cr3+ Broadband Near-Infrared Phosphor※8Locally-ordered A-site vacancy assisted photoluminescence enhancement in simply rare-earth doped perovskite oxide13Luminescence properties and energy transfer of the near-infrared phosphor Ca 3 In 2 Ge 3 O 12 :Cr 3+ ,Nd 3+16Manipulating trap distribution and density by chemical unit cosubstitution for near-infrared persistent luminescent Zn 1−2 x Li x Ga 2+ x O 4 :Cr 3+ solid solutions22A broadband near‐infrared Sc 1 − x (PO 3 ) 3 : X Cr 3+ phosphor with enhanced thermal stability and quantum yield by Yb 3+ codoping28How to Obtain Anti‐Thermal‐Quenching Inorganic Luminescent Materials for Light‐Emitting Diode Applications252Structural Rigidity Control toward Cr3+-Based Broadband Near-Infrared Luminescence with Enhanced Thermal Stability243Glass‐Crystallized Luminescence Translucent Ceramics toward High‐Performance Broadband NIR LEDs120Novel broadband near-infrared emitting phosphor LiGe2(PO4)3:Cr3+ with tuning and enhancement of NIR emission by codoping Sb5+49Ultra-Broadband and high efficiency Near-Infrared Gd3Zn Ga5-2Ge O12:Cr3+ (x = 0–2.0) garnet phosphors via crystal field engineering222Nanochemistry advancing photon conversion in rare-earth nanostructures for theranostics127Broadband near-infrared emitting Sr3Sc4O9: Cr3+ phosphors: Luminescence properties and application in light-emitting diodes46Design of a Novel Near-Infrared Luminescence Material Li2Mg3TiO6:Cr3+ with an Ultrawide Tuning Range Applied to Near-Infrared Light-Emitting Diodes111Chromium(III)-Doped Phosphors of High-Efficiency Two-Site Occupation Broadband Infrared Emission for Vessel Visualization Applications32Spectral engineering and thermometric performance of LiIn(Si2-Ge )O6: Cr3+ phosphor for multi-mode NIR thermometry26NIR emission spectral engineering in NaSc(Si,Ge)2O6: Cr3+ solid-solution phosphors via crystal field regulation24Cr3+/Yb3+/Nd3+-doped Ba2LaGa11O20 broadband NIR phosphors for NIR pc-LED and c-Si solar cells10Highly Efficient and Stable Near‐Infrared Broadband Garnet Phosphor for Multifunctional Phosphor‐Converted Light‐Emitting Diodes118Rapid Nondestructive Detection Enabled by an Ultra‐Broadband NIR pc‐LED137Highly efficient Fe3+-doped A2BB′O6 (A = Sr2+, Ca2+; B, B′ = In3+, Sb5+, Sn4+) broadband near-infrared-emitting phosphors for spectroscopic analysis251Broadband Near-Infrared-Emitting Phosphors with Suppressed Concentration Quenching in a Two-Dimensional Structure47Blue LED‐Pumped Broadband Short‐Wave Infrared Emitter Based on LiMgPO4:Cr3+,Ni2+ Phosphor97Enhancement of Near‐Infrared Phosphor Luminescence Properties via Construction of Stable and Compact Energy Transfer Paths54A super stable Near-Infrared garnet phosphor resistant to thermal Quenching, thermal degradation and hydrolysis57Interstitial Li + Occupancy Enabling Radiative/Nonradiative Transition Control toward Highly Efficient Cr 3+ -Based Near-Infrared Luminescence83Near-Infrared Broadband ZnTa2O6:Cr3+ Phosphor for pc-LEDs and Its Application to Nondestructive Testing64Ultra‐Wide Vis–NIR Mg2Al4Si5O18:Eu2+,Cr3+ Phosphor Containing Unusual NIR Luminescence Induced by Cr3+ Occupying Tetrahedral Coordination for Hyperspectral Imaging66Advances in Chromium‐Activated Phosphors for Near‐Infrared Light