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RESEARCH PAPER · Inorganic Chemistry · 2020

Structural Diversity in Layered Hybrid Perovskites, A2PbBr4 or AA′PbBr4, Templated by Small Disc-Shaped Amines

Yuanyuan Guo, Lin-Jie Yang, Simon Biberger, Jason A. McNulty, Teng Li, Konstantin Schötz, Fabian Panzer, Philip Lightfoot

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Structural Diversity in Layered Hybrid Perovskites, A2PbBr4 or AA′PbBr4, Templated by Small Disc-Shaped AminesOriginalStructural variations in (001)-oriented layered lead halide perovskites, templated by 1,2,4-triazolium16Variable dimensionality in ‘hollow’ hybrid tin iodide perovskites10The 2D Halide Perovskite Rulebook: How the Spacer Influences Everything from the Structure to Optoelectronic Device Efficiency1085Mixed Solvothermal Synthesis of Tn Cluster-Based Indium and Gallium Sulfides Using Versatile Ammonia or Amine Structure-Directing Agents20Layered Double Perovskites75Shedding Light on the Stability and Structure–Property Relationships of Two-Dimensional Hybrid Lead Bromide Perovskites51Structural chemistry of layered lead halide perovskites containing single octahedral layers59New Variants of (110)‐Oriented Layered Lead Bromide Perovskites, Templated by Formamidinium or Pyrazolium11Structural diversity in hybrid lead halides templated by 4-methylimidazolium16“Breathing” organic cation to stabilize multiple structures in low-dimensional Ge-, Sn-, and Pb-based hybrid iodide perovskites10Perovskite-derived structure modulation in the iron sulfate family0Reliably obtaining white light from layered halide perovskites at room temperature26Polar Ferromagnet Induced by Fluorine Positioning in Isomeric Layered Copper Halide Perovskites20Polarity and Ferromagnetism in Two-Dimensional Hybrid Copper Perovskites with Chlorinated Aromatic Spacers48Synthesis and Characterization of (FA)3(HEA)2Pb3I11: A Rare Example of <1 1 0>-Oriented Multilayered Halide Perovskites5Ordered Mixed-Spacer 2D Bromide Perovskites and the Dual Role of 1,2,4-Triazolium Cation38Thermal Enhanced Resistive Switching Performance of <100>‐oriented Perovskite [(TZ‐H) 2 (PbBr 4 )] n with High Working Temperature: a Triazolium/(PbBr 4 ) n 2 n – Interfacial Interaction Insight19Structural Descriptors to Correlate Pb Ion Displacement and Broadband Emission in 2D Halide Perovskites121Short Aromatic Diammonium Ions Modulate Distortions in 2D Lead Bromide Perovskites for Tunable White-Light Emission32Acetamidinium bromoplumbate CH3C ( NH2 ) 2PbBr3 with 4H BaRuO3 structure5Broadband yellow and white emission from large octahedral tilting in (110)-oriented layered perovskites: imidazolium-methylhydrazinium lead halides24Fluorescence Emission Is Highly Structure-Dependent in Hybrid Lead Halides11Design Rules for Obtaining Narrow Luminescence from Semiconductors Made in Solution87Distinct Excitonic Emissions in 2D (C7H7N2)2PbX4 (X = Cl, Br) under Compression11Layered methylhydrazinium lead halide perovskites: new crystal polymorphs with a tailored band gap and photoluminescence colour via halide substitution3Pressure-induced giant emission enhancement, large band gap narrowing and rich polymorphism in two-dimensional 1,2,4-triazolium lead bromide perovskite12Phase Transitions and Dynamics in Mixed Three- and Low-Dimensional Lead Halide Perovskites134Temperature- and Pressure-Dependent Raman and Photoluminescence Studies of Corrugated Imidazolium-Methylhydrazinium Lead Bromide12Formamidine intercalation to broaden photoresponsive range in alternating-cations-interlayered hybrid perovskite2Ferroelectric polarization in 2D halide hybrid perovskites: influence on bulk crystals, thin films, and applications17Insight into the mechanisms of phase transitions in imidazolium lead bromides with varying dimensionality: A comparative vibrational study2Advancing intercalation strategies in layered hybrid perovskites by bringing together synthesis and simulations3Local Symmetry Breaking and Hidden Spin Polarization in 2D Hybrid Perovskites with Nonprimary Ammonium Cations14Impact of Lattice Heterogeneity on Broadband Optical Retardation in Stacked 2D Perovskite Single Crystals1Pressure-Induced Detrapping from Self-Trapped Excitons to Free Excitons toward Enhanced Emission and Piezochromism in Ruddlesden–Popper (110)-Oriented Perovskites6Crystal structure and properties of acetamidinium lead bromide: a new member of the A 3 PbBr 5 halide family2Rare 3 × 3 Layering in High‐Pressure Pseudo‐Perovskite Sr 4 Te 4 O 150Activation Energy of Self-Trapped Excitons in Ruddlesden–Popper ACE2PbBr4 Perovskite under Hydrostatic Pressure0Low-Dimensional Perovskites and Metal Halides across Structures and Functions: Connectivity, Dimensionality, and Emerging Principles1