Sources489Ultra-broadband near-infrared phosphor Li3Sc2(PO4)3:Cr3+ realized by two-sites occupation36Broadband near-infrared luminescence in the NaAlP2O7:Cr3+ phosphor for spectroscopy applications19Enhanced Thermal Stability and Energy Transfer by Crystal‐Field Engineering in a Garnet Phosphor for Thermometry and NIR‐LED48Ultra‐Broadband Green‐Emitting Phosphors without Cyan Gap Based on Double‐Heterovalent Substitution Strategy for Full‐Spectrum WLED Lighting89Two-stage ultra-broadband luminescence of Cr3+-doped multisite layered phosphor Sr3Ga2Ge4O14 and its application in pc-LEDs33Dopant and compositional modulation triggered long-wavelength ultra-broadband and tunable NIR emission in MgO: Cr3+ phosphor for NIR spectroscopy applications53Highly Efficient Broadband Near-Infrared Luminescence with Zero-Thermal-Quenching in Garnet Y3In2Ga3O12:Cr3+ Phosphors185Basal Planes Unlocking and Interlayer Engineering Endows Proton Doped-MoO2.8F0.2 with Fast and Stable Magnesium Storage46Multifunctional optical sensing applications of luminescent ions doped perovskite structured LaGaO3 phosphors in near-infrared spectroscopy50Unraveling the Evolution of Luminescence Center in an Eu‐Doped Orthophosphate: Beyond the Probe Limitation to Trace Activator5Ultra-sensitive luminescence ratiometric thermometry from 2 E→ 4 A 2 transitions of AlTaO 4 :Cr 3+8Broadening and enhancing emission of Cr3+ simultaneously by co-doping Yb3+ in Ga1.4In0.6SnO552Ultra-sensitive low-temperature thermometer regulated by the crystal field strength6Producing Tunable Broadband Near-Infrared Emission through Co-Substitution in (Ga1–xMgx)(Ga1–xGex)O3:Cr3+77A novel efficient broadband near-infrared phosphor LiGaGe 2 O 6 :Cr 3+ with EQE enhancement and spectral tuning by Sc 3+ –Ga 3+ substitution for NIR pc-LED application43Site-Selective Occupancy Control of Cr Ions toward Ultrabroad-Band Infrared Luminescence with a Spectral Width up to 419 nm79Site-selective occupation of Cr3+ ions toward ultra-broadband near-infrared emission stannate phosphors23Improvement the near-infrared luminescence properties of double perovskite phosphor La(Mg0.5Sn0.5In0.5Sc0.5)0.5O3:Cr3+ via co-doping Yb3+8A novel extra-broadband visible-NIR phosphor doped with Ce3+ and Cr3+ towards multifunctional advanced applications20Efficient and Thermally Robust Broadband Near‐Infrared Emission in a Garnet Ca 3 MgHfGe 3 O 12 :Cr 3+ Phosphor48Recent Advances in Chromium‐Doped Near‐Infrared Luminescent Materials: Fundamentals, Optimization Strategies, and Applications252Highly efficient and thermally stable broadband NIR phosphors by rationally bridging Cr 3+ –Yb 3+ in LiScGe 2 O 6 for optical bioimaging69Probing Local Structural Changes by Sharp Luminescent Infrared Nanophosphor for Application in Light-Emitting Diodes27[Zn 2+ –Ge 4+ ] co-substitutes [Ga 3+ –Ga 3+ ] to coordinately broaden the near-infrared emission of Cr 3+ in Ga 2 O 3 phosphors17An Efficient Perovskite‐Like Phosphor with Peak Emission Wavelength at 850 nm for High‐Performance NIR LEDs43Simultaneous Absorption and Near‐Infrared Emission Enhancement of Cr 3+ Ions in MgGa 2 O 4 Spinel Oxide via Anionic F‐Substitution88Super Broadband Near‐Infrared Solid Solution Phosphors with Adjustable Peak Wavelengths from 1165 to 875 nm for NIR Spectroscopy Applications41A broadband near-infrared Cr 3+ -doped phosphor applied to near-infrared light-emitting diodes: enhanced luminescence and thermal stability by annealing20An efficient and thermally stable Cr 3+ -activated Y 2 GdSc 2 Al 2 GaO 12 garnet phosphor for NIR spectroscopy applications14Blue-light-excitable pure and efficient short-wave infrared luminescence via Cr 3+ → Yb 3+ energy transfer in a KYbP 2 O 7 :Cr 3+ phosphor24Cs 2 Ag 0.1 Na 0.9 BiCl 6 :Tm 3+ Double Perovskite: Coprecipitation Preparation and Near-infrared Emission6Electrospinning preparation and high near-infrared temperature sensing performance of one-dimensional Y 2 Ti 2 O 7 :Cr 3+ /Yb 3+ nano wire-embedded-tube structures with low Cr 3+ concentrations12Highly efficient and thermally stable broadband near-infrared emitting garnet Ca 3 Sc 2 Ge 3 O 12 :Cr 3+ ,Ce 3+ phosphors for multiple pc-LED applications33Improving and broadening luminescence in Gd 2− x Al x GaSbO 7 :Cr 3+ phosphors for NIR LED applications76Modulation of Bi 3+ luminescence from broadband green to broadband deep red in Lu 2 WO 6 by Gd 3+ doping and its applications in high color rendering index white LED and near-infrared LED18Quantifying rigidity for thermally stable Cr 3+ phosphors9Ultra-broadening near-infrared emission of Cr 3+ -activated pyroxene phosphors via chemical unit substitution and Yb 3+ co-doping17Understanding the broadband near-infrared luminescence in a highly distorted garnet Ca 4 HfGe 3 O 12 :Cr 3+ phosphor36LaMgGa11O19:Cr3+,Ni2+ as Blue‐Light Excitable Near‐Infrared Luminescent Materials with Ultra‐Wide Emission and High External Quantum Efficiency111Manipulation of the ratio of Li + /Zn 2+ on the structure and persistent luminescence property of Li 2 Zn 0.9992 Ge 3 O 8 :0.08%Cr 3+5Near-Infrared Emission Material with Superlong Afterglow Performance and Its Multifunctional Applications22Energy transfer realizes efficient NIR emitting Ca2ScTaO6:Cr3+, Yb3+ perovskite-structured phosphors39Energy Conversion and Transfer in the Luminescence of CeSc3(BO3)4:Cr3+ Phosphor6Ion Substitution Strategy toward High-Efficiency Near-Infrared Photoluminescence of Cs2KIn1–yAlyF6:Cr3+ Solid Solutions54Versatile Ca 2 LnSbO 6 :Eu 3+ /Mn 4+ (Ln = La, Y, Gd, and Lu) phosphors for temperature sensing and plant growth LED19Wide‐coverage and Efficient NIR Emission from Single‐component Nanophosphors through Shaping Multiple Metal‐halide Packages63Wide‐coverage and Efficient NIR Emission from Single‐component Nanophosphors through Shaping Multiple Metal‐halide Packages9Facile Synthesis of Highly Efficient and Thermally Stable BaAl 4 Sb 2 O 12 :Eu 2+ Phosphor in Air72Achieving High Quantum Efficiency Broadband NIR Mg4Ta2O9:Cr3+ Phosphor Through Lithium‐Ion Compensation189Simultaneous Luminescence Color Tuning and Spectral Broadening of Cr3+ Near-Infrared Emission for Night Vision Application28Enhanced and Broadened NIR Emission of CaZnGe2O6:Cr3+ by Yb3+ Codoping for NIR Applications11Near-Infrared Photoluminescence from Ytterbium- and Erbium-Codoped CsPbCl3 Perovskite Quantum Dots with Negative Thermal Quenching26Ab Initio Site‐Selective Occupancy and Luminescence Enhancement in Broadband NIR Emitting Phosphor Mg 7 Ga 