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  1. Structural variations in (001)-oriented layered lead halide perovskites, templated by 1,2,4-triazolium

    Dalton Transactions · 2020-01-01

    Yuanyuan Guo, Lin-Jie Yang, Jason A. McNulty, Alexandra M. Z. Slawin, Philip Lightfoot

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  2. Variable dimensionality in ‘hollow’ hybrid tin iodide perovskites

    Dalton Transactions · 2020-01-01

    Jason A. McNulty, Alexandra M. Z. Slawin, Philip Lightfoot

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  3. The 2D Halide Perovskite Rulebook: How the Spacer Influences Everything from the Structure to Optoelectronic Device Efficiency

    Chemical Reviews · 2021-01-21

    Xiaotong Li, Justin M. Hoffman, Mercouri G. Kanatzidis

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  4. Mixed Solvothermal Synthesis of Tn Cluster-Based Indium and Gallium Sulfides Using Versatile Ammonia or Amine Structure-Directing Agents

    Inorganic Chemistry · 2021-04-29

    Meng Sun, Shu Zhang, Kai‐Yao Wang, Juan Wang, Lin Cheng, Jia‐Ying Zhu, Yi‐Ming Zhao, Cheng Wang

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  5. Layered Double Perovskites

    Annual Review of Materials Research · 2021-05-05

    Hayden A. Evans, Lingling Mao, Ram Seshadri, Anthony Kevin Cheetham

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  6. Shedding Light on the Stability and Structure–Property Relationships of Two-Dimensional Hybrid Lead Bromide Perovskites

    Chemistry of Materials · 2021-06-24

    Eugenia S. Vasileiadou, Ido Hadar, Mikaël Képénékian, Jacky Even, Qing Tu, Christos D. Malliakas, Daniel Friedrich, Ioannis Spanopoulos, Justin M. Hoffman, Vinayak P. Dravid, Mercouri G. Kanatzidis

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  7. Structural chemistry of layered lead halide perovskites containing single octahedral layers

    IUCrJ · 2021-06-30

    Jason A. McNulty, Philip Lightfoot

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  8. New Variants of (110)‐Oriented Layered Lead Bromide Perovskites, Templated by Formamidinium or Pyrazolium

    European Journal of Inorganic Chemistry · 2021-07-20

    Yuanyuan Guo, Clement Elliott, Jason A. McNulty, David B. Cordes, Alexandra M. Z. Slawin, Philip Lightfoot

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  9. Structural diversity in hybrid lead halides templated by 4-methylimidazolium

    Journal of Solid State Chemistry · 2021-08-02

    Clement Elliott, Jason A. McNulty, David B. Cordes, Alexandra M. Z. Slawin, Philip Lightfoot

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  10. “Breathing” organic cation to stabilize multiple structures in low-dimensional Ge-, Sn-, and Pb-based hybrid iodide perovskites

    Inorganic Chemistry Frontiers · 2022-01-01

    Congcong Chen, Emily E. Morgan, Yang Liu, Jian Chen, Ram Seshadri, Lingling Mao

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  11. Perovskite-derived structure modulation in the iron sulfate family

    Chemical Communications · 2022-01-01

    Yuanqi Lan, Yan Qi, Xinyuan Zhang, Wenjiao Yao, Chenchen Wang, Chun‐Sing Lee, Philip Lightfoot, Yongbing Tang

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  12. Reliably obtaining white light from layered halide perovskites at room temperature

    Chemical Science · 2022-01-01

    Ethan J. Crace, Alexander C. Su, Hemamala I. Karunadasa

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  13. Polar Ferromagnet Induced by Fluorine Positioning in Isomeric Layered Copper Halide Perovskites