2 GeO 12 :Cr 3+150Introducing Jahn-Teller distortion to enhance the practicability of (Ga,Sc)2O3:Cr3+ near-infrared phosphor18Luminescence enhancement of Cr3+ doped garnet phosphor for high-performance LED towards smart NIR light source47Chromium doped broad-band near-infrared emission Mg4Ta2O9: Cr3+ phosphor excited by blue light for NIR-LEDs19Developing Broadband Cr3+-Substituted Phosphor-Converted Near-Infrared Light Sources38Cr3+-Doped NIR Phosphor with Well-Defined Stokes/Anti-Stokes Phonon Sidebands for a Ratiometric Thermometer and Thermally Stable NIR LEDs53Cr3+ doped CaF2 transparent ceramic with effective broadband near-infrared emission9Synthesis and luminescent properties of ZnWO4: Cr3+ nanoparticles for NIR-II fluorescence imaging14Bimodal role of Cr3+ ions: the nanoscaled photothermal agent and luminescence thermometry6Adjustment of Bi 3+ Luminescence and Thermal Quenching Properties by B′-Site Ion Substitution Strategy in Double Perovskite CaLaMgSb/TaO 6 :Bi 3+ Phosphor33Photoluminescent polymer‐based smart window reinforced with electrospun glass nanofibres17Enhancing Infrared Photoluminescence Performance via Li+ Substitution and Yb3+ Codoping in Na3ScSi3O9:Cr3+ Phosphor5Broad Dual Emission by Codoping Cr 3+ ( d → d ) and Bi 3+ ( s → p ) in Cs 2 Ag 0.6 Na 0.4 InCl 6 Double Perovskite24Broad Dual Emission by Codoping Cr 3+ (d→d) and Bi 3+ (s→p) in Cs 2 Ag 0.6 Na 0.4 InCl 6 Double Perovskite112Broad-Band Sensitization in Cr3+–Er3+ Co-Doped Cs2AgInCl6 Double Perovskites with 1.5 μm Near-Infrared Emission88A broadband near-infrared nanoemitter powered by mechanical action110Thermally stable near-infrared emission from a double perovskite K2LiScF6:Cr3+ phosphor for light-emitting diodes31Bifunctional near-infrared-emitting phosphors of chromium (III)-activated antimonates for NIR light-emitting diodes and low-temperature thermometry30Creating an efficient and tunable near-infrared emission by using [Mg2+-Sn4+] chemical unit co-substitution in Ga2O3:Cr3+ phosphor7Multiple defects induced near-infrared self-luminescence of (Ca,Sr)LaMgTaO6 double perovskite phosphor29Achieving Ultra-Wideband NIR-II Emission in Cr3+-Doped Li(Sc,In)(Si,Ge)O4 Phosphors Based on Host Composition Engineering35Efficient trivalent chromium ions doped ZnLu2Al4SiO12 garnet phosphor: Crystal structure, optical properties and application15Bandwidth-based flexible optical fiber thermometry based on sharp line emission regulation of Cr3+ ions34Efficient CrIII Ion Governed Energy Migration for Broadband Near‐Infrared Emission in Ca3Sc2Ge3O12 Garnet Phosphor7Six‐ and five‐coordinated Cr 3+ in Ga 2 GeO 5 invokes tunable broadband near‐infrared emission toward night‐vision applications61How to Achieve Excellent Luminescence Properties of Cr Ion‐Doped Near‐Infrared Phosphors103Wide near-infrared II emissions and LED application of Y2Ti2O7: Cr3+/Yb3+/Nd3+ phosphors5High‐Performance NIR Emission in Chromium‐Doped Garnet Phosphors Enabled by Structure and Excitation Regulation67An ultra broadband NIR phosphor LiScSnO4:Cr3+ with emission wavelength peaking at 900 nm for component analysis14Efficient and ultra-broadband near-infrared emission in perovskite-like Mg4Sb2O9:Cr3+ phosphor5Crystal structure, morphology and enhancement