    Inorganic Chemistry · 2022-02-09

    Ceng Han, Jason A. McNulty, Alasdair J. Bradford, Alexandra M. Z. Slawin, Finlay D. Morrison, Stephen Lee, Philip Lightfoot

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  14. Polarity and Ferromagnetism in Two-Dimensional Hybrid Copper Perovskites with Chlorinated Aromatic Spacers

    Chemistry of Materials · 2022-02-21

    Ceng Han, Alasdair J. Bradford, Jason A. McNulty, Weiguo Zhang, P. Shiv Halasyamani, Alexandra M. Z. Slawin, Finlay D. Morrison, Stephen Lee, Philip Lightfoot

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  15. Synthesis and Characterization of (FA)3(HEA)2Pb3I11: A Rare Example of <1 1 0>-Oriented Multilayered Halide Perovskites

    Chemistry of Materials · 2022-06-28

    Maroua Ben Haj Salah, Nicolas Mercier, Magali Allain, Antonin Leblanc, Jens Dittmer, Chiara Botta, Claudio Quarti, Claudine Katan

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  16. Ordered Mixed-Spacer 2D Bromide Perovskites and the Dual Role of 1,2,4-Triazolium Cation

    Chemistry of Materials · 2022-07-12

    Xiaotong Li, Hao Dong, George Volonakis, Constantinos C. Stoumpos, Jacky Even, Claudine Katan, Peijun Guo, Mercouri G. Kanatzidis

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  17. Thermal Enhanced Resistive Switching Performance of <100>‐oriented Perovskite [(TZ‐H) 2 (PbBr 4 )] n with High Working Temperature: a Triazolium/(PbBr 4 ) n 2 n – Interfacial Interaction Insight

    Advanced Electronic Materials · 2022-08-02

    Kaiyue Song, Binjun Chen, Xiaoli Lin, Hailong Yang, Yue Liu, Yuanzheng Liu, Hao‐Hong Li, Zhi‐Rong Chen

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  18. Structural Descriptors to Correlate Pb Ion Displacement and Broadband Emission in 2D Halide Perovskites

    Journal of the American Chemical Society · 2022-10-03

    Xiang‐Bin Han, Chang‐Qing Jing, Hui-Yuan Zu, Wen Zhang

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  19. Short Aromatic Diammonium Ions Modulate Distortions in 2D Lead Bromide Perovskites for Tunable White-Light Emission

    Chemistry of Materials · 2022-10-20

    Ping Fu, Michael A. Quintero, Claire Welton, Xiaotong Li, Bruno Cucco, Michael C. De Siena, Jacky Even, George Volonakis, Mikaël Képénékian, Runze Liu, Craig C. Laing, Vladislav V. Klepov, Yukun Liu, Vinayak P. Dravid, G. N. Manjunatha Reddy, Can Li, Mercouri G. Kanatzidis

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  20. Acetamidinium bromoplumbate CH3C ( NH2 ) 2PbBr3 with 4H BaRuO3 structure

    Bulletin of the Korean Chemical Society · 2022-12-14

    Hyun‐Jong Lee, Eunji Lee, Ji‐Hyun Cha, Duk‐Young Jung

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  21. Broadband yellow and white emission from large octahedral tilting in (110)-oriented layered perovskites: imidazolium-methylhydrazinium lead halides

    Journal of Materials Chemistry C · 2023-01-01

    Dawid Drozdowski, Katarzyna Fedoruk, Adam Kabański, Mirosław Mączka, Adam Sieradzki, Anna Gągor

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  22. Fluorescence Emission Is Highly Structure-Dependent in Hybrid Lead Halides

    Inorganic Chemistry · 2023-05-02

    Qiang‐Qiang Jia, Meng‐Meng Lun, Gele Teri, Liyan Xie, Da‐Wei Fu, Qiang Guo

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  23. Design Rules for Obtaining Narrow Luminescence from Semiconductors Made in Solution

    Chemical Reviews · 2023-06-13

    Hao Nguyen, Grant J. Dixon, Florence Y. Dou, Shaun M. Gallagher, Stephen Gibbs, Dylan M. Ladd, Emanuele Marino, Justin C. Ondry, James P. Shanahan, Eugenia S. Vasileiadou, Stephen H. Barlow, Daniel R. Gamelin, David S. Ginger, David M. Jonas, Mercouri G. Kanatzidis, Seth R. Marder, Daniel Morton, Christopher B. Murray, Jonathan S. Owen, Dmitri V. Talapin, Michael F. Toney, Brandi Michelle Cossairt

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  24. Distinct Excitonic Emissions in 2D (C7H7N2)2PbX4 (X = Cl, Br) under Compression

    Advanced Science · 2023-11-20

    Hai Zhang, Peijie Zhang, Chenlong Xie, Han Jiang, Bin Xu, Zewei Quan

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  25. Layered methylhydrazinium lead halide perovskites: new crystal polymorphs with a tailored band gap and photoluminescence colour via halide substitution

    Journal of Materials Chemistry C · 2024-01-01

    Dawid Drozdowski, Adam Kabański, Dagmara Stefańska, Maciej Ptak, Mirosław Mączka, Anna Gągor

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  26. Pressure-induced giant emission enhancement, large band gap narrowing and rich polymorphism in two-dimensional 1,2,4-triazolium lead bromide perovskite

    RSC Advances · 2024-01-01

    Mirosław Mączka, Filip Dybała, Artur P. Herman, Waldeci Paraguassu, Antonio José Barros dos Santos, R. Kudrawiec

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  27. Phase Transitions and Dynamics in Mixed Three- and Low-Dimensional Lead Halide Perovskites

    Chemical Reviews · 2024-02-29

    Mantas Šimėnas, Anna Gągor, J. Banys, Mirosław Mączka

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  28. Temperature- and Pressure-Dependent Raman and Photoluminescence Studies of Corrugated Imidazolium-Methylhydrazinium Lead Bromide

    The Journal of Physical Chemistry C · 2024-05-20

    Mirosław Mączka, José Avelar S. da Silva, Wagner P. Gomes, Daniel M. L. Vasconcelos, Filip Dybała, Artur P. Herman, R. Kudrawiec, Paulo Freire

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  29. Formamidine intercalation to broaden photoresponsive range in alternating-cations-interlayered hybrid perovskite

    Chinese Chemical Letters · 2024-07-04

    Yaru Geng, Ruiqing Li, Tingting Zhu, Xinling Li, Qianwen Guan, Ye Huang, Peng Wang, Junlin Li, Junhua Luo

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  30. Ferroelectric polarization in 2D halide hybrid perovskites: influence on bulk crystals, thin films, and applications

    Journal of Materials Chemistry C · 2025-01-01

    Raja Sekhar Muddam, Lethy Krishnan Jagadamma

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  31. Insight into the mechanisms of phase transitions in imidazolium lead bromides with varying dimensionality: A comparative vibrational study

    Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy · 2025-05-15

    Szymon Smółka, E. Kucharska, Maciej Ptak

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  32. Advancing intercalation strategies in layered hybrid perovskites by bringing together synthesis and simulations

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  33. Local Symmetry Breaking and Hidden Spin Polarization in 2D Hybrid Perovskites with Nonprimary Ammonium Cations

    Journal of the American Chemical Society · 2025-08-14

    Rayan Chakraborty, David B. Mitzi

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  34. Impact of Lattice Heterogeneity on Broadband Optical Retardation in Stacked 2D Perovskite Single Crystals

    Advanced Functional Materials · 2025-10-07

    Yixuan Dou, Nicholas Nici, Sunhao Liu, Xiaoming Wang, Yanfa Yan, Carla Slebodnick, Li Na Quan

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  35. Pressure-Induced Detrapping from Self-Trapped Excitons to Free Excitons toward Enhanced Emission and Piezochromism in Ruddlesden–Popper (110)-Oriented Perovskites

    ACS Applied Materials & Interfaces · 2025-10-09

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  36. Crystal structure and properties of acetamidinium lead bromide: a new member of the A 3 PbBr 5 halide family

    Dalton Transactions · 2026-01-01

    Huanzhou Wang, Andrey A. Petrov, Andrey Petrov, Mingming Li, Sergey A. Fateev

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  37. Rare 3 × 3 Layering in High‐Pressure Pseudo‐Perovskite Sr 4 Te 4 O 15

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  38. Activation Energy of Self-Trapped Excitons in Ruddlesden–Popper ACE2PbBr4 Perovskite under Hydrostatic Pressure

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  39. Low-Dimensional Perovskites and Metal Halides across Structures and Functions: Connectivity, Dimensionality, and Emerging Principles

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