of luminescence properties of Cr3+-doped KZnF3 phosphor by using a HF-free hydrothermal method with different chromium sources3High Output Power and High Quantum Efficiency in Novel NIR Phosphor MgAlGa0.7B0.3O4:Cr3+ with Profound FWHM Variation143A novel self-activated near-infrared luminescence of BaLaMgTaO6 phosphor13Effect of ZrO2 and TiO2 on the micro-structure and NIR luminescence of mullite type Cr:Al4B2O9 glass ceramics12Broadband emitting Fe 3+ ‐doped double perovskite‐type antimonates phosphors for NIR spectroscopy applications28Cooperative cationic substitution strategy triggers high blue-light absorptance and near-infrared emission with high quantum efficiency in Cr3+-activated pyroxene-type assembly11Near‐Infrared Nanophosphors Based on CuInSe2 Quantum Dots with Near‐Unity Photoluminescence Quantum Yield for Micro‐LEDs Applications47Chromium Cluster Luminescence: Advancing Near‐Infrared Light‐Emitting Diode Design for Next‐Generation Broadband Compact Light Sources64From Ancient Blue Pigment to Unconventional NIR Phosphor: A Thermal-Stable Near-Infrared I/II Broadband Emission from Ca1–xSrxCuSi4O10 Solid Solution9Tailoring Fe3+‐Activated Broadband NIR Phosphors: Enhancing External Quantum Efficiency and Spectrum Adjustability Through Crystal Field Engineering in Double Perovskite Antimonate Structures46Engineering deep-red Al20B4O36:Cr3+ phosphors for photomorphogenesis9Compositional modulation induced broadband NIR luminescence enhancement in A2ScNbO6:Cr3+ (A = Ba, Sr)12Small Stokes Shift and Two‐Site Occupation in the ANb2O6:Cr3+ (A = Zn/Mg) Phosphors Toward Highly Efficient Ultra‐Broadband Near‐Infrared Emission for Multifunctional Applications24Achieving the performance luminescence of LaMg0.5Sn0.5O3:Cr3+ by [In3+-Sc3+] co-substitution [Mg2+-Sn4+] and its application to the biodetection and night vision lighting4A broadband near-infrared emission Na 3 Al 2 (PO 4 ) 2 F 3 :Cr 3+ phosphor exhibiting zero photoluminescence quenching at 398 K17A Ca 3 Sc 2 Si 3 O 12 :Ce 3+ ,Cr 3+ ,Li + phosphor-in-glass film for high-power laser-driven near-infrared lighting17Achieving broadband near-infrared emission with superior anti-thermal quenching by optimizing the excited-state population of Cr 3+ in Gd 3 ScGa 4 O 12 garnet phosphors107Broadband short-wave infrared Mg 4 Nb 2 O 9 :Cr 3+ ,Li + phosphor for nondestructive safety detection and biomedical imaging17Broadband short-wave near-infrared-emitting phosphor MgNb 2 O 6 :Cr 3+ for pc -LED applications9Efficient and Thermally Stable Cr3+-Doped Phosphor Achieved by Cation Substitution: Plant Lighting Application3Improvement of thermal stability and luminescence in La 3 Zr x Sn 1− x Ga 5 O 14 :0.015Cr 3+ by the substitution of Zr # Sn and its application in level detection, biomedical imaging and night vision monitoring0Ions Co-Substitution Strategy Toward Tunable Broadband Near-Infrared Luminescence from Cr3+ Doped Gallium Oxide Based Phosphors0Long-wavelength near-infrared light emitting Ni 2+ -doped double perovskite molybdate-based solid-solution phosphors43Near-infrared Cr 3+ -doped lead-free halide perovskite microcrystals for information encryption and temperature thermometry34

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